CN107164958A - A kind of tent cloth three-proof finishing agent and preparation method thereof - Google Patents
A kind of tent cloth three-proof finishing agent and preparation method thereof Download PDFInfo
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- CN107164958A CN107164958A CN201710589182.4A CN201710589182A CN107164958A CN 107164958 A CN107164958 A CN 107164958A CN 201710589182 A CN201710589182 A CN 201710589182A CN 107164958 A CN107164958 A CN 107164958A
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- Prior art keywords
- acrylate
- tent cloth
- finishing agent
- proof finishing
- emulsion
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
- C08F220/24—Esters containing halogen containing perhaloalkyl radicals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of tent cloth three-proof finishing agent, include perfluoroalkyl acrylate emulsion by mass fraction：30% 60%；Acrylate modified polyvinyl acetate emulsion：20% 40%；Gelatinized starch：5% 15%.The invention also discloses a kind of preparation method and application of tent cloth three-proof finishing agent.
Description
Technical field
The present invention relates to the fields such as textile dyeing and finishing, chemistry, specially a kind of tent cloth three-proof finishing agent and preparation method thereof.
Background technology
With social development, people's living standard is improved, and is required more and more higher to the water-proof finish of tent, is particularly required
Tent cloth can resistance to hydrostatic pressure, traditional fluorine-containing three-proof finishing agent can assign tent be furnished with well spray waterproof effect, but
It is that stiffness and resistance to hydrostatic pressure effect are less desirable, it would therefore be desirable to a kind of new three-proof finishing agent, to solve to deposit at present
Technical problem.
The content of the invention
The present invention first purpose be：A kind of tent cloth three-proof finishing agent is provided, is allowed to not only there is good spray to prevent
Water effect, with more good resistance to hydrostatic pressure effect.
Realizing the technical scheme of above-mentioned purpose is：A kind of tent cloth three-proof finishing agent, includes perfluoroalkyl by mass fraction
Acrylic acid ester emulsion：30%-60%；Acrylate modified polyvinyl acetate emulsion：20%-40%；Gelatinized starch：5%-
15%.
In a preferred embodiment of the present invention, the perfluoroalkyl acrylate emulsion includes cosolvent by mass fraction：
5%-15%；Compound emulsifying agent：0.5%-5%；Mix monomer：10%-40%；Initiator：0.01%-1%；Deionized water：
50%-80%.
In a preferred embodiment of the present invention, the cosolvent is polyalcohols solvent or alcohol ethers solvent.
In a preferred embodiment of the present invention, the compound emulsifying agent is the emulsifying agent that cation is combined with nonionic.
In a preferred embodiment of the present invention, the initiator is water soluble starter, including ammonium persulfate, persulfuric acid
At least one of potassium, azo diisobutyl amidine hydrochloride.
In a preferred embodiment of the present invention, the mix monomer is included by mass fraction：Perfluoroalkyl hexyl acrylic acid
Ester：20%-70%；Octadecyl acrylate：20%-50%；Process Conditions of Cetane Acrylate：10%-50%；Hydroxy-ethyl acrylate：
0.5%-10%.
Second object of the present invention is：A kind of preparation method of tent cloth three-proof finishing agent is provided.
Realizing the technical scheme of above-mentioned purpose is：A kind of preparation method of tent cloth three-proof finishing agent, comprises the following steps,
S1）Prepare perfluoroalkyl acrylate emulsion；S2）Prepare gelatinized starch；S3）Match somebody with somebody according to the mass fraction described in claim 1
Than mixing perfluoroalkyl acrylate emulsion, acrylate modified polyvinyl acetate emulsion and gelatinized starch, stir, make
Obtain the tent cloth three-proof finishing agent.
In a preferred embodiment of the present invention, the step S1）Comprise the following steps, S11）Prepare mix monomer：Respectively
Perfluoroalkyl ethylhexyl acrylate, octadecyl acrylate, Process Conditions of Cetane Acrylate and hydroxy-ethyl acrylate are added into reactor, risen
Temperature simultaneously maintains the temperature at 30 DEG C -70 DEG C, stirs, mixing time is 20min-50min, and mixed liquid monomer is made；S12）
Prepare pre-emulsion：To cosolvent, compound emulsifying agent is added into the reactor with mix monomer, heat up and maintain the temperature at 30
DEG C -70 DEG C, stir, mixing time is 20min-50min；Deionized water is added dropwise, while high speed shear, is sufficiently stirred for
Uniformly；By homogenizer twice homogenization, homogenization pressure obtains pre-emulsion at 20-40 kilograms；S13）With deionized water by initiator
Dissolving is configured to initiator solution；S14）The pre-emulsion is heated up and 70 DEG C -85 DEG C are maintained the temperature at, described trigger is added dropwise
The agent aqueous solution, until completion of dropping, time for adding is 2h；Controlling reaction temperature is incubated 4h at 70 DEG C -85 DEG C；S15）It is cooled to
Room temperature, filtering, storage, that is, be made perfluoroalkyl acrylate emulsion.
In a preferred embodiment of the present invention, the step S11）In, the mix monomer is included by mass fraction：Perfluor
Alkyl ethylhexyl acrylate：20%-70%；Octadecyl acrylate：20%-50%；Process Conditions of Cetane Acrylate：10%-50%；Propylene
Sour hydroxyl ethyl ester：0.5%-10%；
In a preferred embodiment of the present invention, the step S12）To step S14）In, it is the cosolvent, compound emulsifying agent, mixed
Monomer, initiator, deionized water is closed to be matched according to following mass fraction：Cosolvent：5%-15%；Compound emulsifying agent：
0.5%-5%；Mix monomer：10%-40%；Initiator：0.01%-1%；Deionized water：50%-80%.
In a preferred embodiment of the present invention, the step S13）In, the quality of the initiator accounts for the whole initiation
The 10% of agent aqueous solution quality.
In a preferred embodiment of the present invention, the step S2）Including：The starch is added to deionization at normal temperatures
In water, warming while stirring, and maintain the temperature at 80 DEG C -95 DEG C, it is ensured that starch is fully gelatinized, and gelatinized starch is made；Wherein, its
In, the starch quality accounts for the 5%-10% of whole gelatinized starch quality.
The third object of the present invention is：A kind of application of tent cloth three-proof finishing agent is provided, including with water by the tent
Tent cloth three-proof finishing agent after dilution is directly applied to tent by the concentration dilution of cloth three-proof finishing agent to 10g/L-50g/L
Cloth three-prevention finishing.
It is an advantage of the invention that：Tent cloth three-proof finishing agent of the present invention and its preparation method and application, is ensureing tent
Cloth has good spray waterproof effect, with more good resistance to hydrostatic pressure effect and stiffness.
Embodiment
A kind of embodiment, tent cloth three-proof finishing agent includes perfluoroalkyl acrylate emulsion by mass fraction：30%-
60%；Acrylate modified polyvinyl acetate emulsion：20%-40%；Gelatinized starch：5%-15%.
The perfluoroalkyl acrylate emulsion includes cosolvent by mass fraction：5%-15%；Compound emulsifying agent：
0.5%-5%；Mix monomer：10%-40%；Initiator：0.01%-1%；Deionized water：50%-80%.The mixing is single
Body is included by mass fraction：Perfluoroalkyl ethylhexyl acrylate：20%-70%；Octadecyl acrylate：20%-50%；Acrylic acid
Hexadecyl ester：10%-50%；Hydroxy-ethyl acrylate：0.5%-10%.
The cosolvent is polyalcohols solvent or alcohol ethers solvent, can be specifically：Propane diols, ethylene glycol ethyl ether
Deng.The compound emulsifying agent is the emulsifying agent that cation is combined with nonionic.The initiator is water soluble starter, including mistake
At least one of ammonium sulfate, potassium peroxydisulfate, azo diisobutyl amidine hydrochloride.
Embodiment of the method 1
A kind of preparation method of tent cloth three-proof finishing agent, comprises the following steps.
S1）Prepare perfluoroalkyl acrylate emulsion.Specifically, in step S1）In comprise the following steps.
S11）Prepare mix monomer：Respectively by mass fraction for 40% perfluoroalkyl ethylhexyl acrylate, the third of 40%
Olefin(e) acid octadecyl ester, 15% Process Conditions of Cetane Acrylate and 5% hydroxy-ethyl acrylate add reactor, heat up and maintain the temperature at
50 DEG C, stir, mixing time is 30min, mixed liquid monomer is made.The mass fraction of mix monomer defined in this step
Sum is 1.
Step S12）To step S15）Defined in perfluoroalkyl acrylate emulsion mass fraction sum be 1.
S12）Prepare pre-emulsion：To with hydrotropy of the mass fraction for addition 8% in the reactor of 25% mixed liquid monomer
Agent（Ethylene glycol ethyl ether）, compound emulsifying agent（1.2% OTAC and 0.8% aliphatic alcohol polyethenoxy
Ether）, heat up and maintain the temperature at 50 DEG C, stir, mixing time is 30min；It is added dropwise and goes mass fraction to be 64%
Ionized water, while high speed shear, is stirred；By homogenizer twice homogenization, homogenization pressure is respectively 20 kilograms, 30 public affairs
Jin, obtains pre-emulsion.
S13）With deionized water by initiator（0.1% azo diisobutyl amidine hydrochloride）Dissolving is configured to initiator water
Solution.In the step S13）In, the quality of the initiator accounts for the 10% of the whole initiator solution quality.
S14）The pre-emulsion is heated up and 75 DEG C are maintained the temperature at, the initiator solution is added dropwise, until dripping
Finish, time for adding is 2h；Controlling reaction temperature is incubated 4h at 80 DEG C.
S15）Room temperature is cooled to, filtering, storage are made perfluoroalkyl acrylate emulsion.
S2）Prepare gelatinized starch：The starch is added in deionized water at normal temperatures, warming while stirring, and protected
Temperature is held at 85 DEG C, it is ensured that starch is fully gelatinized, gelatinized starch is made；Wherein, the starch quality accounts for whole gelatinized starch matter
The 5% of amount.
S3）According to the perfluoroalkyl acrylate emulsion of described mass fraction proportioning mixing 60%, 30% acrylic acid
Ester modified polyvinyl acetate emulsion and 10% gelatinized starch, stir, and the tent cloth three-proof finishing agent is made.This step
In rapid, the mass fraction sum for defining three-proof finishing agent is 1.
Embodiment of the method 2
S1）Prepare perfluoroalkyl acrylate emulsion.Specifically, in step S1）In comprise the following steps.
S11）Prepare mix monomer：Respectively by mass fraction for 45% perfluoroalkyl ethylhexyl acrylate, the third of 35%
Olefin(e) acid octadecyl ester, 15% Process Conditions of Cetane Acrylate and 5% hydroxy-ethyl acrylate add reactor, heat up and maintain the temperature at
50 DEG C, stir, mixing time is 30min, mixed liquid monomer is made.The mass fraction of mix monomer defined in this step
Sum is 1.
Step S12）To step S15）Defined in perfluoroalkyl acrylate emulsion mass fraction sum be 1.
S12）Prepare pre-emulsion：To with hydrotropy of the mass fraction for addition 8% in the reactor of 25% mixed liquid monomer
Agent（Propane diols）, compound emulsifying agent（1% OTAC and 1% AEO）, heating
And maintain the temperature at 50 DEG C, stir, mixing time is 30min；The ionized water for going mass fraction to be 64% is added dropwise, together
When high speed shear, stir；By homogenizer twice homogenization, homogenization pressure is respectively 20 kilograms, 30 kilograms, obtains pre-
Emulsion.
S13）With deionized water by initiator（0.1% azo diisobutyl amidine hydrochloride）Dissolving is configured to initiator water
Solution.In the step S13）In, the quality of the initiator accounts for the 10% of the whole initiator solution quality.
S14）The pre-emulsion is heated up and 75 DEG C are maintained the temperature at, the initiator solution is added dropwise, until dripping
Finish, time for adding is 2h；Controlling reaction temperature is incubated 4h at 80 DEG C.
S15）Room temperature is cooled to, filtering, storage are made perfluoroalkyl acrylate emulsion.
S2）Prepare gelatinized starch：The starch is added in deionized water at normal temperatures, warming while stirring, and protected
Temperature is held at 85 DEG C, it is ensured that starch is fully gelatinized, gelatinized starch is made；Wherein, the starch quality accounts for whole gelatinized starch matter
The 5% of amount.
S3）According to the perfluoroalkyl acrylate emulsion of described mass fraction proportioning mixing 60%, 30% acrylic acid
Ester modified polyvinyl acetate emulsion and 10% gelatinized starch, stir, and the tent cloth three-proof finishing agent is made.This step
In rapid, the mass fraction sum for defining three-proof finishing agent is 1.
Application Example
Three-proof finishing agent made from Examples 1 and 2 is diluted to running water after concentration is 10g/L-50g/L, you can directly use
In the three-prevention finishing of tent cloth.
Three are carried out to tent cloth using the three-proof finishing agent of fluorine-containing three-proof finishing agent on the market and the present embodiment 1 and 2
Anti- to arrange, after arrangement, sampling and testing, method of testing and test result are as follows.
Following three three-proof finishing agents are diluted to the working solution that concentration is 40g/L with running water respectively, tent cloth is cut out
21cm*18cm size specification is cut to, the tent cloth cut is immersed in three-proof finishing agent working solution, is impregnated 10 seconds,
The 3kg/cm2 next immersing and rolling of pressure, 100 DEG C of drying, 180 DEG C bake 30 seconds, moisture regain, survey water proofing property.
Spray waterproof test：Have an area of Instrument Ltd. in Wenzhou, Y813 fabric degree of getting wet analyzers, AATCC 22-2005
Textile water repellency is tested.
Resistance to hydrostatic pressure is tested：Have an area of Instrument Ltd. in Wenzhou, YG812DB seepage of water analyzers.
| Spray classification of waterproof | Pressure/KPa needed for tent cloth infiltration | Feel | |
| Embodiment 1 | 100 | 18.06 | It is stiffening |
| Embodiment 2 | 100 | 18.57 | It is stiffening |
| Waterproofing agent LS-620 | 100 | 8.17 | It is partially soft |
These are only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Any modifications, equivalent substitutions and improvements made within principle etc., should be included in the scope of the protection.
Claims (10)
1. a kind of tent cloth three-proof finishing agent, it is characterised in that include by mass fraction
Perfluoroalkyl acrylate emulsion：30%-60%；
Acrylate modified polyvinyl acetate emulsion：20%-40%；
Gelatinized starch：5%-15%.
2. tent cloth three-proof finishing agent according to claim 1, it is characterised in that the perfluoroalkyl acrylate emulsion
Include by mass fraction
Cosolvent：5%-15%；
Compound emulsifying agent：0.5%-5%；
Mix monomer：10%-40%；
Initiator：0.01%-1%；
Deionized water：50%-80%.
3. tent cloth three-proof finishing agent according to claim 2, it is characterised in that the cosolvent is polyalcohols solvent
Or alcohol ethers solvent；The compound emulsifying agent is the emulsifying agent that cation is combined with nonionic；The initiator is water solubility
At least one of initiator, including ammonium persulfate, potassium peroxydisulfate, azo diisobutyl amidine hydrochloride.
4. tent cloth three-proof finishing agent according to claim 2, it is characterised in that the mix monomer presses mass fraction bag
Include：
Perfluoroalkyl ethylhexyl acrylate：20%-70%；
Octadecyl acrylate：20%-50%；
Process Conditions of Cetane Acrylate：10%-50%；
Hydroxy-ethyl acrylate：0.5%-10%.
5. a kind of preparation method of tent cloth three-proof finishing agent, it is characterised in that comprise the following steps,
S1）Prepare perfluoroalkyl acrylate emulsion；
S2）Prepare gelatinized starch；
S3）According to the mass fraction proportioning mixing perfluoroalkyl acrylate emulsion described in claim 1, acrylate modified poly-
Vinyl acetate emulsion and gelatinized starch, stir, and the tent cloth three-proof finishing agent is made.
6. the preparation method of tent cloth three-proof finishing agent according to claim 5, it is characterised in that the step S1）Bag
Include following steps,
S11）Prepare mix monomer：Respectively by perfluoroalkyl ethylhexyl acrylate, octadecyl acrylate, Process Conditions of Cetane Acrylate and
Hydroxy-ethyl acrylate adds reactor, heats up and maintains the temperature at 30 DEG C -70 DEG C, stirs, mixing time is
20min-50min, is made mixed liquid monomer；
S12）Prepare pre-emulsion：Cosolvent, compound emulsifying agent are added into the reactor with mix monomer, heats up and keeps warm
Degree is stirred, mixing time is 20min-50min at 30 DEG C -70 DEG C；Deionized water is added dropwise, while high speed shear, fills
Divide and stir；By homogenizer twice homogenization, homogenization pressure obtains pre-emulsion at 20-40 kilograms；
S13）Initiator dissolving is configured to initiator solution with deionized water；
S14）The pre-emulsion is heated up and 70 DEG C -85 DEG C are maintained the temperature at, the initiator solution is added dropwise, until dripping
Finish, time for adding is 2h；Controlling reaction temperature is incubated 4h at 70 DEG C -85 DEG C；
S15）Room temperature is cooled to, filtering, storage are made perfluoroalkyl acrylate emulsion.
7. the preparation method of tent cloth three-proof finishing agent according to claim 6, it is characterised in that the step S11）
In, the mix monomer is included by mass fraction：Perfluoroalkyl ethylhexyl acrylate：20%-70%；Octadecyl acrylate：
20%-50%；Process Conditions of Cetane Acrylate：10%-50%；Hydroxy-ethyl acrylate：0.5%-10%.
8. the preparation method of tent cloth three-proof finishing agent according to claim 6, it is characterised in that the step S12）Arrive
Step S14）In, the cosolvent, compound emulsifying agent, mix monomer, initiator, deionized water are carried out according to following mass fraction
Proportioning：Cosolvent：5%-15%；Compound emulsifying agent：0.5%-5%；Mix monomer：10%-40%；Initiator：0.01%-
1%；Deionized water：50%-80%；The step S13）In, the initiator quality accounts for the whole initiator solution matter
The 10% of amount.
9. the preparation method of tent cloth three-proof finishing agent according to claim 5, it is characterised in that the step S2）Bag
Include：The starch is added in deionized water at normal temperatures, warming while stirring, and maintains the temperature at 80 DEG C -95 DEG C, it is ensured that
Starch is fully gelatinized, and gelatinized starch is made；
Wherein, the starch quality accounts for the 5%-10% of whole gelatinized starch quality.
10. a kind of application of tent cloth three-proof finishing agent, including arrived the concentration dilution of the tent cloth three-proof finishing agent with water
10g/L-50g/L, tent cloth three-prevention finishing is directly applied to by the tent cloth three-proof finishing agent after dilution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710589182.4A CN107164958A (en) | 2017-07-19 | 2017-07-19 | A kind of tent cloth three-proof finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710589182.4A CN107164958A (en) | 2017-07-19 | 2017-07-19 | A kind of tent cloth three-proof finishing agent and preparation method thereof |
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| CN107164958A true CN107164958A (en) | 2017-09-15 |
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ID=59817074
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| CN201710589182.4A Pending CN107164958A (en) | 2017-07-19 | 2017-07-19 | A kind of tent cloth three-proof finishing agent and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016696A (en) * | 2007-02-15 | 2007-08-15 | 浙江工业大学 | Method of preparing fluorine-containing hydrophobic and oil repellent fabric finishing agent |
| CN105085793A (en) * | 2014-05-20 | 2015-11-25 | 东莞市长安东阳光铝业研发有限公司 | Fluorinated textile finishing agent composition and preparation method therefor |
| CN106555337A (en) * | 2016-11-14 | 2017-04-05 | 苏州联胜化学有限公司 | A kind of cotton real wax print hand feel finishing agent and preparation method thereof |
-
2017
- 2017-07-19 CN CN201710589182.4A patent/CN107164958A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016696A (en) * | 2007-02-15 | 2007-08-15 | 浙江工业大学 | Method of preparing fluorine-containing hydrophobic and oil repellent fabric finishing agent |
| CN105085793A (en) * | 2014-05-20 | 2015-11-25 | 东莞市长安东阳光铝业研发有限公司 | Fluorinated textile finishing agent composition and preparation method therefor |
| CN106555337A (en) * | 2016-11-14 | 2017-04-05 | 苏州联胜化学有限公司 | A kind of cotton real wax print hand feel finishing agent and preparation method thereof |
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