CN107141798A - A kind of auto manufacturing high tenacity anti-corrosion 3D printing material and preparation method thereof - Google Patents
A kind of auto manufacturing high tenacity anti-corrosion 3D printing material and preparation method thereof Download PDFInfo
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- CN107141798A CN107141798A CN201710463191.9A CN201710463191A CN107141798A CN 107141798 A CN107141798 A CN 107141798A CN 201710463191 A CN201710463191 A CN 201710463191A CN 107141798 A CN107141798 A CN 107141798A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/02—Polythioethers; Polythioether-ethers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a kind of auto manufacturing high tenacity anti-corrosion 3D printing material, its raw material includes modified polyphenyl thioether, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, dioctyl phthalate, Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate crystal whiskers, CNT, tossa, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, antioxidant, silane coupler KH 570, modified toughened dose and and modified filler.The present invention also proposes a kind of preparation method of the above-mentioned auto manufacturing with high tenacity anti-corrosion 3D printing material.The 3D printing material prepared has excellent toughness and antiseptic property.
Description
Technical field
Beaten the present invention relates to the technical field of 3D printing material, more particularly to a kind of auto manufacturing with high tenacity anti-corrosion 3D
Print material and preparation method thereof.
Background technology
Polyphenylene sulfide is referred to as " the sixth-largest engineering plastics in the world ", is also one of eight big aerospace materials, polyphenylene sulfide has
Excellent heat resistance, corrosion resistance, high-dimensional stability, also with excellent dielectric properties, excellent fire resistance and protrusion
Adhesive property, be widely used in the fields such as electric, automobile, environmental protection, Aero-Space, but the poor toughness of polyphenylene sulfide,
Intensity is not enough, and it is as one kind of 3D printing material, and it is under the premise of ensureing with excellent antiseptic property, and toughness can not be met
Demand when actual use, so need a kind of auto manufacturing of design badly solves existing skill with high tenacity anti-corrosion 3D printing material
The problem of in art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of auto manufacturing high tenacity anti-corrosion 3D
Printed material and preparation method thereof, the 3D printing material prepared has excellent toughness and antiseptic property.
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
80-120 parts of modified polyphenyl thioether, 20-40 parts of phenolic resin, 15-35 parts of epoxy acrylic resin, 1-5 parts of amino resins, polychlorostyrene
2-6 parts of ethene, 2-8 parts of trimethyl phosphate, 8-16 parts of trimethyl phosphate, 3-9 parts of dioctyl phthalate, 1-5 parts of Firebrake ZB,
1-5 parts of nano-aluminum hydroxide, 4-8 parts of glass microballoon, 2-6 parts of polyphosphoric acids aluminium, 1-6 parts of titanium dioxide, 3-6 parts of glass fibre, carbon
4-8 parts of fiber, 2-5 parts of calcium sulfate crystal whiskers, 1-4 parts of CNT, 2-8 parts of tossa, 1-5 parts of PLLA, gather oneself two
It is sour 2-4 parts, 3-9 parts of butylene terephthalate, 3-6 parts of polypropylene, 2-5 parts of maleic anhydride, 1-4 parts of antioxidant, silane coupled
2-5 parts of agent KH-570, modified toughened dose 4-8 parts, 9-18 parts of modified filler.
Preferably, modified polyphenyl thioether is prepared by following technique：Polyphenylene sulfide and 1,2- dichloroethanes are mixed equal
It is even, then add chloromethyl ether and anhydrous stannic chloride is well mixed, be warming up to 60-80 DEG C, be incubated after 20-40min, drawer with steaming
Distilled water is washed to neutrality, is dried under vacuum to constant weight, then adds tetrahydrofuran and trimethylamine aqueous solution is well mixed, be placed in 80-
10-14h is vibrated in 90 DEG C of constant temperature oscillation casees, neutrality is then washed with distilled water to, constant weight is dried under vacuum to, cooling room temperature is obtained
Modified polyphenyl thioether.
Preferably, in the preparation technology of modified polyphenyl thioether, polyphenylene sulfide, 1,2- dichloroethanes, chloromethyl ether, anhydrous tetrachloro
The weight ratio for changing tin, tetrahydrofuran and trimethylamine aqueous solution is 3-6：2-5：1-4：4-8：2-6：1-4.
Preferably, in the preparation technology of modified polyphenyl thioether, the mass fraction of trimethylamine aqueous solution is 1.5-3.5%.
Preferably, modified toughened dose of raw material includes by weight：5-15 parts of diatomite, 3-9 parts of kaolin, sulfate precipitate
2-5 parts of barium, 1-4 parts of zeolite powder, 3-6 parts of nano aluminium oxide, 2-5 parts of nano titanium oxide, 1-4 parts of talcum powder, powdered whiting
3-5 parts, 2-5 parts of nano-calcium carbonate, 1-5 parts of asbestos fibre, 2-6 parts of dichloroethanes, 3-6 parts of thionyl chloride, 2- propylene -1- alcohol 2-
8 parts.
Preferably, modified toughened dose is prepared by following technique：By diatomite, kaolin, blanc fixe, zeolite
Powder, nano aluminium oxide, nano titanium oxide, talcum powder, powdered whiting, nano-calcium carbonate, asbestos fibre and dichloroethanes are mixed
Close uniform, ultrasonically treated 1-3h is subsequently added into thionyl chloride, and magnetic agitation 20-40min is then warming up to 80-90 DEG C, backflow
20-30h, is cooled to addition 2- propylene -1- alcohol after room temperature and is well mixed, be then warming up to 45-55 DEG C, stir 22-26h, then
Washed 1-4 times with acetone, after centrifugation, by solid in 40-50 DEG C of dry 6-12h, be cooled to room temperature and obtain modified toughened dose.
Preferably, the raw material of modified filler includes by weight：3-9 parts of neopelex, deionized water 5-15
Part, 2-6 parts of nano-ceramic powder, 1-4 parts of molybdenum disulfide, 2-5 parts of magnesium hydroxide, 3-5 parts of aluminium hydroxide, 2-6 parts of antimony trioxide, oxygen
Change 3-6 parts of zinc, 1-4 parts of aluminum sulfate, 2-5 parts of carbamate, 3-8 parts of isopropyl acrylate, polyparaphenylene's benzodiazole fiber
2-9 parts.
Preferably, modified filler is prepared by following technique：Neopelex and deionized water are mixed equal
It is even, 2-4min is stirred, nano-ceramic powder, molybdenum disulfide, magnesium hydroxide, aluminium hydroxide, antimony trioxide and zinc oxide is then added
It is well mixed, stirred under ultrasonic wave, be then heated to 65-75 DEG C, aluminum sulfate is added dropwise and is well mixed, filters, washing, in
45-55 DEG C of vacuum drying 5-7h, is cooled to room temperature, and 2-5h is then calcined in 820-920 DEG C, and cooling is put into hydrochloric acid solution and soaked
1-3h is steeped, filtering is taken out, washing dry, pulverize, be cooled to after room temperature and add carbamate, isopropyl acrylate and poly- pair
Penylene benzodiazole fiber is well mixed, and is warming up to 80-90 DEG C, is incubated 1-3h, and 20- is stirred in 650-850r/min rotating speeds
40min, is cooled to grinding distribution after room temperature and produces modified filler.
A kind of preparation method of auto manufacturing high tenacity anti-corrosion 3D printing material of the present invention, including：Will be modified poly-
Diphenyl sulfide, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, adjacent benzene two
Formic acid dioctyl ester, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, antioxidant and silane
Coupling agent kh-570 is well mixed, and is warming up to 90-120 DEG C, is incubated 1-3h, then stirs 20- in 1200-1400r/min rotating speeds
40min, then add Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber,
Calcium sulfate crystal whiskers, CNT, tossa, modified filler and modified toughened dose are well mixed, in 850-980r/min rotating speeds
1-3h is stirred, 180-220 DEG C is warming up to, is incubated after 2-4h, natural cooling, auto manufacturing is can be prepared by after crushing and screening high
Toughness anti-corrosion 3D printing material.
The present invention a kind of auto manufacturing high tenacity anti-corrosion 3D printing material, its raw material include modified polyphenyl thioether,
Phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, phthalic acid two
Monooctyl ester, Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate are brilliant
It is palpus, CNT, tossa, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, anti-
Oxygen agent, Silane coupling reagent KH-570, modified toughened dose and and modified filler.The 3D printing material prepared has excellent tough
Property and antiseptic property.Wherein, modified polyphenyl thioether is by the way that by polyphenylene sulfide and 1,2- dichloroethanes is well mixed, and then adds chlorine
Methyl ether and anhydrous stannic chloride are well mixed, heat up, insulation, are washed with distilled water to neutrality after drawer, are dried under vacuum to constant weight,
Then add tetrahydrofuran and trimethylamine aqueous solution is well mixed, be placed in constant temperature oscillation case and vibrate, then with distillation water washing
To neutral, constant weight is dried under vacuum to, cooling room temperature obtains modified polyphenyl thioether, applied in 3D printing material of the present invention so that
The 3D printing material of the present invention has excellent toughness and antiseptic property.Wherein, modified toughened dose by by diatomite, kaolinite
Soil, blanc fixe, zeolite powder, nano aluminium oxide, nano titanium oxide, talcum powder, powdered whiting, nano-calcium carbonate, stone
Cotton fiber and dichloroethanes are well mixed, ultrasonically treated, are subsequently added into thionyl chloride, magnetic agitation then heats up, and flow back, cold
But it is well mixed to addition 2- propylene -1- alcohol after room temperature, then heats up, stir, then washed with acetone, will after centrifugation
Solid is dried, and is cooled to room temperature and is obtained modified toughened dose, in the 3D printing material for applying to the present invention so that 3D of the invention is beaten
Print material has excellent toughness.Wherein.Modified filler is stirred by the way that neopelex and deionized water are well mixed
Mix, then add nano-ceramic powder, molybdenum disulfide, magnesium hydroxide, aluminium hydroxide, antimony trioxide and zinc oxide and be well mixed,
Stir, then heat under ultrasonic wave, aluminum sulfate is added dropwise and is well mixed, filters, washing, in vacuum drying, is cooled to room temperature,
Then calcine, cool down, be put into hydrochloric acid solution and soak, filtering is taken out, washing dry, pulverize, be cooled to after room temperature and add amino
Formic acid esters, isopropyl acrylate and polyparaphenylene's benzodiazole fiber are well mixed, heat up, and are incubated, and stirring is cooled to after room temperature
Grinding distribution produces modified filler, applies in 3D printing material of the present invention so that 3D printing material of the present invention has excellent
Toughness and antiseptic property.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of modified polyphenyl thioether can for 80 parts, 85 parts, 90 parts, 95 parts, 100 parts,
105 parts, 110 parts, 115 parts, 120 parts；The parts by weight of phenolic resin can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts；Epoxy third
The parts by weight of olefin(e) acid resin can for 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts,
26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts；The parts by weight of amino resins can for 1 part, 2
Part, 3 parts, 4 parts, 5 parts；The parts by weight of polyvinyl chloride can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of trimethyl phosphate can
Think 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of trimethyl phosphate can for 8 parts, 9 parts, 10 parts, 11 parts, 12
Part, 13 parts, 14 parts, 15 parts, 16 parts；The parts by weight of dioctyl phthalate can for 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts,
9 parts；The parts by weight of Firebrake ZB can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The parts by weight of nano-aluminum hydroxide can for 1 part, 2
Part, 3 parts, 4 parts, 5 parts；The parts by weight of glass microballoon can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts,
8 parts；The parts by weight of polyphosphoric acids aluminium can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of titanium dioxide can for 1 part, 1.5
Part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of glass fibre can for 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of carbon fiber can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts,
7 parts, 7.5 parts, 8 parts；The parts by weight of calcium sulfate crystal whiskers can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Carbon is received
The parts by weight of mitron can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of tossa can be 2
Part, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of PLLA can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of polyadipate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Terephthalic acid (TPA)
The parts by weight of fourth diester can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5
Part, 9 parts；Polyacrylic parts by weight can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of maleic anhydride
It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of antioxidant can for 1 part, 1.5 parts, 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts；The parts by weight of Silane coupling reagent KH-570 can be 2 parts, 2.5 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；
Modified toughened dose of parts by weight can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of modified filler can for 9 parts, 9.5 parts,
10 parts, 10.5 parts, 11 parts, 11.5 parts, 12 parts, 12.5 parts, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts, 16 parts,
16.5 parts, 17 parts, 17.5 parts, 18 parts.
Embodiment 1
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
100 parts of modified polyphenyl thioether, 30 parts of phenolic resin, 25 parts of epoxy acrylic resin, 3 parts of amino resins, 4 parts of polyvinyl chloride, phosphorus
Sour 5 parts of trimethyl, 12 parts of trimethyl phosphate, 6 parts of dioctyl phthalate, 3 parts of Firebrake ZB, 3 parts of nano-aluminum hydroxide, glass
6 parts of microballon, 4 parts of polyphosphoric acids aluminium, 3.5 parts of titanium dioxide, 4.5 parts of glass fibre, 6 parts of carbon fiber, 3.5 parts of calcium sulfate crystal whiskers, carbon
2.5 parts of nanotube, 5 parts of tossa, 3 parts of PLLA, 3 parts of polyadipate, 6 parts of butylene terephthalate, polypropylene
4.5 parts, 3.5 parts of maleic anhydride, 2.5 parts of antioxidant, 3.5 parts of Silane coupling reagent KH-570, modified toughened dose 6 parts, modified filler
13.5 parts.
Embodiment 2
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
80 parts of modified polyphenyl thioether, 40 parts of phenolic resin, 15 parts of epoxy acrylic resin, 5 parts of amino resins, 2 parts of polyvinyl chloride, phosphoric acid
8 parts of trimethyl, 8 parts of trimethyl phosphate, 9 parts of dioctyl phthalate, 1 part of Firebrake ZB, 5 parts of nano-aluminum hydroxide, glass are micro-
4 parts of pearl, 6 parts of polyphosphoric acids aluminium, 1 part of titanium dioxide, 6 parts of glass fibre, 4 parts of carbon fiber, 5 parts of calcium sulfate crystal whiskers, CNT 1
Part, 8 parts of tossa, 1 part of PLLA, 4 parts of polyadipate, 3 parts of butylene terephthalate, 6 parts of polypropylene, maleic acid
2 parts of acid anhydride, 4 parts of antioxidant, 2 parts of Silane coupling reagent KH-570, modified toughened dose 8 parts, 9 parts of modified filler.
Modified polyphenyl thioether is prepared by following technique：By weight by 3 parts of polyphenylene sulfides and 5 parts of 1,2- dichloroethanes
It is well mixed, then add 1 part of chloromethyl ether and 8 parts of anhydrous stannic chlorides are well mixed, be warming up to 60 DEG C, be incubated 40min, drawer
After be washed with distilled water to neutrality, be dried under vacuum to constant weight, it is 1.5% then to add 2 parts of tetrahydrofurans and 4 parts of mass fractions
Trimethylamine aqueous solution is well mixed, and is placed in 90 DEG C of constant temperature oscillation casees and is vibrated 10h, is then washed with distilled water to neutrality, vacuum
Dry to constant weight, cooling room temperature obtains modified polyphenyl thioether.
Modified toughened dose is prepared by following technique：By weight by 5 parts of diatomite, 9 parts of kaolin, 2 parts of precipitated sulfurs
Sour barium, 4 parts of zeolite powders, 3 parts of nano aluminium oxides, 5 parts of nano titanium oxides, 1 part of talcum powder, 5 parts of powdered whitings, 2 parts of nanometers
Calcium carbonate, 5 parts of asbestos fibres and 2 parts of dichloroethanes are well mixed, and ultrasonically treated 3h is subsequently added into 3 parts of thionyl chlorides, and magnetic force is stirred
40min is mixed, 80 DEG C are then warming up to, flow back 30h, 2 parts of 2- propylene -1- alcohol of addition after room temperature is cooled to and is well mixed, then rise
Temperature stirs 22h, is then washed with acetone 4 times, after centrifugation, by solid in 40 DEG C of dry 12h, be cooled to room temperature to 55 DEG C
Obtain modified toughened dose.
Modified filler is prepared by following technique：By weight by 3 parts of neopelexes and 15 parts of deionizations
Water is well mixed, and stirs 2min, then adds 6 parts of nano-ceramic powders, 1 part of molybdenum disulfide, 5 parts of magnesium hydroxides, 3 parts of hydroxides
Aluminium, 6 parts of antimony trioxides and 3 parts of zinc oxide are well mixed, and are stirred under ultrasonic wave, are then heated to 75 DEG C, 1 part of sulphur is added dropwise
Sour aluminium is well mixed, and is filtered, and washing is dried in vacuo 5h in 55 DEG C, is cooled to room temperature, and 2h is then calcined in 920 DEG C, and cooling is put
Enter and 3h soaked in hydrochloric acid solution, filtering is taken out, washing dry, pulverize, be cooled to after room temperature add 2 parts of carbamates, 8 parts
Isopropyl acrylate and 2 parts of polyparaphenylene's benzodiazole fibers are well mixed, and are warming up to 90 DEG C, are incubated 1h, turn in 850r/min
Speed stirring 20min, is cooled to grinding distribution after room temperature and produces modified filler.
Embodiment 3
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
120 parts of modified polyphenyl thioether, 20 parts of phenolic resin, 35 parts of epoxy acrylic resin, 1 part of amino resins, 6 parts of polyvinyl chloride, phosphorus
Sour 2 parts of trimethyl, 16 parts of trimethyl phosphate, 3 parts of dioctyl phthalate, 5 parts of Firebrake ZB, 1 part of nano-aluminum hydroxide, glass
8 parts of microballon, 2 parts of polyphosphoric acids aluminium, 6 parts of titanium dioxide, 3 parts of glass fibre, 8 parts of carbon fiber, 2 parts of calcium sulfate crystal whiskers, CNT 4
Part, 2 parts of tossa, 5 parts of PLLA, 2 parts of polyadipate, 9 parts of butylene terephthalate, 3 parts of polypropylene, maleic acid
5 parts of acid anhydride, 1 part of antioxidant, 5 parts of Silane coupling reagent KH-570, modified toughened dose 4 parts, 18 parts of modified filler.
A kind of preparation method of auto manufacturing high tenacity anti-corrosion 3D printing material of the present invention, including：Will be modified poly-
Diphenyl sulfide, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, adjacent benzene two
Formic acid dioctyl ester, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, antioxidant and silane
Coupling agent kh-570 is well mixed, and is warming up to 120 DEG C, is incubated 1h, is then stirred 20min in 1400r/min rotating speeds, is then added
Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate crystal whiskers, carbon
Nanotube, tossa, modified filler and modified toughened dose are well mixed, stir 1h in 980r/min rotating speeds, are warming up to 220
DEG C, it is incubated after 2h, natural cooling, auto manufacturing's high tenacity anti-corrosion 3D printing material is can be prepared by after crushing and screening.
Embodiment 4
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
85 parts of modified polyphenyl thioether, 35 parts of phenolic resin, 18 parts of epoxy acrylic resin, 4 parts of amino resins, 3 parts of polyvinyl chloride, phosphoric acid
7 parts of trimethyl, 9 parts of trimethyl phosphate, 8 parts of dioctyl phthalate, 2 parts of Firebrake ZB, 4 parts of nano-aluminum hydroxide, glass are micro-
5 parts of pearl, 5 parts of polyphosphoric acids aluminium, 2 parts of titanium dioxide, 5 parts of glass fibre, 5 parts of carbon fiber, 4 parts of calcium sulfate crystal whiskers, CNT 2
Part, 7 parts of tossa, 2 parts of PLLA, 3.5 parts of polyadipate, 4 parts of butylene terephthalate, 5 parts of polypropylene, Malaysia
3 parts of acid anhydrides, 3 parts of antioxidant, 3 parts of Silane coupling reagent KH-570, modified toughened dose 7 parts, 10 parts of modified filler.
Modified polyphenyl thioether is prepared by following technique：By weight by 4 parts of polyphenylene sulfides and 4 parts of 1,2- dichloroethanes
It is well mixed, then add 2 parts of chloromethyl ethers and 7 parts of anhydrous stannic chlorides are well mixed, be warming up to 65 DEG C, be incubated 35min, drawer
After be washed with distilled water to neutrality, be dried under vacuum to constant weight, it is 1.8% then to add 3 parts of tetrahydrofurans and 3 parts of mass fractions
Trimethylamine aqueous solution is well mixed, and is placed in 88 DEG C of constant temperature oscillation casees and is vibrated 11h, is then washed with distilled water to neutrality, vacuum
Dry to constant weight, cooling room temperature obtains modified polyphenyl thioether.
Modified toughened dose is prepared by following technique：By weight by 8 parts of diatomite, 8 parts of kaolin, 3 parts of precipitated sulfurs
Sour barium, 3 parts of zeolite powders, 4 parts of nano aluminium oxides, 4 parts of nano titanium oxides, 2 parts of talcum powder, 4.5 parts of powdered whitings, 3 parts receive
Rice calcium carbonate, 4 parts of asbestos fibres and 3 parts of dichloroethanes are well mixed, and ultrasonically treated 2.5h is subsequently added into 4 parts of thionyl chlorides, magnetic
Power stirs 35min, is then warming up to 82 DEG C, and flow back 28h, is cooled to 3 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, connects
And be warming up to 52 DEG C, stir 23h, then washed 3 times, after centrifugation, by solid in 42 DEG C of dry 11h, be cooled to acetone
Room temperature obtains modified toughened dose.
Modified filler is prepared by following technique：By weight by 4 parts of neopelexes and 12 parts of deionizations
Water is well mixed, and stirs 2.5min, then adds 5 parts of nano-ceramic powders, 2 parts of molybdenum disulfide, 4 parts of magnesium hydroxides, 3.5 parts of hydrogen-oxygens
Change aluminium, 5 parts of antimony trioxides and 4 parts of zinc oxide to be well mixed, stirred under ultrasonic wave, be then heated to 72 DEG C, be added dropwise 2 parts
Aluminum sulfate is well mixed, and is filtered, and washing is dried in vacuo 5.5h in 52 DEG C, is cooled to room temperature, then calcines 3h in 900 DEG C, cold
But, it is put into hydrochloric acid solution and soaks 2.5h, filtering is taken out, washing dry, pulverize, is cooled to 2.5 parts of amino first of addition after room temperature
Acid esters, 7 parts of isopropyl acrylates and 3 parts of polyparaphenylene's benzodiazole fibers are well mixed, and are warming up to 88 DEG C, are incubated 1.5h, in
820r/min rotating speeds stir 25min, are cooled to grinding distribution after room temperature and produce modified filler.
A kind of preparation method of auto manufacturing high tenacity anti-corrosion 3D printing material of the present invention, including：Will be modified poly-
Diphenyl sulfide, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, adjacent benzene two
Formic acid dioctyl ester, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, antioxidant and silane
Coupling agent kh-570 is well mixed, and is warming up to 95 DEG C, is incubated 2.5h, then stirs 35min, Ran Houjia in 1250r/min rotating speeds
Enter Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate crystal whiskers,
CNT, tossa, modified filler and modified toughened dose are well mixed, stir 2.5h in 860r/min rotating speeds, are warming up to
190 DEG C, it is incubated after 3.5h, natural cooling, auto manufacturing's high tenacity anti-corrosion 3D printing material is can be prepared by after crushing and screening.
Embodiment 5
A kind of auto manufacturing proposed by the present invention high tenacity anti-corrosion 3D printing material, its raw material includes by weight：
115 parts of modified polyphenyl thioether, 25 parts of phenolic resin, 32 parts of epoxy acrylic resin, 2 parts of amino resins, 5 parts of polyvinyl chloride, phosphorus
Sour 3 parts of trimethyl, 15 parts of trimethyl phosphate, 4 parts of dioctyl phthalate, 4 parts of Firebrake ZB, 2 parts of nano-aluminum hydroxide, glass
7 parts of microballon, 3 parts of polyphosphoric acids aluminium, 5 parts of titanium dioxide, 4 parts of glass fibre, 7 parts of carbon fiber, 3 parts of calcium sulfate crystal whiskers, CNT 3
Part, 3 parts of tossa, 4 parts of PLLA, 2.5 parts of polyadipate, 8 parts of butylene terephthalate, 4 parts of polypropylene, Malaysia
4 parts of acid anhydrides, 2 parts of antioxidant, 4 parts of Silane coupling reagent KH-570, modified toughened dose 5 parts, 17 parts of modified filler.
Modified polyphenyl thioether is prepared by following technique：By weight by 5 parts of polyphenylene sulfides and 3 parts of 1,2- dichloroethanes
It is well mixed, then add 3 parts of chloromethyl ethers and 5 parts of anhydrous stannic chlorides are well mixed, be warming up to 75 DEG C, be incubated 25min, drawer
After be washed with distilled water to neutrality, be dried under vacuum to constant weight, it is 3.2% then to add 5 parts of tetrahydrofurans and 2 parts of mass fractions
Trimethylamine aqueous solution is well mixed, and is placed in 82 DEG C of constant temperature oscillation casees and is vibrated 13h, is then washed with distilled water to neutrality, vacuum
Dry to constant weight, cooling room temperature obtains modified polyphenyl thioether.
Modified toughened dose is prepared by following technique：By weight by 12 parts of diatomite, 4 parts of kaolin, 4 parts of precipitated sulfurs
Sour barium, 2 parts of zeolite powders, 5 parts of nano aluminium oxides, 3 parts of nano titanium oxides, 3 parts of talcum powder, 3.5 parts of powdered whitings, 4 parts receive
Rice calcium carbonate, 2 parts of asbestos fibres and 5 parts of dichloroethanes are well mixed, and ultrasonically treated 1.5h is subsequently added into 5 parts of thionyl chlorides, magnetic
Power stirs 25min, is then warming up to 88 DEG C, and flow back 22h, is cooled to 7 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, connects
And be warming up to 48 DEG C, stir 25h, then washed with acetone 2 times, after centrifugation, by solid in 48 DEG C of dry 7h, be cooled to room
Temperature obtains modified toughened dose.
Modified filler is prepared by following technique：By weight by 8 parts of neopelexes and 8 parts of deionized waters
It is well mixed, 3.5min is stirred, 3 parts of nano-ceramic powders, 3 parts of molybdenum disulfide, 3 parts of magnesium hydroxides, 4.5 parts of hydroxides are then added
Aluminium, 3 parts of antimony trioxides and 5 parts of zinc oxide are well mixed, and are stirred under ultrasonic wave, are then heated to 68 DEG C, 3 parts of sulphur are added dropwise
Sour aluminium is well mixed, and is filtered, and washing is dried in vacuo 6.5h in 48 DEG C, is cooled to room temperature, then in 840 DEG C of calcining 4h, cooling,
It is put into hydrochloric acid solution and soaks 1.5h, filtering is taken out, washing dry, pulverize, is cooled to 4.5 parts of carbamic acids of addition after room temperature
Ester, 4 parts of isopropyl acrylates and 8 parts of polyparaphenylene's benzodiazole fibers are well mixed, and are warming up to 82 DEG C, are incubated 2.5h, in
680r/min rotating speeds stir 25min, are cooled to grinding distribution after room temperature and produce modified filler.
A kind of preparation method of auto manufacturing high tenacity anti-corrosion 3D printing material of the present invention, including：Will be modified poly-
Diphenyl sulfide, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride, trimethyl phosphate, trimethyl phosphate, adjacent benzene two
Formic acid dioctyl ester, PLLA, polyadipate, butylene terephthalate, polypropylene, maleic anhydride, antioxidant and silane
Coupling agent kh-570 is well mixed, and is warming up to 115 DEG C, is incubated 1.5h, then stirs 25min, Ran Houjia in 1350r/min rotating speeds
Enter Firebrake ZB, nano-aluminum hydroxide, glass microballoon, polyphosphoric acids aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate crystal whiskers,
CNT, tossa, modified filler and modified toughened dose are well mixed, stir 1.5h in 970r/min rotating speeds, are warming up to
210 DEG C, it is incubated after 2.5h, natural cooling, auto manufacturing's high tenacity anti-corrosion 3D printing material is can be prepared by after crushing and screening.
Auto manufacturing in embodiment 1-5 is produced with high tenacity anti-corrosion 3D printing material application to actual 3D printing
In, the performance of resulting product is detected, obtained data are as shown in table 1.
Table 1：
As shown in Table 1, the high tenacity anti-corrosion 3D printing material of the auto manufacturing in embodiment 1- embodiments 5 has excellent
Toughness and antiseptic property.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (9)
1. a kind of auto manufacturing high tenacity anti-corrosion 3D printing material, it is characterised in that its raw material includes by weight：It is modified
80-120 parts of polyphenylene sulfide, 20-40 parts of phenolic resin, 15-35 parts of epoxy acrylic resin, 1-5 parts of amino resins, polyvinyl chloride
2-6 parts, 2-8 parts of trimethyl phosphate, 8-16 parts of trimethyl phosphate, 3-9 parts of dioctyl phthalate, 1-5 parts of Firebrake ZB, nanometer
1-5 parts of aluminium hydroxide, 4-8 parts of glass microballoon, 2-6 parts of polyphosphoric acids aluminium, 1-6 parts of titanium dioxide, 3-6 parts of glass fibre, carbon fiber
4-8 parts, 2-5 parts of calcium sulfate crystal whiskers, 1-4 parts of CNT, 2-8 parts of tossa, 1-5 parts of PLLA, polyadipate 2-4
Part, 3-9 parts of butylene terephthalate, 3-6 parts of polypropylene, 2-5 parts of maleic anhydride, 1-4 parts of antioxidant, silane coupler KH-
570 2-5 parts, modified toughened dose 4-8 parts, 9-18 parts of modified filler.
2. auto manufacturing according to claim 1 high tenacity anti-corrosion 3D printing material, it is characterised in that modified polyphenyl
Thioether is prepared by following technique：By polyphenylene sulfide and 1,2- dichloroethanes is well mixed, and then adds chloromethyl ether and anhydrous
Butter of tin is well mixed, and is warming up to 60-80 DEG C, and neutrality is washed with distilled water to after being incubated 20-40min, drawer, is dried in vacuo
To constant weight, then add tetrahydrofuran and trimethylamine aqueous solution is well mixed, be placed in 80-90 DEG C of constant temperature oscillation case and vibrate 10-
14h, is then washed with distilled water to neutrality, is dried under vacuum to constant weight, and cooling room temperature obtains modified polyphenyl thioether.
3. auto manufacturing according to claim 1 or 2 high tenacity anti-corrosion 3D printing material, it is characterised in that modified
In the preparation technology of polyphenylene sulfide, polyphenylene sulfide, 1,2- dichloroethanes, chloromethyl ether, anhydrous stannic chloride, tetrahydrofuran and front three
The weight ratio of amine aqueous solution is 3-6：2-5：1-4：4-8：2-6：1-4.
4. auto manufacturing's high tenacity anti-corrosion 3D printing material according to claim any one of 1-3, it is characterised in that
In the preparation technology of modified polyphenyl thioether, the mass fraction of trimethylamine aqueous solution is 1.5-3.5%.
5. auto manufacturing's high tenacity anti-corrosion 3D printing material according to claim any one of 1-4, it is characterised in that
Modified toughened dose of raw material includes by weight：5-15 parts of diatomite, 3-9 parts of kaolin, 2-5 parts of blanc fixe, zeolite powder
1-4 parts, 3-6 parts of nano aluminium oxide, 2-5 parts of nano titanium oxide, 1-4 parts of talcum powder, 3-5 parts of powdered whiting, nano-calcium carbonate
2-5 parts of calcium, 1-5 parts of asbestos fibre, 2-6 parts of dichloroethanes, 3-6 parts of thionyl chloride, 2-8 parts of 2- propylene -1- alcohol.
6. auto manufacturing's high tenacity anti-corrosion 3D printing material according to claim any one of 1-5, it is characterised in that
Modified toughened dose is prepared by following technique：By diatomite, kaolin, blanc fixe, zeolite powder, nano aluminium oxide, receive
Rice titanium dioxide, talcum powder, powdered whiting, nano-calcium carbonate, asbestos fibre and dichloroethanes are well mixed, ultrasonically treated 1-
3h, is subsequently added into thionyl chloride, and magnetic agitation 20-40min is then warming up to 80-90 DEG C, and flow back 20-30h, is cooled to room temperature
2- propylene -1- alcohol is added afterwards to be well mixed, and is then warming up to 45-55 DEG C, is stirred 22-26h, then washed 1-4 times with acetone, from
After heart separation, by solid in 40-50 DEG C of dry 6-12h, it is cooled to room temperature and obtains modified toughened dose.
7. auto manufacturing's high tenacity anti-corrosion 3D printing material according to claim any one of 1-6, it is characterised in that
The raw material of modified filler includes by weight：3-9 parts of neopelex, 5-15 parts of deionized water, nano-ceramic powder 2-6
Part, 1-4 parts of molybdenum disulfide, 2-5 parts of magnesium hydroxide, 3-5 parts of aluminium hydroxide, 2-6 parts of antimony trioxide, 3-6 parts of zinc oxide, aluminum sulfate
1-4 parts, 2-5 parts of carbamate, 3-8 parts of isopropyl acrylate, 2-9 parts of polyparaphenylene's benzodiazole fiber.
8. auto manufacturing's high tenacity anti-corrosion 3D printing material according to claim any one of 1-7, it is characterised in that
Modified filler is prepared by following technique：Neopelex and deionized water are well mixed, 2-4min is stirred, so
Nano-ceramic powder, molybdenum disulfide, magnesium hydroxide, aluminium hydroxide, antimony trioxide and zinc oxide are added afterwards well mixed, in ultrasonic wave
Under stir, be then heated to 65-75 DEG C, aluminum sulfate be added dropwise and is well mixed, filters, washing is dried in vacuo 5- in 45-55 DEG C
7h, is cooled to room temperature, and 2-5h is then calcined in 820-920 DEG C, and cooling is put into hydrochloric acid solution and soaks 1-3h, and filtering is taken out, and is washed
Wash, dry, pulverize, be cooled to addition carbamate, isopropyl acrylate and polyparaphenylene's benzodiazole fiber after room temperature mixed
Close uniform, be warming up to 80-90 DEG C, be incubated 1-3h, 20-40min is stirred in 650-850r/min rotating speeds, be cooled to after room temperature and grind
It is scattered to produce modified filler.
9. a kind of preparation side of high tenacity anti-corrosion 3D printing material of auto manufacturing according to claim any one of 1-8
Method, it is characterised in that including：By modified polyphenyl thioether, phenolic resin, epoxy acrylic resin, amino resins, polyvinyl chloride,
Trimethyl phosphate, trimethyl phosphate, dioctyl phthalate, PLLA, polyadipate, butylene terephthalate,
Polypropylene, maleic anhydride, antioxidant and Silane coupling reagent KH-570 are well mixed, are warming up to 90-120 DEG C, are incubated 1-3h, then
20-40min is stirred in 1200-1400r/min rotating speeds, Firebrake ZB, nano-aluminum hydroxide, glass microballoon, poly phosphorus is then added
Sour aluminium, titanium dioxide, glass fibre, carbon fiber, calcium sulfate crystal whiskers, CNT, tossa, modified filler and modified toughened dose
It is well mixed, 1-3h is stirred in 850-980r/min rotating speeds, 180-220 DEG C is warming up to, is incubated after 2-4h, natural cooling, is crushed
Auto manufacturing's high tenacity anti-corrosion 3D printing material is can be prepared by after screening.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107603162A (en) * | 2017-09-14 | 2018-01-19 | 芜湖林电子科技有限公司 | A kind of high-intensity high-tenacity 3D printing material for building |
| CN107698973A (en) * | 2017-09-14 | 2018-02-16 | 芜湖林电子科技有限公司 | A kind of heat-resisting 3D printing material of automobile high-strength |
| CN108059827A (en) * | 2017-11-26 | 2018-05-22 | 天长市荣盛有机硅科技有限公司 | A kind of high-intensity and high-tenacity modified silicon rubber material |
| CN108328923A (en) * | 2018-01-31 | 2018-07-27 | 和县晶晶玻璃制品有限公司 | A kind of corrosion-resistant tempered glass of high stability |
| CN109852056A (en) * | 2018-12-28 | 2019-06-07 | 上海锦湖日丽塑料有限公司 | A kind of carbon fiber enhancing polyphenylene sulfide composition of abrasion resistant fire blocking and preparation method thereof |
| CN110819166A (en) * | 2019-11-25 | 2020-02-21 | 武汉绿之美铸造材料有限公司 | Enhanced special ink for 3D printing |
| US10808438B2 (en) | 2016-04-15 | 2020-10-20 | Larson Manufacturing Company Of South Dakota, Inc. | Door assembly for selectively interlocking opposing doors |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105504813A (en) * | 2015-12-25 | 2016-04-20 | 成都新柯力化工科技有限公司 | Spherical polyphenylene sulfide powdery material for 3D printing and preparation method of spherical polyphenylene sulfide powdery material |
-
2017
- 2017-06-19 CN CN201710463191.9A patent/CN107141798A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105504813A (en) * | 2015-12-25 | 2016-04-20 | 成都新柯力化工科技有限公司 | Spherical polyphenylene sulfide powdery material for 3D printing and preparation method of spherical polyphenylene sulfide powdery material |
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| US10808438B2 (en) | 2016-04-15 | 2020-10-20 | Larson Manufacturing Company Of South Dakota, Inc. | Door assembly for selectively interlocking opposing doors |
| US11542733B2 (en) | 2016-04-15 | 2023-01-03 | Larson Manufacturing Company Of South Dakota, Llc | Door assembly for selectively interlocking opposing doors |
| CN107603162A (en) * | 2017-09-14 | 2018-01-19 | 芜湖林电子科技有限公司 | A kind of high-intensity high-tenacity 3D printing material for building |
| CN107698973A (en) * | 2017-09-14 | 2018-02-16 | 芜湖林电子科技有限公司 | A kind of heat-resisting 3D printing material of automobile high-strength |
| CN108059827A (en) * | 2017-11-26 | 2018-05-22 | 天长市荣盛有机硅科技有限公司 | A kind of high-intensity and high-tenacity modified silicon rubber material |
| CN108328923A (en) * | 2018-01-31 | 2018-07-27 | 和县晶晶玻璃制品有限公司 | A kind of corrosion-resistant tempered glass of high stability |
| CN109852056A (en) * | 2018-12-28 | 2019-06-07 | 上海锦湖日丽塑料有限公司 | A kind of carbon fiber enhancing polyphenylene sulfide composition of abrasion resistant fire blocking and preparation method thereof |
| CN109852056B (en) * | 2018-12-28 | 2021-09-07 | 上海锦湖日丽塑料有限公司 | Wear-resistant flame-retardant carbon fiber reinforced polyphenylene sulfide composition and preparation method thereof |
| CN112226081A (en) * | 2019-07-15 | 2021-01-15 | 中国石油化工股份有限公司 | Laser-sensitized resin composition, and preparation method and application thereof |
| CN112226081B (en) * | 2019-07-15 | 2023-05-02 | 中国石油化工股份有限公司 | Laser sensitization resin composition, preparation method and application thereof |
| CN110819166A (en) * | 2019-11-25 | 2020-02-21 | 武汉绿之美铸造材料有限公司 | Enhanced special ink for 3D printing |
| US11661521B2 (en) | 2019-12-17 | 2023-05-30 | Ticona Llc | Three-dimensional printing system employing a thermotropic liquid crystalline polymer |
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