CN107163386A - A kind of polypropylene recovery material purification and reuse method - Google Patents

A kind of polypropylene recovery material purification and reuse method Download PDF

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Publication number
CN107163386A
CN107163386A CN201710387715.0A CN201710387715A CN107163386A CN 107163386 A CN107163386 A CN 107163386A CN 201710387715 A CN201710387715 A CN 201710387715A CN 107163386 A CN107163386 A CN 107163386A
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CN
China
Prior art keywords
recovery material
polypropylene recovery
purification
polypropylene
aeo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710387715.0A
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Chinese (zh)
Inventor
江玉庆
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Suzhou Ma Peide Office Appliance Manufacturing Co Ltd
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Suzhou Ma Peide Office Appliance Manufacturing Co Ltd
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Publication date
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Priority to CN201710387715.0A priority Critical patent/CN107163386A/en
Publication of CN107163386A publication Critical patent/CN107163386A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/06Recovery or working-up of waste materials of polymers without chemical reactions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/04Chemical paint or ink removers with surface-active agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B2017/001Pretreating the materials before recovery
    • B29B2017/0015Washing, rinsing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Abstract

The present invention relates to a kind of purification of polypropylene recovery material and reuse method, chemical is used to clean polypropylene recovery material at 25 ~ 35 DEG C with except removal ink, wherein, described chemical is 3 ~ 20 by volume ratio:1~4:1 water, AEO 9, AEO 20 are constituted;Polypropylene recovery material after cleaning is crushed;Polypropylene recovery material after crushing is carried out cleaning filtering to remove heavy impurity;Polypropylene recovery material after cleaning is granulated;Polypropylene recovery material after granulation is separated to remove metal impurities;Polypropylene recovery material after separation is dried to the purification completed to described polypropylene recovery material.The method of purification of the present invention successfully eliminates the printing-ink on polypropylene recovery material surface and the pigment of inside, removes other impurities, product surface does not have the defects such as bubble current mark, product mechanical performance, which is met, to be required, percent defective is reduced to 0.5%, reduces plastics cost, reduces the pollution to environment.

Description

A kind of polypropylene recovery material purification and reuse method
Technical field
The invention belongs to the plastics such as stationery watercolor pencil stationery processing and manufacturing industry, and in particular to a kind of polypropylene recovery material purification And reuse method.
Background technology
The polypropylene (PP) such as production in the market and the watercolor pencil scrapped after stationery watercolor pencil and use post sales is returned The composition of material includes:Thermoprint and screen printing ink, pigment, other impurities.Ink main component is:Colorant+binder+auxiliary agent (defoamer+diluent+plasticizer+ultra-violet absorber+drier), ink adhesion is strong, is mixed into PP plastics, in high temperature note It is moulded into type, easily decomposes and cause the defects such as the bubble current mark of injecting products, and polyacrylic molecular chain structure can be destroyed, causes Plastic degradation, weakens PP mechanical strength.
It because PP feed backs are printed ink, pigment and other impurities pollution, therefore can not directly recycle, cause huge Waste, if the production of PP feed backs Direct Regeneration is used, the product of production has the defects such as bubble current mark, impurity, and mechanical performance reaches Less than requiring.
In the prior art, the proportion generally according to PP is 0.905kg/m3, its proportion characteristic smaller than water enter PP feed backs Row physical cleaning, that is, put it into after being stirred 10 minutes in clear water and filter, but this method can not wash ink, using physics PP feed backs progress after cleaning, which is molded obtained product, still more than 35% bubble current mark and impurity percent defective.
Therefore, exploitation PP purification and reuse method, the percent defective reduction for recycling PP feed backs, can be enterprise's band Come economical and reduce pollution, meet environmental requirement.
The content of the invention
The technical problems to be solved by the invention are to provide purification and the reuse method of a kind of polypropylene recovery material, thus side Polypropylene recovery material after method purification is again after injection molding, and the percent defective of product is low.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:
It is an object of the present invention to provide a kind of method of purification of polypropylene recovery material, comprise the following steps:
Step (1), at 25~35 DEG C chemical is used to clean polypropylene recovery material with except removal ink, its In, described chemical is 3~20 by volume ratio:1~4:1 water, AEO-9, AEO-20 composition;
Step (2), by through step (1) clean after polypropylene recovery material crushed;
Step (3), the polypropylene recovery material after being crushed through step (2) is subjected to cleaning filtering to remove heavy impurity;
Step (4), by through step (3) clean after polypropylene recovery material granulated;
Step (5), by through step (4) granulate after polypropylene recovery material separated to remove metal impurities;
Step (6), by through step (5) separate after polypropylene recovery material be dried completion to described polypropylene recovery material Purification.
In the present invention, polypropylene recovery material refers to the plastics stationery such as watercolor pencil, the e-Pointer scrapped.
Preferably, the temperature cleaned in step (1) is 28~32 DEG C, more preferably 30 DEG C.
Preferably, in step (1), described water, described AEO-9, described AEO-20 volume ratio are 18~20:3 ~4:1.It is further preferred that described water, described AEO-9, described AEO-20 volume ratio are 20:4:1.
In the present invention, it is considered to environmental issue, it is to avoid secondary pollution, select with good emulsion dispersion ability, well Acid-fast alkali-proof ability, good biodegradability and avirulent O/W types microemulsion AEO-9 and AEO-20.
Preferably, in step (3), after being cleaned to described polypropylene recovery material, described polypropylene recovery material is carried out Dry.It is further preferred that using blowing drying in step (3).
Because polypropylene recovery material is colourful, therefore, the polypropylene recovery material after recovery can not be used directly, therefore, this hair It is bright preferably, after step (3), before step (4), described method of purification also includes the step matched colors to polypropylene recovery material Suddenly.
It is further preferred that by the polypropylene recovery material after color matching gross mass for based on 100%, the formula of described color matching For:95~97% polypropylene recovery material, 3~5% concentration black color masterbatch.It is further preferable that the formula of described color matching is: 96% polypropylene recovery material, 4% concentration black color masterbatch.
Preferably, in step (4), granulated using extruder, the head of described extruder is provided with 70~100 mesh Screen pack is to remove undissolved impurity.It is further preferred that being filtered using 80 mesh screen packs.
Preferably, step (5) is separated using apparatus for separating metals to described polypropylene recovery material.
Preferably, through the packaged polypropylene recovery material examined after must purifying of step (6) dried polypropylene recovery material.
It is a further object to provide a kind of reuse method of polypropylene recovery material, using above-mentioned polypropylene recovery material Method of purification polypropylene recovery material is purified, then add and accounted for after described purification into the polypropylene recovery material after purification After the nucleator of polypropylene recovery material quality 0.5% be molded obtaining finished product.
Due to polypropylene, feed back is reprocessed after time processing, its mechanical performance and intensity decreases, if using purification Polypropylene recovery material Direct Regeneration production product afterwards, product cracking and insufficient strength, therefore, the present invention is by poly- third after purification Nucleator is added in alkene feed back, warpage is shunk to improve polyacrylic crystallization rate and reduce, bending coefficient, increase poly- third is improved The intensity of alkene, the intensity requirement for making it meet product.
Preferably, described nucleator is Hyperfrom nucleators, more preferably HPN-68L.
Preferably, described finished product is scissors.
The commercially available acquisition of AEO-9, AEO-20, concentration black color masterbatch, HPN-68L used in the present invention.
Because above-mentioned technical proposal is used, the present invention has following advantages compared with prior art:
The method of purification of the present invention successfully eliminates the printing-ink on polypropylene recovery material surface and the pigment of inside, removes Other impurities, so as to not have the defects such as bubble current mark, product machine using the product surface of the polypropylene recovery material reproduction after purification Tool performance, which is met, to be required, percent defective is reduced to 0.5%, and method of the invention reduces plastics cost, reduces the dirt to environment Dye, this method can expand to the application of whole industry, with huge social economic effect.
Embodiment
The application is described in detail with reference to embodiment, but the application is not limited to these embodiments.
Embodiment 1 to 4, comparative example 1:A kind of purification of polypropylene recovery material and reuse method, comprise the following steps:
Step (1), in the first cleaning machine use chemical to clean polypropylene recovery material, except removal ink, to change The formula and cleaning temperature for learning cleaning agent are shown in Table 1;
Step (2), by through step (1) clean after polypropylene recovery material crushed in pulverizer;
Step (3), by through step (2) crush after polypropylene recovery material is carried out in the second cleaning machine with water cleaning filter with Heavy impurity is removed, drying is then blowed;
Step (4), by through step (3) handle after polypropylene recovery material and concentration black color masterbatch be stirred in mixer Color matching, wherein, the quality that feeds intake of polypropylene recovery material is 96%, and the quality that feeds intake of concentration black color masterbatch is 4%;
Step (5), by through step (4) match colors after polypropylene recovery material granulated in an extruder, wherein, extruder Head is provided with 80 mesh screen packs to remove undissolved impurity;
Step (6), the polypropylene recovery material after being granulated through step (5) is subjected to separating and filtering to remove in apparatus for separating metals Metal impurities;
Step (7), by through step (6) separate after polypropylene recovery material be dried in drying machine;
Step (8), it will be packed through step (7) dried polypropylene recovery material in packing machine so as to follow-up recycling;
Step (9), packaged polypropylene recovery material tested, injection production is carried out after the assay was approved obtain finished product to cut Knife, wherein, the addition of nucleator and the test data of finished product scissors are referring to table 1.
Table 1
The embodiment of the present invention 4 shrinks warpage and reduces 0.3% compared with comparative example 1.
Purification and reuse method using the present invention, it is annual to reduce 100 tons of waste material, reduce plastics cost 100*5000= 500000 RMB, reduce environmental pollution, with huge social economic effect.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention, all according to the present invention The equivalent change or modification that Spirit Essence is made, should all be included within the scope of the present invention.

Claims (10)

1. a kind of method of purification of polypropylene recovery material, it is characterised in that:Comprise the following steps:
Step(1), at 25 ~ 35 DEG C use chemical to clean polypropylene recovery material with except removal ink, wherein, it is described Chemical by volume ratio be 3 ~ 20:1~4:1 water, AEO-9, AEO-20 composition;
Step(2), will be through step(1)Polypropylene recovery material after cleaning is crushed;
Step(3), will be through step(2)Polypropylene recovery material after crushing carries out cleaning filtering to remove heavy impurity;
Step(4), will be through step(3)Polypropylene recovery material after cleaning is granulated;
Step(5), will be through step(4)Polypropylene recovery material after granulation is separated to remove metal impurities;
Step(6), will be through step(5)Completion carrying to described polypropylene recovery material is dried in polypropylene recovery material after separation It is pure.
2. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Step(1)It is middle to be cleaned Temperature is 28 ~ 32 DEG C.
3. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Step(1)In, described water, Described AEO-9, described AEO-20 volume ratio are 18 ~ 20:3~4:1.
4. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Step(3)In, described is gathered After propylene feed back is cleaned, described polypropylene recovery material is dried.
5. the method for purification of the polypropylene recovery material according to claim 1 or 4, it is characterised in that:In step(3)Afterwards, step (4)Before, the step of described method of purification also includes matching colors to polypropylene recovery material.
6. the method for purification of polypropylene recovery material according to claim 5, it is characterised in that:By the polypropylene recovery material after color matching Gross mass be 100% meter, the formula of described color matching is:95 ~ 97% polypropylene recovery material, 3 ~ 5% concentration black color masterbatch.
7. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Step(4)In, using extruder Granulated, the head of described extruder is provided with 70 ~ 100 mesh screen packs to remove undissolved impurity.
8. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Step(5)Separated using metal Device is separated to described polypropylene recovery material.
9. the method for purification of polypropylene recovery material according to claim 1, it is characterised in that:Through step(6)It is dried poly- The packaged polypropylene recovery material examined after must purifying of propylene feed back.
10. a kind of reuse method of polypropylene recovery material, it is characterised in that:Using poly- any one of claim 1 to 9 The method of purification of propylene feed back is purified to polypropylene recovery material, is then added into the polypropylene recovery material after purification described in accounting for After the nucleator of polypropylene recovery material quality 0.5% after purification be molded obtaining finished product.
CN201710387715.0A 2017-05-27 2017-05-27 A kind of polypropylene recovery material purification and reuse method Pending CN107163386A (en)

Priority Applications (1)

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CN201710387715.0A CN107163386A (en) 2017-05-27 2017-05-27 A kind of polypropylene recovery material purification and reuse method

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Application Number Priority Date Filing Date Title
CN201710387715.0A CN107163386A (en) 2017-05-27 2017-05-27 A kind of polypropylene recovery material purification and reuse method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115663324A (en) * 2022-08-05 2023-01-31 西安交通大学 Restoration and regeneration process for retired battery diaphragm

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Publication number Priority date Publication date Assignee Title
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CN101863091A (en) * 2010-06-12 2010-10-20 广州丽盈塑料有限公司 Recovery method of package level high-density polyethylene and polypropylene
CN102173007A (en) * 2011-01-30 2011-09-07 路洪洲 Method for recycling thermoplastic polypropylene plastic parts of scraped automobile
CN102952425A (en) * 2012-11-19 2013-03-06 南京信息工程大学 Water-based printing ink cleaning agent and preparation method thereof

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JP2002194154A (en) * 2000-12-27 2002-07-10 Sharp Corp Molded article reclaimed from waste of polypropylene resin and its reclaiming method
CN101863091A (en) * 2010-06-12 2010-10-20 广州丽盈塑料有限公司 Recovery method of package level high-density polyethylene and polypropylene
CN102173007A (en) * 2011-01-30 2011-09-07 路洪洲 Method for recycling thermoplastic polypropylene plastic parts of scraped automobile
CN102952425A (en) * 2012-11-19 2013-03-06 南京信息工程大学 Water-based printing ink cleaning agent and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115663324A (en) * 2022-08-05 2023-01-31 西安交通大学 Restoration and regeneration process for retired battery diaphragm
CN115663324B (en) * 2022-08-05 2023-10-20 西安交通大学 Retired battery diaphragm repairing and regenerating process

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Application publication date: 20170915