CN107142051A - A kind of wood adhesive using starch as raw material - Google Patents
A kind of wood adhesive using starch as raw material Download PDFInfo
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- CN107142051A CN107142051A CN201710230591.5A CN201710230591A CN107142051A CN 107142051 A CN107142051 A CN 107142051A CN 201710230591 A CN201710230591 A CN 201710230591A CN 107142051 A CN107142051 A CN 107142051A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/02—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of wood adhesive using starch as raw material, include the composition of raw materials component of following mass fraction：80 100 parts of starch, 13 parts of buffers, 12 18 parts of oxidants, 5 12 parts of polyvinyl alcohol, 4 10 parts of NMAs, 8 12 parts of bentonites, 12 20 parts of boraxs, 58 parts of agar, 8 15 parts of glycerine, 120 300 parts of water, 0.5 3 parts of sodium hydroxides.Wood adhesive of the present invention using starch as raw material, compared with common adhesives, its caking property, stability are obviously improved, and can preferably be applied to wood bonding, and bonding force is strong, and the timber-work being bonded discharges without toxic and harmful gas.
Description
Technical field
The invention belongs to technical field of adhesive preparation, and in particular to be a kind of wood adhesive using starch as raw material.
Background technology
Increasingly attention with people to household environment-friendlywater condition, for VOC gases, the You Jirong discharged in furniture
Agent etc. it is also proposed increasingly harsher requirement, in the adhesive of traditional furniture, organic solvent all be carried substantially, these are molten
Being difficult of agent discharges completely in a short time, and constantly slow for a long time can outwards produce, the healthy production that this will be to people
Raw influence.Amylan is applicating history the longest one kind as natural adhesive, there is raw material to be easy to get due to it, price
Cheap, corrosion-free, pollution-free, intensity is higher, lightweight, it is easy to use the advantages of, consumption is more and more big.External current research
Direction is to improve its water resistance and adhesive strength, such as adds the improvement that polyvinyl alcohol, urea carry out these performances, is widely used in
The bonding of corrugated case, paper, bafta, trade mark, envelope etc..The preparation method of starch adhesive has a variety of, mainly there is gelatinization
Method, oxidizing process, esterification, etherification method and with other high polymer monomer grafting copolymerization processes, because ative starch relative molecular mass is larger,
The degree of polymerization is higher, and mobility and permeability are poor, and the inner molecular structure of starch must be disintegrated during as adhesive, drop
Solution method mainly has thermal degradation, biodegradable, acid degradation and oxidative degradation etc., chemical property more active hydroxyl in starch molecule
Base and glycosidic bond are easily by various oxidizing, and hydroxyl is oxidized in aldehyde radical, ketone group, carboxyl, molecule under different conditions
Glycosidic bond part be broken, make the starch molecule degree of polymerization reduction, the starch after oxidation is the degree of polymerization containing aldehyde radical and carboxyl
The mixture of low modified starch, heated gelatinization or room temperature in the presence of oxidant are gelatinized and oxygen are made this starch with water
Change starch adhesive.But the production of starch-base timber adhesive and performance especially water resistance, adhesive strength and steady
It is qualitative to fail to be better to improve.
The content of the invention
The invention aims to overcome deficiency of the prior art, there is provided a kind of wood-gluing using starch as raw material
Agent.
To solve the above problems, the technical solution used in the present invention is as follows：
A kind of wood adhesive using starch as raw material, includes the composition of raw materials component of following mass fraction：
80-100 parts of starch, 1-3 parts of buffers, 12-18 parts of oxidants, 5-12 parts of polyvinyl alcohol, 4-10 parts of methylol acryloyls
Amine, 8-12 part bentonite, 12-20 parts of boraxs, 5-8 parts of agar, 8-15 parts of glycerine, 120-300 parts of water, 0.5-3 parts of sodium hydroxides.
Preferably, the composition of raw materials component of following mass fraction is included：90 parts of starch, 3 parts of buffers, 16 parts of oxidants,
10 parts of polyvinyl alcohol, 8 parts of NMAs, 9 parts of bentonites, 15 parts of boraxs, 6 parts of agar, 10 parts of glycerine, 200 parts of water, 1
Part sodium hydroxide.
Compared with prior art, beneficial effects of the present invention are as follows by the present invention：
Wood adhesive of the present invention using starch as raw material, compared with common adhesives, caking property, stability are obtained
To being obviously improved, wood bonding can be preferably applied to, bonding force is strong, and the timber-work being bonded is without toxic and harmful gas
Release.
Embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
A kind of wood adhesive using starch as raw material, includes the composition of raw materials component of following mass fraction：80-100 parts
Starch, 1-3 part buffer, 12-18 parts of oxidants, 5-12 parts of polyvinyl alcohol, 4-10 parts of NMAs, 8-12 parts of swellings
Soil, 12-20 parts of boraxs, 5-8 parts of agar, 8-15 parts of glycerine, 120-300 parts of water, 0.5-3 parts of sodium hydroxides.
Be glued, including bonding, bonding, it is cementing, gluing, refer to that homogeneity or heterogeneous body surface are linked together with adhesive
Technology, lightweight, or sealing, most technological temperature low features, because adhesive bonding technique especially fit continuous with stress distribution
For the connection of unlike material, different-thickness, ultra-thin specification and complex component, so adhesive with fastest developing speed, application industry
It is extremely wide, and have significant impact to high-and-new science and technology progress and people's daily life improvement.
80-100 parts of starch are added by the composition of raw materials component of mass fraction, are a kind of white powders, insoluble in cold water,
Starch granules can expand in hot water, and some starch dissolution is in water, and another part is suspended in water, form colloidal starch
Paste, amylan can be applicating history the longest one kind as natural adhesive in addition, there is raw material to be easy to get because of it, valency
Lattice are cheap, corrosion-free, pollution-free, intensity is higher, it is lightweight, easy to use the advantages of, consumption is more and more big, the starch after oxidation
Oxidized starch adhesive can be made, adhesive strength is higher, and color is glossy；Starch can not be added excessively, otherwise can cause group
Into the easy coagulative precipitation of composition, it is difficult to be oxidized, or even rotten, starch can not also add very few, can influence adhesive strength.
1-3 parts of buffers are added by the composition of raw materials component of mass fraction, the buffer is phosphate and borate
Mixture, can be used under control high-temperature high-pressure state, or under normal temperature and pressure, the solid compositions of gas or liquid fugacity are played
Stable pH value and the effect for keeping stable system, and its pH adjustable range can be increased, by the composition of raw materials group of mass fraction
Divide and add 0.5-3 parts of sodium hydroxides, sodium hydroxide is soluble in water, can be configured to sodium hydroxide solution, body can be adjusted
PH in system, and provide alkaline environment for starch gelatinization.
12-18 parts of oxidants are added by the composition of raw materials component of mass fraction, the oxidant is sodium perborate and crosses boron
The mixture of sour potassium, the effect of single-oxidizer is substantially better than using adhesive made from composite oxidant, and can also carry
The content of high boron element, it is possible to increase the heat resisting temperature of adhesive, and then its heat endurance is improved, oxidant can be by starch point
Chemical property more active hydroxyl and glycosidic bond are easily oxidized in son, and hydroxyl is oxidized in aldehyde radical, ketone group, carboxyl, molecule
Glycosidic bond part be broken, make the starch molecule degree of polymerization reduction, the starch after oxidation is the degree of polymerization containing aldehyde radical and carboxyl
The mixture of low modified starch, heated gelatinization or room temperature in the presence of oxidant are gelatinized and oxygen are made this starch with water
Change starch adhesive, oxidant is excessive or very few can influence the concentration and viscosity of adhesive.
5-12 parts of polyvinyl alcohol are added by the composition of raw materials component of mass fraction, polyvinyl alcohol is used as changing for starch adhesive
Property agent, with long-chain polyhydric alcohol, can be esterified, be etherified, the chemical reactivity such as acetalation, nontoxic, stingless to human body skin
Swash property, additionally it is possible to improve viscosity, the amount of the polyvinyl alcohol added will control proper, otherwise can influence the viscosity of adhesive, enter
And the gluing degree of adhesive and timber can be influenceed, influence the outward appearance of product.
4-10 parts of NMAs and 12-20 parts of boraxs, methylol are added by the composition of raw materials component of mass fraction
There is the methylol of the double bond being conjugated with carbonyl and rich reactivity, i.e. NMA contains not in acrylamide molecules
The polyfunctional monomer of saturation, can be used in the presence of oxygen, heat as crosslinking agent, be widely used in the modified resin of fiber, added
Work dyestuff, plastic binder, soil stabilizer etc., NMA is also as thickener, for increasing liquid phase denseness, mistake
The viscosity and lubricity of many or very few influence adhesive；Boron is not rare element in China, but high yield element, and borax is also made
For crosslinking agent, in addition, borax has antibacterial, anti-corrosion and protects the effect of skin and mucosa, the use time of adhesive can be extended,
And it is harmless, service life so as to prolonging wood product and harm, methylol third will not be produced to human body
Reaction can improve the effect of crosslinking jointly for acrylamide and borax.
Bentonite is a kind of claystone, and 8-12 parts of bentonites, bentonite tool are added by the composition of raw materials component of mass fraction
There is a strong hygroscopicity and dilatancy, adsorbable eight to fifteenfold own vol water, volumetric expansion is up to several times to 30
Times, can be cost-effective with good stability, increase utilization rate；As a form of gel and suspension can be dispersed into aqueous medium,
So that adhesive has certain viscosity, thixotropy and lubricity；Its admixture with water, mud or fine sand have plasticity and
The admixture of cohesiveness, i.e. bentonite and borax has plasticity and cohesiveness；In addition, also there is certain adsorptivity, can
The purpose of reduction leak-off rate is reached, the stability of system is improved.
Emulsifying agent can improve the various surface tension constituted between phase in emulsion, be allowed to form uniform and stable disperse
The material of system or emulsion, emulsifying agent is in a kind of surface reactive material, molecule while having hydrophilic group and lipophilic group, and it gathers
Collection can reduce interfacial tension and reduce the energy formed required for emulsion, so as to improve emulsion on oil/water interface
Energy；5-8 parts of agar are added by the composition of raw materials component of mass fraction, agar is in addition to it may be used as emulsifying agent, also with solidifying
Solidity, stability can be used as thickener, coagulator, suspending agent and stabilizer, be soluble in boiling water, and dilution is still protected at 42 DEG C
Liquid is held, but congeals at 37 DEG C close jelly, it is not stratified, the features such as be not demulsified, and good water solubility, agar is also as auxiliary
Fining agent, accelerates and improves clarification, very few to influence clarification degree, can excessively influence emulsification degree and produce a large amount of bubbles,
Influence is used.
Glycerine is the clear and bright thick liquid of no color or smell taste sweet tea, sweet by 8-15 parts of the composition of raw materials component addition of mass fraction
Oil, glycerine can be used as solvent, lubricant, when 66.7% glycerine freezing point highest, i.e. temperature are -46.5 DEG C, glycerine water solution content
For 66.7%, therefore glycerine also acts as antifreezing agent, it is to avoid adhesive freezes influence and used.
Preparation process is as follows：
（1）Water is first added in stirred tank, 60-75 DEG C is warming up to, preheating can reduce the reaction time, accelerates reaction speed；
（2）Starch, buffer, oxidant, polyvinyl alcohol, sodium hydroxide, reaction are added by the composition of raw materials component of mass fraction
60-75 DEG C of temperature, reaction time 1-2.5h, reaction solution pH8-9.5, is stirred continuously to uniform so that starch is aoxidized, and
And the starch after oxidation can be fully gelatinized in alkaline system environment, and then oxidized starch adhesive is made；
（3）NMA, borax, agar, glycerine are added by the composition of raw materials component of mass fraction, is stirred continuously to equal
It is even, 55-65 DEG C of reaction temperature, emulsion mixture is made in reaction time 1-1.5h, with certain cohesive, plasticity；
（4）50-60 DEG C are cooled to, insulation reaction 1-1.5h stirs so that added material is well mixed, increase starch
The stability and adhesive strength of adhesive；
（5）55-65 DEG C are warming up to, bentonite is added by the composition of raw materials component of mass fraction, stirs, 20- to be mixed
It is well mixed after 30 min, forms finished product, dramatically improve glued membrane adhesive force, glued membrane water resistance and heat resistance is improved, with very
Good stability, outward appearance also can be improved significantly.
【Embodiment one】A kind of wood adhesive using starch as raw material, includes the composition of raw materials group of following mass fraction
Point：80 parts of starch, 1 part of buffer, 12 parts of oxidants, 5 parts of polyvinyl alcohol, 10 parts of NMAs, 10 parts of bentonites, 15
Part borax, 5 parts of agar, 15 parts of glycerine, 150 parts of water, 1 part of sodium hydroxide.
Preparation process is as follows：
（1）100 parts of water is first added in stirred tank, 60 DEG C are warming up to；
（2）Add 80 parts of starch, 1 part of buffer, 12 parts of oxidants, 5 parts of polyvinyl alcohol, 1 part of sodium hydroxide, reaction temperature 65
DEG C, reaction time 1.5h, reaction solution pH8.5 stir；
（3）10 parts of NMAs, 15 parts of boraxs, 5 parts of agar, 15 parts of glycerine are added, are stirred, reaction temperature 60
DEG C, reaction time 1h；
（4）50 DEG C are cooled to, insulation reaction 1h stirs；
（5）55 DEG C are warming up to, 10 parts of bentonites, and remaining 50 parts of water is added, stirs, mixed after 30 min to be mixed
Uniformly, finished product is formed.
【Embodiment two】A kind of wood adhesive using starch as raw material, includes the composition of raw materials group of following mass fraction
Point：90 parts of starch, 3 parts of buffers, 16 parts of oxidants, 10 parts of polyvinyl alcohol, 8 parts of NMAs, 9 parts of bentonites, 15
Part borax, 6 parts of agar, 10 parts of glycerine, 200 parts of water, 1 part of sodium hydroxide.
Preparation process is as follows：
（1）150 parts of water is first added in stirred tank, 65 DEG C are warming up to；
（2）Add 90 parts of starch, 3 parts of buffers, 16 parts of oxidants, 10 parts of polyvinyl alcohol, 1 part of sodium hydroxide, reaction temperature 70
DEG C, reaction time 2h, reaction solution pH9.0 stir；
（3）8 parts of NMAs, 15 parts of boraxs, 6 parts of agar, 10 parts of glycerine are added, are stirred, 60 DEG C of reaction temperature,
Reaction time 1.2h；
（4）50 DEG C are cooled to, insulation reaction 1.2h stirs；
（5）60 DEG C are warming up to, 9 parts of bentonites, and remaining 50 parts of water is added, stirs, mixed after 25 min to be mixed
Uniformly, finished product is formed.
【Embodiment three】A kind of wood adhesive using starch as raw material, includes the composition of raw materials group of following mass fraction
Point：100 parts of starch, 3 parts of buffers, 18 parts of oxidants, 8 parts of polyvinyl alcohol, 10 parts of NMAs, 8 parts of bentonites,
18 parts of boraxs, 5 parts of agar, 12 parts of glycerine, 300 parts of water, 2 parts of sodium hydroxides.
Preparation process is as follows：
（1）200 parts of water is first added in stirred tank, 75 DEG C are warming up to；
（2）Add 100 parts of starch, 3 parts of buffers, 18 parts of oxidants, 8 parts of polyvinyl alcohol, 2 parts of sodium hydroxides, reaction temperature 75
DEG C, reaction time 2.5h, reaction solution pH9.5 stir；
（3）10 parts of NMAs, 18 parts of boraxs, 5 parts of agar, 12 parts of glycerine are added, are stirred, reaction temperature 65
DEG C, reaction time 1.5h；
（4）60 DEG C are cooled to, insulation reaction 1.5h stirs；
（5）65 DEG C are warming up to, 8 parts of bentonites, and remaining 100 parts of water is added, stirs, mixed after 30 min to be mixed
Uniformly, finished product is formed.
Experiment is compared with the wood adhesive and common adhesives of above-described embodiment one, two, three below, plank is entered
Row gluing, and be all divided into 5 × 5 grid, with using the plank of the wood adhesive gluing of embodiment one, two, three and
The plank of common adhesives gluing is used for one group, every group is tested at a temperature of 50 DEG C, 80 DEG C, 100 DEG C respectively, after 48h
The number of squares of remaining gluing on plank is calculated, experimental data is as follows：
Thus experimental result can be drawn：Wood adhesive of the present invention using starch as raw material, with common adhesives phase
Compare, the number of squares of remaining gluing is significantly more than common adhesives on the plank at a temperature of 50 DEG C, 80 DEG C, 100 DEG C, bonds
Property, stability be obviously improved, can preferably be applied to wood bonding, bonding force is strong, and the timber-work being bonded
Without toxic and harmful gas release.
Above content is made for the present invention in conjunction with specific embodiments describes in detail, it is impossible to assert that the present invention is specific real
Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from
Put, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.
Claims (2)
1. a kind of wood adhesive using starch as raw material, it is characterised in that include the composition of raw materials component of following mass fraction：
80-100 parts of starch, 1-3 parts of buffers, 12-18 parts of oxidants, 5-12 parts of polyvinyl alcohol, 4-10 parts of methylol acryloyls
Amine, 8-12 part bentonite, 12-20 parts of boraxs, 5-8 parts of agar, 8-15 parts of glycerine, 120-300 parts of water, 0.5-3 parts of sodium hydroxides.
2. a kind of wood adhesive using starch as raw material as claimed in claim 1, it is characterised in that including following mass parts
Several composition of raw materials components：90 parts of starch, 3 parts of buffers, 16 parts of oxidants, 10 parts of polyvinyl alcohol, 8 parts of methylol acryloyls
Amine, 9 parts of bentonites, 15 parts of boraxs, 6 parts of agar, 10 parts of glycerine, 200 parts of water, 1 part of sodium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710230591.5A CN107142051A (en) | 2017-04-11 | 2017-04-11 | A kind of wood adhesive using starch as raw material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710230591.5A CN107142051A (en) | 2017-04-11 | 2017-04-11 | A kind of wood adhesive using starch as raw material |
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| Publication Number | Publication Date |
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| CN107142051A true CN107142051A (en) | 2017-09-08 |
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| CN201710230591.5A Pending CN107142051A (en) | 2017-04-11 | 2017-04-11 | A kind of wood adhesive using starch as raw material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964467A (en) * | 2019-12-24 | 2020-04-07 | 彭敏 | High-strength adhesive for corrugated board and preparation method thereof |
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|---|---|---|---|---|
| CN101475790A (en) * | 2008-01-04 | 2009-07-08 | 杨光 | Novel timber adhesive and preparation thereof |
| CN102585736A (en) * | 2012-01-12 | 2012-07-18 | 浙江顶立胶业有限公司 | Hot-pressing veneer adhesive and preparation method thereof |
| CN102850957A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Preparation method for wood adhesive with starch as raw material |
| CN103834129A (en) * | 2012-11-22 | 2014-06-04 | 苏斌 | Green and environment friendly powdery building glue powder |
| CN104004478A (en) * | 2014-06-07 | 2014-08-27 | 东莞建泰生物科技有限公司 | Method for fabricating acidolysis acetylated starch adhesive and application of acidolysis acetylated starch adhesive |
-
2017
- 2017-04-11 CN CN201710230591.5A patent/CN107142051A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475790A (en) * | 2008-01-04 | 2009-07-08 | 杨光 | Novel timber adhesive and preparation thereof |
| CN102585736A (en) * | 2012-01-12 | 2012-07-18 | 浙江顶立胶业有限公司 | Hot-pressing veneer adhesive and preparation method thereof |
| CN102850957A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Preparation method for wood adhesive with starch as raw material |
| CN103834129A (en) * | 2012-11-22 | 2014-06-04 | 苏斌 | Green and environment friendly powdery building glue powder |
| CN104004478A (en) * | 2014-06-07 | 2014-08-27 | 东莞建泰生物科技有限公司 | Method for fabricating acidolysis acetylated starch adhesive and application of acidolysis acetylated starch adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964467A (en) * | 2019-12-24 | 2020-04-07 | 彭敏 | High-strength adhesive for corrugated board and preparation method thereof |
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Application publication date: 20170908 |