CN107163350A - A kind of CABLE MATERIALS with antimildew function and preparation method thereof - Google Patents
A kind of CABLE MATERIALS with antimildew function and preparation method thereof Download PDFInfo
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- CN107163350A CN107163350A CN201710536018.7A CN201710536018A CN107163350A CN 107163350 A CN107163350 A CN 107163350A CN 201710536018 A CN201710536018 A CN 201710536018A CN 107163350 A CN107163350 A CN 107163350A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention belongs to electric power field of material technology there is provided a kind of CABLE MATERIALS with antimildew function and preparation method thereof, the described CABLE MATERIALS with antimildew function includes the raw material of following parts by weight：50 75 parts of high density polyethylene (HDPE), 16 29 parts of POE, 19 parts of maleic anhydride grafted polyethylene, 2,45 parts of 5 dimethyl, 2,5 di-tert-butyl peroxide hexane, 13 parts of fire retardant, 5 11 parts of mould inhibitor, 12 parts of antioxidant, 1.3 3.2 parts of plasticizer, 13 parts of compatilizer.A kind of CABLE MATERIALS with antimildew function that the present invention is provided, adds mould inhibitor and antioxidant again in basic material so that the CABLE MATERIALS of preparation both has antimycotic effect, meanwhile, influence the performance of original CABLE MATERIALS without the addition because of antiseptic.
Description
Technical field
The invention belongs to electric power field of material technology, specifically, a kind of CABLE MATERIALS and its preparation side with antimildew function
Method.
Background technology
Present fire-retardant polyethylene cable material has been largely used to electric wire, communication cable, data cable, power cable and heat tracing electricity
The functional materials such as cable, especially with industrial fast development and the continuous improvement of people's living standard, people are to environment and certainly
I increasingly payes attention to health, in life, inevitably touches with bacterium, the electric wire of mould, data wire, so as to derive
Many diseases, or even threat to life.
Since 21 century, cable industry also expands the demand to antibacterial CABLE MATERIALS therewith, wherein, to mould proof fire-retardant
The demand of polyethylene is especially big.Current flame-proof polyethylene is widely used in super-pressure flame retardant cable and Important Project, therefore
Requirement to its mould proof performance also more and more higher, but because flame-proof polyethylene is that resistance is added on the basis of polyvinyl resin
Fire agent to be made, so to the resistance of mould and bacterium be not as so strong as common polythene material.In the prior art, flame-proof polyethylene
CABLE MATERIALS is big most without mould-proof function；Or mould-proof function is not notable, it is impossible to meet the demand of user；Or it is because anti-
Species or the concentration addition of microbial inoculum are improper and cause antibacterial CABLE MATERIALS performance to be decreased obviously, and Ag ' is easily separated out during contact water, and antibacterial has
The effect phase is short, and application value is low, because add antiseptic and cause other critical natures of fire-retardant polyethylene cable material impacted and
Reduce the technological deficiencies such as the value of the CABLE MATERIALS.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of CABLE MATERIALS with antimildew function and preparation
Method.
A kind of CABLE MATERIALS with antimildew function provided according to an aspect of the present invention, the described electricity with antimildew function
Cable material includes the raw material of following parts by weight：50-75 parts of high density polyethylene (HDPE), 16-29 parts of ethylene-octene copolymer, maleic acid
1-9 parts of acid anhydride grafted polyethylene, 4-5 parts of 2,5- dimethyl -2,5- di-tert-butyl peroxide hexane, 1-3 parts of fire retardant, mould inhibitor 5-
11 parts, 1-2 parts of antioxidant, 1.3-3.2 parts of plasticizer, 1-3 parts of compatilizer.
Preferably, the mould inhibitor composition is mixture of Chinese herbal medicines.
Preferably, described mixture of Chinese herbal medicines includes the raw material of following parts by weight：10-15 parts of tree-of-heaven leaf, Ligusticum wallichii 20-
35 parts, 10-11 parts of Chinese yam, 8-12 parts of the bark of eucommia, 3-7 parts of cacumen biotae, 2-6 parts of kuh-seng, 4-8 parts of the tuber of stemona, 1-5 parts of granatum, pine needle
1-4 parts, 2-7 parts of muskmelon pedicel, above-mentioned each composition are mixed after crushed.
Preferably, the fire retardant is halogen-free flame retardants.
Preferably, the halogen-free flame retardants is organophosphor or organophosphor-nitrogen.
Preferably, the compatilizer is PE-g-MAH, and wherein PE melt index is 0.2-10.
Preferably, the antioxidant includes the raw material of following parts by weight：8-12 parts of p-methyl phenol, cyclohexane solvent 30-
50 parts, 0.1-0.15 parts of zirconium sulfate catalyst, 0.8-1.5 parts of large porous strong acid resin catalyst, above-mentioned each raw material is weighed in proportion
Mixing.
There is provided a kind of cable preparation method for material with antimildew function, methods described bag according to another aspect of the present invention
Include following steps：
Step 1: weighing high density polyethylene (HDPE), ethylene-octene copolymer, maleic anhydride according to weight proportion is grafted poly- second
Alkene, 2,5- dimethyl -2,5- di-tert-butyl peroxides hexane are well mixed；
Step 2: the mixture is put into banburying 5-10min in banbury, 152 DEG C -158 DEG C of mixing temperature adds successively
Enter fire retardant, mould inhibitor, antioxidant, plasticizer, compatilizer, discharged after being well mixed, extruded machine pelletizing production line prepares institute
State CABLE MATERIALS.
Compared with prior art, the present invention has following beneficial effect：
(1) a kind of CABLE MATERIALS with antimildew function that the present invention is provided, adds mould inhibitor and anti-again in basic material
Oxidant so that the CABLE MATERIALS of preparation both has antimycotic effect, meanwhile, influence original without the addition because of antiseptic
The performance of CABLE MATERIALS.It is easily long that CABLE MATERIALS produced by the present invention effectively suppresses eight kinds of cables such as aspergillus niger, Aspergillus terreus, Aureobasidium pullulans
Growth, shaping and the breeding of mould, make cable from the infringement of mould；Avoid people mould because being touched using electric wire
Bacterium, it is unhealthful；On the basis of in guarantee electric wire, other are functional, it can avoid being forced to change electricity because of fungus growth
Cable, causes to waste；
(2) a kind of CABLE MATERIALS with antimildew function that the present invention is provided, the antioxidant raw material sources are extensively, green
Environmental protection, pollution-free phenomenon, consumption economy.The present invention has high inoxidizability, and water-fast or wash resistant agent bleeding property is fabulous, no
Discoloration, ageing resistace is excellent, has great enhancing effect to mould proof.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.
Embodiment 1
A kind of CABLE MATERIALS with antimildew function that the present embodiment is provided, the described CABLE MATERIALS with antimildew function includes
The raw material of following parts by weight：75 parts of high density polyethylene (HDPE), 16 parts of ethylene-octene copolymer, maleic anhydride grafted polyethylene 9
Part, 4 parts of 2,5- dimethyl -2,5- di-tert-butyl peroxides hexane, 3 parts of fire retardant, 5 parts of mould inhibitor, 2 parts of antioxidant, plasticizer
1.3 parts, 3 parts of compatilizer.
Wherein, the mould inhibitor composition is mixture of Chinese herbal medicines.
Wherein, described mixture of Chinese herbal medicines includes the raw material of following parts by weight：15 parts of tree-of-heaven leaf, 20 parts of Ligusticum wallichii, mountain
11 parts of medicine, 8 parts of the bark of eucommia, 7 parts of cacumen biotae, 2 parts of kuh-seng, 8 parts of the tuber of stemona, 1 part of granatum, 4 parts of pine needle, 2 parts of muskmelon pedicel, it is above-mentioned it is each into
Divide and mix after crushed.
Wherein, the fire retardant is halogen-free flame retardants.Halogen-free flame retardants halogen containing polymers or combined with halogen containing flame-retardant and
Into flame-retardant mixture there is excellent fire resistance.
Wherein, the halogen-free flame retardants is organophosphor or organophosphor-nitrogen.Organic phosphorus flame retardant is most important in fire retardant
One of kind, with fire-retardant and plasticising double effects, can make it is fire-retardant fully achieve non-halogen, improve the stream in plastic shaping
Dynamic performance, suppresses the residue after burning, and the poisonous gas and corrosive gas of generation are fewer than halogen flame, its fire retardant mechanism
For：One side fire retardant is produced phosphoric acid, metaphosphoric acid, poly-metaphosphoric acid by thermal decomposition, and these phosphoric acids have strong dehydration property, can
Make polymer surfaces dehydration carbonization, and the combustion by evaporation and the decomposition combustion that produce flame can not occur for simple substance carbon, so with resistance
Combustion is acted on；Another aspect fire retardant is heated to produce PO free radicals, HHO free radicals can be largely absorbed, so as to interrupt burning
Reaction.Organic phosphorus flame retardant mainly has phosphate, phosphonate ester and phosphine oxide and heterocyclic etc..
Wherein, the compatilizer is PE-g-MAH, and wherein PE melt index is 10.
Wherein, the antioxidant includes the raw material of following parts by weight：12 parts of p-methyl phenol, 30 parts of cyclohexane solvent, sulphur
Sour 0.15 part of Zr catalyst, 0.8 part of large porous strong acid resin catalyst, weigh above-mentioned each raw material mixing in proportion.
Embodiment 2
A kind of CABLE MATERIALS with antimildew function that the present embodiment is provided, the described CABLE MATERIALS with antimildew function includes
The raw material of following parts by weight：50 parts of high density polyethylene (HDPE), 29 parts of ethylene-octene copolymer, maleic anhydride grafted polyethylene 1
Part, 5 parts of 2,5- dimethyl -2,5- di-tert-butyl peroxides hexane, 1 part of fire retardant, 11 parts of mould inhibitor, 1 part of antioxidant, plasticizer
3.2 parts, 1 part of compatilizer.
Wherein, the mould inhibitor composition is mixture of Chinese herbal medicines.
Wherein, described mixture of Chinese herbal medicines includes the raw material of following parts by weight：10 parts of tree-of-heaven leaf, 35 parts of Ligusticum wallichii, mountain
10 parts of medicine, 12 parts of the bark of eucommia, 3 parts of cacumen biotae, 6 parts of kuh-seng, 4 parts of the tuber of stemona, 5 parts of granatum, 1 part of pine needle, 7 parts of muskmelon pedicel, it is above-mentioned each
Composition is mixed after crushed.
Wherein, the fire retardant is halogen-free flame retardants.Halogen-free flame retardants halogen containing polymers or combined with halogen containing flame-retardant and
Into flame-retardant mixture there is excellent fire resistance.
Wherein, the halogen-free flame retardants is organophosphor or organophosphor-nitrogen.Organic phosphorus flame retardant is most important in fire retardant
One of kind, with fire-retardant and plasticising double effects, can make it is fire-retardant fully achieve non-halogen, improve the stream in plastic shaping
Dynamic performance, suppresses the residue after burning, and the poisonous gas and corrosive gas of generation are fewer than halogen flame, its fire retardant mechanism
For：One side fire retardant is produced phosphoric acid, metaphosphoric acid, poly-metaphosphoric acid by thermal decomposition, and these phosphoric acids have strong dehydration property, can
Make polymer surfaces dehydration carbonization, and the combustion by evaporation and the decomposition combustion that produce flame can not occur for simple substance carbon, so with resistance
Combustion is acted on；Another aspect fire retardant is heated to produce PO free radicals, HHO free radicals can be largely absorbed, so as to interrupt burning
Reaction.Organic phosphorus flame retardant mainly has phosphate, phosphonate ester and phosphine oxide and heterocyclic etc..
Wherein, the compatilizer is PE-g-MAH, and wherein PE melt index is 0.2.
Wherein, the antioxidant includes the raw material of following parts by weight：12 parts of p-methyl phenol, 30-50 parts of cyclohexane solvent,
0.1 part of zirconium sulfate catalyst, 1.5 parts of large porous strong acid resin catalyst, weigh above-mentioned each raw material mixing in proportion.
Embodiment 3
A kind of CABLE MATERIALS with antimildew function that the present embodiment is provided, the described CABLE MATERIALS with antimildew function includes
The raw material of following parts by weight：53 parts of high density polyethylene (HDPE), 17 parts of ethylene-octene copolymer, maleic anhydride grafted polyethylene 3
Part, 4 parts of 2,5- dimethyl -2,5- di-tert-butyl peroxides hexane, 2 parts of fire retardant, 7 parts of mould inhibitor, 1 part of antioxidant, plasticizer
1.7 parts, 2 parts of compatilizer.
Wherein, the mould inhibitor composition is mixture of Chinese herbal medicines.
Wherein, described mixture of Chinese herbal medicines includes the raw material of following parts by weight：12 parts of tree-of-heaven leaf, 25 parts of Ligusticum wallichii, mountain
10 parts of medicine, 9 parts of the bark of eucommia, 6 parts of cacumen biotae, 5 parts of kuh-seng, 5 parts of the tuber of stemona, 4 parts of granatum, 3 parts of pine needle, 3 parts of muskmelon pedicel, it is above-mentioned it is each into
Divide and mix after crushed.
Wherein, the fire retardant is halogen-free flame retardants.Halogen-free flame retardants halogen containing polymers or combined with halogen containing flame-retardant and
Into flame-retardant mixture there is excellent fire resistance.
Wherein, the halogen-free flame retardants is organophosphor or organophosphor-nitrogen.Organic phosphorus flame retardant is most important in fire retardant
One of kind, with fire-retardant and plasticising double effects, can make it is fire-retardant fully achieve non-halogen, improve the stream in plastic shaping
Dynamic performance, suppresses the residue after burning, and the poisonous gas and corrosive gas of generation are fewer than halogen flame, its fire retardant mechanism
For：One side fire retardant is produced phosphoric acid, metaphosphoric acid, poly-metaphosphoric acid by thermal decomposition, and these phosphoric acids have strong dehydration property, can
Make polymer surfaces dehydration carbonization, and the combustion by evaporation and the decomposition combustion that produce flame can not occur for simple substance carbon, so with resistance
Combustion is acted on；Another aspect fire retardant is heated to produce PO free radicals, HHO free radicals can be largely absorbed, so as to interrupt burning
Reaction.Organic phosphorus flame retardant mainly has phosphate, phosphonate ester and phosphine oxide and heterocyclic etc..
Wherein, the compatilizer is PE-g-MAH, and wherein PE melt index is 0.2-10.
Wherein, the antioxidant includes the raw material of following parts by weight：9 parts of p-methyl phenol, 40 parts of cyclohexane solvent, sulfuric acid
0.12 part of Zr catalyst, 0.9 part of large porous strong acid resin catalyst, weigh above-mentioned each raw material mixing in proportion.
Experiment test：
According to the raw material and proportioning described in embodiment 1-3, prepare the CABLE MATERIALS with antimildew function, be divided into 1 group, 2 groups, 3
Group, it is control group to take commercially available common CABLE MATERIALS.Ultraviolet light and aging experiment and fungus-proof test, degradation are carried out to above-mentioned each group
Condition is UVB313 type uviol lamps, and radiation energy is 0.63W/m2/nm；It is first 60 DEG C of radiation 4h in blackboard temperature that conditions of exposure, which is,
Stop radiation afterwards, 4h is condensed at 50 DEG C；Open-assembly time is 1000h.
Test index is that the test result of tensile strength, elongation at break, tearing strength and mildew degree is as shown in table 1.
The test result list of table 1
As can be seen here, the CABLE MATERIALS with antimildew function that the present invention is provided, than general CABLE MATERIALS good mechanical property, and
With significant mildew-proof function.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of CABLE MATERIALS with antimildew function, it is characterised in that：The described CABLE MATERIALS with antimildew function includes as follows
The raw material of parts by weight：50-75 parts of high density polyethylene (HDPE), 16-29 parts of ethylene-octene copolymer, maleic anhydride grafted polyethylene
1-9 parts, 4-5 parts of 2,5- dimethyl -2,5- di-tert-butyl peroxide hexane, 1-3 parts of fire retardant, 5-11 parts of mould inhibitor, antioxidant
1-2 parts, 1.3-3.2 parts of plasticizer, 1-3 parts of compatilizer.
2. a kind of CABLE MATERIALS with antimildew function according to claim 1, it is characterised in that：The mould inhibitor composition is
Mixture of Chinese herbal medicines.
3. a kind of CABLE MATERIALS with antimildew function according to claim 2, it is characterised in that：Described Chinese herbal medicine mixing
Thing includes the raw material of following parts by weight：10-15 parts of tree-of-heaven leaf, 20-35 parts of Ligusticum wallichii, 10-11 parts of Chinese yam, 8-12 parts of the bark of eucommia, side
3-7 parts of CedarLeaves, 2-6 parts of kuh-seng, 4-8 parts of the tuber of stemona, 1-5 parts of granatum, 1-4 parts of pine needle, 2-7 parts of muskmelon pedicel, above-mentioned each composition warp
Mixed after crushing.
4. a kind of CABLE MATERIALS with antimildew function according to claim 1, it is characterised in that：The fire retardant is Halogen
Fire retardant.
5. a kind of CABLE MATERIALS with antimildew function according to claim 4, it is characterised in that：The halogen-free flame retardants is
Organophosphor or organophosphor-nitrogen.
6. a kind of CABLE MATERIALS with antimildew function according to claim 1, it is characterised in that：The compatilizer is PE-
G-MAH, wherein PE melt index are 0.2-10.
7. a kind of CABLE MATERIALS with antimildew function according to claim 1, it is characterised in that：The antioxidant is included such as
The raw material of lower parts by weight：8-12 parts of p-methyl phenol, 30-50 parts of cyclohexane solvent, 0.1-0.15 parts of zirconium sulfate catalyst, macropore
0.8-1.5 parts of strong acid resin catalyst, weighs above-mentioned each raw material mixing in proportion.
8. a kind of preparation method of CABLE MATERIALS with antimildew function as described in claim any one of 1-7, it is characterised in that：
Comprise the following steps：
Step 1: high density polyethylene (HDPE), ethylene-octene copolymer, maleic anhydride grafted polyethylene, 2 are weighed according to weight proportion,
5- dimethyl -2,5- di-tert-butyl peroxides hexane is well mixed；
Step 2: the mixture is put into banburying 5-10min in banbury, 152 DEG C -158 DEG C of mixing temperature sequentially adds resistance
Agent, mould inhibitor, antioxidant, plasticizer, compatilizer are fired, is discharged after being well mixed, extruded machine pelletizing production line prepares the electricity
Cable material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710536018.7A CN107163350A (en) | 2017-07-04 | 2017-07-04 | A kind of CABLE MATERIALS with antimildew function and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710536018.7A CN107163350A (en) | 2017-07-04 | 2017-07-04 | A kind of CABLE MATERIALS with antimildew function and preparation method thereof |
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| CN201710536018.7A Withdrawn CN107163350A (en) | 2017-07-04 | 2017-07-04 | A kind of CABLE MATERIALS with antimildew function and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102210A (en) * | 2018-02-07 | 2018-06-01 | 合肥安力电力工程有限公司 | A kind of Environment-friendlyflame-retardant flame-retardant cable material and preparation method thereof |
| CN108912457A (en) * | 2018-07-18 | 2018-11-30 | 合肥安力电力工程有限公司 | A kind of cracking resistance anti-corrosion cable material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702598A (en) * | 2012-05-22 | 2012-10-03 | 常州大学 | Halogen-free flame-retardant polyolefin cable material capable of resisting 150 DEG C and preparation method thereof |
-
2017
- 2017-07-04 CN CN201710536018.7A patent/CN107163350A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702598A (en) * | 2012-05-22 | 2012-10-03 | 常州大学 | Halogen-free flame-retardant polyolefin cable material capable of resisting 150 DEG C and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102210A (en) * | 2018-02-07 | 2018-06-01 | 合肥安力电力工程有限公司 | A kind of Environment-friendlyflame-retardant flame-retardant cable material and preparation method thereof |
| CN108912457A (en) * | 2018-07-18 | 2018-11-30 | 合肥安力电力工程有限公司 | A kind of cracking resistance anti-corrosion cable material and preparation method thereof |
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Application publication date: 20170915 |