CN107175854B - 一种复合贴面材料 - Google Patents

一种复合贴面材料 Download PDF

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CN107175854B
CN107175854B CN201710391514.8A CN201710391514A CN107175854B CN 107175854 B CN107175854 B CN 107175854B CN 201710391514 A CN201710391514 A CN 201710391514A CN 107175854 B CN107175854 B CN 107175854B
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罗峰
张瑞洋
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Baisheng New Materials Co Ltd
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    • B32—LAYERED PRODUCTS
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/16—Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract

本发明公开了一种复合贴面材料，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；所述耐磨层由以下质量百分比的组分制成：EPDM：40％‑70％、PP：25％‑60％、过氧化物：1‑3％、交联改性剂：1‑3％；所述基体层由POE加入发泡剂、交联剂DCP微发泡而成；所述接着层为织物。通过将耐磨的聚烯烃弹性体复合在发泡的POE材料上，从而实现了表层耐磨耐冲击，基体层柔软的技术效果。

Description

一种复合贴面材料
技术领域
本发明涉及材料技术领域，具体公开了一种复合贴面材料。
背景技术
随着人们生活水平的提高，经常需要用到贴面装饰材料用于家具贴面装饰、墙壁贴面装饰灯，现有的贴面材料都讲究美观度从而忽略了材料本身的耐磨性、耐冲击强度、防水性能等，不少贴面材料不耐磨，特别是人手经常触摸的家具表面、墙壁表面等部位，经常会发生磨损，影响整体装饰效果。
发明内容
基于此，有必要针对现有技术问题，提供一种复合贴面材料，通过将耐磨的聚烯烃弹性体复合在发泡的POE材料上，从而实现了表层耐磨耐冲击，基体层柔软的技术效果。
为实现上述技术目的，本发明采用的技术方案如下：
一种复合贴面材料，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；
所述耐磨层由以下质量百分比的组分制成：
EPDM：40％-70％、
PP：25％-60％、
过氧化物：1-3％、
交联改性剂：1-3％；
所述基体层由POE加入发泡剂、交联剂DCP微发泡而成；
所述接着层为织物。
优选地，所述基体层发泡倍率为5-15倍。
优选地，所述PP中含有不高于50％重量的回收料。
优选地，所述过氧化物选用DCP。
优选地，所述交联改性剂选用多官能环氧树脂。
本发明的有益效果为：本发明公开一种复合贴面材料，通过动态硫化形成的聚烯烃弹性体作为表层耐磨层，大幅提升表面的抗冲击耐磨性能，同时通过发泡POE作为基体层，可保证主体材料的柔软度，从而解决了现有技术中贴面材料不耐冲击不耐磨的技术问题。
具体实施方式
为能进一步了解本发明的特征、技术手段以及所达到的具体目的、功能，下面具体实施方式对本发明作进一步详细描述。
实施例一
一种复合贴面材料，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；
所述耐磨层由以下质量百分比的组分制成：
EPDM：40％、
PP：56％、
过氧化物DCP：1％、
交联改性剂多官能基环氧树脂：3％；
所述基体层由POE加入发泡剂、交联剂DCP微发泡10倍而成；
所述接着层为织物。
实施例二
一种复合贴面材料，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；
所述耐磨层由以下质量百分比的组分制成：
EPDM：70％、
PP：26％、
过氧化物DCP：3％、
交联改性剂多官能基环氧树脂：1％；
所述基体层由POE加入发泡剂、交联剂DCP微发泡20倍而成；
所述接着层为织物。
实施例三
一种复合贴面材料，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；
所述耐磨层由以下质量百分比的组分制成：
EPDM：50％、
PP：25％、
过氧化物DCP：2.5％、
交联改性剂多官能基环氧树脂：2.5％；
所述基体层由POE加入发泡剂、交联剂DCP微发泡15倍而成；
所述接着层为织物。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。

Claims (2)

1.一种复合贴面材料，其特征在于，由上至下依次包括耐磨层、基体层和接着层，所述耐磨层与基体层共挤成型，所述基体层与所述接着层热熔胶粘接；
所述耐磨层由以下质量百分比的组分制成：
EPDM：40％-70％、
PP：25％-60％、
过氧化物：1-3％、
交联改性剂：1-3％；
所述基体层由POE加入发泡剂、交联剂DCP微发泡而成,且发泡倍率为10-20倍；
所述接着层为织物；
所述过氧化物选用DCP；
所述交联改性剂选用多官能环氧树脂。
2.根据权利要求1所述的一种复合贴面材料，其特征在于，所述PP中含有不高于50％重量的回收料。
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WO2019124387A1 (ja) * 2017-12-20 2019-06-27 大日本印刷株式会社 化粧材及び化粧材の製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1250458A (zh) * 1997-01-10 2000-04-12 波利亚里斯聚合物股份公司 挤出贴面结构
CN101020770A (zh) * 2007-03-15 2007-08-22 上海交通大学 乙烯－辛烯共聚物发泡材料的制备方法
CN101973481A (zh) * 2010-09-29 2011-02-16 吴江市康龙橡塑制品有限公司 一种耐久型扶手带
CN203957468U (zh) * 2013-06-03 2014-11-26 大日本印刷株式会社 发泡壁纸
CN205653666U (zh) * 2016-03-23 2016-10-19 上海远冠橡塑制品有限公司 一种3d立体墙贴

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008038522A1 (de) * 2008-08-20 2010-02-25 Bayer Materialscience Ag Kunststoffverbundformteil im Drei-Schicht-Aufbau

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1250458A (zh) * 1997-01-10 2000-04-12 波利亚里斯聚合物股份公司 挤出贴面结构
CN101020770A (zh) * 2007-03-15 2007-08-22 上海交通大学 乙烯－辛烯共聚物发泡材料的制备方法
CN101973481A (zh) * 2010-09-29 2011-02-16 吴江市康龙橡塑制品有限公司 一种耐久型扶手带
CN203957468U (zh) * 2013-06-03 2014-11-26 大日本印刷株式会社 发泡壁纸
CN205653666U (zh) * 2016-03-23 2016-10-19 上海远冠橡塑制品有限公司 一种3d立体墙贴

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