CN107177125A - Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof - Google Patents
Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof Download PDFInfo
- Publication number
- CN107177125A CN107177125A CN201710430891.8A CN201710430891A CN107177125A CN 107177125 A CN107177125 A CN 107177125A CN 201710430891 A CN201710430891 A CN 201710430891A CN 107177125 A CN107177125 A CN 107177125A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- consumption
- preparation
- high temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof, the preparation method includes：1) sodium hydroxide, sodium metasilicate and water are mixed to form high aqueous slkali, then attapulgite, flyash, carbon fiber is added in high aqueous slkali and is stirred, filters to take filter cake to obtain modified coal ash；2) PVC, ABA, Arabic gum, dimethyl silicone polymer, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nano-glass slag and modified coal ash are kneaded that Aero-Space high temperature-resistant cable insulating composite material is made.The composite has excellent insulating properties and high temperature resistant, and the preparation method process is simple, raw material is easy to get.
Description
Technical field
The present invention relates to cable material, in particular it relates to Aero-Space high temperature-resistant cable insulating composite material and its system
Preparation Method.
Background technology
Cable is mainly made up of following four part.Conductor wire core：It is made of high conductivity material (copper or aluminium).According to laying
Requirement of the use condition to cable softness, every core may be formed by solid conductor or multiple conducting wires are stranded；Insulating barrier：
Insulating materials as cable should have high insulaion resistance, high breakdown field strength, low dielectric loss and low Jie
Electric constant.Sealing sheath：Insulated wire cores are protected from the damage of machinery, moisture, moisture, chemical substance, light etc..For moisture-sensitive
Insulation, it is general to use lead or aluminium extrusion sealing sheath；Protect coating：To protect sealing sheath from mechanical damage.
Although existing insulating layer material disclosure satisfy that existing demand, but partial cables need the ring in higher temperature
Worked in border, and then cause its mechanical property produces larger change and even produces to ftracture to make the work that it is difficult to play protection
With.
The content of the invention
, should it is an object of the invention to provide a kind of Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof
Composite has excellent insulating properties and resistance to elevated temperatures, and the preparation method process is simple, raw material is easy to get.
To achieve these goals, the invention provides a kind of system of Aero-Space with high temperature-resistant cable insulating composite material
Preparation Method, including：
1) sodium hydroxide, sodium metasilicate and water are mixed to form high aqueous slkali, then by attapulgite, flyash, carbon fiber
Add in high aqueous slkali and be stirred, filter to take filter cake to obtain modified coal ash；
2) by PVC (polyvinyl chloride), ABA (acrylonitrile-butadiene-acrylate copolymer), Arabic gum, poly dimethyl
Siloxanes, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nano-glass slag and modified coal ash are kneaded to be made
Aero-Space high temperature-resistant cable insulating composite material.
Present invention also offers a kind of Aero-Space high temperature-resistant cable insulating composite material, the Aero-Space high temperature resistant
Cable insulation composite is prepared by above-mentioned preparation method.
By above-mentioned technical proposal, the present invention is obtained multiple by causing under the synergy of each component and each step
Condensation material has excellent insulating properties and resistance to elevated temperatures, and the preparation method process is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in subsequent embodiment part.
Embodiment
The embodiment to the present invention is described in detail below.It should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The end points and any value of disclosed scope are not limited to the accurate scope or value herein, these scopes or
Value should be understood to comprising the value close to these scopes or value.For number range, between the endpoint value of each scope, respectively
It can be combined with each other between the endpoint value of individual scope and single point value, and individually between point value and obtain one or more
New number range, these number ranges should be considered as specific open herein.
The invention provides a kind of preparation method of Aero-Space with high temperature-resistant cable insulating composite material, including：
1) sodium hydroxide, sodium metasilicate and water are mixed to form high aqueous slkali, then by attapulgite, flyash, carbon fiber
Add in high aqueous slkali and be stirred, filter to take filter cake to obtain modified coal ash；
2) by PVC, ABA, Arabic gum, dimethyl silicone polymer, glycerine, o-phthalic acid dibutyl ester, methylcellulose,
Nano-glass slag is kneaded that Aero-Space high temperature-resistant cable insulating composite material is made with modified coal ash.
In the step 1 of above-mentioned preparation method) in, the consumption of each material can be selected in wide scope, but in order that
Obtained composite has excellent insulating properties and resistance to elevated temperatures, it is preferable that in step 1) in, relative to
The flyash of 100 parts by weight, the consumption of sodium hydroxide is 23-57 parts by weight, and the consumption of sodium metasilicate is 5-10 parts by weight, the use of water
Measure as 170-200 parts by weight, the consumption of attapulgite is 18-26 parts by weight, and the consumption of carbon fiber is 5-8 parts by weight.
In the step 1 of above-mentioned preparation method) in, the actual conditions of stirring can be selected in wide scope, but in order to
Make obtained composite that there are excellent insulating properties and resistance to elevated temperatures, it is preferable that in step 1) in, stirring is extremely
Following condition is met less：Whipping temp is 65-80 DEG C, mixing time 5-8h.
In the step 1 of above-mentioned preparation method) in, the actual conditions of mixing can be selected in wide scope, but in order to
Make obtained obtained composite that there are excellent insulating properties and resistance to elevated temperatures, it is preferable that in step 1) in, mix to
Following condition is met less：Mixing temperature is 15-35 DEG C, incorporation time 3-5h.
Meanwhile, in the step 2 of above-mentioned preparation method) in, the consumption of each material can be selected in wide scope, but be
Make obtained composite that there are excellent insulating properties and resistance to elevated temperatures, it is preferable that in step 2) in, relatively
In the PVC relative to 100 parts by weight, ABA consumption is 60-71 parts by weight, and the consumption of Arabic gum is 41-46 parts by weight, is gathered
The consumption of dimethyl siloxane is 14-17 parts by weight, and the consumption of glycerine is 41-55 parts by weight, the use of o-phthalic acid dibutyl ester
Measure as 65-77 parts by weight, the consumption of methylcellulose is 9-17 parts by weight, and the consumption of nano-glass slag is 3-5 parts by weight, modified
The consumption of flyash is 25-36 parts by weight.
In the step 2 of above-mentioned preparation method) in, the actual conditions of mixing can be selected in wide scope, but in order to
Make obtained composite that there are excellent insulating properties and resistance to elevated temperatures, it is preferable that in step 2) in, mixing is extremely
Following condition is met less：Melting temperature is 215-220 DEG C, mixing time 4-6h.
In the step 2 of above-mentioned preparation method) in, PVC and ABA molecular weight can be selected in wide scope, but be
Make obtained composite that there are excellent insulating properties and resistance to elevated temperatures, it is preferable that PVC weight average molecular weight
For 6000-8000, ABA weight average molecular weight is 2000-4000.
Present invention also offers a kind of Aero-Space high temperature-resistant cable insulating composite material, the Aero-Space high temperature resistant
Cable insulation composite is prepared by above-mentioned preparation method.
The present invention will be described in detail by way of examples below.
Embodiment 1
1) sodium hydroxide, sodium metasilicate and water are formed into high aqueous slkali in mixing 1.5h at 25 DEG C, then by attapulgite, powder
Coal ash, carbon fiber add in high aqueous slkali and in stirred at 70 DEG C 6h, filter to take filter cake with obtain modified coal ash (flyash,
Sodium hydroxide, sodium metasilicate and water, attapulgite, the weight ratio of carbon fiber are 100：25：8：190：22：7)；
2) by PVC (weight average molecular weight is 6000-8000), ABA (weight average molecular weight is 2000-4000), Arabic gum, poly-
Dimethyl siloxane, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nano-glass slag and modified coal ash are according to 100：
65：45：16：50：70：15：4：30 weight ratio is insulated again in kneading 5h at 218 DEG C so that Aero-Space high temperature-resistant cable is made
Condensation material A1.
Embodiment 2
1) sodium hydroxide, sodium metasilicate and water are formed into high aqueous slkali in mixing 1h at 15 DEG C, then by attapulgite, fine coal
Ash, carbon fiber are added in high aqueous slkali and in stirring 5h at 65 DEG C, filter to take filter cake to obtain modified coal ash (flyash, hydrogen
Sodium oxide molybdena, sodium metasilicate and water, attapulgite, the weight ratio of carbon fiber are 100：21：5：170：18：5)；
2) by PVC (weight average molecular weight is 6000-8000), ABA (weight average molecular weight is 2000-4000), Arabic gum, poly-
Dimethyl siloxane, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nano-glass slag and modified coal ash are according to 100：
60：41：14：41：65：9：3：25 weight ratio is insulated again in kneading 4h at 215 DEG C so that Aero-Space high temperature-resistant cable is made
Condensation material A2.
Embodiment 3
1) sodium hydroxide, sodium metasilicate and water are formed into high aqueous slkali in mixing 2h at 35 DEG C, then by attapulgite, fine coal
Ash, carbon fiber are added in high aqueous slkali and in stirring 8h at 80 DEG C, filter to take filter cake to obtain modified coal ash (flyash, hydrogen
Sodium oxide molybdena, sodium metasilicate and water, attapulgite, the weight ratio of carbon fiber are 100：27：10：200：26：8)；
2) by PVC (weight average molecular weight is 6000-8000), ABA (weight average molecular weight is 2000-4000), Arabic gum, poly-
Dimethyl siloxane, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nano-glass slag and modified coal ash are according to 100：
71：46：17：55：77：17：5：36 weight ratio is insulated again in kneading 6h at 220 DEG C so that Aero-Space high temperature-resistant cable is made
Condensation material A3.
Comparative example 1
Method according to embodiment 1 carries out that composite B1 is made, unlike, step 1) in flyash is not used.
Comparative example 2
Method according to embodiment 1 carries out that composite B2 is made, unlike, step 1) in attapulgite is not used.
Comparative example 3
Method according to embodiment 1 carries out that composite B3 is made, unlike, step 1) in carbon fiber is not used.
Comparative example 4
Method according to embodiment 1 carries out that composite B4 is made, unlike, step 1) in flyash is not used and recessed
Convex rod soil.
Comparative example 5
Method according to embodiment 1 carries out that composite B4 is made, unlike, step 1) in carbon fiber and powder is not used
Coal ash.
Comparative example 6
Method according to embodiment 1 carries out that composite B4 is made, unlike, step 2) in modified fine coal is not used
Ash.
Detect example 1
Detect the specific insulation (R/ Ω m) of above-mentioned composite and detect its high temperature deformation temperature (DEG C), with multiple
On the basis of compression strength during 25 DEG C of condensation material, its compression strength then is detected in hot conditions, once the change of compression strength
Change difference and reach that 10% temperature then now is high temperature deformation temperature (DEG C).
Table 1
| R(1014Ω·m) | High temperature deformation temperature (DEG C) | |
| A1 | 6.45 | 262 |
| A2 | 6.38 | 258 |
| A3 | 6.46 | 254 |
| B1 | 5.67 | 238 |
| B2 | 5.58 | 236 |
| B3 | 4.67 | 178 |
| B4 | 4.22 | 156 |
| B5 | 4.26 | 145 |
| B6 | 3.78 | 138 |
By above-described embodiment, comparative example and detection example, the composite that the present invention is provided has excellent insulation
Performance and resistance to elevated temperatures.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (8)
1. a kind of Aero-Space preparation method of high temperature-resistant cable insulating composite material, it is characterised in that including：
1) sodium hydroxide, sodium metasilicate and water are mixed to form high aqueous slkali, then added attapulgite, flyash, carbon fiber
In the high aqueous slkali and it is stirred, filters to take filter cake to obtain modified coal ash；
2) by PVC, ABA, Arabic gum, dimethyl silicone polymer, glycerine, o-phthalic acid dibutyl ester, methylcellulose, nanometer
Glass dregs are kneaded that the Aero-Space high temperature-resistant cable insulating composite material is made with the modified coal ash.
2. preparation method according to claim 1, wherein, in step 1) in, relative to the fine coal of 100 parts by weight
Ash, the consumption of the sodium hydroxide is 23-57 parts by weight, and the consumption of the sodium metasilicate is 5-10 parts by weight, the consumption of the water
For 170-200 parts by weight, the consumption of the attapulgite is 18-26 parts by weight, and the consumption of the carbon fiber is 5-8 parts by weight.
3. preparation method according to claim 2, wherein, in step 1) in, the stirring at least meets following condition：Stir
It is 65-80 DEG C, mixing time 5-8h to mix temperature.
4. preparation method according to claim 2, wherein, in step 1) in, the mixing at least meets following condition：It is mixed
It is 15-35 DEG C, incorporation time 3-5h to close temperature.
5. the preparation method according to claim 1-4, wherein, in step 2) in, relative to the institute relative to 100 parts by weight
PVC is stated, the consumption of the ABA is 60-71 parts by weight, and the consumption of the Arabic gum is 41-46 parts by weight, the poly dimethyl
The consumption of siloxanes is 14-17 parts by weight, and the consumption of the glycerine is 41-55 parts by weight, the o-phthalic acid dibutyl ester
Consumption is 65-77 parts by weight, and the consumption of the methylcellulose is 9-17 parts by weight, and the consumption of the nano-glass slag is 3-5
Parts by weight, the consumption of the modified coal ash is 25-36 parts by weight.
6. preparation method according to claim 5, wherein, in step 2) in, the mixing at least meets following condition：It is mixed
It is 215-220 DEG C, mixing time 4-6h to refine temperature.
7. the preparation method according to claim 5 or 6, wherein, the weight average molecular weight of the PVC is 6000-8000, described
ABA weight average molecular weight is 2000-4000.
8. a kind of Aero-Space high temperature-resistant cable insulating composite material, it is characterised in that Aero-Space high temperature resistant electricity
Cable insulating composite material is prepared by the preparation method described in any one in claim 1-7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710430891.8A CN107177125A (en) | 2017-06-09 | 2017-06-09 | Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710430891.8A CN107177125A (en) | 2017-06-09 | 2017-06-09 | Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107177125A true CN107177125A (en) | 2017-09-19 |
Family
ID=59836095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710430891.8A Pending CN107177125A (en) | 2017-06-09 | 2017-06-09 | Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107177125A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003643A (en) * | 2017-11-28 | 2018-05-08 | 安徽华源电缆集团有限公司 | A kind of high-strength tensile layer cable material |
| CN109825006A (en) * | 2019-03-05 | 2019-05-31 | 广东南缆电缆有限公司 | A kind of aerospace high temperature-resistant cable insulating composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911453A (en) * | 2012-09-24 | 2013-02-06 | 冠益实业股份有限公司 | High-impact PVC (polyvinyl chloride)/ABS (poly(acrylonitrile butadiene styrene)) tubing and preparation method thereof |
| CN102993523A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | Buoy communication cable sheath insulating material for ships and preparation method thereof |
| CN105504429A (en) * | 2016-03-01 | 2016-04-20 | 苏州科茂电子材料科技有限公司 | Insulated highly-fire-retardant cable sheath material and preparation method thereof |
-
2017
- 2017-06-09 CN CN201710430891.8A patent/CN107177125A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911453A (en) * | 2012-09-24 | 2013-02-06 | 冠益实业股份有限公司 | High-impact PVC (polyvinyl chloride)/ABS (poly(acrylonitrile butadiene styrene)) tubing and preparation method thereof |
| CN102993523A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | Buoy communication cable sheath insulating material for ships and preparation method thereof |
| CN105504429A (en) * | 2016-03-01 | 2016-04-20 | 苏州科茂电子材料科技有限公司 | Insulated highly-fire-retardant cable sheath material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003643A (en) * | 2017-11-28 | 2018-05-08 | 安徽华源电缆集团有限公司 | A kind of high-strength tensile layer cable material |
| CN109825006A (en) * | 2019-03-05 | 2019-05-31 | 广东南缆电缆有限公司 | A kind of aerospace high temperature-resistant cable insulating composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103992608A (en) | High impact polystyrene sheath material for power cords and preparation method thereof | |
| CN104829937A (en) | Sheath material for aerospace cables and manufacturing method thereof | |
| CN107698906A (en) | Undersea detection steady phase high-strength composite cable and preparation method thereof | |
| CN104031309B (en) | A kind of electric wire and cable jacket composite flame-proof material | |
| CN103928172B (en) | Fire retardant crosslinked polyethylene insulated power cable | |
| CN107177125A (en) | Aero-Space high temperature-resistant cable insulating composite material and preparation method thereof | |
| CN104008799A (en) | Fireproof computer cable supported by framework | |
| CN107857959A (en) | Undersea detection high-strength composite cable and preparation method thereof | |
| CN106700510A (en) | Nylon cable protective sleeve based on bentonite modification and preparation method thereof | |
| CN107337871A (en) | Army material weather proof cable insulating composite material and preparation method thereof | |
| CN105802174B (en) | A kind of makrolon material and its preparation method and application | |
| CN104078140A (en) | Halogen- and phosphorus-free flame-retardant insulated wire and halogen- and phosphorus-free flame-retardant insulated cable | |
| CN103928159B (en) | fireproof power cable | |
| JP2017155093A (en) | Polyvinyl chloride resin composition, and wire and cable prepared therewith | |
| CN104021863A (en) | High temperature and high voltage resisting cable | |
| CN107459703A (en) | Field cable sheath and preparation method thereof | |
| CN103928137B (en) | High temperature resistant segment conductor-core cable | |
| CN108485048A (en) | A kind of cable cover(ing) sizing material and preparation method thereof | |
| CN103928132A (en) | Flame-resistant cable for oil platform | |
| KR101717646B1 (en) | Environmental friendly non-toxic flame retardant high density polyethylene compound for extrusion sheath of ultra high-voltage cable and a method of manufacturing | |
| CN107141651A (en) | Army material high-strength cable insulating composite material and preparation method thereof | |
| CN106751283A (en) | Polyvinyl alcohol epoxy resin cable insulation material and preparation method thereof | |
| CN106683798A (en) | Kaolin modification-based nylon cable protection sleeve and fabrication method thereof | |
| JP2012038648A (en) | Vinyl insulating vinyl sheath cable | |
| JP2016197560A (en) | Electric wire for vehicle and wire harness using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170919 |