CN107163677A - A kind of ink of PE heat shrink films printing and preparation method thereof - Google Patents
A kind of ink of PE heat shrink films printing and preparation method thereof Download PDFInfo
- Publication number
- CN107163677A CN107163677A CN201710342852.2A CN201710342852A CN107163677A CN 107163677 A CN107163677 A CN 107163677A CN 201710342852 A CN201710342852 A CN 201710342852A CN 107163677 A CN107163677 A CN 107163677A
- Authority
- CN
- China
- Prior art keywords
- ink
- heat shrink
- pigment
- shrink films
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of ink of PE heat shrink films printing, include the component of following mass fraction：Polyurethane resin 15~30%, cellulose nitrate 8~10%, kaolin 0~5%, pigment 8~32%, tributyl 2-acetylcitrate 1~2%, silica 0.5~1%, Tissuemat E 1~3%, isopropanol 6~12%, n-butanol 1~5%, n-propyl acetate 8~15%, ethyl acetate 15~30%.The invention also discloses the preparation method of the ink.The ink has good anti-freezing property, the problems such as ink is not in viscous bottle after high-temperature shrink oven during packaging, ink bursts, ink changes colour.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, the ink of more particularly to a kind of PE heat shrink films printing and
Its preparation method.
Background technology
PE heat shrink films are widely used in the one integral piece set of the products such as beer class, herbal tea class, mineral water class, various beverage classes
Packaging, the product pliability is good, and impact resistance, tear resistance are strong, not cracky, not to be afraid of tide, shrinkage factor big.
Packaging mineral water, drinks, various beverage classes are carried out using PE heat shrink films product, can effectively reduce and use into
This, is 40% or so of packed in cases using shrink film, while labor strength can also be reduced with waterproof rain-proof, improves packaging
Efficiency and packaging class, are that instead of the new material of packed in cases.
At present, definitely most tinned drink and very big a part of plastic bottle dixie cup are all using heat shrinkable package shape
Formula, Coca-Cola, Chef Kang, happy bottled and tinned drink outer packing that is precious, adding the famous brand names such as treasured, Wang Laoji are numerous and confused
Switch to PE heat shrink films packaging from packed in cases.It is expected that in following 2~3 years, with the constantly improve of heat shrink films packing technique,
PE heat shrink films packaging can replace packed in cases completely.
Existing in the market can be used for the ink of PE heat shrink films printing mainly based on polyamide resin resin system, due to resin
The defect of performance itself can not also be completely suitable for the processing request of PE heat shrink films packaging.Use the oil of polyamide resin resin system
Ink, is printed on the color film product being made on PE heat shrink films, and in packaging, viscous bottle, oil occurs in ink after high-temperature shrink oven
The defects such as ink explosion, ink discoloration.The anti-freezing property of polyamide system ink is poor simultaneously, and when temperature is less than 5 DEG C, ink will
Start gel to lose flowability, very big trouble is brought to print production, printing quality is severely impacted.
The content of the invention
An object of the present invention is to provide a kind of ink of PE heat shrink films printing, and the ink has well freeze proof
Performance, the problems such as ink is not in viscous bottle after high-temperature shrink oven during packaging, ink bursts, ink changes colour.
The second object of the present invention provides the preparation method of above-mentioned ink.
An object of the present invention is achieved through the following technical solutions：A kind of ink of PE heat shrink films printing, bag
Include the component of following mass fraction：
Polyurethane resin 15~30%, cellulose nitrate 8~10%, kaolin 0~5%, pigment 8~32%, acetyl tributyl citrate three
Butyl ester (ATBC) 1~2%, silica 0.5~1%, Tissuemat E 1~3%, isopropanol 6~12%, n-butanol 1~5%, acetic acid is just
Propyl ester 8~15%, ethyl acetate 15~30%.
In the present invention, polyamide is replaced using polyurethane resin, it is constant to solve the high temperature resistant contraction of product
Color, not glue bottle, under cryogenic ink still can keep good mobile performance, do not interfere with print production.Add second
Acyl ATBC (ATBC) can improve the flexility of ink printing, prevent the generation of ink explosion problem.Add two
Silica and Tissuemat E can avoid the adhesion problems of ink, while preventing that ink will not glue bottle after high-temperature shrinkage.Add poly-
Ethylene waxes can improve the abrasion resistance energy of ink, prevent product in transit link and the wear problem of market circulation process.
The pigment includes but is not limited to titanium dioxide, permanent yellow, permanent bordeaux, phthalocyanine blue or carbon black.
Further, when pigment selects titanium dioxide, the mass fraction proportioning of ink component of the present invention is preferably：Poly- ammonia
Ester tree 15~20%, cellulose nitrate 8~10%, kaolin 3~5%, titanium dioxide 28~32%, tributyl 2-acetylcitrate
(ATBC) 1~2%, silica 0.5~1%, Tissuemat E 1~3%, isopropanol 6~8%, n-butanol 1~3%, n-propyl acetate 8
~10%, ethyl acetate 15~20%.
Further, when pigment selects permanent yellow, permanent bordeaux, phthalocyanine blue or carbon black, the quality of ink component of the present invention
Fraction is matched：
Polyurethane resin 20~30%, cellulose nitrate 8~10%, kaolin 0~3%, pigment 8~11%, acetyl tributyl citrate three
Butyl ester (ATBC) 1~2%, silica 0.5~1%, Tissuemat E 1~2%, isopropanol 8~12%, n-butanol 3~5%, acetic acid is just
Propyl ester 10~15%, ethyl acetate 20~30%.
The two of the object of the invention are achieved through the following technical solutions：A kind of preparation of the printing-ink of PE heat shrink films
Method, comprises the following steps：
(1) each component is prepared according to proportioning；
(2) isopropanol, n-butanol, n-propyl acetate and ethyl acetate are well mixed, obtain mixed solvent, then will mix molten
70~80% parts of agent gross mass are added in dispersion cylinder, under agitation, add cellulose nitrate, stirring to fiber
After plain nitrate is completely dissolved, poly- propylhomoserin resin, tributyl 2-acetylcitrate (ATBC), pigment, kaolin, poly- second are sequentially added
Alkene wax and silica, continue to stir, obtain the mixed material of pulpous state；
(3) when the mixed material for obtaining the step (2) is ground to mixed material fineness and reaches less than 15 microns, add
Remaining mixed solvent, is uniformly dispersed, and then filters, and produces ink.
The beneficial effects of the invention are as follows：
(1) the present invention is to provide a kind of intaglio printing ink used for plastic of PE heat shrink films printing, have on PE heat shrink films
There is bright-colored, printing attractive in appearance, adhesive force is strong, anti-scratching wearproof, and can realize more than 200 meters per minute of high speed printing,
Printing has very strong temperature tolerance, and ink after PE shrink films are shunk is solved well and glues bottle, ink explosion, ink discoloration etc.
Problem.
(2) ink that the present invention is provided has good frost resistance, still has good stream under 0 DEG C of temperature condition
Dynamic performance, can meet the normal production of printing enterprise, be that the production of printing enterprise solves puzzlement, bring convenience.And
Polyamide resin resin system ink can start gel, mobility under the temperature condition less than 5 DEG C and be deteriorated, and have impact on printing enterprise
Normal production.
(3) ink that the present invention is provided is used to print after PE heat shrink films, and the color film product of the PE thermal contractions made is used to wrap
Fill beer, herbal tea, beverage, the outer packing of the product such as drinking water, instead of original packed in cases mode, with production efficiency it is fast,
It is waterproof, wear-resisting, and packing cost can be greatlyd save.
Embodiment
Embodiment 1
Polyurethane resin 16%, cellulose nitrate 10%, kaolin 4%, titanium dioxide 29%, tributyl 2-acetylcitrate (ATBC)
1.5%, silica 0.5%, Tissuemat E 2.5%, isopropanol 8.5%, n-butanol 2%, n-propyl acetate 9%, ethyl acetate 17%.
Preparation method：
(1) each component is prepared according to proportioning；
(2) isopropanol, n-butanol, n-propyl acetate and ethyl acetate are well mixed, obtain mixed solvent, then will mix molten
70~80% parts of agent gross mass are added in dispersion cylinder, under agitation, add cellulose nitrate, stirring to fiber
After plain nitrate is completely dissolved, poly- propylhomoserin resin, tributyl 2-acetylcitrate (ATBC), pigment, kaolin, poly- second are sequentially added
Alkene wax and silica, continue to stir, obtain the mixed material of pulpous state；
(3) when the mixed material for obtaining step (2) is ground to mixed material fineness and reaches less than 15 microns, add remaining
Mixed solvent, is uniformly dispersed, and then filters, and produces ink.
After testing, resulting white ink performance is as follows：
| Performance indications | Performance requirement | Testing result |
| Anti-freezing property | Environment is at 0 DEG C, ink not jelly, the mobility still having had. | In the environment for ink being placed on 0 DEG C, after placing 24 hours, ink does not have jelly, has still had Mobility, ink can be used normally. |
| Resistance to elevated temperatures | In thermal contraction equipment, temperature is 170 ~ 200 DEG C of shrink wrappings Afterwards, the ink in printing will not be tacky, is not bound on bottle. | By actual use checking, product of the present invention is after high-temperature shrinkage packaging, then overhaul, print Ink on product does not have tacky, and ink is not also bonded on bottle. |
| Shrinkage | After thermal contraction, ink layer does not rupture, and does not change colour. | After contraction, ink layer is not split, and word and pattern are remained in that completely, the color of ink Do not change. |
Detection data illustrate above, and the ink of the embodiment has good frost resistance, will not glue bottle, ink explosion, ink change
Color.
Embodiment 2
Polyurethane resin 28%, cellulose nitrate 9%, kaolin 3%, permanent yellow pigment 9.5%, tributyl 2-acetylcitrate
(ATBC) 1.5%, silica 0.5%, Tissuemat E 1%, isopropanol 10%, n-butanol 3%, n-propyl acetate 10%, ethyl acetate
24.5%。
Preparation method be the same as Example 1.
After testing, resulting Yellow ink performance is as follows：
| Performance indications | Performance requirement | Testing result |
| Anti-freezing property | Environment is at 0 DEG C, ink not jelly, the mobility still having had. | In the environment for ink being placed on 0 DEG C, after placing 24 hours, ink does not have jelly, has still had Mobility, ink can be used normally. |
| Resistance to elevated temperatures | In thermal contraction equipment, temperature is 170 ~ 200 DEG C of shrink wrappings Afterwards, the ink in printing will not be tacky, is not bound on bottle. | By actual use checking, product of the present invention is after high-temperature shrinkage packaging, then overhaul, print Ink on product does not have tacky, and ink is not also bonded on bottle. |
| Shrinkage | After thermal contraction, ink layer does not rupture, and does not change colour. | After contraction, ink layer is not split, and word and pattern are remained in that completely, the color of ink Do not change. |
Detection data illustrate above, and the ink of the embodiment has good frost resistance, will not glue bottle, ink explosion, ink change
Color.
Embodiment 3
Polyurethane resin 26%, cellulose nitrate 8%, kaolin 1%, permanent bordeaux pigment 10%, tributyl 2-acetylcitrate
(ATBC) 1.2%, silica 0.5%, Tissuemat E 1%, isopropanol 10%, n-butanol 4%, n-propyl acetate 15%, ethyl acetate
23.3%。
Preparation method be the same as Example 1.
After testing, resulting red ink performance is as follows：
| Performance indications | Performance requirement | Testing result |
| Anti-freezing property | Environment is at 0 DEG C, ink not jelly, the mobility still having had. | In the environment for ink being placed on 0 DEG C, after placing 24 hours, ink does not have jelly, has still had Mobility, ink can be used normally. |
| Resistance to elevated temperatures | In thermal contraction equipment, temperature is 170 ~ 200 DEG C of shrink wrappings Afterwards, the ink in printing will not be tacky, is not bound on bottle. | By actual use checking, product of the present invention is after high-temperature shrinkage packaging, then overhaul, print Ink on product does not have tacky, and ink is not also bonded on bottle. |
| Shrinkage | After thermal contraction, ink layer does not rupture, and does not change colour. | After contraction, ink layer is not split, and word and pattern are remained in that completely, the color of ink Do not change. |
Detection data illustrate above, and the ink of the embodiment has good frost resistance, will not glue bottle, ink explosion, ink change
Color.
Embodiment 4
Polyurethane resin 28%, cellulose nitrate 8%, kaolin 0%, phthalocyanine blue pigment 10%, tributyl 2-acetylcitrate
(ATBC) 1.8%, silica 0.5%, Tissuemat E 1%, isopropanol 12%, n-butanol 5%, n-propyl acetate 13%, ethyl acetate
20.7%。
Preparation method be the same as Example 1.
After testing, resulting blue ink performance is as follows：
| Performance indications | Performance requirement | Testing result |
| Anti-freezing property | Environment is at 0 DEG C, ink not jelly, the mobility still having had. | In the environment for ink being placed on 0 DEG C, after placing 24 hours, ink does not have jelly, has still had Mobility, ink can be used normally. |
| Resistance to elevated temperatures | In thermal contraction equipment, temperature is 170 ~ 200 DEG C of shrink wrappings Afterwards, the ink in printing will not be tacky, is not bound on bottle. | By actual use checking, product of the present invention is after high-temperature shrinkage packaging, then overhaul, print Ink on product does not have tacky, and ink is not also bonded on bottle. |
| Shrinkage | After thermal contraction, ink layer does not rupture, and does not change colour. | After contraction, ink layer is not split, and word and pattern are remained in that completely, the color of ink Do not change. |
Detection data illustrate above, and the ink of the embodiment has good frost resistance, will not glue bottle, ink explosion, ink change
Color.
Embodiment 5
Polyurethane resin 28%, cellulose nitrate 9%, kaolin 0%, charcoal blacks 11%, tributyl 2-acetylcitrate (ATBC)
1.5%, silica 0.5%, Tissuemat E 1.5%, isopropanol 10%, n-butanol 5%, n-propyl acetate 13%, ethyl acetate
20.5%。
Preparation method be the same as Example 1.
After testing, resulting black ink performance is as follows：
| Performance indications | Performance requirement | Testing result |
| Anti-freezing property | Environment is at 0 DEG C, ink not jelly, the mobility still having had. | In the environment for ink being placed on 0 DEG C, after placing 24 hours, ink does not have jelly, has still had Mobility, ink can be used normally. |
| Resistance to elevated temperatures | In thermal contraction equipment, temperature is 170 ~ 200 DEG C of shrink wrappings Afterwards, the ink in printing will not be tacky, is not bound on bottle. | By actual use checking, product of the present invention is after high-temperature shrinkage packaging, then overhaul, print Ink on product does not have tacky, and ink is not also bonded on bottle. |
| Shrinkage | After thermal contraction, ink layer does not rupture, and does not change colour. | After contraction, ink layer is not split, and word and pattern are remained in that completely, the color of ink Do not change. |
Detection data illustrate above, and the ink of the embodiment has good frost resistance, will not glue bottle, ink explosion, ink change
Color.
Claims (5)
1. a kind of ink of PE heat shrink films printing, it is characterized in that, include the component of following mass fraction：
Polyurethane resin 15~30%, cellulose nitrate 8~10%, kaolin 0~5%, pigment 8~32%, acetyl tributyl citrate three
Butyl ester 1~2%, silica 0.5~1%, Tissuemat E 1~3%, isopropanol 6~12%, n-butanol 1~5%, n-propyl acetate 8
~15%, ethyl acetate 15~30%.
2. the ink of PE heat shrink films printing according to claim 1, it is characterized in that, the pigment includes but is not limited to
Titanium dioxide, permanent yellow, permanent bordeaux, phthalocyanine blue or carbon black.
3. the ink of PE heat shrink films printing according to claim 2, it is characterized in that, when pigment selects titanium dioxide,
The mass fraction of the ink component is：Polyurethane tree 15~20%, cellulose nitrate 8~10%, kaolin 3~5%, titanium white
Powder 28~32%, tributyl 2-acetylcitrate 1~2%, silica 0.5~1%, Tissuemat E 1~3%, isopropanol 6~8%, just
Butanol 1~3%, n-propyl acetate 8~10%, ethyl acetate 15~20%.
4. the ink of PE heat shrink films printing according to claim 2, it is characterized in that, when pigment selection permanent yellow, forever
When fast red, phthalocyanine blue or carbon black, the mass fraction of the ink component is：
Polyurethane resin 20~30%, cellulose nitrate 8~10%, kaolin 0~3%, pigment 8~11%, acetyl tributyl citrate three
Butyl ester 1~2%, silica 0.5~1%, Tissuemat E 1~2%, isopropanol 8~12%, n-butanol 3~5%, n-propyl acetate 10
~15%, ethyl acetate 20~30%.
5. the preparation method of the printing-ink of the PE heat shrink films described in claim any one of 1-4, comprises the following steps：
(1) each component is prepared according to proportioning；
(2) isopropanol, n-butanol, n-propyl acetate and ethyl acetate are well mixed, obtain mixed solvent, then will mix molten
70~80% parts of agent gross mass are added in dispersion cylinder, under agitation, add cellulose nitrate, stirring to fiber
After plain nitrate is completely dissolved, sequentially add poly- propylhomoserin resin, tributyl 2-acetylcitrate, pigment, kaolin, Tissuemat E and
Silica, continues to stir, obtains the mixed material of pulpous state；
(3) when the mixed material for obtaining the step (2) is ground to mixed material fineness and reaches less than 15 microns, add
Remaining mixed solvent, is uniformly dispersed, and then filters, and produces ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710342852.2A CN107163677A (en) | 2017-05-16 | 2017-05-16 | A kind of ink of PE heat shrink films printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710342852.2A CN107163677A (en) | 2017-05-16 | 2017-05-16 | A kind of ink of PE heat shrink films printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107163677A true CN107163677A (en) | 2017-09-15 |
Family
ID=59816071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710342852.2A Pending CN107163677A (en) | 2017-05-16 | 2017-05-16 | A kind of ink of PE heat shrink films printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107163677A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796805A (en) * | 2018-12-29 | 2019-05-24 | 洋紫荆油墨（浙江）有限公司 | A kind of extraordinary flexographic ink and preparation method thereof suitable for PE shrink film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585603A (en) * | 2012-02-28 | 2012-07-18 | 东莞市正新包装制品有限公司 | Mixing printing ink for intaglio printing of polyethylene heat shrinking film |
| CN102702857A (en) * | 2012-07-06 | 2012-10-03 | 南雄市星辉化工新材料有限公司 | Benzene-free alcohol-resistant PET (polyethylene terephthalate) thermoshrinkable film plastic printing ink and preparation method thereof |
| CN104263075A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly white printing ink for printing of POF thermal contraction film and preparation method of white printing ink |
| CN104987771A (en) * | 2015-07-20 | 2015-10-21 | 东昌工业（临海）有限公司 | Environment-friendly printing ink for POF shrink film printing |
-
2017
- 2017-05-16 CN CN201710342852.2A patent/CN107163677A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585603A (en) * | 2012-02-28 | 2012-07-18 | 东莞市正新包装制品有限公司 | Mixing printing ink for intaglio printing of polyethylene heat shrinking film |
| CN102702857A (en) * | 2012-07-06 | 2012-10-03 | 南雄市星辉化工新材料有限公司 | Benzene-free alcohol-resistant PET (polyethylene terephthalate) thermoshrinkable film plastic printing ink and preparation method thereof |
| CN104263075A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly white printing ink for printing of POF thermal contraction film and preparation method of white printing ink |
| CN104987771A (en) * | 2015-07-20 | 2015-10-21 | 东昌工业（临海）有限公司 | Environment-friendly printing ink for POF shrink film printing |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796805A (en) * | 2018-12-29 | 2019-05-24 | 洋紫荆油墨（浙江）有限公司 | A kind of extraordinary flexographic ink and preparation method thereof suitable for PE shrink film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102548753B (en) | For the flexible membrane of the printing of packaging for foodstuff | |
| CN101457052B (en) | Gravure transparent ink and preparation method thereof | |
| CN101768388B (en) | Alcohol-soluble environmental intaglio aluminum foil ink and preparation method thereof | |
| US5637139A (en) | Citrus marking jet ink | |
| AU691599B2 (en) | An ink composition and method of printing using the composition | |
| CN102702857B (en) | Benzene-free alcohol-resistant PET (polyethylene terephthalate) thermoshrinkable film plastic printing ink and preparation method thereof | |
| CN101255297B (en) | Environment-friendly type joining material resin for printing ink | |
| CN101705060A (en) | Digital pre-laminating film | |
| CN101671510B (en) | High-gloss direct plating method binding layer coating as well as preparation method and application thereof | |
| CN100500432C (en) | Packaging material | |
| CN103254687B (en) | High-temperature resistant ester-soluble printing ink | |
| CN107163677A (en) | A kind of ink of PE heat shrink films printing and preparation method thereof | |
| CN109628011A (en) | Heat mounting film for printed matter | |
| CN102485814A (en) | Medicinal printing ink and preparation method thereof | |
| CN104962041B (en) | Self-repairing high-molecular memory material for tyre and using method thereof | |
| CN104710857A (en) | Novel aluminium foil gravure ink formula | |
| CN102423975A (en) | Shrink film thermal transfer method | |
| BR102015018906A2 (en) | heat transfer technology packaging label manufacturing process with sequential alphanumeric identification codes | |
| CN101659810B (en) | Environment-friendly compound printing ink | |
| CN111499909A (en) | Low-temperature-resistant high-firmness banner color band | |
| CN213506698U (en) | Scroll ribbon | |
| CN106566400A (en) | Water varnish for protection of printable aluminum foil for drug packing and preparation method of water varnish | |
| CN102719134B (en) | Benzene-free ketone-free universal compound gravure ink and preparation method thereof | |
| CN111690162A (en) | Scroll ribbon | |
| CN102485812A (en) | Medicinal printing ink and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170915 |