CN107189621A - A kind of Marine Antifouling Paint and preparation method thereof - Google Patents
A kind of Marine Antifouling Paint and preparation method thereof Download PDFInfo
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- CN107189621A CN107189621A CN201710499307.4A CN201710499307A CN107189621A CN 107189621 A CN107189621 A CN 107189621A CN 201710499307 A CN201710499307 A CN 201710499307A CN 107189621 A CN107189621 A CN 107189621A
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- Prior art keywords
- antifouling paint
- marine antifouling
- dispersant
- mass fraction
- organic solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C09D161/04, C09D161/18 and C09D161/20
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of Marine Antifouling Paint and preparation method thereof, it is made up of by mass fraction following raw material components：20~70wt% of Polybenzoxazine, 1~30wt% of polyamine, 1~20wt% of o-dihydroxy aromatised fraction, 1~15wt% of yittrium oxide, 2~6wt% of modified pitch, 3~9wt% of modified carbon nano-tube, 5~15wt% of Mn ZrC composite granules, 0.1~10wt% of dispersant, 0.1~6wt% of fibre fluff, 5~30wt% of 1~5wt% of chitosan and organic solvent.Coating provided by the present invention is free of any heavy metal material, and salt-fog resistant time is more than 4200 hours, and the wet-heat resisting time is more than 4200 hours, and with excellent mechanical property.
Description
Technical field
The present invention relates to a kind of heavy Marine Antifouling Paint, more particularly to a kind of Marine Antifouling Paint and preparation method thereof.
Background technology
Weight Marine Antifouling Paint refers to for relatively conventional Marine Antifouling Paint, can be answered in relatively harsh corrosive environment
With, and with the class Marine Antifouling Paint of protection period longer than conventional Marine Antifouling Paint can be reached.Weight Marine Antifouling Paint
Main application fields have：1. emerging ocean engineering：Offshore Units, seashore and bay structure, offshore oil platform；2. it is modern to hand over
Logical transport：Freeway guardrail, bridge, ships and light boats, container, train and railway facility, automobile, airport installation；3. energy industry：
Water conservancy project equipment, water pot, petroleum refinement equipment, oil stockpile equipment (oil pipe, oil tank), power transmission and transforming equipment, nuclear power, colliery；4. it is big
Type industrial enterprise：Paper making equipment, medical equipment, food chemistry equipment, canister inside and outside wall, chemical industry, steel, the pipe of petrochemical plant
Road, storage tank, mine smelting, cement plant, the ground for having corrosive medium, wall cement components；5. urban operating mechanism：Gas piping
And its facility (such as gas chamber), natural gas line, drinking-water facility, refuse treatment plant.
Ocean Marine Antifouling Paint refers to the anticorrosive coating used in marine environment.Because marine environment is very harsh
And with severe corrosive, therefore, marine anticorrosion erosion is the middle problem for being badly in need of conscientiously studying of China's ocean engineering hair.
Marine Antifouling Paint conventional on the market above-mentioned at present can not meet demand in newly built construction, frontier,
It is mainly manifested in：For example salt spray resistance is not high, is usually no more than 1000 hours；Comprehensive anticorrosive performance is single, acidproof alkaline error；Sea
Contain plurality of heavy metal (lead, chromium etc.) in foreign anticorrosive paint, the defect such as pollute to human body and to environment.
CN103205181A discloses a kind of nanometer weight Marine Antifouling Paint, and fraction by weight contains following component：Polyphenyl
Bing 20~70wt% of oxazine, 1~30wt% of polyamine, the nano combined 1~20wt% of conductive fiber of polypyrrole base, yittrium oxide 1~
15wt%, 0.1~10wt% of dispersant, 0.1~6wt% of fibre fluff, 5~30wt% of organic solvent.Its coating provided
Without any heavy metal material, and salt-fog resistant time, more than 3000 hours, acid and alkali-resistance is more than 1000 hours, however, using it for
In ocean engineering, it can still be corroded within a short period of time, moreover, its mechanical property is poor, collided intolerant to seawater scouring, sea ice,
Abrasion when ship is stopped etc..
Therefore, the mechanical property of weight Marine Antifouling Paint how is lifted, and ensures that its excellent corrosion resistance turns into mesh
The emphasis of preceding research.
The content of the invention
To solve the deficiencies in the prior art, the invention provides a kind of Marine Antifouling Paint, coating provided by the present invention
Salt-fog resistant time be more than 4200 hours, the wet-heat resisting time is more than 4200 hours, and with excellent mechanical property.
For up to this purpose, present invention employs following technical scheme：
The invention provides a kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：
The mass fraction sum of each component is 100%.
The present invention in Marine Antifouling Paint by increasing o-dihydroxy aromatised fraction and Mn-ZrC composite granules and changing
Property pitch and chitosan, coating can be made to adapt to ocean engineering environment, in addition to excellent antiseptic property, during its salt spray resistance
Between be more than 4200 hours, the wet-heat resisting time be more than 4200 hours, moreover, also have excellent mechanical property, can sea water resistance punching
Abrasion when brush, sea ice collision, ship are stopped etc..
In the Marine Antifouling Paint of the present invention, contain following component by mass fraction：20~70wt% of Polybenzoxazine, example
Such as 22wt%, 25wt%, 28wt%, 33wt%, 36wt%, 40wt%, 43wt%, 48wt%, 54wt%, 59wt%,
63wt%, 66wt%, 69wt% etc., preferably 30~65wt%, more preferably 40~60wt%；1~30wt% of polyamine,
For example, 3wt%, 6wt%, 9wt%, 14wt%, 18wt%, 20wt%, 25wt%, 27wt% etc., preferably 5~25wt%,
More preferably 10~20wt%；O-dihydroxy 1~20wt% of aromatised fraction, for example, 2wt%, 5wt%, 8wt%,
10wt%, 14wt%, 16wt%, 18wt% etc., preferably 3~15wt%, more preferably 5~10wt%；Yittrium oxide 1~
15wt%, for example, 3wt%, 5wt%, 8wt%, 10wt%, 12wt%, 14wt% etc., preferably 3~10wt%, further
Preferably 4~7wt%；2~6wt% of modified pitch, for example, 3wt%, 4wt%, 5wt% etc., preferably 3~5wt%, enter one
Step is preferably 4~5wt%；3~9wt% of modified carbon nano-tube, for example, 4wt%, 5wt%, 6wt%, 7wt%, 8wt% etc.,
Preferably 4~9wt%, more preferably 6~8wt%；Mn-ZrC 5~15wt% of composite granule, for example, 5wt%,
6wt%, 8wt%, 10wt%, 14wt%, 15wt% etc., preferably 8~10wt%, more preferably 8~9wt%；It is scattered
0.1~10wt% of agent, for example, 0.3wt%, 0.6wt%, 1wt%, 3wt%, 6wt%, 8wt% etc., preferably 0.1~
8wt%, more preferably 0.1~6wt%；0.1~6wt% of fibre fluff, for example, 0.3wt%, 0.6wt%,
0.9wt%, 1.5wt%, 2wt%, 3wt%, 3.5wt%, 4.4wt%, 5.2wt%, 5.7wt% etc., preferably 0.1~
5wt%, more preferably 0.1~4wt%；1~5wt% of chitosan, for example, 2wt%, 3wt%, 4wt%, 5wt% etc.,
Preferably 2~5wt%, more preferably 3~5wt%；5~30wt% of organic solvent, for example, 7wt%, 9wt%,
13wt%, 16wt%, 19wt%, 22wt%, 27wt%, 29wt% etc., preferably 5~18wt%, more preferably 7~
15wt%.
As optimal technical scheme, the Marine Antifouling Paint is made up of by mass fraction following raw material components：
The mass fraction sum of each component is 100%.
As further preferred technical scheme, the Marine Antifouling Paint, by weight fraction are made up of following raw material components：
The mass fraction sum of each component is 100%.
As it should be understood by those skilled in the art that the polybenzoxazine is using the common polyphenyl in this area and evil
Piperazine, for example, can be bisphenol A-type benzoxazine, and the present invention does not do particular determination to its concrete structure.
Term " polyamine " refers to the organic compound for including at least two primary amine groups.The example of available polyamine includes having
The polyamine of at least three amino groups, wherein at least one in three amino groups is primary amino radical, and remaining is primary
Amino, secondary amine or combinations thereof.Example includes H2N(CH2CH2NH)1-10H、H2N(CH2CH2CH2CH2NH)1-10H、H2N
(CH2CH2CH2CH2CH2CH2NH) 1-10H and N (CH2CH2NH2)3, and such as aziridine (i.e. aziridine) straight chain or branch
The polyamine of the polymerization of (including dendrimers) homopolymer and copolymer etc changed.Many such compounds can be obtained or derived from one
As chemical supplier, such as Aldrich Chemical company (Milwaukee, WI) (Aldrich Chemical
Company (Milwaukee, Wis.)) or Connecticut State Waterbury Pfaltz＆Bauer companies (Pfaltz and
Bauer,Inc.(Waterbury,Conn))。
The example of o-dihydroxy aryl compound suitable for curable compositions includes but is not limited to be selected from catechol
With substituted catechol those.The example of suitable substituent includes alkyl alkoxy, aryl, halogen and does not influence reaction
Other substituents.Specific example includes methyl catechol, (uncle) butyl catechol, ethylcatechol, isopropyl catechol, fourth
Base catechol, (uncle) butyl catechol, amyl group catechol, (uncle) amyl group catechol, benzyl catechol, phenethyl catechol, benzene
Base catechol, fluoro catechol, chloro catechol, bromo catechol, methoxyl group catechol, ethyoxyl catechol, formoxyl
Tea phenol, pi-allyl catechol, o-dihydroxy naphthalene.Other available o-dihydroxy aryl compounds include 1,2- and 2,3- dihydroxy
Naphthalene and corresponding senior o-dihydroxy aryl compound.
The o-dihydroxy aryl compound may also include oligomer and polymer with o-dihydroxy aromatic yl group.This
Including the thermoplastic phenolic resin derived from catechol, aldehyde such as formaldehyde and optional monohydric phenol.Reference can be made to United States Patent (USP) 5,
559,513 (Kirk et al.), the document is hereby incorporated herein by.
In the present invention, the modifying agent of the modified pitch is maleic anhydride.
In the present invention, the organic solvent is benzene kind solvent.
In the present invention, described organic solvent is benzene, toluene or dimethylbenzene, or its mixture, preferably dimethylbenzene.
In the present invention, it is 3 in mass ratio by Mo powders, ZrC powders that the Mn-ZrC composite granules, which are,:(1~2) passes through machine
The realization of tool ball-milling method is uniformly mixed and prepared, wherein, the particle diameter of the Mo powders is 50~100 μm, and purity is more than
95wt%；The particle diameter of ZrC powders is 10~100 μm, and purity is more than 95wt%.
Yittrium oxide particle diameter very little, superficial attractive forces are strong, and surface can be big, chemical purity height, good dispersive property, thermal resistance, resistance
In terms of there is special performance, and with superior stability, reinforcing, thickening property and thixotropy.Yittrium oxide has three
Network structure is tieed up, possesses huge specific surface area, shows great activity, network structure can be formed when coating is dried, together
When add the intensity and finish of coating, and improve the suspension of pigment, the color of coating can be kept not fade for a long time.
Scattered, the electro-wetting principle of dispersant in Marine Antifouling Paint, one be dispersant adsorption in powder particles, by cohesion
Powder particles are moistened；Two be that macromolecule dispersing agent is adsorbed on powder particles surface, increase pigment and the interparticle surface of inserts
Electric charge, improves interparticle electrostatic repulsion, and effectively increases interparticle steric hindrance, makes powder particles stabilization in liquid
It is dispersed into possibility.Divided according to molecular structure, dispersant is generally divided into two major classes：Inorganic dispersant and organic dispersing agent.Nothing
It is in the majority with polyphosphoric acid salt in machine dispersant, such as calgon, PTPP, sodium polyphosphate and tetrapotassium pyrophosphate.Its
The mechanism of effect is, by hydrogen bond and chemisorbed, to play electrostatic repulsion stabilization.Its advantage is to inorganic pigment and inserts
Dispersion effect is good, but with the rise of pH value and temperature, polyphosphate is easily hydrolyzed, not good to extended storage stability.It is organic
Dispersant includes polyacrylate, polyamine/maleic acid salt, polyisobutene/maleic acid salt etc..They
Feature is strong absorption or anchorage effect to be produced on powder surface, with longer strand to form steric hindrance, the end of the chain has
Water solubility, the also auxiliary result for having electrostatic repulsion, reaching stabilization having.
Organic dispersing agent is different because of its molecular weight, and performance can be different；Low-molecular-weight type dispersant has one or many
The individual polar group being spatially close, they are adsorbed in surface of pigments, and stabilizing powder particle is carried out with spatial masking effect, so that
Decline viscosity, this kind of dispersant is mainly used in inorganic pigment, because inorganic pigment is ionic structure, there is higher surface pole
Property, dispersant is easy to absorption.And organic pigment is because of its surface group containing C, H, O, no ion activity, so often using HMW
Dispersant, there is the more group that sticks to adsorb on the surface of organic pigment, it can form lasting suction on organic pigment
Attached layer.But the molecular weight of dispersant too great Yi flocculates.So should be according to pigment and inserts type during the type of selection dispersant
And select.Dispersant used in the present invention can be organic dispersing agent, preferably acrylic copolymer solution, further preferably
For BYK2020 dispersant.
Chitosan is added in the present invention can assign Marine Antifouling Paint certain thixotropy and structural viscosity, play thickening anti-settling
Effect.Organic solvent used mainly plays diluting effect in the present invention, with adjusting coating viscosity.
The Marine Antifouling Paint that the present invention is provided, can also include the conven-tional adjuvants in coating, and such as pigment, thickener is prevented
Mixture more than one or both of rotten agent, defoamer etc..
The addition of conven-tional adjuvants can make it that obtained Marine Antifouling Paint performance is more outstanding.Pigment can have coating
Have a predetermined color and luster, pigment of the invention is preferably free of the anti-corrosion paint of heavy metal, such as red lead, zinc yellow, trbasic zinc phosphate, strontium chromate and
Zinc molybdate.Thickener can cause coating to have preferable thixotropy, and the present invention selects nonionic polyurethane class compound.It is anti-
Rotten agent can suppress the fungus growth in coating, coating is kept steady quality.Preservative of the present invention is preferably OIT.
Defoamer can suppress foam, make to be not likely to produce shrinkage cavity and flake during coating application, and defoamer of the invention can use hydrophobic two
The mixture of silica and mineral oil.The addition of conven-tional adjuvants can be added according to the general knowledge of those skilled in the art.
Present invention also offers the preparation method of foregoing Marine Antifouling Paint, comprise the following steps：
First Polybenzoxazine, polyamine, o-dihydroxy aromatised fraction and dispersant are mixed, then by obtained mixture
Mixed with yittrium oxide, modified pitch, modified carbon nano-tube, Mn-ZrC composite granules, fibre fluff, chitosan and organic solvent
Close, so as to obtain the coating.
Marine Antifouling Paint provided by the present invention can be also made by other conventional preparation methods, and the present invention is not spy
It is different to limit.
Compared with prior art, the present invention at least has the advantages that：
The Marine Antifouling Paint that the present invention is provided has excellent mechanical property, and sea water resistance is washed away, sea ice is collided, ship stops
By when wear resistance it is strong, and with excellent decay resistance, salt-fog resistant time is more than 4200 hours, and the wet-heat resisting time is big
In 4200 hours, and with excellent mechanical property.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is used only for help and understands the present invention, is not construed as the concrete restriction to the present invention.
Unless specific instructions, various raw materials of the invention can be by being commercially available；Or according to the routine side of this area
Method is prepared.Unless otherwise defined or described herein, all specialties used herein are ripe with art technology with scientific words
Practice meaning known to personnel identical.In addition any method similar or impartial to described content and material all can be applied to this
In inventive method.
The experimental method of unreceipted actual conditions, is generally determined according to national standard in the following example.If without corresponding
National standard, then according to general international standard, normal condition or according to proposed by manufacturer condition carry out.Unless
Illustrate in addition, otherwise all numbers are mass parts, all percentage is mass percent.
The preparation method of heretofore described Marine Antifouling Paint, comprises the following steps：
First Polybenzoxazine, polyamine, o-dihydroxy aromatised fraction and dispersant are mixed, then by obtained mixture
Mixed with yittrium oxide, modified pitch, modified carbon nano-tube, Mn-ZrC composite granules, fibre fluff, chitosan and organic solvent
Close, so as to obtain the coating.
Embodiment 1
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
2wt%, o-dihydroxy aromatised fraction 10wt%, yittrium oxide 10wt%, modified pitch 3wt%, modified carbon nano-tube 7wt%, Mn-
ZrC composite granule 12wt%, dispersant 5wt%, fibre fluff 6wt%, chitosan 3wt%, organic solvent 22wt%.
Embodiment 2
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 35wt%, polyamine
2wt%, o-dihydroxy aromatised fraction 18wt%, yittrium oxide 5wt%, modified pitch 3wt%, modified carbon nano-tube 7wt%, Mn-
ZrC composite granule 10wt%, dispersant 1wt%, fibre fluff 4wt%, chitosan 5wt%, organic solvent 10wt%.
Embodiment 3
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 67wt%, polyamine
5wt%, o-dihydroxy aromatised fraction 1wt%, yittrium oxide 8wt%, modified pitch 3wt%, modified carbon nano-tube 7wt%, Mn-
ZrC composite granule 5wt%, dispersant 5wt%, fibre fluff 1wt%, chitosan 3wt%, organic solvent 5wt%.
Embodiment 4
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 55wt%, polyamine
8wt%, o-dihydroxy aromatised fraction 2wt%, yittrium oxide 1wt%, modified pitch 3wt%, modified carbon nano-tube 7wt%, Mn-
ZrC composite granule 11wt%, dispersant 1wt%, fibre fluff 1wt%, chitosan 4wt%, organic solvent 8wt%.
Comparative example 1
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, carbon black composite conducting polyester fiber 10wt%, yittrium oxide 10wt%, Mn-ZrC composite granule 12wt%, dispersant
5wt%, fibre fluff 6wt%, organic solvent 22wt%.
Comparative example 2
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, polyaniline composite conductive fiber 10wt%, yittrium oxide 10wt%, Mn-ZrC composite granule 12wt%, dispersant
5wt%, fibre fluff 6wt%, organic solvent 22wt%.
Comparative example 3
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, polypyrrole base organic montmorillonite nano composite conducting fiber 10wt%, yittrium oxide 10wt%, Mn-ZrC composite granule
12wt%, dispersant 5wt%, fibre fluff 6wt%, organic solvent 22wt%.
Comparative example 4
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, polypyrrole base organic montmorillonite nano composite conducting fiber 10wt%, yittrium oxide 10wt%, dispersant 5wt%, fiber
Fine hair 6wt%, organic solvent 34wt%.
Comparative example 5
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, o-dihydroxy aromatised fraction 10wt%, yittrium oxide 10wt%, dispersant 5wt%, fibre fluff 6wt%, organic solvent
34wt%.
Comparative example 6
A kind of Marine Antifouling Paint, it is made up of by mass fraction following raw material components：Polybenzoxazine 20wt%, polyamine
15wt%, yittrium oxide 10wt%, Mn-ZrC composite granule 12wt%, dispersant 5wt%, fibre fluff 6wt%, organic solvent
32wt%.
Performance test：
Tested according to ISO 12944, NORSOK M501, NACE SP0108 anti-corrosion standards related to ISO 20340.
After tested, the coating of embodiment 1~4 tests 4000h, hot resistance test 4000h and circulation through salt spray resistance (salt solution)
Corrosion test 4200h test, as a result shows without exception, and it shows that provided coating is free of any heavy metal material
Material, and salt-fog resistant time, more than 4200 hours, the wet-heat resisting time is more than 4200 hours, and with excellent mechanical property；And it is right
The coating of ratio 1~6 shows abnormal after same test, as a result.
It can thus be seen that the Marine Antifouling Paint in the present invention has excellent Corrosion Protection, it is anti-that it possesses
Rotten performance can be advantageously applied in ocean engineering, be greatly improved the security of extra large work facility, with great application valency
Value.
Applicant states that the present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (8)
1. a kind of Marine Antifouling Paint, it is characterised in that be made up of by mass fraction following raw material components：
The mass fraction sum of each component is 100%.
2. coating according to claim 1, it is characterised in that fraction is made up of following raw material components by weight：
The mass fraction sum of each component is 100%.
3. coating according to claim 1 or 2, it is characterised in that fraction is made up of following raw material components by weight：
The mass fraction sum of each component is 100%.
4. the coating according to claim any one of 1-3, it is characterised in that the modifying agent of the modified pitch is maleic acid
Acid anhydride.
5. the coating according to claim any one of 1-4, it is characterised in that the organic solvent is benzene kind solvent.
6. coating according to claim 5, it is characterised in that described organic solvent is benzene, toluene or dimethylbenzene, or its
Mixture.
7. coating according to claim 6, it is characterised in that the dispersant is sodium tripolyphosphate, sodium tetrapolyphosphate, six
In sodium metaphosphate any one or at least two mixture.
8. the preparation method of the Marine Antifouling Paint according to claim any one of 1-7, it is characterised in that including following step
Suddenly：
First Polybenzoxazine, polyamine, o-dihydroxy aromatised fraction and dispersant are mixed, then by obtained mixture and oxygen
Change yttrium, modified pitch, modified carbon nano-tube, Mn-ZrC composite granules, fibre fluff, chitosan and organic solvent to be mixed,
So as to obtain the coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710499307.4A CN107189621A (en) | 2017-06-27 | 2017-06-27 | A kind of Marine Antifouling Paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710499307.4A CN107189621A (en) | 2017-06-27 | 2017-06-27 | A kind of Marine Antifouling Paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107189621A true CN107189621A (en) | 2017-09-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710499307.4A Pending CN107189621A (en) | 2017-06-27 | 2017-06-27 | A kind of Marine Antifouling Paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113088155A (en) * | 2020-01-09 | 2021-07-09 | 华东理工大学 | Super-hydrophobic coating composition containing full-bio-based benzoxazine, preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104159954A (en) * | 2012-02-10 | 2014-11-19 | 3M创新有限公司 | Anticorrosion coatings |
| CN104277664A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Marine anticorrosive coatings |
| CN106519765A (en) * | 2016-11-17 | 2017-03-22 | 过冬 | Anticorrosive coating and preparation method thereof |
-
2017
- 2017-06-27 CN CN201710499307.4A patent/CN107189621A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104159954A (en) * | 2012-02-10 | 2014-11-19 | 3M创新有限公司 | Anticorrosion coatings |
| CN104277664A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Marine anticorrosive coatings |
| CN106519765A (en) * | 2016-11-17 | 2017-03-22 | 过冬 | Anticorrosive coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113088155A (en) * | 2020-01-09 | 2021-07-09 | 华东理工大学 | Super-hydrophobic coating composition containing full-bio-based benzoxazine, preparation method and application |
| CN113088155B (en) * | 2020-01-09 | 2022-03-29 | 华东理工大学 | Super-hydrophobic coating composition containing full-bio-based benzoxazine, preparation method and application |
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Application publication date: 20170922 |