CN107164949B - A kind of pressure electricity-generating fabric and preparation method thereof - Google Patents
A kind of pressure electricity-generating fabric and preparation method thereof Download PDFInfo
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- CN107164949B CN107164949B CN201710202664.XA CN201710202664A CN107164949B CN 107164949 B CN107164949 B CN 107164949B CN 201710202664 A CN201710202664 A CN 201710202664A CN 107164949 B CN107164949 B CN 107164949B
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- 239000004744 fabric Substances 0.000 title claims abstract description 183
- 238000002360 preparation method Methods 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000758 substrate Substances 0.000 claims abstract description 49
- 239000011229 interlayer Substances 0.000 claims abstract description 44
- 239000010410 layer Substances 0.000 claims abstract description 26
- 239000002322 conducting polymer Substances 0.000 claims abstract description 17
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims description 114
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 81
- 239000008367 deionised water Substances 0.000 claims description 72
- 229910021641 deionized water Inorganic materials 0.000 claims description 72
- 238000000889 atomisation Methods 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 36
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- 238000002156 mixing Methods 0.000 claims description 24
- 239000000178 monomer Substances 0.000 claims description 21
- 230000001590 oxidative effect Effects 0.000 claims description 21
- 238000007747 plating Methods 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 239000003999 initiator Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 16
- 239000004411 aluminium Substances 0.000 claims description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 8
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 8
- 239000003599 detergent Substances 0.000 claims description 8
- 238000007598 dipping method Methods 0.000 claims description 8
- 239000005457 ice water Substances 0.000 claims description 8
- 229940078494 nickel acetate Drugs 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical group [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 7
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000012266 salt solution Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 235000019394 potassium persulphate Nutrition 0.000 claims description 3
- 150000003233 pyrroles Chemical group 0.000 claims description 3
- 229930192474 thiophene Natural products 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 150000002815 nickel Chemical class 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims 1
- 238000006197 hydroboration reaction Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000010248 power generation Methods 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 229920000742 Cotton Polymers 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 229920004934 Dacron® Polymers 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 6
- 229920000128 polypyrrole Polymers 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 description 5
- 239000012279 sodium borohydride Substances 0.000 description 5
- 230000005611 electricity Effects 0.000 description 4
- 229960004756 ethanol Drugs 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 3
- 239000005030 aluminium foil Substances 0.000 description 3
- 229960000935 dehydrated alcohol Drugs 0.000 description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 229920000123 polythiophene Polymers 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005674 electromagnetic induction Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- LJCNRYVRMXRIQR-UHFFFAOYSA-L potassium sodium tartrate Chemical compound [Na+].[K+].[O-]C(=O)C(O)C(O)C([O-])=O LJCNRYVRMXRIQR-UHFFFAOYSA-L 0.000 description 1
- VZOPRCCTKLAGPN-ZFJVMAEJSA-L potassium;sodium;(2r,3r)-2,3-dihydroxybutanedioate;tetrahydrate Chemical compound O.O.O.O.[Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O VZOPRCCTKLAGPN-ZFJVMAEJSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940074446 sodium potassium tartrate tetrahydrate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/63—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing sulfur in the main chain, e.g. polysulfones
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Chemically Coating (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of pressure electricity-generating fabrics and preparation method thereof, belong to new energy and technical field of power generation.The present invention is to be adsorbed with conductive metal film layer using fabric as substrate in substrate outer surface and obtain positive fabric and cathode fabric, is adsorbed with conducting polymer film layer in substrate outer surface and obtains interlayer fabric；Interlayer fabric upper surface and positive fabric lower surface coincide, and interlayer fabric lower surface and cathode fabric upper surface coincide to get pressure electricity-generating fabric is arrived.The advantages that preparation process of the present invention is simple, and condition is easily-controllable, low in cost, consuming little energy, and light weight is flexible, and flexibility is good can be widely applied to wearable electronic clothes, pliable pressure senser element etc..
Description
Technical field
The present invention relates to a kind of pressure electricity-generating fabrics and preparation method thereof, belong to new energy and technical field of power generation.
Background technique
Mechanical energy is converted into the significant process that electricity is widely used in power generation, for centuries, comes from steam stream, wind, water
Big machinery can have been converted into the electric power based on electromagnetic induction.But with body kinematics, vehicle tyre rotation and contraction of muscle
It is also ubiquitous that related gadget can be converted into electricity.These are seemed into small collection of energy into electric power to set to personal electric
Standby charging is in demand.In fact, small mechanical energy has used the calutron of miniaturization and pressure converter to receive
Receive electricity.Piezoelectric material can mutually be converted electric energy and mechanical energy by the inherent function (property) of itself.It is imitated using piezoelectricity
The piezoelectric generating device of electric energy should be converted by mechanical energy such as vibrations have been known, and piezoelectric energy-conversion device is wherein most
For the device of core.
At 1461-1468 pages of the phase of volume 28 the 7th of periodical Advanced Materials, document Polymer-Metal
Using aluminium foil and gold plaque as electrode, PPy plate folder in Schottky Contact with Direct-Current Outputs
In two electrode medium designs at device.Wherein PPy plate is mounted in aluminium electrode, and gold plaque lower surface and PPy plate upper surface coincide, electricity
Signal is drawn by two electrode cables, and gold plaque is by fine and close polyethylene terephthalate (PET) the film support of identical size and PET
Film is fixed in removable dynamic load, is moved up and down gold electrode by load and is generated electric signal.The electric energy that the method generates can be straight
Storage is connect in the capacitor without rectifying with the power supply of electron device.The preparation of conducting polymer plate is used with FTIR (in Fu
Leaf transformation infrared spectroscopy) the identical preparation method of KBr plate, mechanical compaction PPy powder prepares conducting polymer plate, therefore conduction is poly-
Close that object plate is crisp and poor in flexibility: metal electrode uses aluminium foil or gold plaque, although aluminium foil, gold plaque have certain flexibility,
Its flexibility, flexible, can dressing it is ideal not enough.
Summary of the invention
There are problems for above-mentioned, and it is an object of the invention to the technical problem to be solved is that, mentioning by substrate of fabric
A kind of piezo-electric generating fabric out and preparation method thereof.To achieve the above object, technical solution of the invention are as follows:
A kind of pressure electricity-generating fabric, the pressure electricity-generating fabric are made of positive fabric, interlayer fabric and cathode fabric,
Respectively using fabric as substrate, substrate outer surface is adsorbed with conductive nickel metallic diaphragm or leads for positive fabric, interlayer fabric, cathode fabric
Electric silver metal film layer is positive fabric, and it is interlayer fabric, substrate appearance that substrate outer surface, which is adsorbed with conducting polymer film layer,
It is cathode fabric that face, which is adsorbed with conductive aluminum metallic diaphragm, and the lower surface of positive fabric and the upper surface of interlayer fabric coincide, bear
The upper surface of pole fabric and the lower surface of interlayer fabric coincide.
The fabric is cotton fabric or silk fabrics or one of wool fabric or dacron.
The conducting polymer is polypyrrole or one of polyaniline or polythiophene.
A kind of preparation method of pressure electricity-generating fabric, the preparation method the following steps are included:
A. substrate pre-processes
The solution for the preparation that substrate is placed in detergent, sodium carbonate and deionized water in mass ratio is 0.005:0.05:1
In, the water bath processing 1h under the conditions of 80 DEG C, taking-up is cleaned with deionized water to neutrality, and dry 1h, spare under the conditions of 60 DEG C.
B. the preparation of positive fabric
It is in mass ratio that 0.05:0.02:1 is uniformly mixing to obtain solution A by nickel acetate, concentrated hydrochloric acid and deionized water, by boron
Sodium hydride, sodium hydroxide and deionized water are that 0.02:0.01:1 is uniformly mixing to obtain solution B in mass ratio.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Substrate after processing is placed in the chemical plating solution after atomization by chemical plating solution atomization process under the conditions of 30 DEG C
In, 1~2h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed with conductive metal film to get outer surface under the conditions of 60 DEG C
The positive fabric of layer.
C. the preparation of interlayer fabric
In mass ratio it is that 0.135:1 is uniformly mixing to obtain oxidizing initiators solution by oxidant and deionized water, will polymerize
Object monomer, surfactant and deionized water be in mass ratio 0.05~0.1:0.0005:1 be uniformly mixing to obtain monomer mixing it is molten
Liquid.
Substrate after pretreatment is placed in monomer mixture solution, the stirring dipping 30min, Xiang Qi under the conditions of ice-water bath
Oxidizing initiators solution is slowly added dropwise, 1~3h is reacted after completion of dropwise addition, takes out substrate and is sequentially placed into the propyl alcohol that mass ratio is 1:1
It is the hydrochloric acid solution of 0.02g/mL with dehydrated alcohol mixed liquor, concentration, washes twice in deionized water respectively, under the conditions of 60 DEG C
Dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Substrate after pretreatment is placed in plasma processor, handles 6min, then be placed in plasma magnetron sputtering
In film instrument, 30min is handled to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface by target of aluminium.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.The chemical plating solution is one of nickel salt solution or silver salt solution.
The oxidant is one kind of ferric trichloride or potassium peroxydisulfate.
The polymer monomer is pyrroles or one of aniline or thiophene.
The surfactant is cetyl trimethylammonium bromide or neopelex or sodium lignin sulfonate
One of.
Due to the technical solution more than using, preparation method of the invention is had the advantage that
1) fabric is substrate, and using fabric strong adsorption force, flexibility is good, the features such as being arbitrarily bent, be can get uniformly attached
The good conductive metal film layer and conducting polymer film layer of flexibility.
2) chemical plating, the method for plasma magnetron sputtering plating are utilized, is obtained in fabric substrate outer surface equably conductive
Metallic diaphragm obtains equably conducting polymer film layer, party's legal system in fabric substrate outer surface using the method for in-situ polymerization
The advantages that standby simple process, condition is easily-controllable, low in cost, consuming little energy, light weight, its is frivolous for resulting pressure electricity-generating fabric
Soft, foldable can operate with flexible electronic product and the Electronic Clothes field that can be worn convenient for being integrated with clothes.
Detailed description of the invention
Attached drawing 1 is pressure electricity-generating fabric schematic diagram of the invention.
Attached drawing 2 is the electric signal output of pressure electricity-generating fabric of the invention under strain.
Specific embodiment
Present invention is further described in detail combined with specific embodiments below, sees attached drawing.
A kind of pressure electricity-generating fabric, the pressure electricity-generating fabric is by 3 structure of positive fabric 1, interlayer fabric 2 and cathode fabric
At respectively using fabric as substrate, substrate outer surface is adsorbed with conductive nickel metal film for positive fabric 1, interlayer fabric 2, cathode fabric 3
Layer or conductive silver metal film layer are positive fabric 1, and it is interlayer fabric 2 that substrate outer surface, which is adsorbed with conducting polymer film layer,
It is cathode fabric 3 that substrate outer surface, which is adsorbed with conductive aluminum metallic diaphragm, and the lower surface of positive fabric 1 is upper with interlayer fabric 2
Surface profiles, the upper surface of cathode fabric 3 and the lower surface of interlayer fabric 2 coincide.
The fabric is cotton fabric or silk fabrics or one of wool fabric or dacron.
The conducting polymer is polypyrrole or one of polyaniline or polythiophene.
A kind of preparation method of pressure electricity-generating fabric, the preparation method is using following steps processing preparation:
A. substrate pre-processes
The solution for the preparation that substrate is placed in detergent, sodium carbonate and deionized water in mass ratio is 0.005:0.05:1
In, the water bath processing 1h under the conditions of 80 DEG C, taking-up is cleaned with deionized water to neutrality, and dry 1h, spare under the conditions of 60 DEG C.
B. the preparation of positive fabric
It is in mass ratio that 0.05:0.02:1 is uniformly mixing to obtain solution A by nickel acetate, concentrated hydrochloric acid and deionized water, by boron
Sodium hydride, sodium hydroxide and deionized water are that 0.02:0.01:1 is uniformly mixing to obtain solution B in mass ratio.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Substrate after processing is placed in the chemical plating solution after atomization by chemical plating solution atomization process under the conditions of 30 DEG C
In, 1~2h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed with conductive metal film to get outer surface under the conditions of 60 DEG C
The positive fabric of layer.
C. the preparation of interlayer fabric
In mass ratio it is that 0.135:1 is uniformly mixing to obtain oxidizing initiators solution by oxidant and deionized water, will polymerize
Object monomer, surfactant and deionized water be in mass ratio 0.05~0.1:0.0005:1 be uniformly mixing to obtain monomer mixing it is molten
Liquid.
Substrate after pretreatment is placed in monomer mixture solution, the stirring dipping 30min, Xiang Qi under the conditions of ice-water bath
Oxidizing initiators solution is slowly added dropwise, 1~3h is reacted after completion of dropwise addition, takes out substrate and is sequentially placed into the propyl alcohol that mass ratio is 1:1
It is the hydrochloric acid solution of 0.02g/mL with dehydrated alcohol mixed liquor, concentration, washes twice in deionized water respectively, then at 60 DEG C of condition
Lower dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Will through step a, treated that fabric is placed in plasma processor, handle 6min, then be placed in plasma magnetron sputtering
In plated film instrument, 30min is handled to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface by target of aluminium.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Specific embodiment
Embodiment one
Select cotton fabric as substrate according to the above method
A. substrate pre-processes
Cotton fabric is cut into the circle that radius is 2cm, finishing flash is placed on by 0.5g detergent, 5g sodium carbonate and 100g
Deionized water is stirred in the solution being configured to, and water bath processing 1h, taking-up are cleaned with deionized water under the conditions of 80 DEG C
Property, the dry 1h under the conditions of 60 DEG C is spare.
B. the preparation of positive fabric
It takes 5g nickel acetate, 2g concentrated hydrochloric acid and 100g deionized water to be uniformly mixing to obtain solution A, takes 2g sodium borohydride, 1g hydrogen
Sodium oxide molybdena and 100g deionized water are uniformly mixing to obtain solution B.
Pretreated cotton fabric is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Cotton fabric after pretreatment is placed in the chemistry after atomization by chemical nickel-plating solution atomization process under the conditions of 30 DEG C
In nickel plating solution, 1h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed with conduction to get outer surface under the conditions of 60 DEG C
The positive fabric of nickel metal film layer.Wherein chemical nickel-plating solution forms: nickel sulfate 30g/L, sodium hypophosphite 20g/L, sodium citrate
50g/L, pH value 9.
C. the preparation of interlayer fabric
Take 13.5g ferric trichloride and 100g deionized water to be stirred to obtain oxidizing initiators solution, take 5g pyrrole monomer,
0.05g cetyl trimethylammonium bromide and 100g deionized water are stirred to obtain monomer mixture solution.
Cotton fabric after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath, to
Oxidizing initiators solution is slowly added dropwise in it, 1h is reacted after completion of dropwise addition, taking-up cotton fabric is sequentially placed into 50g propyl alcohol and 50g is anhydrous
The mixed liquor of ethyl alcohol, 100mL concentration are the hydrochloric acid of 0.02g/mL, wash twice in deionized water respectively, are done under the conditions of 60 DEG C
Dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Cotton fabric after pretreatment is placed in plasma processor, 6min is handled；It is placed in plasma magnetron sputtering again
In plated film instrument, 30min is handled to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface by target of aluminium.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Embodiment two
Select cotton fabric as substrate according to the above method
A. substrate pre-processes
Cotton fabric is cut into the circle that radius is 2cm, finishing flash is placed on by 0.5g detergent, 5g sodium carbonate and 100g
Deionized water is stirred in the solution being configured to, and water bath processing 1h, taking-up are cleaned with deionized water under the conditions of 80 DEG C
Property, the dry 1h under the conditions of 60 DEG C is spare.
B. the preparation of positive fabric
It takes 5g nickel acetate, 2g concentrated hydrochloric acid and 100g deionized water to be uniformly mixing to obtain solution A, takes 2g sodium borohydride, 1g hydrogen
Sodium oxide molybdena and 100g deionized water are uniformly mixing to obtain solution B.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Cotton fabric after pretreatment is placed in the chemistry after atomization by chemical silvering solution atomization process under the conditions of 30 DEG C
In silver plating solution, 2h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed with conduction to get outer surface under the conditions of 60 DEG C
The positive fabric of silver metal film layer.Wherein chemical silvering solution composition: silver nitrate 10g/L, ammonium hydroxide 200g/L, sodium potassium tartrate tetrahydrate
50g/L, pH value 12.
C. the preparation of interlayer fabric
It takes 13.5g potassium peroxydisulfate and 100g deionized water to be stirred to obtain oxidizing initiators solution, takes 10g aniline list
Body, 0.05g cetyl trimethylammonium bromide and 100g deionized water are stirred to obtain monomer mixture solution.
Cotton fabric after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath, to
Oxidizing initiators solution is slowly added dropwise in it, 3h is reacted after completion of dropwise addition, taking-up cotton fabric is sequentially placed into 50g propyl alcohol and 50g is anhydrous
The mixed liquor of ethyl alcohol, 100mL concentration are the hydrochloric acid of 0.02g/mL, wash twice in deionized water respectively, are done under the conditions of 60 DEG C
Dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Will through step a, treated that cotton fabric is placed in plasma processor, handle 6min；Plasma magnetic control is placed in again to splash
It penetrates in plated film instrument, handles 30min by target of aluminium to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Embodiment three
Select silk fabrics as substrate according to the above method
A. substrate pre-processes
Silk fabrics is cut into the circle that radius is 2cm, finishing flash is placed on by 0.5g detergent, 5g sodium carbonate and 100g
Deionized water is stirred in the solution being configured to, and water bath processing 1h, taking-up are cleaned with deionized water under the conditions of 80 DEG C
Property, the dry 1h under the conditions of 60 DEG C is spare.
B. the preparation of positive fabric
Take 7.5g nickel acetate, 3g concentrated hydrochloric acid and 150g deionized water to be uniformly mixing to obtain solution A, take 3g sodium borohydride,
1.5g sodium hydroxide and 150g deionized water are uniformly mixing to obtain solution B.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Silk fabrics after pretreatment is placed in the chemistry after atomization by chemical nickel-plating solution atomization process under the conditions of 30 DEG C
In nickel plating solution, 1.5h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed under the conditions of 60 DEG C to get outer surface leads
The positive fabric of electric nickel metal film layer.Wherein chemical nickel-plating solution forms: nickel sulfate 30g/L, sodium hypophosphite 20g/L, citric acid
Sodium 50g/L, pH value 9.
C. the preparation of interlayer fabric
It takes 13.5g ferric trichloride and 100g deionized water to be stirred to obtain oxidizing initiators solution, takes 6.7g pyrroles single
Body, 0.05g cetyl trimethylammonium bromide and 100g deionized water are stirred to obtain monomer mixture solution.
Silk fabrics after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath, to
Oxidizing initiators solution is slowly added dropwise in it, 2h is reacted after completion of dropwise addition, taking-up silk fabrics is sequentially placed into 50g propyl alcohol and 50g is anhydrous
The mixed liquor of ethyl alcohol, 100mL concentration are the hydrochloric acid of 0.02g/mL, wash twice in deionized water respectively, are done under the conditions of 60 DEG C
Dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Will through step a, treated that silk fabrics is placed in plasma processor, handle 6min；Plasma magnetic control is placed in again to splash
It penetrates in plated film instrument, handles 30min by target of aluminium to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Example IV
Wool fabric is selected to be used as substrate according to the above method
A. substrate pre-processes
Wool fabric is cut into the circle that radius is 2cm, finishing flash is placed on by 0.5g detergent, 5g sodium carbonate and 100g
Deionized water is stirred in the solution being configured to, and water bath processing 1h, taking-up are cleaned with deionized water under the conditions of 80 DEG C
Property, the dry 1h under the conditions of 60 DEG C is spare.
B. the preparation of positive fabric
Take 7.5g nickel acetate, 3g concentrated hydrochloric acid and 150g deionized water to be uniformly mixing to obtain solution A, take 3g sodium borohydride,
1.5g sodium hydroxide and 150g deionized water are uniformly mixing to obtain solution B.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C.
Chemical nickel-plating solution is placed in the change after atomization in atomization process under the conditions of 30 DEG C, by wool fabric after pretreatment
It learns in nickel plating solution, handles 1.5h, taking-up is washed with deionized water, and dry 1h is adsorbed under the conditions of 60 DEG C to get outer surface
The positive fabric of conductive nickel metallic diaphragm.Wherein chemical nickel-plating solution forms: nickel sulfate 30g/L, sodium hypophosphite 20g/L, lemon
Sour sodium 50g/L, pH value 9.
C. the preparation of interlayer fabric
It takes 13.5g ferric trichloride and 100g deionized water to be stirred to obtain oxidizing initiators solution, takes 8.4g thiophene list
Body, 0.05g cetyl trimethylammonium bromide and 100g deionized water are stirred to obtain monomer mixture solution.
Wool fabric after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath, to
Oxidizing initiators solution is slowly added dropwise in it, 2h is reacted after completion of dropwise addition, taking-up wool fabric is sequentially placed into 50g propyl alcohol and 50g is anhydrous
The mixed liquor of ethyl alcohol, 100mL concentration are the hydrochloric acid of 0.02g/mL, wash twice in deionized water respectively, are done under the conditions of 60 DEG C
Dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Will through step a, treated that wool fabric is placed in plasma processor, handle 6min；Plasma magnetic control is placed in again to splash
It penetrates in plated film instrument, handles 30min by target of aluminium to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Embodiment five
Select dacron as substrate according to the above method
A. substrate pre-processes
By dacron be cut into radius be 2cm circle, finishing flash be placed on by 1g detergent, 10g sodium carbonate and
200g deionized water is stirred in the solution being configured to, and water bath processing 1h, taking-up are cleaned with deionized water under the conditions of 80 DEG C
To neutrality, dry 1h, spare under the conditions of 60 DEG C.
B. the preparation of positive fabric
Take 7.5g nickel acetate, 3g concentrated hydrochloric acid and 150g deionized water to be uniformly mixing to obtain solution A, take 3g sodium borohydride,
1.5g sodium hydroxide and 150g deionized water are uniformly mixing to obtain solution B.
Pretreated substrate is placed in the solution A after atomization by solution A, solution B atomization process under the conditions of 30 DEG C
In, 10~20min being handled, then be placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in
Dry 40min, spare under the conditions of 60 DEG C；
Chemical silvering solution is in atomization process under the conditions of 30 DEG C, after dacron after pretreatment is placed in atomization
In chemical silvering solution, 2h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed under the conditions of 60 DEG C to get outer surface
The positive fabric of conductive silver metal film layer.Wherein chemical silvering solution composition: silver nitrate 10g/L, ammonium hydroxide 200g/L, potassium tartrate
Sodium 50g/L, pH value 12.
C. the preparation of interlayer fabric
It takes 13.5g sodium peroxydisulfate and 100g deionized water to be stirred to obtain oxidizing initiators solution, takes 9.3g aniline list
Body, 0.05g cetyl trimethylammonium bromide and 100g deionized water are stirred to obtain monomer mixture solution.
Dacron after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath,
Oxidizing initiators solution is slowly added dropwise to it, 2h is reacted after completion of dropwise addition, takes out dacron and is sequentially placed into 50g propyl alcohol and 50g
The mixed liquor of dehydrated alcohol, 100mL concentration are the hydrochloric acid of 0.02g/mL, wash twice in deionized water respectively, in 60 DEG C of conditions
Lower dry 1h is to get the interlayer fabric for being adsorbed with conducting polymer film layer to outer surface.
D. the preparation of cathode fabric
Will through step a, treated that dacron is placed in plasma processor, handle 6min；It is placed in plasma magnetic control again
In sputter coating instrument, 30min is handled to get the cathode fabric for being adsorbed with conductive aluminum metallic diaphragm to outer surface by target of aluminium.
E. the upper surface of the lower surface of positive fabric and interlayer fabric is coincide, the upper surface of cathode fabric and interlayer fabric
Lower surface coincide, obtain pressure electricity-generating fabric.
Claims (5)
1. a kind of preparation method of pressure electricity-generating fabric, it is characterised in that: the preparation method the following steps are included:
A. substrate pre-processes
It is in the solution of 0.005:0.05:1 preparation, in 80 that substrate, which is placed in detergent, sodium carbonate and deionized water in mass ratio,
Water bath processing 1h under the conditions of DEG C, taking-up are cleaned with deionized water to neutrality, and dry 1h, spare under the conditions of 60 DEG C；
B. the preparation of positive fabric
It is in mass ratio that 0.05:0.02:1 is uniformly mixing to obtain solution A by nickel acetate, concentrated hydrochloric acid and deionized water, by hydroboration
Sodium, sodium hydroxide and deionized water are that 0.02:0.01:1 is uniformly mixing to obtain solution B in mass ratio；
Pretreated substrate is placed in the solution A after atomization, place by solution A, solution B atomization process under the conditions of 30 DEG C
10~20min is managed, then is placed in solution B after atomization, handles 20~30min, taking-up is washed with deionized water, in 60 DEG C of items
Dry 40min, spare under part；
Substrate after atomization process is placed in the chemical plating solution after atomization by chemical plating solution atomization process under the conditions of 30 DEG C
In, 1~2h is handled, taking-up is washed with deionized water, and dry 1h is adsorbed with conductive metal film to get outer surface under the conditions of 60 DEG C
The positive fabric (1) of layer；
C. the preparation of interlayer fabric
It is in mass ratio that 0.135:1 is uniformly mixing to obtain oxidizing initiators solution by oxidant and deionized water, by polymer list
Body, surfactant and deionized water are that 0.05~0.1:0.0005:1 is uniformly mixing to obtain monomer mixture solution in mass ratio；
Substrate after pretreatment is placed in monomer mixture solution, the stirring dipping 30min under the conditions of ice-water bath, slowly to it
Oxidizing initiators solution is added dropwise, 1~3h is reacted after completion of dropwise addition, takes out substrate and is sequentially placed into the propyl alcohol and nothing that mass ratio is 1:1
Water-ethanol mixed liquor, concentration are the hydrochloric acid solution of 0.02g/mL, wash twice in deionized water respectively, dry under the conditions of 60 DEG C
1h is to get the interlayer fabric (2) for being adsorbed with conducting polymer film layer to outer surface；
D. the preparation of cathode fabric
Substrate after pretreatment is placed in plasma processor, handles 6min, then be placed in plasma magnetron sputtering plating instrument
In, 30min is handled by target of aluminium to get the cathode fabric (3) for being adsorbed with conductive aluminum metallic diaphragm to outer surface；
E. the upper surface of the lower surface of positive fabric (1) and interlayer fabric (2) is coincide, the upper surface of cathode fabric (3) with every
The lower surface of layer fabric (2) coincide to arrive pressure electricity-generating fabric.
2. a kind of preparation method of pressure electricity-generating fabric as described in claim 1, it is characterised in that: the chemical plating solution
For one of nickel salt solution or silver salt solution.
3. a kind of preparation method of pressure electricity-generating fabric as described in claim 1, it is characterised in that: the oxidant is trichlorine
Change one kind of iron or potassium peroxydisulfate.
4. a kind of preparation method of pressure electricity-generating fabric as described in claim 1, it is characterised in that: the polymer monomer is
Pyrroles or one of aniline or thiophene.
5. a kind of preparation method of pressure electricity-generating fabric as described in claim 1, it is characterised in that: the surfactant is
Cetyl trimethylammonium bromide or one of neopelex or sodium lignin sulfonate.
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| CN103066314A (en) * | 2012-12-25 | 2013-04-24 | 武汉纺织大学 | Fabric morphological polymer battery and preparation method thereof |
| CN103493233A (en) * | 2011-09-07 | 2014-01-01 | 皮耶勒意大利有限责任公司 | Composite material comprising a layer of polymeric piezoelectric material matched with a textile substrate and method for making such a composite material |
| CN204861469U (en) * | 2015-08-24 | 2015-12-16 | 扬州大学 | Fabric shoe -pad containing contain core PVDF piezoelectricity fibre |
| JP2016213272A (en) * | 2015-04-30 | 2016-12-15 | 帝人株式会社 | Cloth-like transducer and device including the same |
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| CN103493233A (en) * | 2011-09-07 | 2014-01-01 | 皮耶勒意大利有限责任公司 | Composite material comprising a layer of polymeric piezoelectric material matched with a textile substrate and method for making such a composite material |
| CN103066314A (en) * | 2012-12-25 | 2013-04-24 | 武汉纺织大学 | Fabric morphological polymer battery and preparation method thereof |
| JP2016213272A (en) * | 2015-04-30 | 2016-12-15 | 帝人株式会社 | Cloth-like transducer and device including the same |
| CN204861469U (en) * | 2015-08-24 | 2015-12-16 | 扬州大学 | Fabric shoe -pad containing contain core PVDF piezoelectricity fibre |
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