CN107162077A - A kind of aluminium manufacturer's sewage water treatment method - Google Patents

A kind of aluminium manufacturer's sewage water treatment method Download PDF

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Publication number
CN107162077A
CN107162077A CN201710531969.5A CN201710531969A CN107162077A CN 107162077 A CN107162077 A CN 107162077A CN 201710531969 A CN201710531969 A CN 201710531969A CN 107162077 A CN107162077 A CN 107162077A
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China
Prior art keywords
sewage
aluminium manufacturer
water treatment
treatment method
layer
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CN201710531969.5A
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Chinese (zh)
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CN107162077B (en
Inventor
尚圣杰
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Jieshou City Essence Sti Consultation Service Co Ltd
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Jieshou City Essence Sti Consultation Service Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14Diatomaceous earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28066Surface area, e.g. B.E.T specific surface area being more than 1000 m2/g
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/11Turbidity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Water Treatment By Sorption (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of aluminium manufacturer's sewage water treatment method, it is related to technical field of sewage, a kind of aluminium manufacturer's sewage water treatment method, put into aluminium manufacturer's sewage in sewage disposal ball 1, aluminium manufacturer's sewage per ton and put into 5kg sewage disposal ball, aluminium manufacturer's sewage water treatment method of the present invention, high treating effect, efficiency high.

Description

A kind of aluminium manufacturer's sewage water treatment method
Technical field
The invention belongs to technical field of sewage, and in particular to a kind of aluminium manufacturer's sewage water treatment method.
Background technology
Aluminum i ndustry is the important foundation raw material industry of the national economic development.Since reform and opening-up, by decades Effort, China has turned into world aluminum production, consumption big country, while also having evolved into the aluminium section bar production and processing of global maximum State.However, as shown by data is held with industries such as transportation, construction industry, real estate, food packing industry, household electrical appliances and electronics The development of continuous quick health, China's aluminium alloy extrusions market demand capacity is still very huge, and market prospects are very wide.
The development of aluminum i ndustry along with large amount of sewage generation, if its sewage without processing, arbitrarily discharge if, it is right Environment causes great destruction, the safety of the drinking water of serious threat people.
The content of the invention
The purpose of the present invention is that there is provided a kind of aluminium manufacturer's sewage water treatment method the problem of being directed to existing.
The present invention is achieved by the following technical solutions:
A kind of aluminium manufacturer's sewage water treatment method, puts into sewage disposal ball, aluminium manufacturer's sewage per ton into aluminium manufacturer's sewage and puts into 5-10kg Sewage disposal ball;
The sewage disposal ball is made up of three-decker, respectively sandwich layer, intermediate layer and outer layer, intermediate layer parcel sandwich layer, outer layer Wrap up intermediate layer;
The sandwich layer presses 10-15 by activated sludge and fibert based active carbon:1 mass ratio is mixed;
The intermediate layer 3-5 is pressed by alga oligosaccharides, cyclodextrin, gelatin:6-8:4-6 mass ratios are mixed;
The outer layer adds ultra-fine carbon dust, sintering aid and binding agent, successively by 15-18 using diatomite as primary raw material:1-2: 3-6:0.5-0.8 mass ratio is mixed.
Further, the outer layer is hollow ball structure, and intermediate layer is hollow ball structure, the solid spherical structure in sandwich layer position.
Further, hazelnut shell is was crushed 120 mesh sieves by the fibert based active carbon preparation method, by overcritical Carbon dioxide treatment, processing pressure is 6MPa, and processing time is 20-25min, and carbonization temperature is 380 DEG C, and carbonization time is 2 small When, activation process is then carried out, temperature of living in is 620 DEG C, and soak time is 90min.
Further, the fibert based active carbon specific surface area is 2950m2/g, and micro pore volume is 0.34cm3/g.
Further, the sintering aid is bentonite.
Further, the binding agent is lac resin.
Further, the outer layer preparation method is:After diatomite is uniformly mixed with sintering aid, 250 mesh sieves are crossed, so Calcined 2 hours at 500-540 DEG C afterwards, then naturally cool to 450 DEG C, add ultra-fine carbon dust, after uniform mixing, insulation 30min, then room temperature is naturally cooled to, then mixed with binding agent, outer layer is made.
The sewage disposal bulb diameter is 4cm, and the sandwich layer maximum gauge is 2cm, and intermediate layer maximum gauge is 3cm, outside Layer maximum gauge is 4cm.
The present invention has advantages below compared with prior art:The present invention handles aluminium by using the sewage disposal ball of preparation Factory's sewage, treatment effeciency is high, and high treating effect can handle 1 ton of aluminium manufacturer's sewage, energy every time using 5-10kg sewage disposal ball Reach circular treatment 10-20 times;The sewage disposal ball prepared in the present invention is made of three layers of different structure, and sandwich layer is become silted up using activity Mud is mixed with fibert based active carbon by certain mass ratio, by the association that fibert based active carbon is added in activated sludge Same-action, can improve that simple activated sludge is poor to COD, ammonia nitrogen removal effect in sewage, and especially winter temperature is relatively low In the case of, the drawbacks of effect is worse, by the way that activated sludge is wrapped in into sewage disposal core layer, can avoid activated sludge with Water is washed dilution or reduces the situation of wastewater treatment efficiency because mud accumulation is fixed on bottom, by the way that sewage disposal is made Ball, sewage disposal ball can pass through the diatom of the preparation on sewage disposal ball top layer with drainage flow without being destroyed by force by sewage Soil, with fabulous adsorption function, can be adsorbed a large amount of suspension, silica in sewage well, in Interbed can be acted synergistically with sandwich layer, and effective removal can be carried out to the COD in sewage, SS, ammonia nitrogen and other ions, be removed Rate is good, and removal effect is thorough, efficiency high.
Figure of description
Fig. 1 is sewage disposal chou composition.
Embodiment
Embodiment 1
A kind of aluminium manufacturer's sewage water treatment method, input 5kg in sewage disposal ball 1, aluminium manufacturer's sewage per ton is put into aluminium manufacturer's sewage Sewage disposal ball 1;
The sewage disposal ball 1 is made up of three-decker, respectively sandwich layer 4, intermediate layer 3 and outer layer 2, the parcel sandwich layer of intermediate layer 3 4, the parcel of outer layer 2 intermediate layer 3;
The sandwich layer presses 10 by activated sludge and fibert based active carbon:1 mass ratio is mixed;
3 are pressed by alga oligosaccharides, cyclodextrin, gelatin in the intermediate layer:6:4 mass ratios are mixed;
The outer layer adds ultra-fine carbon dust, sintering aid and binding agent, successively by 15 using diatomite as primary raw material:1:3:0.5 Mass ratio be mixed.
The outer layer is hollow ball structure, and intermediate layer is hollow ball structure, the solid spherical structure in sandwich layer position.
Hazelnut shell is was crushed 120 mesh sieves by the fibert based active carbon preparation method, by supercritical carbon dioxide Processing, processing pressure is 6MPa, and processing time is 20min, and carbonization temperature is 380 DEG C, and carbonization time is 2 hours, is then carried out Activation process, temperature of living in is 620 DEG C, and soak time is 90min.
The fibert based active carbon specific surface area is 2950m2/g, and micro pore volume is 0.34cm3/g.
The sintering aid is bentonite.
The binding agent is lac resin.
The outer layer preparation method is:After diatomite is uniformly mixed with sintering aid, 250 mesh sieves are crossed, then in 500- Calcined 2 hours at 540 DEG C, then naturally cool to 450 DEG C, add ultra-fine carbon dust, after uniform mixing, be incubated 30min, then it is natural Room temperature is cooled to, is then mixed with binding agent, outer layer is made.
The sewage disposal bulb diameter is 4cm, and the sandwich layer maximum gauge is 2cm, and intermediate layer maximum gauge is 3cm, outside Layer maximum gauge is 4cm.
Embodiment 2
A kind of aluminium manufacturer's sewage water treatment method, input 10kg in sewage disposal ball 1, aluminium manufacturer's sewage per ton is put into aluminium manufacturer's sewage Sewage disposal ball 1;
The sewage disposal ball 1 is made up of three-decker, respectively sandwich layer 4, intermediate layer 3 and outer layer 2, the parcel sandwich layer of intermediate layer 3 4, the parcel of outer layer 2 intermediate layer 3;
The sandwich layer presses 15 by activated sludge and fibert based active carbon:1 mass ratio is mixed;
5 are pressed by alga oligosaccharides, cyclodextrin, gelatin in the intermediate layer: 8:6 mass ratios are mixed;
The outer layer adds ultra-fine carbon dust, sintering aid and binding agent, successively by 18 using diatomite as primary raw material: 2: 6: 0.8 mass ratio is mixed.
The outer layer is hollow ball structure, and intermediate layer is hollow ball structure, the solid spherical structure in sandwich layer position.
Hazelnut shell is was crushed 120 mesh sieves by the fibert based active carbon preparation method, by supercritical carbon dioxide Processing, processing pressure is 6MPa, and processing time is 25min, and carbonization temperature is 380 DEG C, and carbonization time is 2 hours, is then carried out Activation process, temperature of living in is 620 DEG C, and soak time is 90min.
The fibert based active carbon specific surface area is 2950m2/g, and micro pore volume is 0.34cm3/g.
The sintering aid is bentonite.
The binding agent is lac resin.
The outer layer preparation method is:After diatomite is uniformly mixed with sintering aid, 250 mesh sieves are crossed, then in 500- Calcined 2 hours at 540 DEG C, then naturally cool to 450 DEG C, add ultra-fine carbon dust, after uniform mixing, be incubated 30min, then it is natural Room temperature is cooled to, is then mixed with binding agent, outer layer is made.
The sewage disposal bulb diameter is 4cm, and the sandwich layer maximum gauge is 2cm, and intermediate layer maximum gauge is 3cm, outside Layer maximum gauge is 4cm.
Embodiment 3
A kind of aluminium manufacturer's sewage water treatment method, puts into sewage disposal ball 1, aluminium manufacturer's sewage per ton into aluminium manufacturer's sewage and puts into 5-10kg Sewage disposal ball 1;
The sewage disposal ball 1 is made up of three-decker, respectively sandwich layer 4, intermediate layer 3 and outer layer 2, the parcel sandwich layer of intermediate layer 3 4, the parcel of outer layer 2 intermediate layer 3;
The sandwich layer presses 12 by activated sludge and fibert based active carbon:1 mass ratio is mixed;
4 are pressed by alga oligosaccharides, cyclodextrin, gelatin in the intermediate layer:7:5 mass ratios are mixed;
The outer layer adds ultra-fine carbon dust, sintering aid and binding agent, successively by 17 using diatomite as primary raw material:1-2:5: 0.6 mass ratio is mixed.
The outer layer is hollow ball structure, and intermediate layer is hollow ball structure, the solid spherical structure in sandwich layer position.
Hazelnut shell is was crushed 120 mesh sieves by the fibert based active carbon preparation method, by supercritical carbon dioxide Processing, processing pressure is 6MPa, and processing time is 22min, and carbonization temperature is 380 DEG C, and carbonization time is 2 hours, is then carried out Activation process, temperature of living in is 620 DEG C, and soak time is 90min.
The fibert based active carbon specific surface area is 2950m2/g, and micro pore volume is 0.34cm3/g.
The sintering aid is bentonite.
The binding agent is lac resin.
The outer layer preparation method is:After diatomite is uniformly mixed with sintering aid, 250 mesh sieves are crossed, then in 500- Calcined 2 hours at 540 DEG C, then naturally cool to 450 DEG C, add ultra-fine carbon dust, after uniform mixing, be incubated 30min, then it is natural Room temperature is cooled to, is then mixed with binding agent, outer layer is made.
The sewage disposal bulb diameter is 4cm, and the sandwich layer maximum gauge is 2cm, and intermediate layer maximum gauge is 3cm, outside Layer maximum gauge is 4cm.
Comparative example 1:Differed only in embodiment 1 only with equivalent amount of active sludge treatment.
Comparative example 2:Differed only in embodiment 1 in sewage disposal ball center core layer without fibert based active carbon.
Comparative example 3:Differed only in embodiment 1 in sewage disposal ball intermediate layer without alga oligosaccharides.
Comparative example 4;Differed only in embodiment 1 in sewage disposal ectosphere without ultra-fine carbon dust.
Comparative example 5:Differed only in embodiment 1 in sewage disposal ectosphere without sintering aid bentonite.
Experiment:
Handled using aluminium manufacturer's waste water of such as table 1 as sample waste water:
Table 1
Discharge standard/《Integrated wastewater standard of drainage》(GB8978-1996)
CODCr(mg/L) 1200 ≤90
SS(mg/L) 155 ≤60
Ammonia nitrogen (mg/L) 22 ≤10
Turbidity 60 ≤10
pH 12 6-9
Above-mentioned aluminium manufacturer's waste water is handled with method in comparative example with embodiment, contrasted:
Table 2
CODCr(mg/L) SS(mg/L) Ammonia nitrogen (mg/L) Turbidity pH
Embodiment 1 33 55 6 5 8
Embodiment 2 31 52 5 4 8
Embodiment 3 32 53 6 5 8
Comparative example 1 200 102 14 32 11
Comparative example 2 65 78 9 8 9
Comparative example 3 35 57 10 6 8
Comparative example 4 38 58 7 6 8
Comparative example 5 40 61 6 7 8
As can be seen from Table 2, sewage water treatment method of the present invention is to aluminium manufacturer's good sewage processing effect.

Claims (7)

1. a kind of aluminium manufacturer's sewage water treatment method, it is characterised in that sewage disposal ball, aluminium manufacturer's sewage per ton are put into aluminium manufacturer's sewage Middle input 5-10kg sewage disposal ball;
The sewage disposal ball is made up of three-decker, respectively sandwich layer, intermediate layer and outer layer, intermediate layer parcel sandwich layer, outer layer Wrap up intermediate layer;
The sandwich layer presses 10-15 by activated sludge and fibert based active carbon:1 mass ratio is mixed;
The intermediate layer 3-5 is pressed by alga oligosaccharides, cyclodextrin, gelatin:6-8:4-6 mass ratios are mixed;
The outer layer adds ultra-fine carbon dust, sintering aid and binding agent, successively by 15-18 using diatomite as primary raw material:1-2: 3-6:0.5-0.8 mass ratio is mixed.
2. a kind of aluminium manufacturer's sewage water treatment method according to claim 1, it is characterised in that the outer layer is hollow chou Structure, intermediate layer is hollow ball structure, the solid spherical structure in sandwich layer position.
3. a kind of aluminium manufacturer's sewage water treatment method according to claim 1, it is characterised in that the fibert based active carbon system Hazelnut shell is was crushed 120 mesh sieves by Preparation Method, and by supercritical carbon dioxide treatment, processing pressure is 6MPa, processing time For 20-25min, carbonization temperature is 380 DEG C, and carbonization time is 2 hours, then carries out activation process, and temperature of living in is 620 DEG C, Soak time is 90min.
4. a kind of aluminium manufacturer's sewage water treatment method according to claim 3, it is characterised in that the fibert based active carbon ratio Surface area is 2950m2/g, and micro pore volume is 0.34cm3/g.
5. a kind of aluminium manufacturer's sewage water treatment method according to claim 1, it is characterised in that the sintering aid is swelling Soil.
6. a kind of aluminium manufacturer's sewage water treatment method according to claim 1, it is characterised in that the binding agent is lac tree Fat.
7. a kind of aluminium manufacturer's sewage water treatment method according to claim 1, it is characterised in that the outer layer preparation method is: After diatomite is uniformly mixed with sintering aid, 250 mesh sieves are crossed, are then calcined 2 hours at 500-540 DEG C, it is then naturally cold But to 450 DEG C, ultra-fine carbon dust is added, after uniform mixing, 30min is incubated, then naturally cool to room temperature, it is then mixed with binding agent Close, outer layer is made.
CN201710531969.5A 2017-07-03 2017-07-03 A kind of aluminium manufacturer's sewage water treatment method Expired - Fee Related CN107162077B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585075A (en) * 2018-05-19 2018-09-28 陈文� A kind of high-efficient sewage material for water treatment and preparation method thereof
CN110127805A (en) * 2019-06-18 2019-08-16 山东虎力机械有限公司 A kind of processing method of sewage
CN110127804A (en) * 2019-06-18 2019-08-16 山东虎力机械有限公司 A kind of sewage treating material
CN112717893A (en) * 2020-12-02 2021-04-30 青岛科技大学 Sewage treatment agent and application thereof in heavy metal wastewater
CN113087034A (en) * 2021-03-31 2021-07-09 南京金湖环保科技有限公司 Coated purification deodorant for sewage treatment and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000271033A (en) * 1999-03-24 2000-10-03 Kvk Corp Shower head
CN101537279A (en) * 2008-03-17 2009-09-23 戴长虹 Water treatment filtering material
CN102951696A (en) * 2012-11-16 2013-03-06 内蒙古民族大学 Application of modified activated carbon in sewage treatment

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000271033A (en) * 1999-03-24 2000-10-03 Kvk Corp Shower head
CN101537279A (en) * 2008-03-17 2009-09-23 戴长虹 Water treatment filtering material
CN102951696A (en) * 2012-11-16 2013-03-06 内蒙古民族大学 Application of modified activated carbon in sewage treatment

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585075A (en) * 2018-05-19 2018-09-28 陈文� A kind of high-efficient sewage material for water treatment and preparation method thereof
CN110127805A (en) * 2019-06-18 2019-08-16 山东虎力机械有限公司 A kind of processing method of sewage
CN110127804A (en) * 2019-06-18 2019-08-16 山东虎力机械有限公司 A kind of sewage treating material
CN110127805B (en) * 2019-06-18 2020-05-19 江苏永威环境科技股份有限公司 Sewage treatment method
CN110127804B (en) * 2019-06-18 2020-07-07 工大环境股份有限公司 Sewage treatment material
CN112717893A (en) * 2020-12-02 2021-04-30 青岛科技大学 Sewage treatment agent and application thereof in heavy metal wastewater
CN112717893B (en) * 2020-12-02 2022-05-27 宿迁博辰科技信息有限公司 Sewage treatment agent and application thereof in heavy metal wastewater
CN113087034A (en) * 2021-03-31 2021-07-09 南京金湖环保科技有限公司 Coated purification deodorant for sewage treatment and preparation process thereof

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