CN107151491B - A kind of aqueous rust transfer priming paint and preparation method thereof suitable for corroding steel surface - Google Patents
A kind of aqueous rust transfer priming paint and preparation method thereof suitable for corroding steel surface Download PDFInfo
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- CN107151491B CN107151491B CN201710318176.5A CN201710318176A CN107151491B CN 107151491 B CN107151491 B CN 107151491B CN 201710318176 A CN201710318176 A CN 201710318176A CN 107151491 B CN107151491 B CN 107151491B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/08—Homopolymers or copolymers of vinylidene chloride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/12—1,2-Dichloroethene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
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Abstract
The aqueous rust that the invention discloses a kind of suitable for corroding steel surface shifts priming paint and preparation method thereof, is applied to corrosion steel surface.The aqueous rust transfer priming paint is made of vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion, phosphate modified polyacrylate aqueous dispersion, non-ionic wetting dispersing agent, anti-settling agent, pigment, filler, polyether silicone defoaming agent, coalescing agent, substrate wetting agents, isothiazolinone, polyurethane associative thickener and water.The aqueous rust transfer priming paint is one-component, self-drying type product, and storage stability is high, turns rust excellent in efficiency, and the coating of formation has excellent vapour resistance and long-effective corrosion.
Description
Technical field
The present invention relates to one kind be applied to corrosion steel surface, have rust conversion and anticorrosion properties aqueous priming paint and its
Preparation method.
Background technique
Steel is the most commonly used metal material of modern society.Loss caused by steel corrosion, not only shows material
The destruction that shape, color, mechanical property etc. are subject to, it is often more important that making the credit rating of its product, engineering reduces, essence
Degree, sensitivity are impaired, influence its use value and even scrap, the major accident of fatal crass but will be caused under individual cases.
The application of anticorrosive paint is the main means of current control steel corrosion.In order to obtain excellent protection effect, pass
System anticorrosive paint needs to carry out ground stringent processing of rust removing before construction.Wherein, by hand, time-consuming for powertool cleaning, and
Oxide skin, iron rust removing are not thorough.Sandblasting or shot peening are high-efficient, but can significantly improve product cost, bring strong powder
Dirt and noise can't thoroughly handle the dead angle in complex job face, it is most important that will cause steel construction and be thinned, it is strong to reduce it
Degree.Therefore, for be difficult to thoroughly derust product, engineering (such as: heavy construction, bridge, the equipment of complexity, coal gas storage cabinet) with
And require save manpower, working hour, cost protection occasion, realize application over rust be particularly important.
Currently, domestic application over rust coating is based on the products such as solvent type epoxy, haloflex, chlorinated rubber.It is applied
Aromatic hydrocarbons, alkanes, ketone and esters solvent are largely used during work, environment friendly is poor.Country is to waving after 2010
Limit row's policy of hair property organic matter (VOC) is gradually tightened.Such as: in September, 2013, " the prevention and control of air pollution action that State Council prints and distributes
Plan " it clearly proposes to improve the VOC emission requirement of the key industrys such as coating, study and define VOC Regulation Policy on Pollution Discharge Fee.2015 1
The moon 26, National Ministry of Finance combines with the State Tax Administration to have issued " about the notice for imposing the consumption tax to coating "." notice "
It is required that the coating to (VOC) content of volatile organic compounds under Construction State higher than 420g/L was in production, commission from 1 day 2 months 15 years
Processing and import link impose the consumption tax, and the applicable tax rate is 4%.In face of increasingly serious Environmental Protection Situation, the water of application over rust
Propertyization upgrading is imperative.
Summary of the invention
The present invention be directed to above-mentioned problems to provide a kind of aqueous rust transfer priming paint suitable for corroding steel surface
And preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
It is a kind of suitable for corrode steel surface aqueous rust shift priming paint, the priming paint by 10~50 mass parts inclined two chloroethene
Alkene-acrlylonitrile-acrylate multi-copolymerization emulsion, the phosphate modified polyacrylate aqueous dispersion of 10~50 mass parts, 0.1
The non-ionic wetting dispersing agent of~10 mass parts, the anti-settling agent of 0.1~5 mass parts, the pigment of 1~15 mass parts, 1~20 matter
Measure the filler of part, the polyether silicone defoaming agent of 0.01~1 mass parts, 1~10 mass parts coalescing agent, 0.1~1 mass parts
Substrate wetting agents, the isothiazolinone of 0.1~1 mass parts, 0.3~3 mass parts polyurethane associative thickener and 1~30
The water of mass parts forms；
Wherein: the vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion is to be prepared via a method which
It arrives:
(1) by the vinylidene chloride of 60~80 mass parts, the acrylonitrile of 5~10 mass parts, 2~5 mass parts acrylic acid,
The water of the esters of acrylic acid soft monomer of 10~20 mass parts, the mixed surfactant of 2~6 mass parts and 80~120 mass parts
Monomer pre-emulsion is made under agitation, the esters of acrylic acid soft monomer is that n-butyl acrylate or acrylic acid are different pungent
Ester；
(2) it takes 1/5 monomer pre-emulsion to be added in the reactor of nitrogen protection first, is warming up to 55~65 DEG C；Secondly will
The azo diisobutyl amidine hydrochloric acid salt initiators of 0.3~1.2 mass parts are configured to 10% aqueous solution, take wherein 1/5 initiator
Aqueous solution is added in reactor, stirring polymerization 1h；It is later that remaining monomer pre-emulsion and remaining initiator solution is same
When instill reactor in, 3~4h is added dropwise, and continues to be stirred to react 1h；Finally, being warming up to 70 DEG C, 1h is kept the temperature, it is cooling, add
Enter phosphate buffer regulation system pH value to 2.0~4.5, filtering can be obtained vinylidene chloride-acrlylonitrile-acrylate
Multi-copolymerization emulsion；
The phosphate modified polyacrylate aqueous dispersion is to be prepared via a method which to obtain: by 25~45 mass
Senecioate-the etherophosphoric acid of part, the acrylic acid of 2~5 mass parts, the methyl methacrylate of 25~40 mass parts, 15~35
The butyl acrylate of mass parts, the azodiisobutyronitrile of 0.2~1.0 mass parts, 2~8 mass parts mixed surfactant and
Monomer-initiator mixing pre-emulsion is made in the water of 90~130 mass parts under high velocity agitation；Take the 1/4 mixing pre-emulsification
Liquid is added in the reactor of nitrogen protection, is warming up to 65~70 DEG C, stirring polymerization 1h；Remaining mixing pre-emulsion is delayed later
Slow to instill in reactor, 3~4h is added dropwise, and continues to be stirred to react 1h；Then, 80~90 DEG C are warming up to, 1h is kept the temperature；It is cold
But, phosphate buffer regulation system pH value is added to 2.0~6.0, filtering can be obtained phosphate modified polyacrylate water
Dispersion.
In some preferred technical solutions: the priming paint by 35~50 mass parts vinylidene chloride-acrylonitrile-acrylic acid
Ester multi-copolymerization emulsion, the phosphate modified polyacrylate aqueous dispersion of 15~35 mass parts, 0.4~1.5 mass parts it is non-
Ionic wetting dispersing agent, the anti-settling agent of 0.1~0.5 mass parts, the pigment of 2~7 mass parts, 5~20 mass parts filler,
The polyether silicone defoaming agent of 0.05~0.2 mass parts, the coalescing agent of 1~5 mass parts, the substrate profit of 0.1~0.5 mass parts
Humectant, the isothiazolinone of 0.1~0.3 mass parts, the polyurethane associative thickener of 0.3~1.2 mass parts and 10~20 matter
Measure the water composition of part.
Described in technical solution of the present invention vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation method
Mixed surfactant is Nonyl pheno base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl front three
The mixture of base ammonium bromide, the mixed proportion of three are 1:1.5:1.
Blending surface described in the phosphate modified polyacrylate aqueous dispersion preparation method of technical solution of the present invention is living
Property agent be Nonyl pheno base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and 1- allyloxy -3- (4- nonyl benzene
Phenol) -2- propyl alcohol polyoxyethylene (10) ether monophosphate mixture, the mixed proportion of three is 1:1:2.
In technical solution of the present invention: the anti-settling agent is fumed silica or the sea organically-modified lithium of this BENTONE-LT of name
Montmorillonite auxiliary rheological agents；The pigment is iron oxide red, iron oxide black or carbon black；The filler be blanc fixe, sericite,
One or more of talcum powder；The coalescing agent is alcohol ester 12 or dipropylene；The non-ionic wetting
Dispersing agent is 190 wetting dispersing agent of Digao Dispers 757W wetting dispersing agent or Bi Ke DISPERBYK；The polyethers silicon
Oxygen alkane defoaming agent is 810 defoaming agent of Digao Foamex；245 substrate wetting agents of substrate wetting agents Digao Wet KL are finished
Gram BYK-345 substrate wetting agents or Bi Ke BYK-346 substrate wetting agents；The polyurethane associative thickener is Hai Mingsi
299 thickener of RHEOLATE.
A kind of aqueous rust suitable for corroding steel surface shifts the preparation method of priming paint, and this method is the condition in stirring
The lower non-ionic wetting dispersing agent that 0.1~10 mass parts are sequentially added into the water of 10~50 mass parts, 0.1~5 mass parts
Anti-settling agent, the pigment of 1~15 mass parts, the filler of 1~20 mass parts and 0.01~1 mass parts polyether silicone defoaming
Agent is dispersed with stirring to uniformly without agglomeration, obtaining slurry；Then, slurry fineness is ground to less than 40 μm using sand mill, stirring
Vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion, 10 of 10~50 mass parts is added in the lower slurry to after grinding
The phosphate modified polyacrylate aqueous dispersions of~50 mass parts, the coalescing agent of 1~10 mass parts, 0.1~1 mass parts
The polyurethane associative thickener of substrate wetting agents, the isothiazolinone of 0.1~1 mass parts, 0.3~3 mass parts is stirred to equal
Even no shrinkage cavity can be obtained aqueous rust transfer priming paint；
Wherein: the vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion is to be prepared via a method which
It arrives: by the vinylidene chloride of 60~80 mass parts, the acrylonitrile of 5~10 mass parts, the acrylic acid of 2~5 mass parts, 10~20 matter
Measure the esters of acrylic acid soft monomer of part, the water of 80~120 mass parts of mixed surfactant of 2~6 mass parts is made under stiring
At monomer pre-emulsion, the esters of acrylic acid soft monomer is n-butyl acrylate or Isooctyl acrylate monomer；Take 1/5 monomer pre-
Lotion is added in the reactor of nitrogen protection, is warming up to 55~65 DEG C；By the azo diisobutyl amidine salt of 0.3~1.2 mass parts
Hydrochlorate initiator is configured to 10% aqueous solution, takes in wherein 1/5 initiator solution addition reactor, stirring polymerization 1h；It
Remaining monomer pre-emulsion and remaining initiator solution are instilled in reactor simultaneously afterwards, 3~4h is added dropwise, and after
It is continuous to be stirred to react 1h；Then, 70 DEG C are warming up to, 1h is kept the temperature；It is cooling, addition phosphate buffer regulation system pH value to 2.0~
4.5；Filtering, can be obtained vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion；
The phosphate modified polyacrylate aqueous dispersion is to be prepared via a method which to obtain: by 25~45 mass
Senecioate-the etherophosphoric acid of part, the acrylic acid of 2~5 mass parts, the methyl methacrylate of 25~40 mass parts, 15~35
The butyl acrylate of mass parts, the azodiisobutyronitrile of 0.2~1.0 mass parts, 2~8 mass parts mixed surfactant and
Monomer-initiator mixing pre-emulsion is made in the water of 90~130 mass parts under high velocity agitation；Take the 1/4 pre- cream of above-mentioned mixing
Change liquid to be added in the reactor of nitrogen protection, is warming up to 65~70 DEG C, stirring polymerization 1h；Later by remaining mixing pre-emulsion
It is slowly dropped into reactor, 3~4h is added dropwise, and continues to be stirred to react 1h；Then, 80~90 DEG C are warming up to, 1h is kept the temperature；It is cold
But, phosphate buffer regulation system pH value is added to 2.0~6.0, filtering can be obtained phosphate modified polyacrylate water
Dispersion.
The above-mentioned aqueous rust suitable for corroding steel surface shifts the preparation method of priming paint: being formulated the mass parts of each component
It is as follows:
The phosphorus of the vinylidene chloride of 35~50 mass parts-acrlylonitrile-acrylate multi-copolymerization emulsion, 15~35 mass parts
Acid esters modified polyacrylate aqueous dispersion, the non-ionic wetting dispersing agent of 0.4~1.5 mass parts, 0.1~0.5 mass parts
Anti-settling agent, the pigment of 2~7 mass parts, the filler of 5~20 mass parts, 0.05~0.2 mass parts polyether silicone defoaming
Agent, the coalescing agent of 1~5 mass parts, the substrate wetting agents of 0.1~0.5 mass parts, 0.1~0.3 mass parts isothiazoline
The water of ketone, the polyurethane associative thickener of 0.3~1.2 mass parts and 10~20 mass parts.
The above-mentioned aqueous rust suitable for corroding steel surface shifts the preparation method of priming paint: the anti-settling agent is gas phase two
Silica or the sea organically-modified hectorite auxiliary rheological agents of this BENTONE-LT of name；The pigment is iron oxide red, iron oxide black
Or carbon black；The filler is one or more of blanc fixe, sericite, talcum powder；The coalescing agent is alcohol ester ten
Two or dipropylene；The non-ionic wetting dispersing agent is Digao Dispers 757W wetting dispersing agent or Bi Ke
190 wetting dispersing agent of DISPERBYK；The polyether silicone defoaming agent is 810 defoaming agent of Digao Foamex；The base
245 substrate wetting agents of material wetting agent Digao Wet KL or the wetting of Bi Ke BYK-345 substrate wetting agents or Bi Ke BYK-346 substrate
Agent；The polyurethane associative thickener is 299 thickener of Hai Mingsi RHEOLATE.
The above-mentioned aqueous rust suitable for corroding steel surface shifts the preparation method of priming paint: vinylidene chloride-acrylonitrile-
Mixed surfactant described in acrylate multi-copolymerization emulsion is Nonyl pheno base ether, methylacryoyloxyethyl
The mixture of trimethyl ammonium chloride and cetyl trimethylammonium bromide, the mixed proportion of three are 1:1.5:1.
The above-mentioned aqueous rust suitable for corroding steel surface shifts the preparation method of priming paint: phosphate modified polyacrylic acid
Mixed surfactant described in ester aqueous dispersion is Nonyl pheno base ether, methylacryoyloxyethyl trimethyl ammonia chloride
The mixture of ammonium and 1- allyloxy -3- (4- nonyl phenol) -2- propyl alcohol polyoxyethylene (10) ether monophosphate, the mixing ratio of three
Example is 1:1:2.
Aqueous rust transfer priming paint disclosed in this invention mainly passes through infiltration, two modes of action of conversion realize the stabilization of iron rust
Change.Firstly, film forming matter and macromolecular is helped to turn rust agent supplemented by the phosphate modified polyacrylate aqueous dispersion of design.Both it participates in setting
Rouge film forming, and stable metal salt can be formed with iron rust, it is strong, easy to overcome inorganic phosphate, small molecule organic phosphoric acid free property
The problems such as migration.Secondly, the vinylidene chloride-the third that synthesis partial size is small, permeability is strong, adhesive force is high, dry film vapour resistance is good
Alkene nitrile-acrylate multi-copolymerization emulsion is main film forming matter.Pass through itself and phosphate modified polyacrylate aqueous dispersion
Film forming altogether forms firm iron rust clad, inhibits corrosion diffusion.Third, entire resin system use quasi- soap-free polymerization and sun
Ion emulsification system.While promoting resin shear stability, have lower pH value, can effectively avoid resin dechlorination decomposition.
4th, unique double film forming matter blending systems make product can be according to rusty scale thickness flexibly adjustment vinylidene chloride-acrylonitrile-
The portfolio ratio of acrylate multi-copolymerization emulsion and phosphate modified polyacrylate aqueous dispersion, obtain it is optimal turn rust,
Protection effect.
Beneficial effects of the present invention:
Aqueous rust transfer priming paint storage stability height, turn rust excellent in efficiency, the adhesive force of the disclosure of the invention are good, the coating of formation
Possess excellent vapour resistance, resistance to salt water, humidity resistance and long-effective corrosion.
Specific embodiment
Below with reference to embodiment, the present invention will be further described, and but the scope of the present invention is not limited thereto:
Embodiment 1
(1) vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation: by inclined two chloroethene of 75 mass parts
Alkene, the acrylonitrile of 5 mass parts, the acrylic acid of 2.5 mass parts, the Isooctyl acrylate monomer of 15 mass parts, 4 mass parts blending surface
Activating agent (Nonyl pheno base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl trimethylammonium bromide
Mixture, the mixed proportion of three is 1:1.5:1), the water of 100 mass parts monomer pre-emulsion is made under stiring.Take 1/5
Above-mentioned mix monomer pre-emulsion be added nitrogen protection reactor in, be warming up to 60 DEG C.By two isobutyl of azo of 0.6 mass parts
Base amidine hydrochloric acid salt initiators are configured to 10% aqueous solution, take in wherein 1/5 initiator solution addition reactor, stirring polymerization
1h.Remaining mix monomer pre-emulsion and initiator solution are instilled in reactor simultaneously, 4h is added dropwise, and continues to stir
Mix reaction 1h.Then, 70 DEG C are warming up to, 1h is kept the temperature.It is cooling, phosphate buffer regulation system pH value is added to 2.0~4.5.
Filtering can be obtained solid vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion containing for 49.8%.
(2) preparation of phosphate modified polyacrylate aqueous dispersion: by senecioate-etherophosphoric acid of 40 mass parts, 3
The acrylic acid of mass parts, the methyl methacrylate of 35 mass parts, the butyl acrylate of 10 mass parts, 0.4 mass parts azo
Mixed surfactant (the Nonyl pheno base ether, methylacryoyloxyethyl trimethyl chlorine of bis-isobutyronitrile, 3 mass parts
Change the mixture of ammonium and 1- allyloxy -3- (4- nonyl phenol) -2- propyl alcohol polyoxyethylene (10) ether monophosphate, the mixing of three
Ratio is 1:1:2), the water of 110 mass parts monomer-initiator mixing pre-emulsion is made under high velocity agitation.Take 1/4 it is above-mentioned
It mixes pre-emulsion to be added in the reactor of nitrogen protection, is warming up to 70 DEG C, stirring polymerization 1h.By remaining mixing pre-emulsion
It is slowly dropped into reactor, 3.5h is added dropwise, and continues to be stirred to react 1h.Then, 90 DEG C are warming up to, 1h is kept the temperature.It is cooling, add
Enter phosphate buffer regulation system pH value to 2.0~6.0.Filtering, can be obtained it is solid containing for 43.5% it is phosphate modified poly-
Acrylate aqueous dispersion.
(3) enlightening of 0.8 mass parts the preparation of aqueous rust transfer priming paint: is sequentially added into the water of 11 mass parts under stiring
High Dispers 757W wetting dispersing agent, 200 fumed silica of Degussa AEROSIL of 0.2 mass parts, 7 mass parts oxygen
Change the Digao Foamex810 defoaming of iron oxide black pigment, the blanc fixe of 12 mass parts, the sericite of 5 mass parts, 0.05 mass parts
Agent is dispersed with stirring to uniformly without agglomeration, obtaining slurry.Then, slurry fineness is ground to less than 40 μm using sand mill.It is stirring
The phosphoric acid of the lower vinylidene chloride that 45 mass parts are added into slurry-acrlylonitrile-acrylate multi-copolymerization emulsion, 15 mass parts
Ester modified polyacrylate aqueous dispersion, the dipropylene of 4.5 mass parts, 0.2 mass parts 245 base of Digao Wet KL
This 299 thickener of RHEOLATE of material wetting agent, the isothiazolinone of 0.2 mass parts, the extra large name of 0.5 mass parts, is stirred until homogeneous
No shrinkage cavity can be obtained the solid aqueous rust transfer priming paint #1 containing for 54.2%.
Embodiment 2
(1) vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation: same as Example 1.
(2) preparation of phosphate modified polyacrylate aqueous dispersion: same as Example 1.
(3) enlightening of 0.8 mass parts the preparation of aqueous rust transfer priming paint: is sequentially added into the water of 11 mass parts under stiring
High Dispers 757W wetting dispersing agent, 200 fumed silica of Degussa AEROSIL of 0.2 mass parts, 7 mass parts oxygen
Change the Digao Foamex810 defoaming of iron oxide black pigment, the blanc fixe of 12 mass parts, the sericite of 5 mass parts, 0.05 mass parts
Agent is dispersed with stirring to uniformly without agglomeration, obtaining slurry.Then, slurry fineness is ground to less than 40 μm using sand mill.It is stirring
The phosphoric acid of the lower vinylidene chloride that 30 mass parts are added into slurry-acrlylonitrile-acrylate multi-copolymerization emulsion, 30 mass parts
Ester modified polyacrylate aqueous dispersion, the dipropylene of 3.5 mass parts, 0.2 mass parts 245 base of Digao Wet KL
This 299 thickener of RHEOLATE of material wetting agent, the isothiazolinone of 0.2 mass parts, the extra large name of 0.5 mass parts, is stirred until homogeneous
No shrinkage cavity can be obtained the solid aqueous rust transfer priming paint #2 containing for 53.9%.
The main performance index of aqueous rust transfer priming paint #1 (embodiment 1) and aqueous rust transfer priming paint #2 (embodiment 2) is such as
Under:
The key technical indexes of the aqueous rust transfer priming paint of table 1
Main performance index of the aqueous rust transfer priming paint of table 2 under different rusty scale thickness
[a]Test plate (panel) applies 2 aqueous rust transfer priming paint, and for 24 hours, paint film overall thickness (50 ± 10) μm, curing period is at per pass interval
7d；[b]Test plate (panel) applies 2 aqueous rust and shifts priming paint and 1 single-component water-based acrylic acid top-coat, per pass interval for 24 hours, priming paint total thickness
It spends (50 ± 10) μm, finishing coat overall thickness (25 ± 5) μm, curing period 7d.Film thickness is on the sandblasting steel plate that applies under equal conditions
Subject to film thickness.
Water resistance, resistance to salt water, humidity resistance and the salt fog resistance of two aqueous rust transfer priming paint are compared it can be found that phosphorus
The lower priming paint #1 of acid esters modified polyacrylate aqueous dispersion ratio is more suitable for being protected under low rusty scale thickness.Improve phosphorus
After acid esters modified polyacrylate aqueous dispersion ratio (priming paint #2), priming paint turns rust ability and is obviously improved, under high rusty scale thickness
Guard time be obviously prolonged.It can be seen that double film forming matter blending systems that the present invention designs can be adjusted according to rusty scale thickness and be led
The portfolio ratio of film forming matter and auxiliary film forming matter obtains optimal turn of rust, protection effect.
Embodiment 3
(1) vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation: by inclined two chloroethene of 60 mass parts
Alkene, the acrylonitrile of 8 mass parts, the acrylic acid of 3 mass parts, the n-butyl acrylate of 10 mass parts, the blending surface of 3 mass parts are living
Property agent (Nonyl pheno base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl trimethylammonium bromide
Monomer pre-emulsion is made for the water of 1:1.5:1), 100 mass parts in the mixed proportion of mixture, three under stiring.Take 1/5
Above-mentioned mix monomer pre-emulsion is added in the reactor of nitrogen protection, is warming up to 60 DEG C.By the azo diisobutyl of 0.4 mass parts
Amidine hydrochloric acid salt initiators are configured to 10% aqueous solution, take in wherein 1/5 initiator solution addition reactor, stirring polymerization
1h.Remaining mix monomer pre-emulsion and initiator solution are instilled in reactor simultaneously, 3.5h is added dropwise, and continues
It is stirred to react 1h.Then, 70 DEG C are warming up to, 1h is kept the temperature.It is cooling, addition phosphate buffer regulation system pH value to 2.0~
4.5.Filtering can be obtained solid vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion containing for 45.5%.
(2) preparation of phosphate modified polyacrylate aqueous dispersion: by senecioate-etherophosphoric acid of 25 mass parts, 2
The acrylic acid of mass parts, the methyl methacrylate of 40 mass parts, the butyl acrylate of 20 mass parts, 0.5 mass parts azo
Mixed surfactant (the Nonyl pheno base ether, methylacryoyloxyethyl trimethyl chlorine of bis-isobutyronitrile, 5 mass parts
Change the mixture of ammonium and 1- allyloxy -3- (4- nonyl phenol) -2- propyl alcohol polyoxyethylene (10) ether monophosphate, the mixing of three
Ratio is 1:1:2), the water of 110 mass parts monomer-initiator mixing pre-emulsion is made under high velocity agitation.Take 1/4 it is above-mentioned
It mixes pre-emulsion to be added in the reactor of nitrogen protection, is warming up to 70 DEG C, stirring polymerization 1h.By remaining mixing pre-emulsion
It is slowly dropped into reactor, 4h is added dropwise, and continues to be stirred to react 1h.Then, 90 DEG C are warming up to, 1h is kept the temperature.It is cooling, it is added
Phosphate buffer regulation system pH value is to 2.0~6.0.Filtering can be obtained solid phosphate modified poly- third containing for 45.2%
Olefin(e) acid ester aqueous dispersion.
(3) finishing for 0.3 mass parts the preparation of aqueous rust transfer priming paint: is sequentially added into the water of 10 mass parts under stiring
Gram 190 wetting dispersing agent of DISPERBYK, the extra large name of 0.4 mass parts this BENTONE LT montmorillonitic clay class auxiliary rheological agents, 6.5
The ferric oxide red colorant of mass parts, the blanc fixe of 7 mass parts, the talcum powder of 6 mass parts, 0.1 mass parts Digao
810 defoaming agent of Foamex is dispersed with stirring to uniformly without agglomeration.Then, slurry fineness is ground to less than 40 μm using sand mill.
Vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion, 35 mass parts of 35 mass parts are added into slurry under stiring
Phosphate modified polyacrylate aqueous dispersion, the alcohol esters 12 of 2.5 mass parts, 0.1 mass parts Bi Ke BYK-345 substrate
This 299 thickener of RHEOLATE of wetting agent, the isothiazolinone of 0.2 mass parts, the extra large name of 0.8 mass parts, is stirred until homogeneous nothing
Shrinkage cavity can be obtained the solid aqueous rust transfer priming paint containing for 49.8%.It is water resistance >=5d of the primer coating (50 ± 10 μm), resistance to
Salt >=3d, humidity resistance >=168h, salt fog resistance >=120h.
Embodiment 4
(1) vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation: by inclined two chloroethene of 65 mass parts
Alkene, the acrylonitrile of 6 mass parts, the acrylic acid of 3 mass parts, the n-butyl acrylate of 12 mass parts, 2.5 mass parts blending surface
Activating agent (Nonyl pheno base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl trimethylammonium bromide
Mixture, the mixed proportion of three is 1:1.5:1), the water of 100 mass parts monomer pre-emulsion is made under stiring.Take 1/5
Above-mentioned mix monomer pre-emulsion be added nitrogen protection reactor in, be warming up to 60 DEG C.By two isobutyl of azo of 0.3 mass parts
Base amidine hydrochloric acid salt initiators are configured to 10% aqueous solution, take in wherein 1/5 initiator solution addition reactor, stirring polymerization
1h.Remaining mix monomer pre-emulsion and initiator solution are instilled in reactor simultaneously, 3.5h is added dropwise, and continues
It is stirred to react 1h.Then, 70 DEG C are warming up to, 1h is kept the temperature.It is cooling, addition phosphate buffer regulation system pH value to 2.0~
4.5.Filtering can be obtained solid vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion containing for 47.0%.
(2) preparation of phosphate modified polyacrylate aqueous dispersion: by senecioate-etherophosphoric acid of 30 mass parts,
The acrylic acid of 2.5 mass parts, the methyl methacrylate of 32 mass parts, the butyl acrylate of 26 mass parts, 0.7 mass parts idol
Mixed surfactant (the Nonyl pheno base ether, methylacryoyloxyethyl trimethyl of nitrogen bis-isobutyronitrile, 4 mass parts
The mixture of ammonium chloride and 1- allyloxy -3- (4- nonyl phenol) -2- propyl alcohol polyoxyethylene (10) ether monophosphate, three's is mixed
Monomer-initiator mixing pre-emulsion is made for the water of 1:1:2), 110 mass parts in composition and division in a proportion example under high velocity agitation.Take 1/4 it is upper
It states mixing pre-emulsion to be added in the reactor of nitrogen protection, is warming up to 70 DEG C, stirring polymerization 1h.By remaining mixing pre-emulsification
Liquid is slowly dropped into reactor, and 4h is added dropwise, and continues to be stirred to react 1h.Then, 90 DEG C are warming up to, 1h is kept the temperature.It is cooling, add
Enter phosphate buffer regulation system pH value to 2.0~6.0.Filtering, can be obtained it is solid containing for 46.1% it is phosphate modified poly-
Acrylate aqueous dispersion.
(3) Bi Ke of 1 mass parts the preparation of aqueous rust transfer priming paint: is sequentially added into the water of 18 mass parts under stiring
190 wetting dispersing agent of DISPERBYK, 200 fumed silicas of Degussa AEROSIL of 0.4 mass parts, 3.5 mass parts
Carbon black pigment, the blanc fixe of 8 mass parts, 0.1 mass parts 810 defoaming agent of Digao Foamex, be dispersed with stirring to uniform nothing
Agglomeration.Then, slurry fineness is ground to less than 40 μm using sand mill.Inclined the two of 48 mass parts are added into slurry under stiring
Chloride-acrylonitrile-acrylate multi-copolymerization emulsion, the phosphate modified polyacrylate aqueous dispersion of 20 mass parts, 1 matter
Measure dipropylene, the Bi Ke BYK-346 substrate wetting agents of 0.5 mass parts, the isothiazolinone of 0.2 mass parts, 1 matter of part
This 299 thickener of RHEOLATE of the extra large name of part is measured, being stirred until homogeneous no shrinkage cavity can be obtained the solid aqueous rust turn containing for 43.0%
Move priming paint.Water resistance >=7d, resistance to salt water >=4d, the humidity resistance >=192h, salt fog resistance of the primer coating (50 ± 10 μm)
≥120h。
Claims (6)
1. a kind of aqueous rust suitable for corroding steel surface shifts priming paint, it is characterised in that: the priming paint is by 10 ~ 50 mass parts
The phosphate modified polyacrylate moisture of vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion, 10 ~ 50 mass parts
Granular media, the non-ionic wetting dispersing agent of 0.1 ~ 10 mass parts, the anti-settling agent of 0.1 ~ 5 mass parts, the pigment of 1 ~ 15 mass parts, 1 ~
The filler of 20 mass parts, the polyether silicone defoaming agent of 0.01 ~ 1 mass parts, the coalescing agent of 1 ~ 10 mass parts, 0.1 ~ 1 mass
The polyurethane associative thickener and 1 ~ 30 of the substrate wetting agents of part, the isothiazolinone of 0.1 ~ 1 mass parts, 0.3 ~ 3 mass parts
The water of mass parts forms；
Wherein: the vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion is to be prepared via a method which to obtain:
(1) by the vinylidene chloride of 60 ~ 80 mass parts, the acrylonitrile of 5 ~ 10 mass parts, the acrylic acid of 2 ~ 5 mass parts, 10 ~ 20 matter
The water of the esters of acrylic acid soft monomer of part, the mixed surfactant of 2 ~ 6 mass parts and 80 ~ 120 mass parts is measured in stirring condition
Under be made monomer pre-emulsion, the esters of acrylic acid soft monomer is n-butyl acrylate or Isooctyl acrylate monomer；
(2) it takes 1/5 monomer pre-emulsion to be added in the reactor of nitrogen protection first, is warming up to 55 ~ 65 °C；Secondly by 0.3 ~
The azo diisobutyl amidine hydrochloric acid salt initiators of 1.2 mass parts are configured to 10% aqueous solution, take wherein 1/5 initiator solution
It is added in reactor, 1 h of stirring polymerization；Remaining monomer pre-emulsion and remaining initiator solution are instilled simultaneously later
In reactor, 3 ~ 4 h are added dropwise, and continue to be stirred to react 1 h；Finally, being warming up to 70 °C, 1 h is kept the temperature, it is cooling, phosphorus is added
For phthalate buffer regulation system pH value to 2.0 ~ 4.5, it is polynary total to can be obtained vinylidene chloride-acrlylonitrile-acrylate for filtering
Poly- lotion；
The phosphate modified polyacrylate aqueous dispersion is prepared via a method which to obtain: by 25 ~ 45 mass parts
Senecioate-etherophosphoric acid, the acrylic acid of 2 ~ 5 mass parts, the methyl methacrylate of 25 ~ 40 mass parts, 15 ~ 35 mass parts
Butyl acrylate, the azodiisobutyronitrile of 0.2 ~ 1.0 mass parts, the mixed surfactant of 2 ~ 8 mass parts and 90 ~ 130 mass
Monomer-initiator mixing pre-emulsion is made in the water of part under high velocity agitation；It takes the 1/4 mixing pre-emulsion that nitrogen is added to protect
In the reactor of shield, 65 ~ 70 °C are warming up to, 1 h of stirring polymerization；Remaining mixing pre-emulsion is slowly dropped into reactor later
In, 3 ~ 4 h are added dropwise, and continue to be stirred to react 1 h；Then, 80 ~ 90 °C are warming up to, 1 h is kept the temperature；It is cooling, phosphate is added
For buffer regulation system pH value to 2.0 ~ 6.0, filtering can be obtained phosphate modified polyacrylate aqueous dispersion；
Mixed surfactant described in vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation method is nonyl
The mixture of base phenol polyethenoxy base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl trimethylammonium bromide,
The mixed proportion of three is 1:1.5:1；
Mixed surfactant described in phosphate modified polyacrylate aqueous dispersion preparation method is polyoxyethylene nonyl phenyl second
Alkene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and 1- allyloxy -3-(4- nonyl phenol) -2- propyl alcohol polyoxyethylene
(10) mixture of ether monophosphate, the mixed proportion of three are 1:1:2.
2. the aqueous rust transfer priming paint according to claim 1 for being suitable for corroding steel surface, it is characterised in that: the priming paint
By vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion of 35 ~ 50 mass parts, 15 ~ 35 mass parts it is phosphate modified
Polyacrylate aqueous dispersion, the non-ionic wetting dispersing agent of 0.4 ~ 1.5 mass parts, the anti-settling agent of 0.1 ~ 0.5 mass parts, 2 ~
The pigment of 7 mass parts, the filler of 5 ~ 20 mass parts, the polyether silicone defoaming agent of 0.05 ~ 0.2 mass parts, 1 ~ 5 mass parts at
Film auxiliary agent, the substrate wetting agents of 0.1 ~ 0.5 mass parts, the isothiazolinone of 0.1 ~ 0.3 mass parts, 0.3 ~ 1.2 mass parts it is poly-
Urethane association thickener and the water of 10 ~ 20 mass parts composition.
3. the aqueous rust transfer priming paint according to claim 1 for being suitable for corroding steel surface, it is characterised in that: described
Anti-settling agent is fumed silica or the sea organically-modified hectorite auxiliary rheological agents of this BENTONE-LT of name；The pigment is oxidation
Iron oxide red, iron oxide black or carbon black；The filler is one or more of blanc fixe, sericite, talcum powder；The film forming
Auxiliary agent is alcohol ester 12 or dipropylene；The non-ionic wetting dispersing agent is Digao Dispers 757W wetting point
190 wetting dispersing agent of powder or Bi Ke DISPERBYK；The polyether silicone defoaming agent is the defoaming of Digao Foamex 810
Agent；245 substrate wetting agents of substrate wetting agents Digao Wet KL or Bi Ke BYK-345 substrate wetting agents or Bi Ke BYK-
346 substrate wetting agents；The polyurethane associative thickener is 299 thickener of Hai Mingsi RHEOLATE.
4. it is a kind of suitable for corrode steel surface aqueous rust shift priming paint preparation method, it is characterised in that: this method be
Sequentially added under conditions of stirring into the water of 10 ~ 50 mass parts 0.1 ~ 10 mass parts non-ionic wetting dispersing agent, 0.1 ~ 5
The anti-settling agent of mass parts, the pigment of 1 ~ 15 mass parts, the filler of 1 ~ 20 mass parts and 0.01 ~ 1 mass parts polyether silicone disappear
Infusion is dispersed with stirring to uniformly without agglomeration, obtaining slurry；Then, slurry fineness is ground to less than 40 μm using sand mill,
Vinylidene chloride-acrlylonitrile-acrylate multi-component copolymer cream of 10 ~ 50 mass parts is added under stirring into the slurry after grinding
Liquid, the phosphate modified polyacrylate aqueous dispersion of 10 ~ 50 mass parts, the coalescing agent of 1 ~ 10 mass parts, 0.1 ~ 1 mass parts
Substrate wetting agents, the isothiazolinone of 0.1 ~ 1 mass parts, 0.3 ~ 3 mass parts polyurethane associative thickener, stirring is to equal
Even no shrinkage cavity can be obtained aqueous rust transfer priming paint；
Wherein: the vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion is to be prepared via a method which to obtain:
By the vinylidene chloride of 60 ~ 80 mass parts, the acrylonitrile of 5 ~ 10 mass parts, the acrylic acid of 2 ~ 5 mass parts, 10 ~ 20 mass parts
Esters of acrylic acid soft monomer, 2 ~ 6 mass parts the water of 80 ~ 120 mass parts of mixed surfactant that monomer is made under stiring is pre-
Emulsion, the esters of acrylic acid soft monomer are n-butyl acrylate or Isooctyl acrylate monomer；1/5 monomer pre-emulsion is taken to be added
In the reactor of nitrogen protection, it is warming up to 55 ~ 65 °C；By the azo diisobutyl amidine hydrochloric acid salt initiators of 0.3 ~ 1.2 mass parts
It is configured to 10% aqueous solution, is taken in wherein 1/5 initiator solution addition reactor, 1 h of stirring polymerization；It later will be remaining
Monomer pre-emulsion and remaining initiator solution instill in reactor simultaneously, and 3 ~ 4 h are added dropwise, and continue to be stirred to react
1 h；Then, 70 °C are warming up to, 1 h is kept the temperature；It is cooling, phosphate buffer regulation system pH value is added to 2.0 ~ 4.5；Filtering,
It can be obtained vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion；
The phosphate modified polyacrylate aqueous dispersion is prepared via a method which to obtain: by 25 ~ 45 mass parts
Senecioate-etherophosphoric acid, the acrylic acid of 2 ~ 5 mass parts, the methyl methacrylate of 25 ~ 40 mass parts, 15 ~ 35 mass parts
Butyl acrylate, the azodiisobutyronitrile of 0.2 ~ 1.0 mass parts, the mixed surfactant of 2 ~ 8 mass parts and 90 ~ 130 mass
Monomer-initiator mixing pre-emulsion is made in the water of part under high velocity agitation；Take 1/4 above-mentioned mixing pre-emulsion that nitrogen is added
In the reactor of protection, 65 ~ 70 °C are warming up to, 1 h of stirring polymerization；Remaining mixing pre-emulsion is slowly dropped into reaction later
In device, 3 ~ 4 h are added dropwise, and continue to be stirred to react 1 h；Then, 80 ~ 90 °C are warming up to, 1 h is kept the temperature；It is cooling, phosphoric acid is added
For salt buffer regulation system pH value to 2.0 ~ 6.0, filtering can be obtained phosphate modified polyacrylate aqueous dispersion；
Mixed surfactant described in vinylidene chloride-acrlylonitrile-acrylate multi-copolymerization emulsion preparation method is nonyl
The mixture of base phenol polyethenoxy base ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and cetyl trimethylammonium bromide,
The mixed proportion of three is 1:1.5:1；
Mixed surfactant described in phosphate modified polyacrylate aqueous dispersion preparation method is polyoxyethylene nonyl phenyl second
Alkene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and 1- allyloxy -3-(4- nonyl phenol) -2- propyl alcohol polyoxyethylene
(10) mixture of ether monophosphate, the mixed proportion of three are 1:1:2.
5. the preparation method of the aqueous rust transfer priming paint according to claim 4 for being suitable for corroding steel surface, feature
Be: the mass parts of each component are as follows in the priming paint:
The vinylidene chloride of 35 ~ 50 mass parts-acrlylonitrile-acrylate multi-copolymerization emulsion, 15 ~ 35 mass parts phosphate change
Property polyacrylate aqueous dispersion, the non-ionic wetting dispersing agent of 0.4 ~ 1.5 mass parts, 0.1 ~ 0.5 mass parts anti-settling agent,
The pigment of 2 ~ 7 mass parts, the filler of 5 ~ 20 mass parts, the polyether silicone defoaming agents of 0.05 ~ 0.2 mass parts, 1 ~ 5 mass parts
Coalescing agent, the substrate wetting agents of 0.1 ~ 0.5 mass parts, the isothiazolinone of 0.1 ~ 0.3 mass parts, 0.3 ~ 1.2 mass parts
The water of polyurethane associative thickener and 10 ~ 20 mass parts.
6. the preparation method of the aqueous rust transfer priming paint according to claim 4 for being suitable for corroding steel surface, feature
Be: the anti-settling agent is fumed silica or the sea organically-modified hectorite auxiliary rheological agents of this BENTONE-LT of name；It is described
Pigment is iron oxide red, iron oxide black or carbon black；The filler is one of blanc fixe, sericite, talcum powder or several
Kind；The coalescing agent is alcohol ester 12 or dipropylene；The non-ionic wetting dispersing agent is Digao Dispers
190 wetting dispersing agent of 757W wetting dispersing agent or Bi Ke DISPERBYK；The polyether silicone defoaming agent is Digao
810 defoaming agent of Foamex；245 substrate wetting agents of substrate wetting agents Digao Wet KL or Bi Ke BYK-345 substrate profit
Humectant or Bi Ke BYK-346 substrate wetting agents；The polyurethane associative thickener is the thickening of Hai Mingsi RHEOLATE 299
Agent.
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| CN107880664A (en) * | 2017-12-22 | 2018-04-06 | 江苏怡成屏障科技有限公司 | Environmentally friendly low-carbon rotation rust coating and preparation method thereof |
| CN108531007A (en) * | 2018-05-21 | 2018-09-14 | 清远市贝客音涂料有限公司 | A kind of anticorrosive aqueous turn fire prevention priming paint and preparation method thereof that becomes rusty |
| CN108794703B (en) * | 2018-06-27 | 2020-12-18 | 常州光辉化工有限公司 | Preparation method of polyacrylate anticorrosive emulsion with excellent salt mist resistance function |
| CN115477874A (en) * | 2022-10-14 | 2022-12-16 | 北京汇聚和新材料有限公司 | Water-based antirust primer and preparation method thereof |
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