CN107176843A - A kind of light fire brick - Google Patents

A kind of light fire brick Download PDF

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Publication number
CN107176843A
CN107176843A CN201710331560.9A CN201710331560A CN107176843A CN 107176843 A CN107176843 A CN 107176843A CN 201710331560 A CN201710331560 A CN 201710331560A CN 107176843 A CN107176843 A CN 107176843A
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parts
fire brick
light fire
mine tailing
eutectic
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CN201710331560.9A
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Inventor
袁海强
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Changxing County Meishan Industrial Furnace Co Ltd
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Changxing County Meishan Industrial Furnace Co Ltd
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Priority to CN201710331560.9A priority Critical patent/CN107176843A/en
Publication of CN107176843A publication Critical patent/CN107176843A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3281Copper oxides, cuprates or oxide-forming salts thereof, e.g. CuO or Cu2O
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3289Noble metal oxides
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
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    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient

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  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The present invention relates to a kind of light fire brick, it is made up of the material of following mass fraction:35 parts of 15 25 parts of high viscous Concave-convex clay rod powder, 25 30 parts of Concave-convex clay rod mine tailing, 45 50 parts of pyroclastic rock mixture, 25 30 parts of diatomite mine tailing, 18 25 parts of expanded vermiculite, 15 18 parts of gangue, 15 18 parts of bentonite mine tailing, 78 parts of sintering aid, 15 parts of bonding agent and carboxymethyl ammonium acrylate.The present invention improves the heat-resisting quantity of refractory material, anti-wear performance, thermal shock resistance, thermal conductivity, high temperature corrosion etc., extends the service life of refractory material.

Description

A kind of light fire brick
Technical field
The present invention relates to field of material technology, especially a kind of refractory material.
Background technology
Refractory material refers to that refractoriness is not less than 1500 DEG C of a class inorganic non-metallic material, and refractoriness refers to refractory material Bullet sample is in the case of no loading, and resistance high temperature action is without softening molten Celsius temperature.Refractory material includes Natural crystal and manufactured according to certain industrial requirements, with certain mechanical behavior under high temperature, good volume stability, and And material necessary to be various high temperature resistant equipment.Refractory material is widely used in chemical industry, oil, metallurgy, machine-building, power etc. Industrial circle, consumption is maximum especially in metallurgical industry, and irreplaceable important function is played in hot industry production development.
Critical component during refractory material is equipped as hot industry is to realize the guarantee that high temperature resistant equipment runs well, closely It is continuous to refractory material over year to propose new requirement, and existing refractory material high temperature corrosion and inoxidizability are undesirable, surely Qualitative difference, usage cycles are shorter, therefore, seek a kind of new refractory material, the service life for extending high temperature resistant equipment There is great meaning.
The content of the invention
It is an object of the invention to provide a kind of light fire brick, heat-resisting quantity, the anti-wear performance of refractory material are improved, heat Stability, thermal conductivity, high temperature corrosion etc. are shaken, the service life of refractory material is extended.
To achieve these goals, the present invention uses following technical scheme:
A kind of light fire brick, is made up of the material of following mass fraction:15-25 parts of high viscous Concave-convex clay rod powder, concave convex rod 25-30 parts of stone clay mine tailing, 45-50 parts of pyroclastic rock mixture, 25-30 parts of diatomite mine tailing, 18-25 parts of expanded vermiculite, 15-18 parts of gangue, 15-18 parts of bentonite mine tailing, 7-8 parts of sintering aid, 15 parts of bonding agent and carboxymethyl ammonium acrylate 3-5 Part.
Preferably, bonding agent is the mixture of silicate hydrolyzate liquid, magnesium chloride and molasse.
Preferably, bonding agent is put into the silicic acid of 80 parts by weight by the magnesium chloride of 3 parts by weight and the molasse of 15 parts by weight Ethyl ester hydrolyzate and obtain.
Preferably, sintering aid is Rh-B-Si eutectic points oxide and Mn-Cu eutectic point hopcalites, institute It is 6.5-7 to state the quality parts ratio between Rh-B-Si eutectic points oxide and Mn-Cu eutectic point oxides:0.5-0.8.
Preferably, Rh, B and Si mol ratio are 5-10 in wherein described Rh-B-Si eutectic points oxide:42- 62:Mn and Cu mol ratio is 0.2-0.3 in 20-37, the Mn-Cu eutectic points oxide:1.6-2.9.
Preferably, the fusing point of sintering aid is 900-1100 DEG C.
The present invention compared with prior art, improves heat-resisting quantity, the anti-wear performance of refractory material, thermal shock resistance, heat Conductance, high temperature corrosion etc., extend the service life of refractory material.
Embodiment
Hereinafter, the preferred plan for implementing the present invention is illustrated.
The production method of the refractory material of the present invention can be conventional method or following steps:
Matrix component is added in the kneading machines such as edge runner first and carried out after mixed processing, adhesive is added, at 175-200 DEG C Lower mixing 30-45min, then adds sintering aid, is heat-treated under nonoxidizing atmosphere or reducing atmosphere, heat treatment temperature For 1150-1300 DEG C, the time is 55min, and the refractory material of the present invention is obtained after cooling.
Embodiment 1
A kind of light fire brick, is made up of the material of following mass fraction:15 parts of high viscous Concave-convex clay rod powder, attapulgite glue Native 25 parts of mine tailing, 45 parts of pyroclastic rock mixture, 25 parts of diatomite mine tailing, 18 parts of expanded vermiculite, 15 parts of gangue, bentonite 3 parts of 15 parts of mine tailing, 7 parts of sintering aid, 15 parts of bonding agent and carboxymethyl ammonium acrylate.
Bonding agent is put into the silicate hydrolyzate liquid of 80 parts by weight by the magnesium chloride of 3 parts by weight and the molasse of 15 parts by weight And obtain.
Sintering aid is Rh-B-Si eutectic points oxide and Mn-Cu eutectic point hopcalites, the Rh-B-Si Quality parts ratio between eutectic point oxide and Mn-Cu eutectic point oxides is 6.5:0.5.
Rh, B and Si mol ratio are 5 in wherein described Rh-B-Si eutectic points oxide:42:20, the Mn- Mn and Cu mol ratio is 0.2 in Cu eutectic point oxides:1.6.The fusing point of sintering aid is 900 DEG C.
There is at preferable thermal conductivity, 1000 DEG C obtained refractory material heat conduction, which to wash one's face and rinse one's mouth, can reach 35W/ (mk), Mohs Hardness is higher than corundum hardness, and anti-wear performance is 8 times of high-alumina brick.
Embodiment 2
A kind of light fire brick, is made up of the material of following mass fraction:20 parts of high viscous Concave-convex clay rod powder, attapulgite glue Native 28 parts of mine tailing, 47 parts of pyroclastic rock mixture, 27 parts of diatomite mine tailing, 22 parts of expanded vermiculite, 16 parts of gangue, bentonite 4 parts of 17 parts of mine tailing, 8 parts of sintering aid, 15 parts of bonding agent and carboxymethyl ammonium acrylate.
Bonding agent is put into the silicate hydrolyzate liquid of 80 parts by weight by the magnesium chloride of 3 parts by weight and the molasse of 15 parts by weight And obtain.
Sintering aid is Rh-B-Si eutectic points oxide and Mn-Cu eutectic point hopcalites, the Rh-B-Si Quality parts ratio between eutectic point oxide and Mn-Cu eutectic point oxides is 6. 7:0.75.
Rh, B and Si mol ratio are 7 in wherein described Rh-B-Si eutectic points oxide:52:27, the Mn- Mn and Cu mol ratio is 0.25 in Cu eutectic point oxides:1.9.The fusing point of sintering aid is 1000 DEG C.
There is at preferable thermal conductivity, 1000 DEG C obtained refractory material heat conduction, which to wash one's face and rinse one's mouth, can reach 38W/ (mk), Mohs Hardness is higher than corundum hardness, and anti-wear performance is 8.5 times of high-alumina brick.
Embodiment 3
A kind of light fire brick, is made up of the material of following mass fraction:25 parts of high viscous Concave-convex clay rod powder, attapulgite glue Native 30 parts of mine tailing, 50 parts of pyroclastic rock mixture, 30 parts of diatomite mine tailing, 25 parts of expanded vermiculite, 18 parts of gangue, bentonite 5 parts of 18 parts of mine tailing, 8 parts of sintering aid, 15 parts of bonding agent and carboxymethyl ammonium acrylate.
Bonding agent is put into the silicate hydrolyzate liquid of 80 parts by weight by the magnesium chloride of 3 parts by weight and the molasse of 15 parts by weight And obtain.
Sintering aid is Rh-B-Si eutectic points oxide and Mn-Cu eutectic point hopcalites, the Rh-B-Si Quality parts ratio between eutectic point oxide and Mn-Cu eutectic point oxides is 7:0.8.
Rh, B and Si mol ratio are 10 in wherein described Rh-B-Si eutectic points oxide: 62:37, the Mn- Mn and Cu mol ratio is 0.3 in Cu eutectic point oxides: 2.9.The fusing point of sintering aid is 1100 DEG C.
There is at preferable thermal conductivity, 1000 DEG C obtained refractory material heat conduction, which to wash one's face and rinse one's mouth, can reach 37W/ (mk), Mohs Hardness is higher than corundum hardness, and anti-wear performance is 9 times of high-alumina brick.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be defined by claim.

Claims (6)

1. a kind of light fire brick, it is characterised in that be made up of the material of following mass fraction:High viscous Concave-convex clay rod powder 15-25 parts, it is 25-30 parts of Concave-convex clay rod mine tailing, 45-50 parts of pyroclastic rock mixture, 25-30 parts of diatomite mine tailing, swollen Swollen vermiculite 18-25 parts, 15-18 parts of gangue, 15-18 parts of bentonite mine tailing, 7-8 parts of sintering aid, 15 parts of bonding agent and carboxylic first 3-5 parts of base ammonium acrylate.
2. a kind of light fire brick according to claim 1, it is characterised in that bonding agent is silicate hydrolyzate liquid, chlorine Change the mixture of magnesium and molasse.
3. a kind of light fire brick according to claim 2, it is characterised in that bonding agent by 3 parts by weight magnesium chloride with The molasse of 15 parts by weight puts into the silicate hydrolyzate liquid of 80 parts by weight and obtained.
4. a kind of light fire brick according to claim 1, it is characterised in that sintering aid is Rh-B-Si eutectic point oxygen Compound and Mn-Cu eutectic point hopcalites, the Rh-B-Si eutectic points oxide and Mn-Cu eutectic points oxide it Between quality parts ratio be 6.5-7:0.5-0.8.
5. a kind of light fire brick according to claim 4, it is characterised in that wherein described Rh-B-Si eutectic points oxidation Rh, B and Si mol ratio are 5-10 in thing:42-62:Mn and Cu in 20-37, the Mn-Cu eutectic points oxide Mol ratio be 0.2-0.3:1.6-2.9.
6. a kind of light fire brick according to claim 5, it is characterised in that the fusing point of sintering aid is 900-1100 ℃。
CN201710331560.9A 2017-05-11 2017-05-11 A kind of light fire brick Pending CN107176843A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4963191A (en) * 1989-08-16 1990-10-16 Solid Flue Chimney Systems, Inc. Cementing compositions
CN101657304A (en) * 2007-02-07 2010-02-24 元进国际有限公司 Be used to make the preparation of the refractory material of steel ingot
CN102863235A (en) * 2012-09-30 2013-01-09 许庆华 Method for producing attapulgite volcaniclastic rock light refractory aggregate
CN104072158A (en) * 2014-06-12 2014-10-01 浙江长兴电子厂有限公司 Aluminum nitride sintering auxiliary agent and preparation method thereof as well as preparation method of aluminum nitride ceramic substrate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4963191A (en) * 1989-08-16 1990-10-16 Solid Flue Chimney Systems, Inc. Cementing compositions
CN101657304A (en) * 2007-02-07 2010-02-24 元进国际有限公司 Be used to make the preparation of the refractory material of steel ingot
CN102863235A (en) * 2012-09-30 2013-01-09 许庆华 Method for producing attapulgite volcaniclastic rock light refractory aggregate
CN104072158A (en) * 2014-06-12 2014-10-01 浙江长兴电子厂有限公司 Aluminum nitride sintering auxiliary agent and preparation method thereof as well as preparation method of aluminum nitride ceramic substrate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
袁林等: "《绿色耐火材料》", 31 January 2015, 中国建材工业出版社 *

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Application publication date: 20170919