CN107142044A - A kind of rubber adhesive - Google Patents
A kind of rubber adhesive Download PDFInfo
- Publication number
- CN107142044A CN107142044A CN201710448402.1A CN201710448402A CN107142044A CN 107142044 A CN107142044 A CN 107142044A CN 201710448402 A CN201710448402 A CN 201710448402A CN 107142044 A CN107142044 A CN 107142044A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- parts
- rubber
- filler
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/164—Aluminum halide, e.g. aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of rubber adhesive, described adhesive by mass component by being constituted as follows：56 62 parts of solvent, 98 104 parts of nitrile rubber, 70 95 parts of phenolic resin, 13 parts of curing agent, 0.4 1.2 parts of accelerator, 46 parts of plasticizer, 37 parts of activator, 24 parts of age resistor, 0.2 0.5 parts of stearic acid, 47 parts of filler, 13 parts of aluminium chloride.The invention provides a kind of rubber adhesive, this adhesive has good heat-resisting and weatherability, can bond the object of various materials, and be firmly bonded.
Description
Technical field
The present invention relates to technical field of polymer materials, more particularly to a kind of rubber adhesive.
Background technology
Every medium that of the same race or solid material surface not of the same race can be glued together is referred to as adhesive,
Also referred to as adhesive.The method for connecting the surface of solids by the bonding force of adhesive is called bonding or glue.World's adhesive work
Industry still belongs to the preferable chemical industry of development, and global adhesive sales volume is more than 12,000,000 t/a, global consumption structure within 1998
35% is accounted for for packaging, building accounts for 25%, timber processing accounts for 20%, Automobile Transportation accounts for 10%, other to account for 10%.It is expected that
Between 2000-2010, developed country's synthetic adhesive industry will keep 3% development speed.
Adhesive is much all used outdoor, it is necessary to be exposed to the elements, and various weather conditions are required for experience, still
Existing adhesive in the presence of a harsh environment when, adhesive easily splits, aging, loses cohesive.
The content of the invention
In view of this, the invention provides a kind of rubber adhesive, this adhesive has well heat-resisting and weather-proof
Property, the object of various materials can be bonded, and be firmly bonded.
A kind of rubber adhesive, described adhesive by mass component by being constituted as follows：
Preferably, described adhesive by mass component by being constituted below：
Preferably, the solvent is ethyl ketone and butanone at least one therein.
Preferably, the solvent butanone.
Preferably, the curing agent is any in hexa, metaformaldehyde, sulphur.
Preferably, the curing agent is hexa.
Preferably, the accelerator is any in benzothiazole disulfide, captax, a- sulfurio benzo thiazoles.
Preferably, the activator is one or both of magnesia, zinc oxide.
Preferably, the age resistor is antioxidant 4020.
Preferably, the filler is at least one of carbon black, stannous chloride and aluminium chloride.
The beneficial effects of the present invention are：The invention provides a kind of rubber adhesive, this adhesive has well resistance to
Heat and weatherability, can bond the object of various materials, and be firmly bonded.
Embodiment
To illustrate the thought and purpose of the present invention, below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1
Rubber adhesive, adhesive by mass component by being constituted as follows：
Rubber adhesive preparation method：
Rubber is put into mill and kneaded, filler is added after kneading, is kneaded 15 minutes；Added in reactor
Solvent, partially filled agent, stir, and add age resistor, continue to stir 3 hours；Rubber by mixing is put into reactor
In, phenolic resin is added, curing agent, accelerator, plasticizer, activator, stearic acid, filler, aluminium chloride is stirred, dissolved,
65 DEG C are warming up to, is reacted 7 hours, is then cooled to room temperature, discharging；Rubber after grafting is added in mixer, opened
Machine is stirred 10 minutes, adds remaining filler, is stirred 1.5 hours, discharging, packaging.
Embodiment 2
Rubber adhesive, adhesive by mass component by being constituted as follows：
Rubber adhesive preparation method：
Rubber is put into mill and kneaded, filler is added after kneading, is kneaded 15 minutes；Added in reactor
Solvent, partially filled agent, stir, and add age resistor, continue to stir 3 hours；Rubber by mixing is put into reactor
In, phenolic resin is added, curing agent, accelerator, plasticizer, activator, stearic acid, filler, aluminium chloride is stirred, dissolved,
65 DEG C are warming up to, is reacted 7 hours, is then cooled to room temperature, discharging；Rubber after grafting is added in mixer, opened
Machine is stirred 10 minutes, adds remaining filler, is stirred 1.5 hours, discharging, packaging.
Embodiment 3
Rubber adhesive, adhesive by mass component by being constituted as follows：
Rubber adhesive preparation method：
Rubber is put into mill and kneaded, filler is added after kneading, is kneaded 15 minutes；Added in reactor
Solvent, partially filled agent, stir, and add age resistor, continue to stir 3 hours；Rubber by mixing is put into reactor
In, phenolic resin is added, curing agent, accelerator, plasticizer, activator, stearic acid, filler, aluminium chloride is stirred, dissolved,
65 DEG C are warming up to, is reacted 7 hours, is then cooled to room temperature, discharging；Rubber after grafting is added in mixer, opened
Machine is stirred 10 minutes, adds remaining filler, is stirred 1.5 hours, discharging, packaging.
Embodiment 4
Rubber adhesive, adhesive by mass component by being constituted as follows：
Rubber adhesive preparation method：
Rubber is put into mill and kneaded, filler is added after kneading, is kneaded 15 minutes；Added in reactor
Solvent, partially filled agent, stir, and add age resistor, continue to stir 3 hours；Rubber by mixing is put into reactor
In, phenolic resin is added, curing agent, accelerator, plasticizer, activator, stearic acid, filler, aluminium chloride is stirred, dissolved,
65 DEG C are warming up to, is reacted 7 hours, is then cooled to room temperature, discharging；Rubber after grafting is added in mixer, opened
Machine is stirred 10 minutes, adds remaining filler, is stirred 1.5 hours, discharging, packaging.
Embodiment 1-4 is done into salt-fog resistant test：
Acetic acid salt spray test (ASS experiments) grows up on the basis of neutral salt spray test.It is in 5% chlorine
Change in sodium solution and add some glacial acetic acid, the pH value of solution is reduced to 3 or so, solution becomes acid, the salt fog eventually formed
Become acid by neutral salt spray.
The two good metallic plates for scribbling adhesive coating of uniformity are placed wherein, the multiple for placing 24h respectively is placed
Time, tested.
Take out, the shear strength to cohesive is tested, be not put into acetic acid salt spray test scribble adhesive coating
Metallic plate carry out cohesive comparison.
From characterization result as can be seen that after salt mist experiment, intensity is with the increase of salt fog time, shear strength
Decline, still, the amplitude of decline is very small, it can be seen that the resistance to saltfog of the adhesive can be very good.
Above is to specific embodiment provided by the present invention.
The present invention is described in detail specification, and specific case used herein is former to the structure of the present invention
Reason and embodiment are set forth, and above example is only intended to the method and its core concept for helping to understand the present invention；Together
When, for those of ordinary skill in the art, according to the thought of the present invention, can in specific embodiments and applications
There is change part, in summary, this specification content should not be construed as limiting the invention.
Claims (10)
1. a kind of rubber adhesive, it is characterised in that described adhesive by mass component by being constituted as follows：
。
2. adhesive as claimed in claim 1, it is characterised in that described adhesive by mass component by being constituted below：
。
3. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The solvent is that ethyl ketone and butanone are therein extremely
Few one kind.
4. adhesive as claimed in claim 3, it is characterised in that：The solvent butanone.
5. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The curing agent is hexa, trimerization
It is any in formaldehyde, sulphur.
6. adhesive as claimed in claim 5, it is characterised in that：The curing agent is hexa.
7. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The accelerator is benzothiazole disulfide, promoted
Enter any in agent M, a- sulfurio benzo thiazole.
8. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The activator is magnesia, in zinc oxide
It is one or two kinds of.
9. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The age resistor is antioxidant 4020.
10. the adhesive as described in claim 1 to 2 is any, it is characterised in that：The filler be carbon black, stannous chloride with
At least one of and aluminium chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710448402.1A CN107142044A (en) | 2017-06-14 | 2017-06-14 | A kind of rubber adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710448402.1A CN107142044A (en) | 2017-06-14 | 2017-06-14 | A kind of rubber adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107142044A true CN107142044A (en) | 2017-09-08 |
Family
ID=59782888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710448402.1A Pending CN107142044A (en) | 2017-06-14 | 2017-06-14 | A kind of rubber adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107142044A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110917726A (en) * | 2019-12-12 | 2020-03-27 | 上海科格思过滤材料有限公司 | Preparation method of novel frameless filter material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108274A (en) * | 2011-01-27 | 2011-06-29 | 安徽安大中鼎橡胶技术开发有限公司 | Phenolic-nitrile rubber hot vulcanized adhesive and preparation method thereof |
| CN105255391A (en) * | 2015-09-25 | 2016-01-20 | 安徽大松树脂有限公司 | Glue hardening agent used for promoting vulcanization |
-
2017
- 2017-06-14 CN CN201710448402.1A patent/CN107142044A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108274A (en) * | 2011-01-27 | 2011-06-29 | 安徽安大中鼎橡胶技术开发有限公司 | Phenolic-nitrile rubber hot vulcanized adhesive and preparation method thereof |
| CN105255391A (en) * | 2015-09-25 | 2016-01-20 | 安徽大松树脂有限公司 | Glue hardening agent used for promoting vulcanization |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110917726A (en) * | 2019-12-12 | 2020-03-27 | 上海科格思过滤材料有限公司 | Preparation method of novel frameless filter material |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170908 |