CN107175854B - 一种复合贴面材料 - Google Patents

一种复合贴面材料 Download PDF

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CN107175854B
CN107175854B CN201710391514.8A CN201710391514A CN107175854B CN 107175854 B CN107175854 B CN 107175854B CN 201710391514 A CN201710391514 A CN 201710391514A CN 107175854 B CN107175854 B CN 107175854B
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layer
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composite surface
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CN107175854A (zh
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罗峰
张瑞洋
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Baisheng New Materials Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/16Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2312/00Crosslinking

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

本发明公开了一种复合贴面材料,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;所述耐磨层由以下质量百分比的组分制成:EPDM:40%‑70%、PP:25%‑60%、过氧化物:1‑3%、交联改性剂:1‑3%;所述基体层由POE加入发泡剂、交联剂DCP微发泡而成;所述接着层为织物。通过将耐磨的聚烯烃弹性体复合在发泡的POE材料上,从而实现了表层耐磨耐冲击,基体层柔软的技术效果。

Description

一种复合贴面材料
技术领域
本发明涉及材料技术领域,具体公开了一种复合贴面材料。
背景技术
随着人们生活水平的提高,经常需要用到贴面装饰材料用于家具贴面装饰、墙壁贴面装饰灯,现有的贴面材料都讲究美观度从而忽略了材料本身的耐磨性、耐冲击强度、防水性能等,不少贴面材料不耐磨,特别是人手经常触摸的家具表面、墙壁表面等部位,经常会发生磨损,影响整体装饰效果。
发明内容
基于此,有必要针对现有技术问题,提供一种复合贴面材料,通过将耐磨的聚烯烃弹性体复合在发泡的POE材料上,从而实现了表层耐磨耐冲击,基体层柔软的技术效果。
为实现上述技术目的,本发明采用的技术方案如下:
一种复合贴面材料,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;
所述耐磨层由以下质量百分比的组分制成:
EPDM:40%-70%、
PP:25%-60%、
过氧化物:1-3%、
交联改性剂:1-3%;
所述基体层由POE加入发泡剂、交联剂DCP微发泡而成;
所述接着层为织物。
优选地,所述基体层发泡倍率为5-15倍。
优选地,所述PP中含有不高于50%重量的回收料。
优选地,所述过氧化物选用DCP。
优选地,所述交联改性剂选用多官能环氧树脂。
本发明的有益效果为:本发明公开一种复合贴面材料,通过动态硫化形成的聚烯烃弹性体作为表层耐磨层,大幅提升表面的抗冲击耐磨性能,同时通过发泡POE作为基体层,可保证主体材料的柔软度,从而解决了现有技术中贴面材料不耐冲击不耐磨的技术问题。
具体实施方式
为能进一步了解本发明的特征、技术手段以及所达到的具体目的、功能,下面具体实施方式对本发明作进一步详细描述。
实施例一
一种复合贴面材料,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;
所述耐磨层由以下质量百分比的组分制成:
EPDM:40%、
PP:56%、
过氧化物DCP:1%、
交联改性剂多官能基环氧树脂:3%;
所述基体层由POE加入发泡剂、交联剂DCP微发泡10倍而成;
所述接着层为织物。
实施例二
一种复合贴面材料,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;
所述耐磨层由以下质量百分比的组分制成:
EPDM:70%、
PP:26%、
过氧化物DCP:3%、
交联改性剂多官能基环氧树脂:1%;
所述基体层由POE加入发泡剂、交联剂DCP微发泡20倍而成;
所述接着层为织物。
实施例三
一种复合贴面材料,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;
所述耐磨层由以下质量百分比的组分制成:
EPDM:50%、
PP:25%、
过氧化物DCP:2.5%、
交联改性剂多官能基环氧树脂:2.5%;
所述基体层由POE加入发泡剂、交联剂DCP微发泡15倍而成;
所述接着层为织物。
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。

Claims (2)

1.一种复合贴面材料,其特征在于,由上至下依次包括耐磨层、基体层和接着层,所述耐磨层与基体层共挤成型,所述基体层与所述接着层热熔胶粘接;
所述耐磨层由以下质量百分比的组分制成:
EPDM:40%-70%、
PP:25%-60%、
过氧化物:1-3%、
交联改性剂:1-3%;
所述基体层由POE加入发泡剂、交联剂DCP微发泡而成,且发泡倍率为10-20倍;
所述接着层为织物;
所述过氧化物选用DCP;
所述交联改性剂选用多官能环氧树脂。
2.根据权利要求1所述的一种复合贴面材料,其特征在于,所述PP中含有不高于50%重量的回收料。
CN201710391514.8A 2017-05-27 2017-05-27 一种复合贴面材料 Active CN107175854B (zh)

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JPWO2019124387A1 (ja) * 2017-12-20 2021-01-28 大日本印刷株式会社 化粧材及び化粧材の製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1250458A (zh) * 1997-01-10 2000-04-12 波利亚里斯聚合物股份公司 挤出贴面结构
CN101020770A (zh) * 2007-03-15 2007-08-22 上海交通大学 乙烯-辛烯共聚物发泡材料的制备方法
CN101973481A (zh) * 2010-09-29 2011-02-16 吴江市康龙橡塑制品有限公司 一种耐久型扶手带
CN203957468U (zh) * 2013-06-03 2014-11-26 大日本印刷株式会社 发泡壁纸
CN205653666U (zh) * 2016-03-23 2016-10-19 上海远冠橡塑制品有限公司 一种3d立体墙贴

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008038522A1 (de) * 2008-08-20 2010-02-25 Bayer Materialscience Ag Kunststoffverbundformteil im Drei-Schicht-Aufbau

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1250458A (zh) * 1997-01-10 2000-04-12 波利亚里斯聚合物股份公司 挤出贴面结构
CN101020770A (zh) * 2007-03-15 2007-08-22 上海交通大学 乙烯-辛烯共聚物发泡材料的制备方法
CN101973481A (zh) * 2010-09-29 2011-02-16 吴江市康龙橡塑制品有限公司 一种耐久型扶手带
CN203957468U (zh) * 2013-06-03 2014-11-26 大日本印刷株式会社 发泡壁纸
CN205653666U (zh) * 2016-03-23 2016-10-19 上海远冠橡塑制品有限公司 一种3d立体墙贴

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