CN107185378A - A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant - Google Patents

A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant Download PDF

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Publication number
CN107185378A
CN107185378A CN201710437956.1A CN201710437956A CN107185378A CN 107185378 A CN107185378 A CN 107185378A CN 201710437956 A CN201710437956 A CN 201710437956A CN 107185378 A CN107185378 A CN 107185378A
Authority
CN
China
Prior art keywords
flue gas
tower body
purifying column
column tower
water tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710437956.1A
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Chinese (zh)
Inventor
张利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Yunquan Chemical Anticorrosive Equipment Co Ltd
Original Assignee
Taicang Yunquan Chemical Anticorrosive Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Yunquan Chemical Anticorrosive Equipment Co Ltd filed Critical Taicang Yunquan Chemical Anticorrosive Equipment Co Ltd
Priority to CN201710437956.1A priority Critical patent/CN107185378A/en
Publication of CN107185378A publication Critical patent/CN107185378A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Abstract

The invention discloses a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant, including:Purifying column tower body, purifying column tower body uses cylindrical structure form, in purifying column tower body lower end, connection is provided with water tank, it is provided with flue gas mouthful on purifying column tower body sidewall, mouth spray is provided with purifying column tower body upper end, mouth spray is connected to water tank by pipeline, the liquid of water tank is entering shower by pipeline, sprayed in mouth spray, realize the circulation of shower water, a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant of the invention, structure design is compact, pass through double base extraction sulfur dioxide so that the sulfur dioxide reaction in flue gas is complete, improves environmental quality.

Description

A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant
Technical field
The present invention relates to technical field of environment protection equipment, more particularly to a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant.
Background technology
With China's expanding economy and the progress of society, environmental issue is increasingly serious, and present acid rain problem is that country is anti- The major issue controlled, the main component of acid rain is sulfur dioxide, and in order to reduce the discharge of sulfur dioxide, country has promulgated desulfurization Hard and fast rule, in the discharge of sulfur dioxide, smeltery and power plant are the discharge rich anies influential family of sulfur dioxide, in order to reduce dioxy Change the discharge of sulphur, presently mainly based on Limestone-gypsum Wet Flue Gas Desulfurization Process technique, substantial amounts of lime stone is added in absorption tower Carry out calcium sulfite, the calcium sulfate generated after sulfur dioxide absorption, sulfur dioxide absorption, reach the purpose for removing sulfur dioxide, adopt Use Ca(OH)2, in operation, easy fouling so that the spray nozzle clogging of processing, and alkali charge is high, the sludge quantity of generation Greatly, and sulfur dioxide treatment not exclusively, therefore, the invention provides a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant, using acid-base neutralization, Through fully chemical reaction, so as to be separated off acid ingredient, handling process rationally, is capable of the sulfur dioxide of efficient process power plant, Sulfur trioxide, does not pollute surrounding environment.
The content of the invention
The present invention solves the technical problem of a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant is provided, power plant can be effectively removed Sulfur dioxide, sulfur trioxide, and and surrounding environment will not be polluted, operating efficiency is high, easy for installation.
A kind of described Introduction For Flue Gas Desulfarization System Of Electric Power Plant, including:Purifying column tower body, purifying column tower body uses cylindrical structure shape Formula, in purifying column tower body lower end, connection is provided with water tank, and water tank is rectangular parallelepiped structure form, and in water tank lower end, connection is provided with bottom Seat, purifying column tower body uses double-layer structure form, and internal layer uses polypropylene material, and outer layer uses metal framework supporting layer.
It is provided with flue gas mouthful on purifying column tower body sidewall, enters flue gas mouthful and power-plant flue gas discharge is connected to by pipeline Mouthful.
Mouth spray is provided with purifying column tower body upper end, mouth spray is connected to water tank by pipeline, and the liquid of water tank is logical Piping enters shower, is sprayed in mouth spray, realizes the circulation of shower water.
Connection is provided with pumping motor between mouth spray and the pipeline of water tank, and water extraction is sprayed to realize by pumping motor For circulation power.
Dosing tank is connected to by circulating line on water tank, dosing tank is rectangular parallelepiped structure form, is set on dosing tank NAOH alkali liquor inlets have been put, have passed through mouth spray so that the sulfur dioxide in flue gas is contacted with water, sulfurous acid, SO2+H2O- is generated> To generate sulfurous acid solution progress acid-base neutralization anti-with to be alkaline matter with sulfur dioxide be dissolved in water for H2SO3, NAOH desulphurization stage reason Should, NA2SO3 and H2SO3 further reacts generation NAHSO3, NAHSO3 and accelerates generation sodium sulfite with NAOH reactions again;Generation Sodium sulfite recycled as absorbent, it is untapped after peroxidating, discharged as harmless aqueous sodium persulfate solution, NA2SO3+H2SO3=NAHSO3, NAHSO3+NAOH=2NA2SO3+2H2O, NA2SO3+1/2O2=NA2SO4.
In water tank bottom there is provided sewage draining exit, by sewage draining exit so that reacted sewage discharge, a kind of optimization technique side Case, sewage draining exit connection is provided with electromagnetic valve, is easy to control the discharge of sludge by electromagnetic valve.
In order that alkali lye and flue gas are fully contacted, packing layer is provided with purifying column tower body, filler uses Pall ring Or Raschig ring structure, filler uses polypropylene material, increases the contact area of shower water and waste gas, improve clean-up effect, be Facilitate the addition and exclusion of filler, a kind of optimal technical scheme on described purifying column tower body is also provided with filler import With filler outlet.
Waste gas outlet is provided with purifying column tower body top, the waste gas handled by packing layer is entered by waste gas outlet Alkali lye pond, alkali lye pond uses rectangular parallelepiped structure form, calcium hydroxide is provided with alkali lye pond, by calcium hydroxide so that dioxy Change the further purified treatment of sulphur.
Air outlet slit is provided with alkali lye pond, air outlet slit is connected to chimney by pipeline, is handled by alkali lye pond Air is discharged by chimney, and is provided with air exhauster in chimney lower end, and power is provided for air discharge by air exhauster.
A kind of optimal technical scheme, in order to ensure air quality, air quality detector is provided with chimney device top With rain cap structure, air quality detector is easy to detection discharge air quality.
The beneficial effects of the invention are as follows:A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant of the present invention, structure design is compact, passes through double alkali Liquid handles sulfur dioxide so that the sulfur dioxide reaction in flue gas is complete, is adapted to the waste discharge gas disposal of industry-by-industry enterprise of China, Atmospheric environment is protected after treatment, improves environmental quality.
Brief description of the drawings
Fig. 1 is a kind of structural representation of Introduction For Flue Gas Desulfarization System Of Electric Power Plant of the invention;
The mark of each part is as follows in accompanying drawing:
1 is mouth spray, and 2 be purifying column tower body, 3 packing layers, and 4 be water tank, and 5 be pumping motor, and 6 be sewage draining exit, and 7 be dosing tank, 8 It is chimney for air exhauster, 9,10 be alkali lye pond, and 11 be into flue gas mouthful.
Embodiment
Presently preferred embodiments of the present invention is described in detail below in conjunction with the accompanying drawings, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, apparent is clearly defined so as to be made to protection scope of the present invention.
Referring to Fig. 1, the embodiment of the present invention includes:
A kind of described Introduction For Flue Gas Desulfarization System Of Electric Power Plant, including:Purifying column tower body, purifying column tower body uses cylindrical structure form, In purifying column tower body lower end, connection is provided with water tank, and water tank is rectangular parallelepiped structure form, and in water tank lower end, connection is provided with base, Purifying column tower body uses double-layer structure form, and internal layer uses polypropylene material, and outer layer uses metal framework supporting layer.
It is provided with flue gas mouthful on purifying column tower body sidewall, enters flue gas mouthful and power-plant flue gas discharge is connected to by pipeline Mouthful.
Mouth spray is provided with purifying column tower body upper end, mouth spray is connected to water tank by pipeline, and the liquid of water tank is logical Piping enters shower, is sprayed in mouth spray, realizes the circulation of shower water.
Connection is provided with pumping motor between mouth spray and the pipeline of water tank, and water extraction is sprayed to realize by pumping motor For circulation power.
Dosing tank is connected to by circulating line on water tank, dosing tank is rectangular parallelepiped structure form, is set on dosing tank NAOH alkali liquor inlets have been put, have passed through mouth spray so that the sulfur dioxide in flue gas is contacted with water, sulfurous acid, SO2+H2O- is generated> To generate sulfurous acid solution progress acid-base neutralization anti-with to be alkaline matter with sulfur dioxide be dissolved in water for H2SO3, NAOH desulphurization stage reason Should, NA2SO3 and H2SO3 further reacts generation NAHSO3, NAHSO3 and accelerates generation sodium sulfite with NAOH reactions again;Generation Sodium sulfite recycled as absorbent, it is untapped after peroxidating, discharged as harmless aqueous sodium persulfate solution, NA2SO3+H2SO3=NAHSO3, NAHSO3+NAOH=2NA2SO3+2H2O, NA2SO3+1/2O2=NA2SO4.
In water tank bottom there is provided sewage draining exit, by sewage draining exit so that reacted sewage discharge, a kind of optimization technique side Case, sewage draining exit connection is provided with electromagnetic valve, is easy to control the discharge of sludge by electromagnetic valve.
In order that alkali lye and flue gas are fully contacted, packing layer is provided with purifying column tower body, filler uses Pall ring Or Raschig ring structure, filler uses polypropylene material, increases the contact area of shower water and waste gas, improve clean-up effect, be Facilitate the addition and exclusion of filler, a kind of optimal technical scheme on described purifying column tower body is also provided with filler import With filler outlet.
Waste gas outlet is provided with purifying column tower body top, the waste gas handled by packing layer is entered by waste gas outlet Alkali lye pond, alkali lye pond uses rectangular parallelepiped structure form, calcium hydroxide is provided with alkali lye pond, by calcium hydroxide so that dioxy Change the further purified treatment of sulphur.
Air outlet slit is provided with alkali lye pond, air outlet slit is connected to chimney by pipeline, is handled by alkali lye pond Air is discharged by chimney, and is provided with air exhauster in chimney lower end, and power is provided for air discharge by air exhauster.
A kind of optimal technical scheme, in order to ensure air quality, air quality detector is provided with chimney device top With rain cap structure, air quality detector is easy to detection discharge air quality.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair Equivalent structure or equivalent flow conversion that bright specification and accompanying drawing content are made, or directly or indirectly it is used in other related skills Art field, is included within the scope of the present invention.

Claims (4)

1. a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant, it is characterised in that including:Purifying column tower body, purifying column tower body uses cylinder knot Configuration formula, in purifying column tower body lower end, connection is provided with water tank, and water tank is rectangular parallelepiped structure form, connects and sets in water tank lower end Base, purifying column tower body uses double-layer structure form, and internal layer uses polypropylene material, and outer layer uses metal framework supporting layer, It is provided with flue gas mouthful on purifying column tower body sidewall, enters flue gas mouthful and power-plant flue gas outlet is connected to by pipeline, in purification Tower tower body upper end is provided with mouth spray, and mouth spray is connected to water tank by pipeline, and the liquid of water tank is entering spray by pipeline Pipe, sprays in mouth spray, and connection is provided with pumping motor between mouth spray and the pipeline of water tank, is to realize by pumping motor Shower water provides circulation power, and dosing tank is connected to by circulating line on water tank, and dosing tank is rectangular parallelepiped structure form, NAOH alkali liquor inlets are provided with dosing tank, pass through mouth spray so that the sulfur dioxide in flue gas is contacted with water, sulfurous is generated Acid, SO2+H2O->H2SO3, NAOH desulphurization stage reason with to be alkaline matter with sulfur dioxide be dissolved in water generates sulfurous acid solution and enter Row acid-base neutralization reaction, NA2SO3 and H2SO3 further reacts generation NAHSO3, NAHSO3 and accelerates generation sub- with NAOH reactions again Sodium sulphate;The sodium sulfite of generation is recycled as absorbent, untapped after peroxidating, is used as harmless sodium sulphate water Solution discharge, NA2SO3+H2SO3=NAHSO3, NAHSO3+NAOH=2NA2SO3+2H2O, NA2SO3+1/2O2=NA2SO4, Water tank bottom is provided with sewage draining exit, by sewage draining exit so that reacted sewage discharge, in order that alkali lye and flue gas fully connect Touch, packing layer is provided with purifying column tower body, filler uses Pall ring or Raschig ring structure, and filler uses polypropylene material Material, is provided with waste gas outlet, the waste gas handled by packing layer enters alkali lye by waste gas outlet on purifying column tower body top Pond, alkali lye pond uses rectangular parallelepiped structure form, and calcium hydroxide is provided with alkali lye pond, and air is provided with alkali lye pond and is gone out Mouthful, air outlet slit is connected to chimney by pipeline, and the air handled by alkali lye pond is discharged by chimney, and in chimney lower end There is provided air exhauster, power is provided by air exhauster for air discharge.
2. a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant according to claim 1, it is characterised in that sewage draining exit connection is provided with electromagnetism Valve, is easy to control the discharge of sludge by electromagnetic valve.
3. a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant according to claim 1, it is characterised in that also set up on purifying column tower body Filler import and filler outlet.
4. a kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant according to claim 1, it is characterised in that be provided with chimney device top Air quality detector and rain cap structure.
CN201710437956.1A 2017-06-12 2017-06-12 A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant Pending CN107185378A (en)

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CN201710437956.1A CN107185378A (en) 2017-06-12 2017-06-12 A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant

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Application Number Priority Date Filing Date Title
CN201710437956.1A CN107185378A (en) 2017-06-12 2017-06-12 A kind of Introduction For Flue Gas Desulfarization System Of Electric Power Plant

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107670438A (en) * 2017-10-26 2018-02-09 深圳市贝优通新能源技术开发有限公司 A kind of intelligent exhaust treatment system for preform production equipment
CN109224819A (en) * 2018-11-02 2019-01-18 辽宁新瑞碳材料科技有限公司 A kind of purification method of high temperature furnace sulfur-containing tail gas
CN109224799A (en) * 2018-11-02 2019-01-18 辽宁新瑞碳材料科技有限公司 A kind of purification system of high temperature furnace sulfur-containing tail gas

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105363334A (en) * 2015-11-20 2016-03-02 太仓市振锋化工设备有限公司 Polypropylene exhaust gas packing spray tower
CN105642100A (en) * 2016-03-24 2016-06-08 太仓运权化工防腐设备有限公司 Polypropylene acid mist and waste gas purification tower
CN206027399U (en) * 2016-08-21 2017-03-22 华电电力科学研究院 Novel flue gas desulfurization of thermal power plant device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105363334A (en) * 2015-11-20 2016-03-02 太仓市振锋化工设备有限公司 Polypropylene exhaust gas packing spray tower
CN105642100A (en) * 2016-03-24 2016-06-08 太仓运权化工防腐设备有限公司 Polypropylene acid mist and waste gas purification tower
CN206027399U (en) * 2016-08-21 2017-03-22 华电电力科学研究院 Novel flue gas desulfurization of thermal power plant device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107670438A (en) * 2017-10-26 2018-02-09 深圳市贝优通新能源技术开发有限公司 A kind of intelligent exhaust treatment system for preform production equipment
CN109224819A (en) * 2018-11-02 2019-01-18 辽宁新瑞碳材料科技有限公司 A kind of purification method of high temperature furnace sulfur-containing tail gas
CN109224799A (en) * 2018-11-02 2019-01-18 辽宁新瑞碳材料科技有限公司 A kind of purification system of high temperature furnace sulfur-containing tail gas

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Application publication date: 20170922