CN107185404A - A kind of gas cleaning absorption tower and its flue gas purifying method and application - Google Patents

A kind of gas cleaning absorption tower and its flue gas purifying method and application Download PDF

Info

Publication number
CN107185404A
CN107185404A CN201710569774.XA CN201710569774A CN107185404A CN 107185404 A CN107185404 A CN 107185404A CN 201710569774 A CN201710569774 A CN 201710569774A CN 107185404 A CN107185404 A CN 107185404A
Authority
CN
China
Prior art keywords
absorption tower
area
gas
flue gas
tower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710569774.XA
Other languages
Chinese (zh)
Inventor
朱廷钰
李玉然
张帅
范朝伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Kejie Environmental Protection Engineering Co ltd
Institute of Process Engineering of CAS
Original Assignee
Guangdong Kejie Environmental Protection Engineering Co ltd
Institute of Process Engineering of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Kejie Environmental Protection Engineering Co ltd, Institute of Process Engineering of CAS filed Critical Guangdong Kejie Environmental Protection Engineering Co ltd
Priority to CN201710569774.XA priority Critical patent/CN107185404A/en
Publication of CN107185404A publication Critical patent/CN107185404A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • B01D2258/0291Flue gases from waste incineration plants

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of gas cleaning absorption tower and its flue gas purifying method and application, including the first porous barrier and the second porous barrier inside the absorption tower are vertically arranged at, the firstth adjacent area, the secondth area and the 3rd area will be divided into inside absorption tower;The tower wall lower end in the firstth area is provided with air inlet, the firstth area and is provided with flue gas demarcation strip, and firstth area is isolated into Shang Qu and lower area, and the tube wall lower end in lower area is provided with air inlet, and the tube wall upper end in upper area sets gas outlet;Gas baffle is posted on first porous barrier, the lower edge of gas baffle is integrated with flue gas demarcation strip;Secondth area is filled with activated carbon;3rd area is provided with ammonia-spraying grid;Highly it is less than the top edge of the gas baffle.By setting flue gas demarcation strip and gas baffle, the efficiency of physical absorption and chemisorbed is improved, so as to improve purification efficiency, exhaust gas volumn can be handled for 4500Nm3/ more than h, and controllability, strong adaptability, convenient and efficient.

Description

A kind of gas cleaning absorption tower and its flue gas purifying method and application
Technical field
The present invention relates to flue gas purifying equipment technical field, more particularly to a kind of gas cleaning absorption tower and its flue gas it is net Change methods and applications.
Background technology
Requirement with country to environmental protection is more and more tighter, and coke oven flue gas qualified discharge standard is more and more tighter, and coke oven flue gas is net Chemical industry skill not yet full maturity at present, each side research and design personnel by use for reference other industry smoke gas treatment technology or Importing Foreign Advanced Technology is attempted.Activated carbon method flue gas desulfurization and denitrification technology is more ripe in steel industry application, the skill Art can not only remove the SO in flue gas simultaneously2And NOx, also with not water consumption, non-secondary pollution, the powder effectively removed in flue gas Dirt and heavy metal (such as mercury) pollutant, the advantages of Sulphur ressource can be reclaimed by adsorbent reactivation, Jiao can be advantageously applied to The gold solidification of kiln gas muscle is administered.Coke oven flue gas characteristic is in addition to high nitrogen low-sulfur, also containing hydrogen sulfide, tar, heavy metal, hydro carbons etc. Component, different coke oven constructions, different operating modes cause smoke components complicated and changeable, and the fluctuation of sulfur content excursion is big, these The factor to be taken in during the structure design for being all coke oven flue gas absorption tower.The removing effect of active carbon flue gas desulfurizing denitration technology Fruit is directly influenceed by inside reactor structure, therefore, improves the structure of reactor, and improve reactor is to the adaptability of flue gas Each designer's obligation one can't decline.
The primary raw material of denitration integrated device is special-purpose activated charcoal, and it is that a kind of comprehensive strength is (pressure-resistant, wear-resisting Damage, impact resistance), specific surface area higher than the conventional activated carbon sorbing material smaller than conventional activated carbon.Industrial application is special at present Activated carbon is often made as cylindric.
Active carbon desulfurization technological principle is to be based on SO2SO in the absorption and catalytic action of activated carbon surface, flue gas2 At a temperature of 120 DEG C~160 DEG C, it is that sulfuric acid is adsorbed in activated carbon hole to be reacted with oxygen, water vapour in flue gas.
Physical absorption:SO2→SO2(SO2Absorption is in activated carbon micropore),
Chemisorbed:SO2+O2→SO3, SO3+nH2O→H2SO4+(n-1)H2O;
NH is sprayed during denitration3, (NH is depended on to sulfate conversion3/SO2), react and be:
H2SO4+NH3→NH4HSO4
NH4HSO4+NH3→(NH4)2SO4
Spray ammonia and carry out denitration, activated carbon is used as removing NOxCarrier and catalyst, NOxAnd NH3About 107 DEG C of temperature~ At 167 DEG C, occurs catalytic reaction in burnt primary surface, by NOxIt is decomposed into N2And H2O, is adsorbed on activated carbon, and key reaction formula is such as Under:
4NO+O2+4NH3→4N2+6H2O
NH4HSO4+NH3→(NH4)2SO4
Activated carbon is recycled, and adsorbs SO2Activated carbon afterwards is transported to regenerator, when being heated to 400 DEG C or so, release Go out SO2
The flue gas desulfurization and denitrification tower of existing more maturation can be divided into two major classes, integral type desulphurization denitration tower and two-part desulfurization Denitrating tower, wherein, two-part desulphurization denitration tower can preferably avoid the presence of sulphur to de- in the low nitrogen gas cleaning of reply high-sulfur Sulphur denitration has undesirable effect, therefore is preferably applied in steel sintering, pelletizing flue gas desulfurization and denitration technique, and coke oven flue gas High nitrogen low-sulfur then more suitable for applying integral type desulphurization denitration tower, but the presence of sulphur is for direct integral type desulphurization denitration tower Denitration ability there is larger negative effect, how quickly and conveniently to remove sulphur, improve desulfuration efficiency, improve different sulfur content When absorption tower adaptibility to response be coke oven flue gas desulphurization denitration need solution the problem of.
The content of the invention
In view of problems of the prior art, an object of the present invention is to provide a kind of suitable coke oven flue gas characteristic Activated carbon desulfurization denitrification integral absorption tower internal structure, flue gas in tower can be made reasonably to sequentially pass through desulfurization zone and denitration Area, in the case where ensureing removal efficiency, improves absorption tower to the adaptability of flue gas, makes industrial production more efficient more convenient.
For up to this purpose, the present invention is adopted the following technical scheme that:
In a first aspect, the invention provides a kind of gas cleaning absorption tower, including it is vertically provided at the absorption tower Internal the first porous barrier (15) and the second porous barrier (17), will be divided into inside the absorption tower the firstth adjacent area, Secondth area and the 3rd area.
The tower wall lower end in firstth area is provided with air inlet, firstth area and is provided with flue gas demarcation strip (13), will Firstth area is isolated into Shang Qu and lower area, and the tube wall lower end in the lower area is provided with air inlet (11), the tube wall in the upper area Upper end sets gas outlet (12);Gas baffle (14) is posted on first porous barrier (15), for example, gas baffle (14) can It is connected to using nut connected mode on the first porous barrier (15), lower edge and the flue gas point of the gas baffle (14) Dividing plate (13) integration.
Secondth area is filled with activated carbon.
3rd area is provided with ammonia-spraying grid (16);The height of the ammonia-spraying grid (16) is less than the gas baffle (14) top edge.
Gas cleaning absorption tower in the present invention sets flue gas to separate before flue gas enters active carbon layer in admittance area Plate and gas baffle, flue gas demarcation strip make flue gas reasonably pass through activated carbon at least twice, complete purification purpose.Gas baffle is kept away Exempt from flue gas directly to flow through from admittance area and be not passed through activated carbon.
It should also be noted that, in the present invention, term " comprising " or its any other variant are intended to non-exclusive Property include so that process, method, article or equipment including a series of key elements not only include those key elements, and Also include other key elements for being not expressly set out, or also include for this process, method, article or equipment inherently Key element.In the absence of more restrictions, the key element limited by sentence " including ... ", it is not excluded that including the key element Process, method, article or equipment in also there is other identical element.
Preferably, first porous barrier (15) is parallel with second porous barrier (17).
Preferably, the distance between first porous barrier (15) and second porous barrier (17) are 1~2.5m, Such as 1m, 1.1m, 1.2m, 1.3m, 1.4m, 1.5m, 1.6m, 1.7m, 1.8m, 1.9m, 2.0m, 2.1m, 2.2m, 2.3m, 2.4m Or 2.5m etc., preferably 1.5~2m.
Preferably, the percent opening of first porous barrier (15) and second porous barrier (17) is selected independently of one another From 30%~50%, such as 30%, 32%, 35%, 36%, 38%, 39%, 40%, 42%, 43%, 45%, 48%, 49% Or 50% etc., preferably 35%~45%.The maximum increase percent opening under the premise of ensuring that plate intensity and activated carbon be not excessive, simultaneously Percent opening distribution can be adjusted according to computer simulation flue gas flow field uniformity results, perforate is suitably reduced in airflow field close quarters Rate so that flue gas more flows to the larger region of resistance, increases the overall uniformity in inside reactor flow field with this, improves and inhale Produce effects really.
Preferably, the flue gas demarcation strip (13) is horizontally disposed with.
Preferably, the flue gas demarcation strip (13) is 1~5m with the distance of air inlet bottom, such as 1m, 1.5m, 2m, 2.5m, 3m, 3.5m, 4m, 4.5m or 5m etc., preferably 2~4m.Flue gas demarcation strip can be by human weld or in top chain band Dynamic adjusting position, is suitably adjusted according to gas approach size and flue gas characteristic.
Preferably, the distance of the top edge of the gas baffle (14) and lower edge be 2~4m, such as 2m, 2.2m, 2.3m, 2.5m, 2.8m, 3m, 3.2m, 3.5m, 3.8m or 4m etc., preferably 2.5~3.5m.
Cooperated between flue gas demarcation strip of the present invention, the height of gas baffle and the thickness of active carbon layer, flue gas separates Plate is fixedly connected with gas baffle bottom so that flue gas will be suitably larger than activated carbon completely into activated carbon, gas baffle height The thickness of layer, makes all flue gases may pass through activated carbon, realizes double absorption, further improves gas cleaning rate.
Preferably, the absorption tower is cuboid absorption tower.
Preferably, the absorption tower is long 2~10m, wide 3~6m, high 8~30m cuboid absorption tower.For example, long 2m, 3m, 4m, 5m, 6m, 7m, 8m, 9m or 10m etc., wide 3m, 3.2m, 3.5m, 3.8m, 4m, 4.2m, 4.5m, 4.8m, 5m, 5.2m, 5.5m, 5.8m or 6m etc., high 8m, 9m, 10m, 12m, 15m, 18m, 20m, 22m, 25m, 28m or 30m etc..
Second aspect, the invention provides a kind of method using absorption tower purifying smoke as described in relation to the first aspect, bag Include:SO will be contained2And NOxFlue gas be passed through absorption tower from air inlet (11), while ammonia is passed through from ammonia-spraying grid (16), in tower After interior absorption, net gas is discharged from gas outlet (12).
Preferably, the flow velocity for being passed through flue gas is 10~25m/s, such as 10m/s, 12m/s, 15m/s, 18m/s, 20m/ S, 22m/s or 25m/s etc., preferably 15~20m/s.
Preferably, the flow velocity for being passed through ammonia is 10~20m/s, such as 10m/s, 11m/s, 12m/s, 13m/s, 14m/ S, 15m/s, 16m/s, 17m/s, 18m/s, 19m/s or 20m/s etc., preferably 10~15m/s.
The third aspect, the invention provides absorption tower as described in relation to the first aspect in cock-oven gas purifying device, sintering flue gas Application in processing unit, glass kiln flue gas processing device and waste incineration station emission-control equipment.
Compared with prior art, the present invention at least has the advantages that:
(1) gas cleaning absorption tower of the invention sets flue gas to separate before flue gas enters active carbon layer in admittance area Plate and gas baffle, flue gas demarcation strip avoid flue gas and are directly flowed through from admittance area and be not passed through activated carbon, and gas baffle makes Flue gas reasonably passes through activated carbon at least twice.Both collaborations mutually, improve the efficiency of physical absorption and chemisorbed, so that Purification efficiency is improved, exhaust gas volumn can be handled for 4500Nm3/ more than h;
(2) present invention can set flue gas demarcation strip, the height of gas baffle and active carbon layer according to the flow performance of flue gas Thickness, controllability is strong, improves absorption tower to the adaptability of flue gas, the environmental requirement of qualified discharge is completed convenient and efficient.
Brief description of the drawings
Fig. 1 is the front view for the column for smoke purification that the embodiment of the present invention 1 is provided;
Fig. 2 is the internal structure top view for the column for smoke purification that the embodiment of the present invention 1 is provided;
Fig. 3 is the front view for the column for smoke purification that the embodiment of the present invention 2 is provided;
Fig. 4 is the front view for the column for smoke purification that the embodiment of the present invention 3 is provided;
Fig. 5 is the front view for the column for smoke purification that the embodiment of the present invention 4 is provided;
Marked in figure:
11、21、31、41:Air inlet;12、22、32、42:Gas outlet;13、23、33、43:Flue gas demarcation strip;14、24、 34、44:Gas baffle;15、25、35、45:First porous barrier;16、26、36、46:Ammonia-spraying grid;17、27、37、47:Second Porous barrier
Embodiment
Further illustrate technical scheme below in conjunction with the accompanying drawings and by embodiment.But following realities Example is only the simple example of the present invention, does not represent or limit the scope of the present invention, protection scope of the present invention It is defined by claims.
Embodiment 1
Smoke absorption tower as illustrated in fig. 1 and 2, tower body size is long 2m, width 4m, high 8m, and can handle exhaust gas volumn is 6000Nm3/h.Smoke absorption tower includes being vertically provided at the first porous barrier 15 and the second porous barrier inside absorption tower 17, percent opening is 45%, and two plates are parallel to each other, and distance is 2m, the firstth area, the secondth area from left to right will be divided into inside tower With the 3rd area;Firstth area, the wide each 1m of exhaust gases passes in the 3rd area;
Being horizontally disposed with firstth area has flue gas demarcation strip 13, and the distance with air inlet bottom is 2m, and the firstth area is isolated into Shang Qu and lower area, the tube wall lower end in lower area are provided with air inlet 11, and the tube wall upper end in upper area sets gas outlet 12;First it is porous every Gas baffle 14 is posted on plate 15, the lower edge of gas baffle 14 is integrated with flue gas demarcation strip 13;The top of gas baffle 14 The distance of edge and lower edge is 3m;
Secondth area is full of activated carbon;
3rd area is provided with ammonia-spraying grid 16, the highly top edge less than the gas baffle 14.
The method for carrying out purifying absorption to coke oven flue gas using smoke absorption tower as illustrated in fig. 1 and 2, step is as follows:
SO will be contained2(content is in 1000mg/m3Below) and NOxCoke oven flue gas be passed through absorption tower from air inlet 11, be passed through The flow velocity of flue gas is 20m/s, while being passed through ammonia from ammonia-spraying grid 16, flow velocity is 13m/s, and after being absorbed in tower, net gas is from going out Gas port 12 is discharged, and flue gas is reached emission of industrial pollutants standard.
Embodiment 2
Smoke absorption tower as shown in Figure 3, the difference with the smoke absorption tower of embodiment 1 is:Gas baffle 24 it is upper The distance of edge and lower edge is 2.5m.
The method for carrying out purifying absorption to coke oven flue gas using smoke absorption tower as shown in Figure 3, step is as follows:
SO will be contained2(content is in 1000~1500mg/m3) and NOxCoke oven flue gas be passed through absorption tower from air inlet 21, lead to Enter flue gas flow velocity be 20m/s, while being passed through ammonia from ammonia-spraying grid 26, flow velocity is 13m/s, in tower absorb after, net gas from Gas outlet 22 is discharged, and flue gas is reached emission of industrial pollutants standard.
Embodiment 3
Smoke absorption tower as shown in Figure 4, tower body size is long 6m, width 4m, high 20m, and can handle exhaust gas volumn is 45000Nm3/h.Smoke absorption tower includes being vertically provided at the first porous barrier 35 and the second porous barrier inside absorption tower 37, percent opening is 40%, and two plates are parallel to each other, and distance is 2m, the firstth area, the secondth area from left to right will be divided into inside tower With the 3rd area;Firstth area, the wide each 1m of exhaust gases passes in the 3rd area;
Being horizontally disposed with firstth area has flue gas demarcation strip 33, and the distance with air inlet bottom is 2m, and the firstth area is isolated into Shang Qu and lower area, the tube wall lower end in lower area are provided with air inlet 31, and the tube wall upper end in upper area sets gas outlet 32;First it is porous every Gas baffle 34 is posted on plate 35, the lower edge of gas baffle 34 is integrated with flue gas demarcation strip 33;The top of gas baffle 34 The distance of edge and lower edge is 3m;
Secondth area is full of activated carbon;
3rd area is provided with ammonia-spraying grid 36, the highly top edge less than the gas baffle 34.
The method for carrying out purifying absorption to coke oven flue gas using smoke absorption tower as shown in Figure 4, step is as follows:
SO will be contained2(content is in 1000mg/m3Below) and NOxCoke oven flue gas be passed through absorption tower from air inlet 41, be passed through The flow velocity of flue gas is 20m/s, while being passed through ammonia from ammonia-spraying grid 46, flow velocity is 15m/s, and after being absorbed in tower, net gas is from going out Gas port 42 is discharged so that the SO in neat stress2Content is less than 30mg/m3, NO contents are less than 150mg/m3, reach regulation discharge mark It is accurate.
Embodiment 4
Smoke absorption tower as shown in Figure 5, the difference with the smoke absorption tower of embodiment 3 is:Flue gas demarcation strip 43 with The distance of the bottom of air inlet 41 is 3m.
The method for carrying out purifying absorption to coke oven flue gas using smoke absorption tower as shown in Figure 5, step is as follows:
SO will be contained2(content is in 1000~1500mg/m3) and NOxCoke oven flue gas be passed through absorption tower from air inlet 41, lead to Enter flue gas flow velocity be 20m/s, while being passed through ammonia from ammonia-spraying grid 46, flow velocity is 15m/s, in tower absorb after, net gas from Discharge gas outlet 42 so that the SO in neat stress2Content is less than 30mg/m3, NO contents are less than 150mg/m3, reach that regulation is discharged Standard.
Embodiment 5
For absorption tower used in the gas cleaning of waste incineration station, structure is similar with housing structure in embodiment 4, tower body size For long 6m, wide 4m, high 14m, exhaust gas volumn can be handled for 30000Nm3/ h, the first porous barrier being arranged inside absorption tower and Two porous barriers, percent opening is 42% or so, and two plates are parallel to each other, and distance is 2m.Flue gas demarcation strip is arranged on apart from air inlet Mouth bottom 3m position, the lower edges distance of gas baffle is 3m, and the flow velocity for being passed through flue gas is 18m/s, the ammonia being passed through Flow velocity is 13m/s.
When flue gas passes twice through activated carbon, the SO contained in flue gas2, heavy metal, dust, aromatic hydrocarbons harm gas first Absorption mixes completion denitrification process and the processing of further deep purifying, final flue gas with ammonia in activated carbon bottom, then flue gas Realize qualified discharge requirement.
Embodiment 6
It is similar with absorbing tower structure shown in Fig. 1 and Fig. 2, unlike:Tower body size is long 2m, width 3.1m, high 8m, can be located Reason exhaust gas volumn is 4800Nm3/h.The percent opening of first porous barrier and the second porous barrier is 50%, and distance is 1.5m, the One area, the wide each 0.8m of exhaust gases passes in the 3rd area;The distance of flue gas demarcation strip and air inlet bottom is 1m, gas baffle 14 it is upper The distance of edge and lower edge is 2.5m.
The method for carrying out purifying absorption to glass kiln flue gas using this smoke absorption tower, step is as follows:
SO will be contained2(content is in 1000mg/m3Below) and NOxCoke oven flue gas be passed through absorption tower from air inlet, be passed through cigarette The flow velocity of gas is 10m/s, while being passed through ammonia from ammonia-spraying grid, flow velocity is 10m/s, and after being absorbed in tower, net gas is from gas outlet Discharge, reaches regulated discharge standard.
Embodiment 7
It is similar with absorbing tower structure shown in Fig. 1 and Fig. 2, unlike:Tower body size is long 10m, width 6m, high 30m, can be located Reason exhaust gas volumn is 150000Nm3/h.The percent opening of first porous barrier and the second porous barrier is 30%, and distance is 2.5m, Firstth area, the wide each 1.75m of exhaust gases passes in the 3rd area;The distance of flue gas demarcation strip and air inlet bottom is 5m, gas baffle 14 Top edge and lower edge distance be 4m.
The method for carrying out purifying absorption to sintering flue gas using this smoke absorption tower, step is as follows:
SO will be contained2(content is in 3500mg/m3Below) and NOxCoke oven flue gas be passed through absorption tower from air inlet, be passed through cigarette The flow velocity of gas is 25m/s, while being passed through ammonia from ammonia-spraying grid, flow velocity is 20m/s, and after being absorbed in tower, net gas is from gas outlet Discharge, reaches regulated discharge standard.
Applicant states that the present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment, But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within the present invention's Within the scope of protection domain and disclosure.

Claims (10)

1. a kind of gas cleaning absorption tower, it is characterised in that including be vertically provided inside the absorption tower more than first Hole dividing plate (15) and the second porous barrier (17), will be divided into the firstth adjacent area, the secondth area and the 3rd inside the absorption tower Area;
Flue gas demarcation strip (13) is provided with firstth area, firstth area is isolated into Shang Qu and lower area, the lower area Tube wall lower end is provided with air inlet (1), and the tube wall upper end in the upper area sets gas outlet (12);First porous barrier (15) On post gas baffle (14), the lower edge of the gas baffle (14) is integrated with the flue gas demarcation strip (13);
Secondth area is filled with activated carbon;
3rd area is provided with ammonia-spraying grid (16);The height of the ammonia-spraying grid (16) is less than the gas baffle (14) Top edge.
2. absorption tower as claimed in claim 1, it is characterised in that first porous barrier (15) with described second it is porous every Plate (17) is parallel;
Preferably, the distance between first porous barrier (15) and second porous barrier (17) are 1~2.5m, It is preferred that 1.5~2m.
3. absorption tower as claimed in claim 1 or 2, it is characterised in that first porous barrier (15) and described more than second The percent opening of hole dividing plate (17) is each independently selected from 30%~50%, preferably 35%~45%.
4. the absorption tower as described in any one of claims 1 to 3, it is characterised in that the flue gas demarcation strip (13) and air inlet The distance of mouth bottom is 1~5m, preferably 2~4m.
5. the absorption tower as described in any one of Claims 1 to 4, it is characterised in that the top edge of the gas baffle (14) with The distance of lower edge is 2~4m, preferably 2.5~3.5m.
6. a kind of absorption tower as described in any one of Claims 1 to 5, it is characterised in that the absorption tower absorbs for cuboid Tower.
7. a kind of absorption tower as described in any one of claim 1~6, it is characterised in that the absorption tower is long 2~10m, width 3~6m, high 8~30m cuboid absorption tower.
8. a kind of method of absorption tower purifying smoke using as described in any one of claim 1~7, it is characterised in that including: SO will be contained2And NOxFlue gas be passed through absorption tower from air inlet (11), while be passed through ammonia from ammonia-spraying grid (16), inhaled in tower After receipts, net gas is discharged from gas outlet (12).
9. method as claimed in claim 8, it is characterised in that the flow velocity for being passed through flue gas is 10~25m/s, preferably 15~ 20m/s;
Preferably, the flow velocity for being passed through ammonia is 10~20m/s, preferably 10~15m/s.
10. absorption tower is in cock-oven gas purifying device, sintering flue gas treatment device, glass as described in any one of claim 1~7 Application in furnace flue gas processing unit and waste incineration station emission-control equipment.
CN201710569774.XA 2017-07-13 2017-07-13 A kind of gas cleaning absorption tower and its flue gas purifying method and application Pending CN107185404A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710569774.XA CN107185404A (en) 2017-07-13 2017-07-13 A kind of gas cleaning absorption tower and its flue gas purifying method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710569774.XA CN107185404A (en) 2017-07-13 2017-07-13 A kind of gas cleaning absorption tower and its flue gas purifying method and application

Publications (1)

Publication Number Publication Date
CN107185404A true CN107185404A (en) 2017-09-22

Family

ID=59882336

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710569774.XA Pending CN107185404A (en) 2017-07-13 2017-07-13 A kind of gas cleaning absorption tower and its flue gas purifying method and application

Country Status (1)

Country Link
CN (1) CN107185404A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158886A (en) * 2017-05-25 2017-09-15 中国重型机械研究院股份公司 A kind of activated coke movable block combination type flue gas desulfurization denitration adsorbent equipment
CN108543403A (en) * 2018-04-08 2018-09-18 中冶长天国际工程有限责任公司 A kind of activated carbon adsorption Tower System and system for desulfuration and denitration

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230724A (en) * 2013-04-22 2013-08-07 西安热工研究院有限公司 New cross-convective flue gas purification absorption tower
CN103405982A (en) * 2013-07-02 2013-11-27 香港诺曼泰壹环保科技有限公司 Smoke purification device
CN104353356A (en) * 2014-11-26 2015-02-18 北京首钢国际工程技术有限公司 Pelletizing flue gas cleaning and adsorbing tower of travelling grate machine
CN205435208U (en) * 2015-12-09 2016-08-10 常州汉邦工程塑料股份有限公司 Active carbon absorption device
CN106693603A (en) * 2015-11-13 2017-05-24 中冶长天国际工程有限责任公司 Activated carbon method flue gas cleaning device and flue gas cleaning method
CN106731449A (en) * 2016-11-23 2017-05-31 中国科学院过程工程研究所 A kind of column for smoke purification
CN206240303U (en) * 2016-11-14 2017-06-13 一重集团大连工程建设有限公司 A kind of adverse current, the integrated activated coke smoke eliminator of cross-current type series connection

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230724A (en) * 2013-04-22 2013-08-07 西安热工研究院有限公司 New cross-convective flue gas purification absorption tower
CN103405982A (en) * 2013-07-02 2013-11-27 香港诺曼泰壹环保科技有限公司 Smoke purification device
CN104353356A (en) * 2014-11-26 2015-02-18 北京首钢国际工程技术有限公司 Pelletizing flue gas cleaning and adsorbing tower of travelling grate machine
CN106693603A (en) * 2015-11-13 2017-05-24 中冶长天国际工程有限责任公司 Activated carbon method flue gas cleaning device and flue gas cleaning method
CN205435208U (en) * 2015-12-09 2016-08-10 常州汉邦工程塑料股份有限公司 Active carbon absorption device
CN206240303U (en) * 2016-11-14 2017-06-13 一重集团大连工程建设有限公司 A kind of adverse current, the integrated activated coke smoke eliminator of cross-current type series connection
CN106731449A (en) * 2016-11-23 2017-05-31 中国科学院过程工程研究所 A kind of column for smoke purification

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158886A (en) * 2017-05-25 2017-09-15 中国重型机械研究院股份公司 A kind of activated coke movable block combination type flue gas desulfurization denitration adsorbent equipment
CN108543403A (en) * 2018-04-08 2018-09-18 中冶长天国际工程有限责任公司 A kind of activated carbon adsorption Tower System and system for desulfuration and denitration
CN108543403B (en) * 2018-04-08 2020-07-03 中冶长天国际工程有限责任公司 Activated carbon adsorption tower system and SOx/NOx control system

Similar Documents

Publication Publication Date Title
CN206444401U (en) A kind of flying dust flue gas combination purification system for burning city domestic garbage
CN107551757A (en) A kind of flue gas desulfurization and denitration method and device
CN204672123U (en) A kind of waste gas purification tower with swirling flow plate
CN108295565A (en) The method and system of flue gas desulfurization and denitrification
CN107596798B (en) Pre-dedusting, desulfurizing and denitrating integrated treatment device and method
CN107469561A (en) A kind of gas cleaning absorption tower and its processing method
CN102430318A (en) System for desulfurizing and denitrating active coke flue gas, and process method
CN107551756A (en) Prevent the flue gas desulfurization and denitration method and device of corrosion
CN105597531B (en) A kind of desulfuring and denitrifying apparatus and technique for cock-oven gas purifying
CN204656311U (en) A kind of cleaning system of coal-fired plant flue gas
CN103203160B (en) Flue gas combined desulfurization denitration demercuration device and method thereof
CN110548378A (en) Method for synchronously treating sulfur dioxide and nitrogen oxide in sintering flue gas by low-temperature dry single tower
CN102895839A (en) Device and method for performing integrated purification on smoke
CN104607015A (en) Multi-pollutant co-purification method and multi-pollutant co-purification system for sintering flue gas
CN206240259U (en) A kind of flue gas desulfurization and denitrification device
CN102794080A (en) Method and device for comprehensively treating pollutants jointly aiming at waste heat recovery of flue gas in coke oven
CN104353356A (en) Pelletizing flue gas cleaning and adsorbing tower of travelling grate machine
CN105363340A (en) Activated carbon dry-method smoke purifying method and device capable of achieving simultaneous desulfurization and denitrification
CN102371113A (en) Flue gas purifying treatment method and system
CN107961770A (en) The regenerative system and renovation process of adsorbent in a kind of cock-oven gas purifying
CN206240258U (en) Prevent the flue gas desulfurization and denitrification device of corrosion
CN107998817B (en) Single tower type fume purifier flue gas purification method
CN103203182B (en) Flue gas combined desulfurization denitration demercuration device and method
CN107185404A (en) A kind of gas cleaning absorption tower and its flue gas purifying method and application
CN105056723A (en) Twin-tower type flue gas deep purification device through plasma coupling and sodium based absorption and method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170922

RJ01 Rejection of invention patent application after publication