CN107141537A - Rubber composition for standard testing tire tread - Google Patents

Rubber composition for standard testing tire tread Download PDF

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Publication number
CN107141537A
CN107141537A CN201710543207.7A CN201710543207A CN107141537A CN 107141537 A CN107141537 A CN 107141537A CN 201710543207 A CN201710543207 A CN 201710543207A CN 107141537 A CN107141537 A CN 107141537A
Authority
CN
China
Prior art keywords
parts
weight
rubber
tire tread
standard testing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710543207.7A
Other languages
Chinese (zh)
Inventor
焦文秀
孙希华
丁全勇
韩玉瑶
周宇
邓世涛
李居龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Triangle Tyre Co Ltd
Original Assignee
Triangle Tyre Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Triangle Tyre Co Ltd filed Critical Triangle Tyre Co Ltd
Priority to CN201710543207.7A priority Critical patent/CN107141537A/en
Publication of CN107141537A publication Critical patent/CN107141537A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/80Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86Optimisation of rolling resistance, e.g. weight reduction 

Abstract

The present invention relates to field of rubber technology, specifically a kind of rubber composition for standard testing tire tread, it is characterised in that:Include the butadiene rubber of 5 15 parts by weight, the natural rubber of 5 25 parts by weight and 60 90 parts by weight butadiene-styrene rubber, coordinate 50 75 parts by weight of carbon black per, 10 30 parts by weight filling oil and 1.5 2.5 parts by weight sulphur, and tyre industry often to use the rubber chemicals of parts by weight.This invention ensures that the reliability of the mechanical property such as the tensile strength of sizing material, stress at definite elongation, there is the tire prepared simultaneously scientific and effective snowfield to grasp the effect of Performance Evaluation, it can be used for other assessments, such as wear hardness, the resistive energy of rolling, pavement friction characteristic, noise, the rubber composition at tire tread position is tested for 195/75R14 TE305 specification standards.

Description

Rubber composition for standard testing tire tread
Technical field
It is a kind of rubber group for standard testing tire tread position the present invention relates to a kind of rubber for tire technical field The rubber composition at compound, specifically 195/75R14 TE305 specification standards test tire tread position.
Background technology
It is well known that ISO and international metering vocabulary are to " standard substance(Reference material)" give and define:" have one Kind or it is a variety of enough the uniform characteristic determined well, to calibrating measuring device, evaluate measuring method or give material assign A kind of material or material of value ", standard testing tire is the standard substance in tyre industry, and it serves primarily in tyre performance survey Examination and the implementation and application of grade scale, are the necessary conditions of the uniformity and comparativity that ensure measurement result.
In the world, the outdoor test of tire, such as wetland and snowfield grasp performance test, are carried out using standard testing tire Method of comparison, i.e., the standard testing tire for stablizing, meeting specification using one group of performance is used as normative reference, the same standard testing of other tires Tire carries out the contrast test with the conditions of on the road surface of standardization.Its performance index is tested for test tire with standard tire The ratio of data.
At present, the standard testing tire used in the world is that company of Michelin produces without competition.And sought unity of standard according to it, by There is provided used to global each Tire testing company after its plant produced specified.Cause standard testing tire procurement cycle length, Price is high, seriously constrains the progress of China's Tire testing and certification work.
To break trade monopoly, preferably promote the development of China's tyre industry, according to the market demand, China has carried out mark The R&D work of quasi- test tire, has filled up the blank of tyre industry.Standard tire has the class tire of C1, C2 and C3 tri-.Wherein C1 class tires have 225/60R16 TC105 and 195/75R14 TE305.
Tyre crown position is directly contacted with ground, therefore, and the performance of tyre surface formula grasps performance to the snowfield of tire and risen To crucial effect.Tyre surface formula is adjusted, the snowfield that can effectively adjust tire grasps index.
The content of the invention
The purpose of the present invention is exactly that there is provided a kind of 195/75R14 TE305 specification marks in order to overcome existing technical deficiency There is the rubber composition at quasi- test tire tread position, the tire of preparation scientific and effective snowfield to grasp the work of Performance Evaluation With, it can be used for other and assess, such as wear hardness, the resistive energy of rolling, pavement friction characteristic, noise.
The present invention solve above-mentioned technical problem use technical scheme be:A kind of rubber for standard testing tire tread Composition, it is characterised in that:Include the butadiene rubber of 5-15 parts by weight, the natural rubber and 60-90 parts by weight of 5-25 parts by weight Butadiene-styrene rubber, coordinates 50-75 parts by weight of carbon black per, 10-30 parts by weight filling oil and 1.5-2.5 parts by weight sulphur, and tire row Industry often uses the rubber chemicals of parts by weight.
Preferably, the natural rubber is to mark glue from Thailand 20#, it is 5-20 parts by weight.
Preferably, the butadiene-styrene rubber is emulsion polymerized styrene butadiene rubber, it is 60-85 parts by weight.
Preferably, the carbon black is selects N375, it is 50-70 parts by weight.
Preferably, the filling oil is RAE oil, it is 15-30 parts by weight.
The beneficial effects of the invention are as follows, it is ensured that the reliability of the mechanical property such as tensile strength, stress at definite elongation of sizing material, together When the effect that there is scientific and effective snowfield to grasp Performance Evaluation of the tire for preparing, can be used for other assessments, such as abrasivity , resistive energy, pavement friction characteristic, noise etc. can be rolled, tire tread position is tested for 195/75R14 TE305 specification standards Rubber composition.
Embodiment
With reference to embodiment, the present invention will be further described:
It can be prepared according to existing conventional techniques using raw material components of the present invention, content and tire production process, specifically Step is as follows:
One section of milling maternal rubber:Natural gum is added in banbury GK400, oil removing, sulphur, the accelerator such as carbon black, age resistor is added Outside raw material, press bolt 30s, plus environment protection oil presses bolt 30s, and bolt, pressure bolt to 155 DEG C of dumpings are carried again.
Two sections of milling maternal rubbers:One section of rubber master batch is added, pressure bolt keeps 30s, carries and press bolt 30s after bolt again, carries and presses bolt extremely after bolt 155 DEG C of dumpings.
Finished composition is kneaded:Two-stage mixing glue, sulphur and accelerator are added, pressure bolt keeps 30s, carries and bolt is pressed after bolt to 105 DEG C Dumping.
In order to verify the reliability of effect of the present invention, with reference to comparative example, the present invention is described in detail, but this hair It is bright to be not limited to these embodiments.Cooperation table and physical and mechanical properties test result are shown in Table one, table two.
As can be seen from Table II, embodiment is compared with comparative example, and tensile strength stills remain in 20.0Mpa or so, 100% Stress at definite elongation is maintained at 3Mpa, and 300% stress at definite elongation reaches 13.9MPa, and hardness is maintained at 65 degree or so, and tearing strength is 54 KN/m.Show the good mechanical properties of sizing material of the present invention.
According to the method for real train test, the test that snowfield grasps index is carried out to finished product tire.By taking embodiment 2 as an example, trial-production Four composition product tires, every group of 4 tires, test data is as shown in Table 3.The snowfield of four groups of tires grasp index be respectively 1.01, 1.03rd, 1.02,1.03, illustrate that tyre performance is stable, the standard testing tire grasps performance with the snowfield to other tires and entered The effect that row is assessed.
Based on above test result, the tire of embodiment of the present invention can be very good to play as standard testing tire It is acted on.
Table one:Inventive composition coordinates table(Each material content unit is in this table:Parts by weight)
Composition no Comparative example 1 Comparative example 2 Embodiment 1 Embodiment 2 Embodiment 3
Butadiene rubber 25 20 5 10 15
Natural rubber 30 30 20 10 5
ESBR 45 50 75 80 80
Carbon black 45 45 55 60 70
Environment protection oil 35 35 30 25 15
Antioxidant 4020 1 1 1 1 1
Anti-aging agent RD 0.5 0.5 0.5 0.5 0.5
Vulcanizing agent 2.0 2.0 2.0 2.0 2.0
Accelerator 1.5 1.5 1.5 1.5 1.5
Table two:Composition physical property table
150℃*30min Comparative example 1 Comparative example 2 Embodiment 1 Embodiment 2 Embodiment 3
Shao Er A type hardness testers/degree 64 62 64 65 65
Tensile strength/Mpa 21.6 20.4 20.1 20.1 20.3
Elongation at break/% 427 405 394 382 375
100% stress at definite elongation/Mpa 2.8 2.7 3.1 3.0 3.0
300% stress at definite elongation/Mpa 13.6 13.5 13.5 13.9 14.1
Tearing strength/(KN/m) 59 57 58 54 53
Table three:Tire snowfield grasps index test result table

Claims (5)

1. a kind of rubber composition for standard testing tire tread, it is characterised in that:Suitable fourth rubber including 5-15 parts by weight Glue, the natural rubber and 60-90 parts by weight butadiene-styrene rubber of 5-25 parts by weight coordinate 50-75 parts by weight of carbon black per, 10-30 parts by weight Filling oil and 1.5-2.5 parts by weight sulphur, and tyre industry often use the rubber chemicals of parts by weight.
2. it is used for the rubber composition of standard testing tire tread according to claim 1, it is characterised in that described is natural Rubber is to mark glue from Thailand 20#, is 5-20 parts by weight.
3. it is used for the rubber composition of standard testing tire tread according to claim 1, it is characterised in that described butylbenzene Rubber is emulsion polymerized styrene butadiene rubber, is 60-85 parts by weight.
4. it is used for the rubber composition of standard testing tire tread according to claim 1, it is characterised in that described carbon black It is 50-70 parts by weight to select N375.
5. it is used for the rubber composition of standard testing tire tread according to claim 1, it is characterised in that described filling Oil is RAE oil, is 15-30 parts by weight.
CN201710543207.7A 2017-07-05 2017-07-05 Rubber composition for standard testing tire tread Pending CN107141537A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710543207.7A CN107141537A (en) 2017-07-05 2017-07-05 Rubber composition for standard testing tire tread

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710543207.7A CN107141537A (en) 2017-07-05 2017-07-05 Rubber composition for standard testing tire tread

Publications (1)

Publication Number Publication Date
CN107141537A true CN107141537A (en) 2017-09-08

Family

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CN201710543207.7A Pending CN107141537A (en) 2017-07-05 2017-07-05 Rubber composition for standard testing tire tread

Country Status (1)

Country Link
CN (1) CN107141537A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112646241A (en) * 2020-12-18 2021-04-13 正新橡胶(中国)有限公司 Standard sample preparation method for rubber viscosity test and rubber sample test method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104086836A (en) * 2014-07-14 2014-10-08 宁国市日格美橡塑制品有限公司 Wear-resisting rubber material for tires
CN104650416A (en) * 2013-11-19 2015-05-27 青岛欧美亚橡胶工业有限公司 Truck tire tread base rubber
CN104672528A (en) * 2013-11-28 2015-06-03 招远市东晟橡胶制品有限公司 Carbon-black-containing rubber tire
CN105037824A (en) * 2015-07-23 2015-11-11 杭州朝阳橡胶有限公司 Tread rubber composition of all-steel truck snow tire

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104650416A (en) * 2013-11-19 2015-05-27 青岛欧美亚橡胶工业有限公司 Truck tire tread base rubber
CN104672528A (en) * 2013-11-28 2015-06-03 招远市东晟橡胶制品有限公司 Carbon-black-containing rubber tire
CN104086836A (en) * 2014-07-14 2014-10-08 宁国市日格美橡塑制品有限公司 Wear-resisting rubber material for tires
CN105037824A (en) * 2015-07-23 2015-11-11 杭州朝阳橡胶有限公司 Tread rubber composition of all-steel truck snow tire

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112646241A (en) * 2020-12-18 2021-04-13 正新橡胶(中国)有限公司 Standard sample preparation method for rubber viscosity test and rubber sample test method
CN112646241B (en) * 2020-12-18 2022-09-13 正新橡胶(中国)有限公司 Standard sample preparation method for rubber viscosity test and rubber sample test method

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Application publication date: 20170908

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