CN107185366A - A kind of special boiler of power plant fume environment protection abatement equipment and its method - Google Patents

A kind of special boiler of power plant fume environment protection abatement equipment and its method Download PDF

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Publication number
CN107185366A
CN107185366A CN201710414771.9A CN201710414771A CN107185366A CN 107185366 A CN107185366 A CN 107185366A CN 201710414771 A CN201710414771 A CN 201710414771A CN 107185366 A CN107185366 A CN 107185366A
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CN
China
Prior art keywords
flue gas
slurries
power plant
environment protection
pans
Prior art date
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Pending
Application number
CN201710414771.9A
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Chinese (zh)
Inventor
林海
冯翀
顾娜
朱万方
其他发明人请求不公开姓名
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Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd
Original Assignee
Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd
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Application filed by Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd filed Critical Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd
Priority to CN201710414771.9A priority Critical patent/CN107185366A/en
Publication of CN107185366A publication Critical patent/CN107185366A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/346Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/102Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2045Hydrochloric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2047Hydrofluoric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/12Methods and means for introducing reactants
    • B01D2259/126Semi-solid reactants, e.g. slurries

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention discloses a kind of special boiler of power plant fume environment protection abatement equipment, tower container top is provided with smoke air inlet provided with pans and serous granule cutter, top sidewall, tower container bottom is provided with the flue gas gas outlet connected with flue gas processing device provided with ash-discharging device, bottom sidewall, flue gas processing device is connected with blowdown stack, and pans are connected with the slurry storage tank for the calcium hydroxide slurries that are stored with and connecting pipeline is provided with regulating valve and mass flowmenter;Calcium hydroxide slurries are pumped into pans through slurries, slurries high pressure injects serous granule cutter in pans, the sour gas that slurries enter through serous granule cutter cuts into droplet and smoke air inlet reacts, the solid of reaction generation is discharged through ash-discharging device, reacted gas enters flue gas processing device from flue gas gas outlet, and the gas after being handled through flue gas processing device is discharged from blowdown stack.The present invention can adapt to it is a variety of containing sulphur concentration and adapt to many varying duties of boiler, the need for meeting stable operation.

Description

A kind of special boiler of power plant fume environment protection abatement equipment and its method
Technical field
The present invention relates to a kind of smoke gas treatment technical field, and in particular to a kind of special boiler of power plant fume environment protection, which is administered, to be set Standby and its administering method, is special defects power plant mainly for power plant.Such as biomass electric power plant, the small-sized fire of garbage power plant including part Power power plant.
Background technology
At present, special boiler of power plant tail gas environment protection treating is mainly entered using a variety of tower class containers such as semidry method (CFB), wet methods Row processing;At home in fume environment protection governance approach, the advantage of semidry method is that water requirement is less, but needs boiler to have stable bear Lotus, relatively low sulfur content, and treatment effect is general, operational effect is undesirable;Wet method is relatively wide to boiler flexibility, but needs Boiler smoke is wanted to compare " pure ", although otherwise desulfurized effect is fine, operational effect can be unstable.
The content of the invention
Goal of the invention:Present invention aims at there is provided a kind of special boiler of power plant flue gas ring in view of the shortcomings of the prior art Abatement equipment and its administering method are protected, strong adaptability, running is stable.
Technical scheme:Special boiler of power plant fume environment protection abatement equipment of the present invention, be connected to boiler back end ductwork and Between blowdown stack, including device and flue gas processing device are neutralized, the neutralization device is tower container, during tower container top is provided with Between tank and serous granule cutter, top sidewall be communicated with the smoke air inlet of boiler back end ductwork, tower container bottom is provided with Ash-discharging device, bottom sidewall are provided with the flue gas gas outlet connected with the flue gas processing device, flue gas processing device and discharge cigarette Chimney is connected, and the pans are connected and the slurry storage tank and the centre with the slurry storage tank for the calcium hydroxide slurries that are stored with The connecting pipeline of tank is provided with regulating valve and mass flowmenter;Calcium hydroxide slurries are pumped into the pans, pans through slurries Interior slurries high pressure injects the serous granule cutter, and slurries enter through serous granule cutter cuts into droplet with smoke air inlet The sour gas reaction entered, reaction generation dryness particle is discharged through the ash-discharging device, and reacted gas is from flue gas gas outlet Into the flue gas processing device, the gas after being handled through flue gas processing device is discharged from blowdown stack.
Above-mentioned technical proposal is further improved, the solid content of the calcium hydroxide slurries is 10%.
Further, the cutting accuracy of the slurries cutter is 50um.
Further, the flue gas processing device includes flue, dust arrester, the air-introduced machine being sequentially connected.
Further, the flue be carbon steel material, the dust arrester be fiber bag precipitator, the air-introduced machine be from Wind formula single suction air-introduced machine.
Further, the tower container material quality is that carbon steel applies squama.
Further, provided with double-current spray gun body in the tower container.
Using the method for the progress smoke gas treatment of above-mentioned special boiler of power plant fume environment protection abatement equipment, including following step Suddenly:
(1)The calcium hydroxide slurries high pressure of solid content 10% is injected into serous granule cutter;
(2)Slurries are reacted through serous granule cutter cuts into 50um droplet with pending flue gas;
(3)The solid of reaction generation is discharged through ash-discharging device, and reacted gas is after dust arrester after-treatment by drawing Blower fan is discharged.
Beneficial effect:Tower upper vessel portion of the present invention injects absorbent, and absorbent is can adjust concentration, in slurries storage Deposit and regulating valve and mass flowmenter are set on the connecting pipeline of tank and pans, can be dense according to flue gas sulfur-bearing by control system Degree carries out Flow-rate adjustment:It is just chain when flue gas sulfur content is high to tune up control valve opening, so that increase the quantity of absorbent, Ensure that depickling reaction is normally carried out, vice versa, so as to realize the SO according to acidic flue gas2Determine with HCL concentration regulation slurries pump Amount input is a variety of containing sulphur concentration to adapt to pans, can adapt to many varying duties of boiler;
Existing many reaction units, such as CFB devices, very sensitive to load variations, regulation needs longer time, it is necessary to accumulate foot Enough beds and the time for setting up thickness of bed layer;Meanwhile, load variations need certain adjustable range, and such as 30% load is to leave the bed Layer is substantially difficult to set up, so that bed stoppage in transit phenomenon of collapsing;The present invention does not have substantially because depickling principle is active atomizing The interference of situation described above, the need for disclosure satisfy that stable operation;The sorrow poisoned in governance process without collapse bed or slurries;Increase Plus fault reaction device disclosure satisfy that the average requirement of environmental administration's smoke emissioning concentration;It disclosure satisfy that non-wastewater discharge requirement; Water consumption very little, also disclosure satisfy that the environmental requirement of northwest water-deficient area power plant in addition to for special power plant.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Embodiment
Technical solution of the present invention is described in detail below by accompanying drawing, but protection scope of the present invention is not limited to The embodiment.
Embodiment 1:Special boiler of power plant fume environment protection abatement equipment as shown in Figure 1, location arrangements are in boiler tail cigarette After gas discharge section, belong to general temperature section, cost is than less expensive, i.e., upstream is that boiler back end ductwork, downstream are blowdown stack, mainly Structure includes neutralizing device, flue 2, dust arrester 3, air-introduced machine 4;Neutralization device is tower container 1, during the top of tower container 1 is provided with Between tank and serous granule cutter, top sidewall be communicated with the smoke air inlet of boiler back end ductwork, the bottom of tower container 1 is provided with Ash-discharging device 5, bottom sidewall are provided with the flue gas gas outlet connected with the flue gas processing device, pans and the calcium hydroxide that is stored with The slurry storage tank connection of slurries, connecting pipeline is provided with regulating valve 6 and mass flowmenter 7;Boiler back end ductwork enters with flue gas Gas port is connected, and flue gas gas outlet is connected through flue 2 with dust arrester 3, and dust arrester 3 is connected through air-introduced machine 4 with air draft chimney;Tower The material of container 1 is that carbon steel applies squama, and flue material is carbon steel, and dust arrester 3 is fiber bag precipitator, and air-introduced machine 4 is centrifugal Single suction air-introduced machine 4, material are carbon steel, and regulating valve 6 is DN150 PN10, the output 4 ~ 20mA signals of mass flowmenter 7.
Slaked lime powder quantitative watering is configured to the calcium hydroxide slurries that solid content is 10%, and calcium hydroxide slurries are sieved through reciprocating sieve After store to slurry storage tank, according to pending flue gas SO2Slurries are quantified by slurries pump, regulating valve with HCL concentration(Observation Mass flowmenter)Pans are sent into, slurries high pressure in pans is injected into serous granule dispenser, slurries are cut through serous granule Device cuts into 50 μm of droplet, and the smoke contacts entered with smoke air inlet react rapidly, the SO in gas2, HCl and other acid Property medium by absorption cleaning, meanwhile, partly with oxygen occur oxidation reaction, make CaSO3It is converted into CaSO4.Main chemical reactions are such as Under:
SO2Absorbed by droplet:SO2+ Ca(OH)2→CaSO3﹢ H2O;
Part SO2Complete following reaction:SO2+ 1/2O2+ Ca(OH)2→CaSO4+ H2O;
With other acidic materials(Such as SO3、HCl、HF)Reaction:
SO3+Ca(OH)2→CaSO4+H2O;
2HCl+Ca(OH)2→CaCl2+H2O;
2HF+Ca(OH)2→CaF2+H2O;
Because calcium hydroxide slurries are cut into superfine small particle droplet, deacidification agent and SO are increased2The specific surface area of contact, Reaction is extremely rapid and has high removing SO2Efficiency.Pass through CFD technical finesses in tower container of the present invention;Ensure to complete anti- Slurries droplet after answering quickly " flash distillation " can generate dry particl, will not cause " wall built-up ".According to cigarette in tower container of the present invention The certain double-current spray gun body of gas parameter setting, can be used in boiler and other failures.
As described above, although the present invention has been represented and described with reference to specific preferred embodiment, it must not be explained For to the limitation of itself of the invention., can be right under the premise of the spirit and scope of the present invention that appended claims are defined are not departed from Various changes can be made in the form and details for it.

Claims (8)

1. a kind of special boiler of power plant fume environment protection abatement equipment, is connected between boiler back end ductwork and blowdown stack, it is special Levy and be:Including neutralizing device and flue gas processing device, the neutralization device is tower container, tower container top provided with pans and Serous granule cutter, top sidewall are communicated with the smoke air inlet of boiler back end ductwork, and tower container bottom is provided with and unloads grey dress Put, bottom sidewall is provided with the flue gas gas outlet connected with the flue gas processing device, flue gas processing device is connected with blowdown stack, The pans connected with the slurry storage tank for the calcium hydroxide slurries that are stored with and the slurry storage tank and the pans company Siphunculus road is provided with regulating valve and mass flowmenter;Calcium hydroxide slurries are pumped into slurries in the pans, pans through slurries High pressure injects the serous granule cutter, the acid that slurries enter through serous granule cutter cuts into droplet and smoke air inlet Property gas reaction, reaction generation dryness particle discharge through the ash-discharging device, reacted gas from flue gas gas outlet entrance The flue gas processing device, the gas after being handled through flue gas processing device is discharged from blowdown stack.
2. the special boiler of power plant fume environment protection abatement equipment according to right 1, it is characterised in that:The calcium hydroxide slurries Solid content is 10%.
3. the special boiler of power plant fume environment protection abatement equipment according to right 1, it is characterised in that:The slurries cutter Cutting accuracy is 50um.
4. the special boiler of power plant fume environment protection abatement equipment according to right 1, it is characterised in that:The flue gas processing device Including the flue, dust arrester, air-introduced machine being sequentially connected.
5. the special boiler of power plant fume environment protection abatement equipment according to right 4, it is characterised in that:The flue is carbon steel material Matter, the dust arrester is fiber bag precipitator, and the air-introduced machine is from wind formula single suction air-introduced machine.
6. the special boiler of power plant fume environment protection abatement equipment according to right 1, it is characterised in that:The tower container material quality is Carbon steel applies squama.
7. the special boiler of power plant fume environment protection abatement equipment according to right 1, it is characterised in that:It is provided with the tower container Double-current spray gun body.
8. according to the smoke treating method of any special boiler of power plant fume environment protection abatement equipment of right 1 to 7, its feature exists In comprising the following steps:
(1)The calcium hydroxide slurries high pressure of solid content 10% is injected into serous granule cutter;
(2)Slurries are reacted through serous granule cutter cuts into 50um droplet with pending flue gas;
(3)The dryness particle of reaction generation is discharged through ash-discharging device, and reacted gas leads to after dust arrester after-treatment Cross air-introduced machine discharge.
CN201710414771.9A 2017-06-05 2017-06-05 A kind of special boiler of power plant fume environment protection abatement equipment and its method Pending CN107185366A (en)

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CN201710414771.9A CN107185366A (en) 2017-06-05 2017-06-05 A kind of special boiler of power plant fume environment protection abatement equipment and its method

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Application Number Priority Date Filing Date Title
CN201710414771.9A CN107185366A (en) 2017-06-05 2017-06-05 A kind of special boiler of power plant fume environment protection abatement equipment and its method

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007236A (en) * 2006-12-22 2007-08-01 清华大学 Preparation method of ultra-fine desulfurizer slurry and device thereof
CN104722181A (en) * 2015-02-04 2015-06-24 绿色动力环保集团股份有限公司 Combined deacidifying and dedusting method and system of domestic garbage incineration flue gas
US20150367282A1 (en) * 2014-06-24 2015-12-24 Alstom Technology Ltd High rotational momentum disperser and use
CN206082151U (en) * 2016-09-23 2017-04-12 上海市机电设计研究院有限公司 Desulfurization and dust removal system of living beings power plant based on two -stage is removed dust
CN207187467U (en) * 2017-06-05 2018-04-06 江苏海澜正和环境科技有限公司 A kind of special boiler of power plant fume environment protection abatement equipment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007236A (en) * 2006-12-22 2007-08-01 清华大学 Preparation method of ultra-fine desulfurizer slurry and device thereof
US20150367282A1 (en) * 2014-06-24 2015-12-24 Alstom Technology Ltd High rotational momentum disperser and use
CN104722181A (en) * 2015-02-04 2015-06-24 绿色动力环保集团股份有限公司 Combined deacidifying and dedusting method and system of domestic garbage incineration flue gas
CN206082151U (en) * 2016-09-23 2017-04-12 上海市机电设计研究院有限公司 Desulfurization and dust removal system of living beings power plant based on two -stage is removed dust
CN207187467U (en) * 2017-06-05 2018-04-06 江苏海澜正和环境科技有限公司 A kind of special boiler of power plant fume environment protection abatement equipment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
滕斌: "半干法烟气脱硫的实验及机理研究", 《中国博士学位论文全文数据库》 *

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Application publication date: 20170922

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