A kind of roof of the vehicle high intensity sandwich base material and its production method
Technical field
The present invention relates to roof of the vehicle base material processing technique field, more specifically to a kind of roof of the vehicle with high-strength
Spend sandwich base material and its production method.
Background technology
At present, the automobile ceiling sandwich base material of PU+GF+PE structures has two kinds of processing technologys, i.e., using PE
Or the PP thermoplasticity dry process bonded and the thermosetting wet processing being molded using PU reactions.
Existing roof of the vehicle sandwich base material, it is mostly be using non-woven fabrics, rubber powder, glass, glued membrane, PU plate shapes into
Composite construction, this composite construction needs have good cohesive force between each layer, while need to have high intensity and springform
Amount, wherein the intensity of this composite construction is provided mainly by PU plates and glass, but due to dry formed automotive ceiling sandwich
The process conditions limitation of base material, when PU panel densities are higher than 40kg/m3When, sandwich substrate forming can be impacted, its table
Easily there is the phenomenon of injustice in face;And when glass fiber content is too high, the addition of rubber powder and glued membrane will also increase on year-on-year basis, input cost
Increase, otherwise can cause the problem of sandwich base material cohesive force declines.Therefore, it is existing for the higher roof of the vehicle of intensity requirement
Some technologies can not further be increased roof of the vehicle intensity.For this problem, a kind of vehicle top how is researched and developed
The problem of canopy is current urgent need to resolve with the good sandwich base material of high intensity, cohesive force and its production method.
Sandwich base material its production method that roof of the vehicle is made of polyurethane plate mainly has following several:
Through retrieval, Chinese patent CN101088742, be on automobile ceiling production technology, the process production
Multilayer composite board of polyurethane is to unreel non-woven fabrics on the conveyer belt of recombination line, sow or lay successively short glass fiber,
Hot melt adhesive stick, PU plates, short glass fiber, hot melt adhesive stick, are heated to 150-260 DEG C, in certain pressure through recombination line
Under it is heated, cooling after composite board is made.Although the production technology is to go out Rigid foam polyurethane by One-step production, by
The hot melt adhesive stick used in production process is poor with polyurethane cohesive force, and glass stratum reticulare is easily layered up and down.
Chinese patent CN101628498, is the production method on polyurethane plate for automobile ceiling:Will be first multiple
Non-woven fabrics, short glass fiber, hot-melt adhesive powder are tiled or sowed on the crawler belt of conjunction machine, then in certain temperature and pressure
Under obtain glue glass cloth;Then tile glue glass cloth, adhesive film, rigid polyurethane successively from bottom to top on the workbench of composite production line
Plate is steeped, then short glass fiber, hot-melt adhesive powder are sowed successively on hard polyurethane foam plate, tile hot melt adhesive film, certain temperature
Multilayer composite board of polyurethane is obtained with compound under pressure, this usual intensity of composite board and modulus of elasticity have certain limitation.
Chinese patent CN2011103980826, this application case discloses a kind of roof of the vehicle sandwich base material and its life
Production method, it is by I layers of non-woven fabrics, the first short glass fiber layer, the first PUR bisque, the first hot melt adhesive film to be characterized in it
Layer, PU flaggies, the second short glass fiber layer, the first type sandwich base material of the second PUR bisque composition;In first type sandwich base
The second PUR film layer and the 3rd PUR bisque are set on material successively, the 4th hot-melt adhesive powder is set successively under first type sandwich base material
II layers of layer, the 3rd short glass fiber and non-woven fabrics;Its production method is that each layer is combined into roof of the vehicle sandwich through roll-in
Base material, but the sandwich base material can not generally meet the requirement of roof of the vehicle high intensity under special circumstances.
The content of the invention
1. the invention technical problem to be solved
It is an object of the invention to overcome the problem of its intensity of roof of the vehicle is not enough in the prior art, there is provided a kind of roof of the vehicle
With high intensity sandwich base material and its production method, need what is strengthened on correspondence roof of the vehicle using technical scheme
Strengthen cloth using glass and local strengthening is carried out to sandwich base material in position so that sandwich base material disclosure satisfy that roof of the vehicle is high-strength
The demand of degree, while the interlayer of sandwich base material has good cohesive force, makes it have good dimensional stability.
2. technical scheme
To reach above-mentioned purpose, the technical scheme that the present invention is provided is:
A kind of roof of the vehicle high intensity sandwich base material of the present invention, including base material and glass strengthen cloth, and the base material is under
It is supreme to be followed successively by the first PET nonwoven layers, the first GF fiberglass layers, the first PE rubber powders layer, the first PE adhesive films or PP adhesive films, PU
Flaggy, the 2nd GF fiberglass layers, the 2nd PE rubber powders layer, the 2nd PE adhesive films or PP adhesive films, the glass strengthen cloth and are arranged on base
Corresponding its, which is made, on material needs the position of local strengthening on roof of the vehicle, the first PE adhesive films or PP adhesive films and PU flaggies
Between, be equipped with glass between the 2nd PE rubber powders layer and the 2nd PE adhesive films or PP adhesive films and strengthen cloth, the base material and glass
Strengthen cloth and high intensity sandwich base material is made through roll-forming together;
The glass strengthen cloth be by the 2nd PET nonwoven layers in orlop, be then sequentially provided with thereon the 3rd GF fiberglass layers,
3rd PE rubber powders layer, the 3rd PE adhesive films or PP adhesive films, then each layer composite construction through roll-forming together;
Wherein, glass between the first PE adhesive films or PP adhesive films and PU flaggies strengthen the 3rd PE adhesive films in cloth or
PP adhesive films are contacted with PU flaggies, and the 2nd PE rubber powders layer and the glass between the 2nd PE adhesive films or PP adhesive films strengthen cloth
In the 3rd PE adhesive films or PP adhesive films contacted with the 2nd PE adhesive films or PP adhesive films.
A kind of production method of roof of the vehicle high intensity sandwich base material of the present invention, its step is as follows:
(1)Make and strengthen cloth:It is to use the 2nd PET non-woven fabrics, the 3rd GF glasses, the 3rd PE rubber powders, the 3rd PE glued membranes or PP
The composite I of glued membrane formation, making step is as follows:
Step one:Tile the 2nd PET non-woven fabrics on the conveyer belt of composite production line, then sows or lay successively in the above the
Three GF glasses, the 3rd PE rubber powders, the 3rd PE glued membranes or PP glued membranes formation composite I;
Step 2:Composite I is sent into heating furnace using crawler type special conveying device to be preheated, preheating temperature is 140-
160 DEG C, preheating time is 2-5s;
Then reuse crawler type special conveying device and composite I is sent into electrical heating area using radiant type heating, heating temperature
Spend for 160-210 DEG C, the heat time is 20-30s;
Step 3:Heated composite I is pressed in the case where pressure is 3.0-6.0bar pressure roller;
Step 4:Composite I after pressing is sent into the temperature of water cooling to be cooled down in 8-28 DEG C of coldplate, glass is made
Fibre strengthens cloth;
Step 5:The glass cooled down reinforcement cloth is wound;
(2)Make high intensity sandwich base material:Tile the first PET non-woven fabrics on the conveyer belt of composite production line, then thereon
Sow or lay successively the first GF glasses, the first PE rubber powders, the first PE glued membranes or PP glued membranes, glass and strengthen cloth, PU plates, second in face
GF glasses, the 2nd PE rubber powders, glass strengthen cloth, the 2nd PE glued membranes or PP glued membranes formation composite II, then using 180-250
DEG C temperature heats 30-80s to composite II, and finally carrying out roll-in to composite II under 7-12MPa pressure is combined, cooling
High intensity sandwich base material is made afterwards.
It is used as further improvement of the present invention, the particle diameter of the 3rd PE rubber powders(α)It is distributed as:
3rd PE rubber powders of α >=220 μm account for mass percent≤6% of total 3rd PE rubber powders;
220μm>The mass percent that 3rd PE rubber powders of α >=110 μm account for total 3rd PE rubber powders is 51 ± 10%;
110μm>The mass percent that 3rd PE rubber powders of α >=77 μm account for total 3rd PE rubber powders is 30 ± 10%;
77 μm of α < the 3rd PE rubber powders account for mass percent≤13% of total 3rd PE rubber powders.
As further improvement of the present invention, the weight per unit area of the 2nd PET non-woven fabrics is 30-55g/m2,
Size changing rate %:L≥-2.0 T≥-1.5.
As further improvement of the present invention, the Cutting Length of the 3rd GF glasses is 20-30mm, and it, which is cut, is sprinkling upon the
Weight per unit area on two PET non-woven fabrics is 25-55g/m2。
As further improvement of the present invention, the 3rd PE adhesive films or PP adhesive film weight per unit areas are
25-55g/m2, and its temperature in laying is 110-140 DEG C.
As further improvement of the present invention, the weight per unit area that the glass strengthens cloth is 140-210 g/m2。
3. beneficial effect
The technical scheme provided using the present invention, compared with prior art, with following remarkable result:
The present invention by between the first PE adhesive films or PP adhesive films and PU flaggies, the 2nd PE rubber powders layer and the 2nd PE glued membranes
Glass is equipped between layer or PP adhesive films and strengthens cloth, the shaping of sandwich base material is on the one hand ensure that, on the other hand improves
The local strength of sandwich base material, meets the use demand of higher-strength roof of the vehicle, while the present invention is by rationally setting
Glass strengthens cloth layers of material, and makes the reasonable process parameter for strengthening cloth, high intensity sandwich base material by setting so that glass
Fibre strengthens cloth while high intensity is met so that high intensity sandwich base material interlayer has good caking property, it is ensured that three
The dimensional stability of Mingzhi's base material, while there is its one side away from non-woven fabrics higher cohesive force to combine to form automobile with facial ornament
Ceiling, and this sandwich base material has good flatness.
Brief description of the drawings
Fig. 1 is a kind of structural representation of roof of the vehicle high intensity sandwich base material of the present invention;
Fig. 2 strengthens the structural representation of cloth for glass in the present invention.
Label declaration in schematic diagram:
1st, the first PET nonwoven layers;2nd, the first GF fiberglass layers;3rd, the first PE rubber powders layer;4th, the first PE adhesive films or PP adhesive films;
5th, PU flaggies;6th, the 2nd GF fiberglass layers;7th, the 2nd PE rubber powders layer;8th, the 2nd PE adhesive films or PP adhesive films;9th, glass strengthens cloth;
91st, the 2nd PET nonwoven layers;92nd, the 3rd GF fiberglass layers;93rd, the 3rd PE rubber powders layer;94th, the 3rd PE adhesive films or PP glue
Film layer.
Embodiment
To further appreciate that present disclosure, the present invention is described in detail in conjunction with the accompanying drawings and embodiments.
Embodiment 1
As shown in Figure 1 and Figure 2, a kind of roof of the vehicle of the present embodiment high intensity sandwich base material, including base material and glass are strengthened
Cloth 9, base material sequentially consists of the first PET nonwoven layers 1, the first GF fiberglass layers 2, the first PE rubber powders the 3, the first PE glued membranes of layer
Layer or PP adhesive films 4, PU flaggies 5, the 2nd GF fiberglass layers 6, the 2nd PE rubber powders the 7, the 2nd PE adhesive films of layer or PP adhesive films 8, glass
Fibre reinforcement cloth 9, which is arranged on base material corresponding its and is made, needs the position of local strengthening on roof of the vehicle, the first PE adhesive films or PP
Glass reinforcement is equipped between adhesive film 4 and PU flaggies 5, between the 2nd PE rubber powders layer 7 and the 2nd PE adhesive films or PP adhesive films 8
Cloth 9, herein what deserves to be explained is, two pieces of glasses strengthen cloth 9 and corresponded to need the position of local strengthening on roofs of the vehicle, base material and
Glass strengthens cloth 9 and high intensity sandwich base material is made through roll-forming together.
It is, in orlop, the 3rd GF glasses to be then sequentially provided with thereon by the 2nd PET nonwoven layers 91 that glass, which strengthens cloth 9,
PE rubber powders the 93, the 3rd PE adhesive films of layer of layer the 92, the 3rd or PP adhesive films 94, then each layer composite junction through roll-forming together
Structure.
Wherein, the glass between the first PE adhesive films or PP adhesive films 4 and PU flaggies 5 strengthens the 3rd PE glued membranes in cloth 9
Layer or PP adhesive films 94 are contacted with PU flaggies 5, the glass between the 2nd PE rubber powders layer 7 and the 2nd PE adhesive films or PP adhesive films 8
The 3rd PE adhesive films or PP adhesive films 94 strengthened in cloth 9 are contacted with the 2nd PE adhesive films or PP adhesive films 8, and this example example passes through
Glass between first PE adhesive films or PP adhesive films 4 and PU flaggies 5 strengthens the 3rd PE adhesive films or PP adhesive films 94 in cloth 9
Contacted with PU flaggies 5, on the one hand can effectively ensure that this glass strengthens the 2nd PET non-woven fabrics and the first PE adhesive films in cloth 9
Or the caking property of PP adhesive films 4, while can effectively ensure that this glass strengthens the 3rd PE adhesive films or PP adhesive films 94 in cloth 9
With the cementability of PU flaggies 5, and then ensure that this glass strengthen cloth 9 be located at base material in stability;Pass through the 2nd PE rubber powders layer 7
Glass between the 2nd PE adhesive films or PP adhesive films 8 strengthens the 3rd PE adhesive films or PP adhesive films 94 and second in cloth 9
PE adhesive films or PP adhesive films 8 are contacted, and can effectively improve the flatness of high intensity sandwich substrate surface, it is ensured that itself and vapour
The stability that car roof facial ornament is combined.
A kind of production method of roof of the vehicle high intensity sandwich base material of the present embodiment, its step is as follows:
(1)Make and strengthen cloth:It is to use the 2nd PET non-woven fabrics, the 3rd GF glasses, the 3rd PE rubber powders, the 3rd PE glued membranes or PP
The composite I of glued membrane formation, making step is as follows:
Step one:Tile the 2nd PET non-woven fabrics on the conveyer belt of composite production line, then sows or lay successively in the above the
Three GF glasses, the 3rd PE rubber powders, the 3rd PE glued membranes or PP glued membranes formation composite I;
Step 2:Composite I is sent into heating furnace using crawler type special conveying device to be preheated, preheating temperature is 140-
160 DEG C, preheating time is 2-5s;
Then reuse crawler type special conveying device and composite I is sent into electrical heating area using radiant type heating, heating temperature
Spend for 160-210 DEG C, the heat time is 20-30s;
Step 3:Heated composite I is pressed in the case where pressure is 3.0-6.0bar pressure roller;
Step 4:Composite I after pressing is sent into the temperature of water cooling to be cooled down in 8-28 DEG C of coldplate, glass is made
Fibre strengthens cloth 9;
Step 5:The glass cooled down reinforcement cloth 9 is wound;
Wherein, the weight per unit area of the 2nd PET non-woven fabrics of the present embodiment is 30-55g/m2, size changing rate %:L≥-2.0
T >=-1.5, what deserves to be explained is L is the rate of change of length direction herein, T is the rate of change of width;3rd GF glasses
Cutting Length is 20-30mm, and it is 25-55g/m that it, which cuts the weight per unit area being sprinkling upon on the 2nd PET non-woven fabrics,2;3rd PE glued membranes
Layer or PP adhesive film weight per unit areas be 25-55g/m2, and its temperature in laying is 110-140 DEG C;
The particle diameter of the 3rd PE rubber powders of the present embodiment(α)It is distributed as:
3rd PE rubber powders of α >=220 μm account for mass percent≤6% of total 3rd PE rubber powders;
220μm>The mass percent that 3rd PE rubber powders of α >=110 μm account for total 3rd PE rubber powders is 51 ± 10%;
110μm>The mass percent that 3rd PE rubber powders of α >=77 μm account for total 3rd PE rubber powders is 30 ± 10%;
77 μm of α < the 3rd PE rubber powders account for mass percent≤13% of total 3rd PE rubber powders, and the present embodiment utilizes different-grain diameter α)
PE rubber powders and different quality percentage, on the one hand avoid PE rubber powder sizes(α)Too small, particle diameter(α)Too small PE glue
When silty amount is more, the dusting amount of PE rubber powders is difficult to control during PE rubber powder dustings are carried out, and the dusting amount of PE rubber powders is missed
The larger phenomenon of difference;On the other hand PE rubber powder sizes are avoided(α)Excessive, particle diameter(α)When excessive PE rubber powder quality is more,
Carry out after PE rubber powder dustings, excessive PE rubber powders are difficult the phenomenon melted during heating composite.The present invention is by using difference
Particle diameter(α)PE rubber powders and different quality percentage so that particle diameter of different sizes(α)PE rubber powders during unrestrained energy
Enough make particle diameter(α)Appropriate PE rubber powders are unrestrained uniform, and it is good that rear effect is dissolved in heating;Simultaneously during PE rubber powder dustings are carried out
Good control can be carried out to the dusting amount of PE rubber powders.
The present embodiment is by controlling the 2nd PET non-woven fabrics, the weight per unit area of the 3rd PE adhesive films or PP adhesive films, the
Two PET non-woven fabrics size changing rates, the Cutting Length of the 3rd GF glasses, the particle diameter of the 3rd PE rubber powders(α)The parameters such as distribution so that
While glass strengthens cloth 9 with higher intensity, combined with higher interlayer adhesion and with roof of the vehicle facial ornament
Cohesive force.
(2)Make high intensity sandwich base material:Tile the first PET non-woven fabrics on the conveyer belt of composite production line, then
It is sowed or laid successively above the first GF glasses, the first PE rubber powders, the first PE glued membranes or PP glued membranes, glass and strengthens cloth 9, PU
Plate, the 2nd GF glasses, the 2nd PE rubber powders, glass strengthen cloth 9, the 2nd PE glued membranes or PP glued membranes formation composite II, then adopt
30-80s is heated to composite II with 180-250 DEG C of temperature, roll-in finally is carried out to composite II under 7-12MPa pressure
It is compound, high intensity sandwich base material is made after cooling.
Vertical well known, on the one hand roof of the vehicle sandwich base material will ensure its intensity requirement, while needing to ensure Sanming City
Control the cohesive force that base material is combined with facial ornament, it is emphasized that:The present embodiment by the first PE adhesive films or PP adhesive films 4 with
Glass, which is equipped with, between PU flaggies 5, between the 2nd PE rubber powders layer 7 and the 2nd PE adhesive films or PP adhesive films 8 strengthens cloth 9, a side
Face ensure that the shaping of sandwich base material, on the other hand improve the local strength of sandwich base material, meet higher-strength vapour
The use demand of car roof, while the present embodiment is by rationally setting glass to strengthen the layers of material of cloth 9, and is added by setting to make
Qiang Bu, high intensity sandwich base material reasonable process parameter so that glass strengthens cloth 9 while high intensity is met so that high
Intensity sandwich base material interlayer has good caking property, it is ensured that the dimensional stability of sandwich base material, while it is away from nothing
Spinning the one side of cloth, there is higher cohesive force to combine to form roof of the vehicle with facial ornament, and this sandwich base material has well smooth
Degree.
Schematical above that the present invention and embodiments thereof are described, the description does not have restricted, institute in accompanying drawing
What is shown is also one of embodiments of the present invention, and actual structure is not limited thereto.So, if the common skill of this area
Art personnel are enlightened by it, without departing from the spirit of the invention, are designed and the technical scheme without creative
Similar frame mode and embodiment, all should belong to protection scope of the present invention.