CN107163671A - A kind of aqueous suppression gloss oil and preparation method thereof - Google Patents
A kind of aqueous suppression gloss oil and preparation method thereof Download PDFInfo
- Publication number
- CN107163671A CN107163671A CN201710583609.XA CN201710583609A CN107163671A CN 107163671 A CN107163671 A CN 107163671A CN 201710583609 A CN201710583609 A CN 201710583609A CN 107163671 A CN107163671 A CN 107163671A
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- aqueous
- gloss oil
- water
- suppression
- oil
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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Abstract
Processing technique field is printed the present invention relates to wallpaper, more particularly to a kind of to be used for suppressing aqueous suppression gloss oil of wallpaper foaming and preparation method thereof, the aqueous suppression gloss oil is in percentage by weight, composed of the following components：Ethanol 24 ~ 31%, frothing inhibitor 17 ~ 21%, aqueous blending oil 48 ~ 59%, water-based thickener 0.5 ~ 1.5%.Compared with the conventional oil-based gloss oil that suppresses, there is this product production to facilitate, the features such as preparing and use simple, and the product of production is tasteless, voc contents are zero, environmental protection.
Description
Technical field
Processing technique field is printed the present invention relates to wallpaper, more particularly to a kind of aqueous suppression gloss oil and its preparation side
Method.
Background technology
Gloss oil, is the coating that use in printed matter surface decoration technology a kind of has ornamental and protectiveness, gloss oil warp
The techniques such as coating, levelling, drying are crossed, uniform and thin transparent bright layer can be formed in paper surface, with gorgeous hall
The surface gloss of emperor.Gloss oil is coated with printed matter can not only increase the value of print product, and can strengthen ink
Resistance to rotary light performance, increases solar heat protection, the moisture protection of ink, plays protection trace, improve the effect of print product performance.
In the production of wallpaper, the production of especially concavo-convex wallpaper is allowed to be presented recessed, it is necessary to use suppression gloss oil for suppressing wallpaper foaming
Convex uneven sense of touch, the technique is more at present to suppress gloss oil using oiliness, although although oiliness suppresses gloss oil and can reach good effect
Really, but oiliness suppresses the discharge of the aromatic hydrocarbon solvent such as toluene, butanone in gloss oil, influence printing worker's working environment, possible band
Carry out occupational disease hazards, or even cause atmosphere pollution.
The content of the invention
The invention provides aqueous suppression gloss oil of a kind of novel environment friendly and preparation method thereof, aqueous suppression light of the invention
Oil, tasteless, no organic volatile, with good glossiness, wearability and chemical resistance, is mainly used as producing concavo-convex wallpaper
Raw material, for suppressing wallpaper foaming, makes wallpaper that rough sense of touch is presented, enriches interior decoration.
The present invention is adopted the following technical scheme that：A kind of aqueous suppression gloss oil, in percentage by weight, by following components group
Into：Ethanol 24 ~ 31%, frothing inhibitor 17 ~ 21%, aqueous blending oil 48 ~ 59%, water-based thickener 0.5 ~ 1.5%.
In a preferred embodiment of the present invention, in percentage by weight, it is composed of the following components：Ethanol 27%, foaming
Inhibitor 19%, aqueous blending oil 53%, water-based thickener 1%.
As preferred, the frothing inhibitor is water-soluble phenylpropyl alcohol triazole.
As preferred, the water-based thickener is aqueous polyurethane thickener.
A kind of aqueous preparation method for suppressing gloss oil, including following preparation process：By above-mentioned percentage by weight, in a reservoir
Ethanol is first added, middle addition frothing inhibitor slow while stirring after stirring is completely dissolved for 10 minutes to frothing inhibitor, is added
Blending oil, after stirring, adjusts solution viscosity to 18 seconds/No. 3 cup with water-based thickener, is stirred for needed for producing within 30 minutes
Aqueous suppression gloss oil.
Compared with prior art, the beneficial effects of the present invention are：The present invention using the aqueous inhibitor of German import as main material,
The use of ethanol is solvent, is aided with part water-based emulsion and is prepared from, compared with conventional oil-based suppression gloss oil, this product has production
It is convenient, the features such as preparing and use simple, the product of production is tasteless, and voc contents are zero, environmental protection.This aqueous suppression gloss oil,
Change oiliness for a long time and suppress toluene in gloss oil, the emission problem of the aromatic hydrocarbon solvent such as butanone improves printing worker's work
Environment, reduces the occupational disease hazards therefore brought and atmosphere pollution, improves the environmental protection grade of print product.
Embodiment
To make the purpose of the present invention, technical scheme and effect clearer, clear and definite, below to the present invention further specifically
It is bright.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, but it is not intended to limit the present invention.
The aqueous suppression gloss oil of the present invention is a kind of raw material for being used to produce concavo-convex wallpaper, is mainly used in suppressing wallpaper hair
Bubble, general to make printing surface not foam using the intaglio printing aqueous suppression gloss oil during production, non-printed side foaming, so that wall
Rough sense of touch is presented in paper, enriches interior decoration.
The aqueous suppression gloss oil, is, using the aqueous inhibitor of German import as main material, the use of ethanol to be solvent, be aided with part water
Property the gloss oil with high texture environment protecting that is prepared from of emulsion, tasteless, voc contents are zero, can meet existing market to print
The environmental requirement of brush product.
Specifically, aqueous suppression gloss oil provided by the present invention, in percentage by weight, composed of the following components：
Ethanol 24 ~ 31%, frothing inhibitor 17 ~ 21%, aqueous blending oil 48 ~ 59%, water-based thickener 0.5 ~ 1.5%.
Wherein, the frothing inhibitor is water-soluble phenylpropyl alcohol triazole, and the water-based thickener thickens for aqueous polyurethane
Agent.
In the present embodiment, ethanol is purchased from market, and content need to be up to more than 95.Main function foams for dissolving in this formula
Inhibitor.
Frothing inhibitor uses the water-soluble phenylpropyl alcohol triazole from German Yang Ying groups, needle-like, Water/oil dual-purpose, in addition
When can heat, can not heat, can also use at normal temperatures.In this formula, used as PVC foam inhibitor, energy
Effectively control frostproof froth n degree in wallpaper foaming process.For example, foam wallpaper is by PVC paste shape resin, reheated after stamp
Foaming is formed.But foaming foaming agent used, such as AC foaming agents, foaming process is often difficult to control to, merely from addition
Upper allotment is difficult to make multi-level printing quality, and the wallpaper frothing inhibitor of Yang Ying groups of Germany, is added to foaming agent
During can effectively suppress foaming degree, turn white in addition, the inhibitor is also prevented from wallpaper, protection wallpaper inside color it is long
Time is stable, and especially for wallpaper beautiful in colour, the metal of the inside forever can slowly fade, can be effective with wallpaper inhibitor
Improve the anti oxidation time of wallpaper.
Aqueous blending oil, the flow-like transparent body, mainly by water-based acrylic resin, water-based emulsion and the polymerization of a variety of auxiliary agents
Form, with film forming speed it is fast, do not flow side, do not glue it is colored, non-foaming, without any smell, it is non-ignitable, nontoxic the features such as.In this formula
In, used as bridging agent, adhesive force of the enhancing gloss oil to paper.General ink company is on sale, domestic east star ink, the sincere water of Hao
Ink, just new ink has production.
Water-based thickener uses aqueous polyurethane thickener, in this formula, for adjusting gloss oil liquid viscosity.
Embodiment 1
A kind of aqueous suppression gloss oil, it is in percentage by weight, composed of the following components：Ethanol 27%, water-soluble phenylpropyl alcohol triazole
19%, aqueous blending oil 53%, aqueous polyurethane thickener 1%.
Preparation method：Under normal temperature, by above-mentioned percentage by weight, ethanol is first added in a reservoir, is slowly added to while stirring
Frothing inhibitor, after stirring is completely dissolved for 10 minutes to frothing inhibitor, adds blending oil, after stirring, with aqueous thickening
Agent adjusts solution viscosity to 18 seconds/No. 3 cup（The numerical value is measured using international viscosity detector）, 30 points of moderate-speed mixer
Clock produces institute's water requiremen and suppresses gloss oil.The aqueous suppression gloss oil obtained is filtered using 150 gauzes, and is distributed into 16L or 30L plastics
Bucket, sealing preserve is stand-by.
Embodiment 2
A kind of aqueous suppression gloss oil, it is in percentage by weight, composed of the following components：Ethanol 24.5%, the water-soluble nitrogen of phenylpropyl alcohol three
Azoles 17%, aqueous blending oil 57%, aqueous polyurethane thickener 1.5%.
Preparation method is identical with embodiment 1.
Embodiment 3
A kind of aqueous suppression gloss oil, it is in percentage by weight, composed of the following components：Ethanol 30.5%, the water-soluble nitrogen of phenylpropyl alcohol three
Azoles 21%, aqueous blending oil 48%, aqueous polyurethane thickener 0.5%.
Preparation method is identical with embodiment 1.
Claims (5)
1. a kind of aqueous suppression gloss oil, in percentage by weight, composed of the following components：Ethanol 24 ~ 31%, frothing inhibitor
17 ~ 21%, aqueous blending oil 48 ~ 59%, water-based thickener 0.5 ~ 1.5%.
2. aqueous suppression gloss oil according to claim 1, it is characterised in that：In percentage by weight, by following components
Composition：Ethanol 27%, frothing inhibitor 19%, aqueous blending oil 53%, water-based thickener 1%.
3. the aqueous suppression gloss oil according to claim 1-2 any one, it is characterised in that：The frothing inhibitor is water
Dissolubility phenylpropyl alcohol triazole.
4. the aqueous suppression gloss oil according to claim 1-2 any one, it is characterised in that：The water-based thickener is water
Property polyurethane thickener.
5. a kind of preparation method of aqueous suppression gloss oil as described in claim 1 ~ 2 any one, it is characterised in that：Including
Following preparation process：By above-mentioned percentage by weight, ethanol is first added in a reservoir, and middle addition foaming slow while stirring suppresses
Agent, after stirring is completely dissolved for 10 minutes to frothing inhibitor, adds blending oil, after stirring, and adjusts molten with water-based thickener
Fluid viscosity is stirred for producing within 30 minutes institute's water requiremen suppression gloss oil to 18 seconds/No. 3 cup.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710583609.XA CN107163671A (en) | 2017-07-18 | 2017-07-18 | A kind of aqueous suppression gloss oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710583609.XA CN107163671A (en) | 2017-07-18 | 2017-07-18 | A kind of aqueous suppression gloss oil and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107163671A true CN107163671A (en) | 2017-09-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710583609.XA Pending CN107163671A (en) | 2017-07-18 | 2017-07-18 | A kind of aqueous suppression gloss oil and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030130376A1 (en) * | 2001-10-25 | 2003-07-10 | Ramasamy Krishnan | Publication gravure printing inks based on silicone modified water-based emulsions |
| CN1644795A (en) * | 2004-12-03 | 2005-07-27 | 华南理工大学 | Acrylic acid emulsion gloss, oil, its production and use |
| CN103215859A (en) * | 2013-05-06 | 2013-07-24 | 淮北诺菲雅新材壁纸有限公司 | Non-woven embossed wallpaper |
| CN103694787A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Special-purpose water-base 3D (Three-Dimensional) piling printing ink for wallpaper gravure printing and preparation method thereof |
| CN104005262A (en) * | 2014-06-03 | 2014-08-27 | 山西金博雅油墨科技有限责任公司 | Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish |
| CN105672052A (en) * | 2016-01-12 | 2016-06-15 | 新乡市胜美壁纸有限公司 | Preparation technology of matte imitating foamed wallpaper |
-
2017
- 2017-07-18 CN CN201710583609.XA patent/CN107163671A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030130376A1 (en) * | 2001-10-25 | 2003-07-10 | Ramasamy Krishnan | Publication gravure printing inks based on silicone modified water-based emulsions |
| CN1644795A (en) * | 2004-12-03 | 2005-07-27 | 华南理工大学 | Acrylic acid emulsion gloss, oil, its production and use |
| CN103215859A (en) * | 2013-05-06 | 2013-07-24 | 淮北诺菲雅新材壁纸有限公司 | Non-woven embossed wallpaper |
| CN103694787A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Special-purpose water-base 3D (Three-Dimensional) piling printing ink for wallpaper gravure printing and preparation method thereof |
| CN104005262A (en) * | 2014-06-03 | 2014-08-27 | 山西金博雅油墨科技有限责任公司 | Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish |
| CN105672052A (en) * | 2016-01-12 | 2016-06-15 | 新乡市胜美壁纸有限公司 | Preparation technology of matte imitating foamed wallpaper |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170915 |
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