CN107142446A - The strong powder zincizing product of a kind of high rigidity, corrosion resisting property - Google Patents
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property Download PDFInfo
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- CN107142446A CN107142446A CN201710294378.0A CN201710294378A CN107142446A CN 107142446 A CN107142446 A CN 107142446A CN 201710294378 A CN201710294378 A CN 201710294378A CN 107142446 A CN107142446 A CN 107142446A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
Abstract
The invention discloses the strong powder zincizing product of a kind of high rigidity, corrosion resisting property, comprise the following steps and be made:(1) powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, sealed;(2) step (1) drum-type heating stove is rotated, is warming up to 350 370 DEG C;(3) it is 350 370 DEG C to control temperature, increases ultrasonic wave, the power of ultrasonic wave is 160 200W, drum-type heating stove rotating speed is risen into 80r/min, then reduction of speed to 1r/min from 1r/min, such Circularly liftable;(4) after the 18min of powder zincizing 15, it is slowly cooled to room temperature, the strong powder zincizing product of high rigidity, corrosion resisting property is made.The powder zincizing product hardness of the present invention is high, and wear-resisting, corrosion resisting property is strong, appearance uniform and not damaged.
Description
【Technical field】
The invention belongs to steel surface chemical heat treatment technology field, and in particular to a kind of high rigidity, corrosion resisting property are strong
Powder zincizing product.
【Background technology】
Traditional " steel piece powder zincizing technology ".Powder zincizing is also known as hot zincizing, is solid-state multicomponent thermochemical treatment surface peening
One kind in technology.Solid-state multicomponent thermochemical treatment surface strengthening technology is the diffusion effect for utilizing metallic atom under heated condition,
One or more metallic elements are penetrated into metallic article surface and form an a kind of class chemical heat treatment process of alloy protective layer,
The protective coating that this technique is formed is referred to as thermal diffusion coating by the U.S.ASTM standard published for 2008, passes through thermal diffusion coating
Handling process can be obviously improved that metal material surface is corrosion-resistant, wear-resistant, anti-oxidant and the performance such as shock resistance, effectively expand
The application of big metal material.
Powder zincizing is exactly a kind of specific thermal diffusion surface strengthening technology, and it is diffused into using Zn-ef ficiency under heated condition
Enter a kind of chemical heat treatment process that steel structural part surface prepares zn-fe alloy protective layer, powder zincizing coating can be effective
Improve the anticorrosive of steel structural part surface, resistance to surface oxidation and abrasion resistance properties.Comprehensive analysis machinery industry standard
JB/T 5067-1999《Steel piece powder zincizing》, European standard EN13811-2003《The zinc diffusion coating of ironwork is detailed
Specification》And the data such as domestic/external sherardising process, before the typical process flow of domestic/external powder zincizing mainly includes
3 processes such as processing, hot zincizing and post processing.
Pre-treatment for the greasy dirt of article surface, rusty stain are cleaned out, the process typically used be pickling, shot-peening or
Sandblasting, but this 3 kinds of methods have different limitations.
Pickling is greasy dirt, the rusty stain that steel piece surface is removed by the method for chemical reaction, but simultaneously can be chemical anti-
Hydrogen atom is produced during answering and is entered in steel piece.Because hydrogen atom activity is very big, its activity everywhere in product can be produced
Raw 2 kinds of consequences:1) product is under force-free state, and hydrogen atom is assembled in product forms hydrogen molecule, and hydrogen molecule is at accumulation position
Expansion produces internal stress, and then product is produced hydrogen embrittlement micro-crack, causes easily to be broken during product stress.2) product is in stress shape
Under state, hydrogen atom is movable in product, builds up as hydrogen molecule.Hydrogen molecule produces internal stress in the expansion of accumulation position, and then
Product is produced hydrogen embrittlement delay micro-crack, be easily broken after causing product stress.Therefore, this method is generally not suitable for machining
Steel piece.
Shot-peening or sandblasting are greasy dirt, the rusty stain that steel piece surface is removed by the method for continuous machinery strike, but simultaneously
Mechanical damage can be left in article surface.For the not high product of surface requirements, this kind of method can be applicable;Can not for surface
The product of mass lesions, this kind of method can not be applicable.And the surface of steel piece is machined typically by processing, shot-peening
Or sandblasting can damage the form and position tolerance and configuration of surface of product, thus this method is generally not suitable for machining steel piece.
As known from the above, the technique such as pickling, shot-peening or sandblasting is not suitable for before machining steel piece powder zincizing
Processing.
Heating zincizing is to mix steel piece, zinc powder and inertia impact media to be filled in sealed rustless steel container,
And container is placed in heat-treatment furnace, 360-450 DEG C is heated in the case where container rotates and a period of time is incubated, utilized
The diffusion of metallic atom, in component surface formation Fe/Zn alloy protecting layers.
From the process of heating zincizing, it is the process of an average tempering, without introducing hydrogen atom during zincizing
Environment, thus be not in as electroless zinc plating because introduce hydrogen atom caused by hydrogen embrittlement be inclined to.In addition, being inhaled at a temperature of this
Effusion can largely be spread by entering the hydrogen atom of steel matrix, thus have the effect of certain dehydrogenation (>=200 DEG C, be incubated 8-24h).
But most of hydrogen atom can only be removed, it is impossible to remove whole hydrogen atoms, hydrogen molecule can not be removed.Therefore, zincizing process is heated
It can not be completely eliminated due to the hydrogen embrittlement hidden danger that pickling is brought to machining steel piece.
In addition, different from traditional powder embedding chemical heat treatment process (embed product in the powder in inactive state
Lower heating), industrialization sherardising process is heated under continuous rolling condition, between mixture of powders and workpiece
Mechanical friction, percussion not only contributes to the close contact at fresh diffusion penetration enhancer and processed interface, and to be added
Heat medium temperature homogenization, and effectively facilitate metallurgical diffusion chemical reaction.
Product is under continuous rolling, friction, impact conditions, although inertia impact media can play sizable barrier and slow
Punching is acted on, but it is unavoidable occur between product, mutually collided between product and container, between product and frock, cause article surface form
There is light weight damage.Therefore, heating zincizing process can not prevent the configuration of surface damage of machining steel piece.
From upper analysis, conventional powder zincizing technique can make machining steel piece hydrogen embrittlement hidden danger, or big face occur
Accumulate disfiguring workpiece and cause its form and position tolerance and configuration of surface Quality Down, thus be not suitable for being machined steel piece powder
Zincizing, i.e. powder zincizing technology are difficult to the extensive use in machining steel piece.
Outdoor steel structure and fastener, freeway guardrail, bridge, hot-water heating utensil, architectural hardware, automobile, engineering machinery
Deng iron and steel parts, the iron and steel parts used in the engineering such as sintered metal product and chemical industry, ocean, metallurgy, generating, usually
Need corrosion-resistant overcoat.Zinc is most-often used chemical element in steel and iron parts surfacecti proteon:Dip galvanized, thickness typically exists
15-130 μm, member planar has significant difference with corner thickness of coating, and lack of homogeneity is difficult to control;Electro-galvanized layer, thickness is general
At 5-25 μm, plane coating uniformity is good, but the coating of component inside cavity is thin, and sometimes without coating;Thermal spraying zinc layers, thickness
Generally 84-300 μm, also thick 3mm can be reached, thickness evenness is poor, and compactness is low;Sherardised coating, thickness is solely dependent upon zincizing
The technological parameters such as agent, heating-up temperature and soaking time, it is substantially unrelated with the shape of component and position, it is threaded when processing, recessed
During the steel and iron parts of the complicated shape such as groove and endoporus, the thickness of zinc coat is almost identical, and general thickness can be between 10-100 μm
Selection, is accurately controlled near a certain thickness value by adjusting soaking time.
Powder zincizing, is that powder zincizing agent and steel and iron parts are co-located in sealing container, is heated to 400 DEG C or so, makes work
Property zinc atom is internally permeated by the surface of steel and iron parts, and the process of uniform zinc-iron alloy layer is formed on its top layer.Relatively
In other method, the zinc consumption of powder zincizing is low, save raw material;Production process is pollution-free, and working condition is good;Production equipment
Simply, using low with maintenance cost.Powder zincizing has that corrosion resistance is strong, hardness in the zinc-iron alloy layer that steel and iron parts surface is formed
The advantages of high, wear-resistant, scratch resistance, paintability are good.
Burn into corrosion is the natural enemy of ferrous materials.It is lost it is estimated that world's output of steel there are about 1/10th in burn into rust
Erosion.It was verified that under a variety of environment such as marine atmosphere, severe industrial atmosphere, the corrosion resistance of zinc coat is better than galvanizing, electricity
Zinc-plated and stainless steel.Zincizing layer surface Vickers hardness can reach 250-400, and galvanizing, electrolytic zinc-coated steel sheet ironware surface are pure
Zinc, coating Vickers hardness is only 70 or so, therefore zincizing is compared with galvanizing and electrogalvanizing, the surface abrasion resistance of steel and iron parts and anti-
Abrade performance much better.In general, the pre-treatment of zincizing production is only with shot-blasting machine derusting edible vegetable oil, and is removed with cloth bag
Dirt.Powder zincizing technology is oozed for the solid of zinc, is produced without zinc fume, and workpiece enters in closed utensil again with powder zincizing agent
Row infiltration and separation, do not pollute to surrounding environment.According to measuring and calculating, the zinc consumption of hot-galvanized steel ironware ton product is 100 kilograms
Left and right, and powder zincizing is only 30 kilograms or so, only accounts for the 30% of galvanizing.In addition, also corroding this galvanizing without zinc pot
Hard nut to crack.The zinc coat of zincizing product is uniform, and is one-level with the adhesion of paint, can realize to be combined after japanning and prevent
Shield, its corrosion resistance is superior to galvanizing, electrogalvanizing and single zinc coat.The steel product handled through zincizing does not influence material
Mechanical property.The temperature of zincizing processing is lower than galvanizing 100-280 DEG C, and the hydrogen atom that steel matrix is sucked at a temperature of this has spread ease
Go out.Therefore the harm without hydrogen embrittlement in the application, is also avoided that some high intensity parts such as spring mechanics caused by treatment temperature height
The drawbacks of hydraulic performance decline.So, powder zincizing has broad application prospects.
But, the zincizing time that existing powder zincizing agent and its technique for applying need is long;Zinc-iron alloy layer it is corrosion-resistant
Performance can also be improved further;Steel and iron parts surface is bonded with zincizing agent, it is necessary to clear up;Used powder zincizing agent caking, no
It is easy to recycling.
【The content of the invention】
The technical problem to be solved in the present invention is to provide the strong powder zincizing product of a kind of high rigidity, corrosion resisting property, to solve
Certainly existing zincizing agent activity is low, infiltration rate slow, and the zinc coat thickness of formation is small, is not enough saved in use, and gained product has surface
The problems such as damage.The powder zincizing product hardness of the present invention is high, and wear-resisting, corrosion resisting property is strong, appearance uniform and not damaged.
In order to solve the above technical problems, the present invention uses following technical scheme:
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property, it is characterised in that comprise the following steps and be made:
(1) powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, sealed;
(2) step (1) drum-type heating stove is rotated, is warming up to 350-370 DEG C;
(3) it is 350-370 DEG C to control temperature, increases ultrasonic wave, the power of ultrasonic wave is 160-200W, by drum-type heating
Stove rotating speed rises to 80r/min, then reduction of speed to 1r/min from 1r/min, such Circularly liftable;
(4) after powder zincizing 15-18min, it is slowly cooled to room temperature, the strong powder zincizing of high rigidity, corrosion resisting property is made
Product.
Further, powder zincizing agent described in step (1), in units of parts by weight, including following raw material:Zinc powder 60-
100 parts, 2-6 parts of sepiolite powder, 3-5 parts of aluminium powder, 1-2 parts of alumina powder, 1-3 parts of magnesium powder, 0.6-2 parts of cobalt powder, lead powder 0.4-1.5
Part, 0.8-1.4 parts of stearic acid aluminium powder, 0.2-0.5 parts of boron nitride powder, 0.5-1 parts of silicon dioxide powder, 0.6-1.2 parts of Graphene powder,
0.1-0.3 parts of hardening agent, 0.2-0.4 parts of dispersant, 0.3-0.6 parts of conditioning agent, 0.8-1.2 parts of activator, energizer 0.6-0.9
Part, 0.3-0.6 parts of stabilizer.
Preferably, the diameter 1-100nm of the Graphene powder particle.
Preferably, the hardening agent is 701 powder hardening agents.
Preferably, the dispersant is in units of weight, including following raw material:Bi2O38-12 parts, aminopropyl-triethoxy
9-15 parts of silane, 16-20 parts of aluminium carbide, Nb2O58-15 parts, 15-22 parts of magnesium sulfate.
Preferably, the conditioning agent is esters of acrylic acid conditioning agent.
Preferably, the activator is ammonium chloride.
Preferably, the energizer is acetic acid ytterbium.
Preferably, the stabilizer is bentone soil stabilizer.
Preferably, the preparation method of the powder zincizing agent, comprises the following steps:
S1:Weigh 60-100 parts of zinc powder, 2-6 parts of sepiolite powder, 3-5 parts of aluminium powder, alumina powder 1-2 respectively by weight
Part, 1-3 parts of magnesium powder, 0.6-2 parts of cobalt powder, 0.4-1.5 parts of lead powder, 0.8-1.4 parts of stearic acid aluminium powder, 0.2-0.5 parts of boron nitride powder,
0.5-1 parts of silicon dioxide powder, 0.6-1.2 parts of Graphene powder, 0.1-0.3 parts of hardening agent, 0.2-0.4 parts of dispersant, conditioning agent
0.3-0.6 parts, 0.8-1.2 parts of activator, 0.6-0.9 parts of energizer, 0.3-0.6 parts of stabilizer;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder,
Boron nitride powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, using mechanical ball grinding machine, in temperature
Spend for 72-85 DEG C, microwave power is ball milling 8-12min under 200-350W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 64-70 DEG C, microwave power in temperature
For ball milling 5-8min again under 150-180W, mixture B is made;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 100-105 DEG C in temperature,
Nitrogen protection is lower to dry 2-2.2h, and powder zincizing agent is made.
The invention has the advantages that:
(1) zincizing agent of the invention activity is high, and infiltration rate is fast, and recycling performance is excellent, and zinc coat thickness is considerable, uniform,
High with product bond strength, hardness is high, and wear-resisting, corrosion resisting property is strong, and excellent appearance is without piebald etc., production cost bottom, it is adaptable to each
Metal material and component are planted, with certain economic benefit, and its preparation method and application method are simple, convenient to implement;
(2) with patent document (publication number:CN103952661B sherardising temperature) is compared, zincizing temperature of the invention
It is lower, be conducive to saving the energy;
(3) do not lumpd during zincizing of the present invention, be easy to recycle, do not bonded with product, it is easy to the cleaning of product.
【Embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the present invention's
Protection domain, but do not limit the scope of the invention.
In embodiment, the powder zincizing agent, in units of parts by weight, including following raw material:60-100 parts of zinc powder, sea
2-6 parts of afrodite powder, 3-5 parts of aluminium powder, 1-2 parts of alumina powder, 1-3 parts of magnesium powder, 0.6-2 parts of cobalt powder, 0.4-1.5 parts of lead powder, tristearin
Sour aluminium powder 0.8-1.4 parts, 0.2-0.5 parts of boron nitride powder, 0.5-1 parts of silicon dioxide powder, 0.6-1.2 parts of Graphene powder, hardening agent
0.1-0.3 parts, it is 0.2-0.4 parts of dispersant, 0.3-0.6 parts of conditioning agent, 0.8-1.2 parts of activator, 0.6-0.9 parts of energizer, steady
Determine 0.3-0.6 parts of agent.
The granularity of the zinc powder is 300-500 mesh, Zn content >=98.5%.
The sepiolite powder contains sepiolite more than 98.2%, 6-28 μm of particle diameter.
The aluminium powder contains aluminium more than 95.5%, 0.5-8 μm of particle diameter.
The aluminum oxide salic more than 99.3%, particle diameter 50-100nm.
The magnesium powder contains magnesium more than 95.5%, 0.1-10 μm of particle diameter.
The cobalt powder contains cobalt more than 95.5%, 0.2-8 μm of particle diameter.
The lead powder leaded more than 95.5%, 0.4-6 μm of particle diameter.
1-12 μm of the particle diameter of the stearic acid aluminium powder.
0.2-10 μm of the diameter of the boron nitride powder particle.
1-10 μm of the diameter of the silica powder particles.
The diameter 1-100nm of the Graphene powder particle.
The hardening agent is 701 powder hardening agents.
The dispersant is in units of weight, including following raw material:Bi2O38-12 parts, aminopropyl triethoxysilane 9-15
Part, 16-20 parts of aluminium carbide, Nb2O58-15 parts, 15-22 parts of magnesium sulfate.
The conditioning agent is esters of acrylic acid conditioning agent.
The activator is ammonium chloride.
The energizer is acetic acid ytterbium.
The stabilizer is bentone soil stabilizer.
The preparation method of the powder zincizing agent, comprises the following steps:
S1:Weigh 60-100 parts of zinc powder, 2-6 parts of sepiolite powder, 3-5 parts of aluminium powder, alumina powder 1-2 respectively by weight
Part, 1-3 parts of magnesium powder, 0.6-2 parts of cobalt powder, 0.4-1.5 parts of lead powder, 0.8-1.4 parts of stearic acid aluminium powder, 0.2-0.5 parts of boron nitride powder,
0.5-1 parts of silicon dioxide powder, 0.6-1.2 parts of Graphene powder, 0.1-0.3 parts of hardening agent, 0.2-0.4 parts of dispersant, conditioning agent
0.3-0.6 parts, 0.8-1.2 parts of activator, 0.6-0.9 parts of energizer, 0.3-0.6 parts of stabilizer;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder,
Boron nitride powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, using mechanical ball grinding machine, in temperature
Spend for 72-85 DEG C, microwave power is ball milling 8-12min under 200-350W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 64-70 DEG C, microwave power in temperature
For ball milling 5-8min again under 150-180W, mixture B is made;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 100-105 DEG C in temperature,
Nitrogen protection is lower to dry 2-2.2h, and powder zincizing agent is made.
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property, comprises the following steps and is made:
(1) the powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, capping
Sealing;
(2) step (1) drum-type heating stove is rotated, is warming up to 350-370 DEG C;
(3) it is 350-370 DEG C to control temperature, increases ultrasonic wave, the power of ultrasonic wave is 160-200W, by drum-type heating
Stove rotating speed rises to 80r/min, then reduction of speed to 1r/min from 1r/min, such Circularly liftable;
(4) after powder zincizing 15-18min, it is slowly cooled to room temperature, the strong powder zincizing of high rigidity, corrosion resisting property is made
Product.
It is illustrated below by more specifically embodiment.
Embodiment 1
A kind of powder zincizing agent, in units of parts by weight, including following raw material:85 parts of zinc powder, 4 parts of sepiolite powder, aluminium powder
3.8 parts, 1.6 parts of alumina powder, 2 parts of magnesium powder, 1.5 parts of cobalt powder, 1 part of lead powder, 1 part of stearic acid aluminium powder, 0.4 part of boron nitride powder, two
0.8 part of silica powder, 1 part of Graphene powder, 0.2 part of hardening agent, 0.3 part of dispersant, 0.5 part of conditioning agent, 1 part of activator, urge and oozing
0.8 part of agent, 0.5 part of stabilizer.
The granularity of the zinc powder is 300-500 mesh, Zn content 98.5%.
The sepiolite powder contains sepiolite 98.2%, 6-28 μm of particle diameter.
The aluminium powder contains aluminium 95.5%, 0.5-8 μm of particle diameter.
The aluminum oxide salic 99.3%, particle diameter 50-100nm.
The magnesium powder contains magnesium 95.5%, 0.1-10 μm of particle diameter.
The cobalt powder contains cobalt 95.5%, 0.2-8 μm of particle diameter.
The lead powder leaded 95.5%, 0.4-6 μm of particle diameter.
1-12 μm of the particle diameter of the stearic acid aluminium powder.
0.2-10 μm of the diameter of the boron nitride powder particle.
1-10 μm of the diameter of the silica powder particles.
The diameter 1-100nm of the Graphene powder particle.
The hardening agent is 701 powder hardening agents.
The dispersant is in units of weight, including following raw material:Bi2O310 parts, 12 parts of aminopropyl triethoxysilane,
18 parts of aluminium carbide, Nb2O512 parts, 18 parts of magnesium sulfate.
The conditioning agent is esters of acrylic acid conditioning agent.
The activator is ammonium chloride.
The energizer is acetic acid ytterbium.
The stabilizer is bentone soil stabilizer.
The preparation method of the powder zincizing agent, comprises the following steps:
S1:Weigh 85 parts of zinc powder, 4 parts of sepiolite powder, 3.8 parts of aluminium powder, 1.6 parts of alumina powder, magnesium powder 2 respectively by weight
Part, 1.5 parts of cobalt powder, 1 part of lead powder, 1 part of stearic acid aluminium powder, 0.4 part of boron nitride powder, 0.8 part of silicon dioxide powder, 1 part of Graphene powder,
0.2 part of hardening agent, 0.3 part of dispersant, 0.5 part of conditioning agent, 1 part of activator, 0.8 part of energizer, 0.5 part of stabilizer;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder,
Boron nitride powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, using mechanical ball grinding machine, in temperature
Spend for 80 DEG C, microwave power is ball milling 10min under 280W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 68 DEG C in temperature, microwave power is
Ball milling 7min again under 170W, is made mixture B;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 102 DEG C, nitrogen in temperature
Protection is lower to dry 2.1h, and powder zincizing agent is made.
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property, comprises the following steps and is made:
(1) the powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, capping
Sealing;
(2) step (1) drum-type heating stove is rotated, is warming up to 360 DEG C;
(3) it is 360 DEG C to control temperature, increases ultrasonic wave, and the power of ultrasonic wave is 180W, by drum-type heating stove rotating speed from
1r/min rises to 80r/min, then reduction of speed to 1r/min, such Circularly liftable;
(4) after powder zincizing 17min, it is slowly cooled to room temperature, the strong powder zincizing system of high rigidity, corrosion resisting property is made
Part.
Embodiment 2
A kind of powder zincizing agent, in units of parts by weight, including following raw material:62 parts of zinc powder, 2.2 parts of sepiolite powder, aluminium
3 parts of powder, 1 part of alumina powder, 1 part of magnesium powder, 0.8 part of cobalt powder, 0.5 part of lead powder, 0.8 part of stearic acid aluminium powder, 0.3 part of boron nitride powder,
0.5 part of silicon dioxide powder, 0.6 part of Graphene powder, 0.1 part of hardening agent, 0.2 part of dispersant, 0.3 part of conditioning agent, activator 0.8
Part, 0.6 part of energizer, 0.3 part of stabilizer.
The granularity of the zinc powder is 300-500 mesh, and Zn content is 99%.
The sepiolite powder contains sepiolite 98.6%, 6-28 μm of particle diameter.
The aluminium powder contains aluminium 96.2%, 0.5-8 μm of particle diameter.
The aluminum oxide salic 99.5%, particle diameter 50-100nm.
The magnesium powder contains magnesium 95.8%, 0.1-10 μm of particle diameter.
The cobalt powder contains cobalt 95.7%, 0.2-8 μm of particle diameter.
The lead powder leaded 97.2%, 0.4-6 μm of particle diameter.
1-12 μm of the particle diameter of the stearic acid aluminium powder.
0.2-10 μm of the diameter of the boron nitride powder particle.
1-10 μm of the diameter of the silica powder particles.
The diameter 1-100nm of the Graphene powder particle.
The hardening agent is 701 powder hardening agents.
The dispersant is in units of weight, including following raw material:Bi2O38 parts, 9 parts of aminopropyl triethoxysilane, carbon
Change 16 parts of aluminium, Nb2O58 parts, 15 parts of magnesium sulfate.
The conditioning agent is esters of acrylic acid conditioning agent.
The activator is ammonium chloride.
The energizer is acetic acid ytterbium.
The stabilizer is bentone soil stabilizer.
The preparation method of the powder zincizing agent, comprises the following steps:
S1:Weigh 62 parts of zinc powder, 2.2 parts of sepiolite powder, 3 parts of aluminium powder, 1 part of alumina powder, magnesium powder 1 respectively by weight
Part, 0.8 part of cobalt powder, 0.5 part of lead powder, 0.8 part of stearic acid aluminium powder, 0.3 part of boron nitride powder, 0.5 part of silicon dioxide powder, Graphene powder
0.6 part, 0.1 part of hardening agent, 0.2 part of dispersant, 0.3 part of conditioning agent, 0.8 part of activator, 0.6 part of energizer, stabilizer 0.3
Part;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder,
Boron nitride powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, using mechanical ball grinding machine, in temperature
Spend for 72 DEG C, microwave power is ball milling 12min under 200W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 64 DEG C in temperature, microwave power is
Ball milling 8min again under 150W, is made mixture B;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 100 DEG C, nitrogen in temperature
Protection is lower to dry 2.2h, and powder zincizing agent is made.
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property, comprises the following steps and is made:
(1) the powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, capping
Sealing;
(2) step (1) drum-type heating stove is rotated, is warming up to 350 DEG C;
(3) it is 350 DEG C to control temperature, increases ultrasonic wave, and the power of ultrasonic wave is 160W, by drum-type heating stove rotating speed from
1r/min rises to 80r/min, then reduction of speed to 1r/min, such Circularly liftable;
(4) after powder zincizing 18min, it is slowly cooled to room temperature, the strong powder zincizing system of high rigidity, corrosion resisting property is made
Part.
Embodiment 3
A kind of powder zincizing agent, in units of parts by weight, including following raw material:96 parts of zinc powder, 5 parts of sepiolite powder, aluminium powder
4.8 parts, 2 parts of alumina powder, 3 parts of magnesium powder, 2 parts of cobalt powder, 1.5 parts of lead powder, 1.2 parts of stearic acid aluminium powder, 0.5 part of boron nitride powder, two
1 part of silica powder, 1.2 parts of Graphene powder, 0.3 part of hardening agent, 0.4 part of dispersant, 0.6 part of conditioning agent, 1.2 parts of activator, urge
0.9 part of penetration enhancer, 0.6 part of stabilizer.
The granularity of the zinc powder is 300-500 mesh, Zn content 99.2%.
The sepiolite powder contains sepiolite 98.8%, 6-28 μm of particle diameter.
The aluminium powder contains aluminium 96.1%, 0.5-8 μm of particle diameter.
The aluminum oxide salic 99.5%, particle diameter 50-100nm.
The magnesium powder contains magnesium 96.5%, 0.1-10 μm of particle diameter.
The cobalt powder contains cobalt 95.5%, 0.2-8 μm of particle diameter.
The lead powder leaded 95.5%, 0.4-6 μm of particle diameter.
1-12 μm of the particle diameter of the stearic acid aluminium powder.
0.2-10 μm of the diameter of the boron nitride powder particle.
1-10 μm of the diameter of the silica powder particles.
The diameter 1-100nm of the Graphene powder particle.
The hardening agent is 701 powder hardening agents.
The dispersant is in units of weight, including following raw material:Bi2O312 parts, 14 parts of aminopropyl triethoxysilane,
20 parts of aluminium carbide, Nb2O515 parts, 22 parts of magnesium sulfate.
The conditioning agent is esters of acrylic acid conditioning agent.
The activator is ammonium chloride.
The energizer is acetic acid ytterbium.
The stabilizer is bentone soil stabilizer.
The preparation method of the powder zincizing agent, comprises the following steps:
S1:Weigh 96 parts of zinc powder, 5 parts of sepiolite powder, 4.8 parts of aluminium powder, 2 parts of alumina powder, magnesium powder 3 respectively by weight
Part, 2 parts of cobalt powder, 1.5 parts of lead powder, 1.2 parts of stearic acid aluminium powder, 0.5 part of boron nitride powder, 1 part of silicon dioxide powder, Graphene powder 1.2
Part, 0.3 part of hardening agent, 0.4 part of dispersant, 0.6 part of conditioning agent, 1.2 parts of activator, 0.9 part of energizer, 0.6 part of stabilizer;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder,
Boron nitride powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, using mechanical ball grinding machine, in temperature
Spend for 85 DEG C, microwave power is ball milling 8min under 350W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 70 DEG C in temperature, microwave power is
Ball milling 5min again under 180W, is made mixture B;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 105 DEG C, nitrogen in temperature
Protection is lower to dry 2h, and powder zincizing agent is made.
The strong powder zincizing product of a kind of high rigidity, corrosion resisting property, comprises the following steps and is made:
(1) the powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, capping
Sealing;
(2) step (1) drum-type heating stove is rotated, is warming up to 370 DEG C;
(3) it is 370 DEG C to control temperature, increases ultrasonic wave, and the power of ultrasonic wave is 200W, by drum-type heating stove rotating speed from
1r/min rises to 80r/min, then reduction of speed to 1r/min, such Circularly liftable;
(4) after powder zincizing 15min, it is slowly cooled to room temperature, the strong powder zincizing system of high rigidity, corrosion resisting property is made
Part.
Using embodiment 1-3 powder zincizing agent and application method, product zincizing result is detected, while contrasting patent document
(publication number:CN103952661B) the zincizing of powder zincizing agent (application method is identical with embodiment 1-3 application method respectively,
Labeled as implementation 4-6) result, it is as a result as shown in the table.
As seen from the above table, compared with the zincizing agent of documents, zinc coat after powder zincizing agent zincizing product of the invention
Thickness is bigger, and hardness is higher, illustrates that the zincizing agent activity of the present invention is bigger, zincizing speed is faster.
The specific implementation of the invention is not to be limited to these illustrations for above content, is led for technology belonging to the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined by the claims submitted should be all considered as belonging to.
Claims (10)
1. the strong powder zincizing product of a kind of high rigidity, corrosion resisting property, it is characterised in that comprise the following steps and be made:
(1) powder zincizing agent is loaded in the ceramic-lined cylinder of drum-type heating stove with being intended to the product of zincizing, sealed;
(2) step (1) drum-type heating stove is rotated, is warming up to 350-370 DEG C;
(3) it is 350-370 DEG C to control temperature, increases ultrasonic wave, the power of ultrasonic wave is 160-200W, and drum-type heating stove is turned
Speed rises to 80r/min, then reduction of speed to 1r/min from 1r/min, such Circularly liftable;
(4) after powder zincizing 15-18min, it is slowly cooled to room temperature, the strong powder zincizing product of high rigidity, corrosion resisting property is made.
2. the strong powder zincizing product of high rigidity according to claim 1, corrosion resisting property, it is characterised in that in step (1)
The powder zincizing agent, in units of parts by weight, including following raw material:60-100 parts of zinc powder, 2-6 parts of sepiolite powder, aluminium powder 3-5
Part, 1-2 parts of alumina powder, 1-3 parts of magnesium powder, 0.6-2 parts of cobalt powder, 0.4-1.5 parts of lead powder, 0.8-1.4 parts of stearic acid aluminium powder, nitridation
0.2-0.5 parts of boron powder, 0.5-1 parts of silicon dioxide powder, 0.6-1.2 parts of Graphene powder, 0.1-0.3 parts of hardening agent, dispersant 0.2-
0.4 part, 0.3-0.6 parts of conditioning agent, 0.8-1.2 parts of activator, 0.6-0.9 parts of energizer, 0.3-0.6 parts of stabilizer.
3. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that the graphite
The diameter 1-100nm of alkene powder particles.
4. powder zincizing agent according to claim 2, it is characterised in that the hardening agent is 701 powder hardening agents.
5. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that described scattered
Agent is in units of weight, including following raw material:Bi2O38-12 parts, 9-15 parts of aminopropyl triethoxysilane, aluminium carbide 16-20
Part, Nb2O58-15 parts, 15-22 parts of magnesium sulfate.
6. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that the regulation
Agent is esters of acrylic acid conditioning agent.
7. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that the activation
Agent is ammonium chloride.
8. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that described urge is oozed
Agent is acetic acid ytterbium.
9. the strong powder zincizing product of high rigidity according to claim 2, corrosion resisting property, it is characterised in that the stabilization
Agent is bentone soil stabilizer.
10. the strong powder zincizing product of high rigidity, corrosion resisting property according to claim 1-9, it is characterised in that the powder
The preparation method of last zincizing agent, comprises the following steps:
S1:Weigh 60-100 parts of zinc powder, 2-6 parts of sepiolite powder, 3-5 parts of aluminium powder, 1-2 parts of alumina powder, magnesium respectively by weight
1-3 parts of powder, 0.6-2 parts of cobalt powder, 0.4-1.5 parts of lead powder, 0.8-1.4 parts of stearic acid aluminium powder, 0.2-0.5 parts of boron nitride powder, dioxy
0.5-1 parts of SiClx powder, 0.6-1.2 parts of Graphene powder, 0.1-0.3 parts of hardening agent, 0.2-0.4 parts of dispersant, conditioning agent 0.3-0.6
Part, 0.8-1.2 parts of activator, 0.6-0.9 parts of energizer, 0.3-0.6 parts of stabilizer;
S2:By step S1 zinc powder and sepiolite powder, aluminium powder, alumina powder, magnesium powder, cobalt powder, lead powder, stearic acid aluminium powder, nitridation
Boron powder, silicon dioxide powder, Graphene powder, dispersant, conditioning agent, activator are well mixed, and using mechanical ball grinding machine, are in temperature
72-85 DEG C, microwave power is ball milling 8-12min under 200-350W, and mixture A is made;
S3:Hardening agent, energizer are added into mixture A made from step S2, is 64-70 DEG C in temperature, microwave power is
Ball milling 5-8min again under 150-180W, is made mixture B;
S4:Stabilizer is added into mixture B made from step S3 and is well mixed, is then 100-105 DEG C, nitrogen in temperature
Protection is lower to dry 2-2.2h, and powder zincizing agent is made.
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Cited By (3)
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CN111041410A (en) * | 2019-12-23 | 2020-04-21 | 南宁普来得工贸有限公司 | High-bonding-strength wear-resistant powder zincizing workpiece |
CN111876723A (en) * | 2020-08-11 | 2020-11-03 | 盐城科奥机械有限公司 | Zinc impregnation method and anti-corrosion metal part |
CN114686801A (en) * | 2022-04-19 | 2022-07-01 | 福建宏贯路桥防腐科技股份有限公司 | Novel powder zinc impregnation and infiltration assisting process |
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CN105839047A (en) * | 2016-06-16 | 2016-08-10 | 福建大统铁路精密装备股份有限公司 | Zincizing infiltrated layer corrosion resistance process for metal |
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CN101122005A (en) * | 2007-07-23 | 2008-02-13 | 天津大学 | Method for processing fast powder sherardizing surface coat |
CN103952661A (en) * | 2014-04-29 | 2014-07-30 | 西安理工大学 | Solid zincizing agent and preparation method thereof |
CN105543775A (en) * | 2016-03-02 | 2016-05-04 | 河北科技大学 | Quick powder sheradizing agent and use method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111041410A (en) * | 2019-12-23 | 2020-04-21 | 南宁普来得工贸有限公司 | High-bonding-strength wear-resistant powder zincizing workpiece |
CN111876723A (en) * | 2020-08-11 | 2020-11-03 | 盐城科奥机械有限公司 | Zinc impregnation method and anti-corrosion metal part |
CN111876723B (en) * | 2020-08-11 | 2023-08-29 | 盐城科奥机械有限公司 | Zinc impregnation method and anti-corrosion metal piece |
CN114686801A (en) * | 2022-04-19 | 2022-07-01 | 福建宏贯路桥防腐科技股份有限公司 | Novel powder zinc impregnation and infiltration assisting process |
CN114686801B (en) * | 2022-04-19 | 2024-01-02 | 福建宏贯路桥防腐科技股份有限公司 | Powder zinc impregnation and permeation assisting process |
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