CN107140916A - A kind of low-cost environmental-protecting mortar - Google Patents

A kind of low-cost environmental-protecting mortar Download PDF

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Publication number
CN107140916A
CN107140916A CN201710490171.0A CN201710490171A CN107140916A CN 107140916 A CN107140916 A CN 107140916A CN 201710490171 A CN201710490171 A CN 201710490171A CN 107140916 A CN107140916 A CN 107140916A
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parts
mortar
low
sand
water
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CN201710490171.0A
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CN107140916B (en
Inventor
程旺生
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Guangzhou Yingde Construction Engineering Co ltd
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Hunan Seven Weft Technology Co Ltd
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • C04B18/144Slags from the production of specific metals other than iron or of specific alloys, e.g. ferrochrome slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention belongs to building material technical field, a kind of low-cost environmental-protecting mortar is disclosed.The mortar is made up of the raw material of following parts by weight:150 230 parts of Portland cement, 30 80 parts of zeolite powder, 500 700 parts of ferronickel slag sand, 700 1000 parts of river sand, 0.2 0.5 parts of water-retaining admixture, 0.5 2 parts of slow setting early strength agent, 10 0.15 0.3 parts of polyoxyethylene nonylphenol ether.Mortar workability of the present invention is good, it is easy to extrude mix, and plumpness is high.Industrial solid castoff ferronickel slag can largely be utilized, you can help, which is dissolved, handles ferronickel slag, reduces environmental pollution, the problem of also solving the problem that natural sand shortage of resources is killed two birds with one stone.

Description

A kind of low-cost environmental-protecting mortar
Technical field
The invention belongs to building material technical field, and in particular to a kind of low-cost environmental-protecting mortar.
Background technology
Mortar refers to inorganic coagulation material, fine aggregate, admixture, water, and the other components determined according to performance are pressed The architecture engineering material of proper proportion cooperation, mixing and hardened formation, main serve bonds, pads and transmitted stress etc.. Mortar is a kind of functional material, and an entirety is generally collectively formed with matrix, and such as masonry mortar is to glue building block, brick bulk Become an entirety, common bearing load;For another example motar, is applied to building substrate surface, except obtaining smooth table Outside face, the effect of protection basic unit is also acted as.Therefore, in addition to requiring mortar and there is certain intensity, also require mortar have compared with Good water-retaining property, crack resistance etc., the additive of increase water retentivity of mortar is most for cellulose ethers product at present, such The problem of there is high price, influence mortar strength in product.In addition with the continuous increase of current construction scale, many places face The situation of natural sand scarcity of resources, and because river sand exploitation does great damage to riverbed and surrounding natural environment, part river Quicksand resource is prevented or restricted from exploitation, river sand resource worsening shortages.
The content of the invention
The present invention is in view of the above-mentioned problems, provide a kind of low-cost environmental-protecting mortar, and the mortar is replaced using part industrial residue River sand resource, and cellulose ethers is replaced with the relatively low lignocellulosic of price, reaching reduces cost, saves the mesh of natural resources 's.To reach above-mentioned purpose, the present invention is adopted the following technical scheme that.
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:150-230 parts of Portland cement, 30-80 parts of zeolite powder, 500-700 parts of ferronickel slag sand, 700-1000 parts of river sand, 0.2-0.5 parts of water-retaining admixture, slow setting early strength agent 0.5-2 parts, 0.15-0.3 parts of emulsifier op-10.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is made up of lignin fibre, cellulose ether and xanthans.
It is preferred that, the cellulose ether is carboxymethyl SE-cellulose ether or ethoxyl methyl cellulose ether.
It is preferred that, the lignin fibre is to pass through the organic fiber that chemical treatment is obtained by straw.
It is furthermore preferred that the water-retaining admixture presses weight by lignin fibre, carboxymethyl SE-cellulose ether and xanthans Amount compares 1-3:1-2:1 composition.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 1-9:1-3:1 composition.
Zeolite powder of the present invention is that natural zeolite is obtained after grinding, is one kind with SiO2And Al2O3Based on day Right mineral, can be with Ca (OH)2The a series of hydrated product of reaction generation, with good pozzolanic activity.Due to ferronickel slag Formation temperature is higher, has certain hydration reaction activity under high alkali environment, there is the risk of certain alkali-aggregate reaction, Zeolite powder has excellent suppression alkali-aggregate reaction performance, can effectively suppress the generation of alkali-aggregate reaction.In addition, zeolite powder Construct opening big, there is many uniform cavities and ducts, in the energy adsorption moisture in mortar whipping process, reduction mortar Bleeding, improves the water-retaining property of mortar.Ferronickel slag sand is different with the grain type of river sand, and the present invention replaces river using part of nickel scum sand Sand, can play improvement plaster workability, improve the effect of mortar strength.Ferronickel slag sand is different with the water absorption rate of natural river sand, Particle of the particle diameter less than 0.075mm contains substantial amounts of clay, organic matter etc. in river sand, and water requirement is larger, and these materials influence The development of intensity.Broken ferronickel slag sand surface is relatively smooth, densification, and water absorption is small, can increase mortar mobility and denseness;River The rounder and more smooth smoothness of sand profile, and ferronickel slag sand is formed by Mechanical Crushing, with certain angular structures, makes to have between aggregate The mechanical engagement of effect, is conducive to increasing the compression strength of mortar;Sand contains the mineral such as tricalcium silicate, dicalcium silicate in ferronickel slag, With certain hydration reaction activity, the interfacial structure of binder materials and ferronickel slag sand can be improved, adhesion strength is improved;Cellulose Effect of the ethers additive to mortar adhesiveness and adhesion strength is the most obvious, and mortar becomes viscous after incorporation, and adhesiveness improves, and glues Knotting strength is improved, but compression strength is substantially reduced, and cost is higher.Lignin fibre is the three dimensional network with obvious cross-linked effect Shape structure, with preferable water imbibition, fiber reinforcement and thickening effect, can improve the workability and cracking resistance of mortar Performance, is used in conjunction with cellulose ether, it is possible to reduce the consumption of cellulose ether, improves mortar strength.Cellulose ether and lignin Fiber acts synergistically, and reaches water conservation, thickening, enhancing, the optimum efficiency of cracking resistance;Calcium saccharate has good delay to cement in itself Solidifying effect, with sodium sulphate and dimethylethanolamine it is compound after, can increase substantially the early strength of mortar, later strength also have compared with It is big to improve, overcome the problem of later strength is reduced after exclusive use sodium sulphate.In addition, calcium saccharate is a kind of surfactant, It has good peptizaiton to cement granules, therefore can increase the workability and mobility of mortar, with certain diminishing Effect.Emulsifier op-10 can improve the emulsibility and foaming effect of mortar, improve the plumpness of mortar and use volume.
Two aspect below beneficial effects of the present invention major embodiment:
(1) mortar workability of the present invention is good, it is easy to extrude mix, and plumpness and adhesion strength are high, the adhesiveness with masonry Can be good.
(2) present invention is a large amount of utilizes industrial solid castoff ferronickel slag, you can help, which is dissolved, handles ferronickel slag, reduces environment Pollution, the problem of also solving the problem that natural sand shortage of resources is killed two birds with one stone.
Embodiment
With reference to embodiment, the present invention will be described, it will be appreciated that embodiment described herein be merely to illustrate and The present invention is explained, is not intended to limit the present invention.
Embodiment 1
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:150 parts of Portland cement, zeolite 80 parts of powder, 500 parts of ferronickel slag sand, 1000 parts of river sand, 0.2 part of water-retaining admixture, 0.5 part of slow setting early strength agent, emulsifier op-10 0.15 part.
The water-retaining admixture is made up of lignin fibre, cellulose ethers and xanthans.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 1:3:1 composition.
Embodiment 2
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:230 parts of Portland cement, zeolite 30 parts of powder, 700 parts of ferronickel slag sand, 700 parts of river sand, 0.5 part of water-retaining admixture, 2 parts of slow setting early strength agent, emulsifier op-10 0.3 Part.
The water-retaining admixture is made up of lignin fibre, cellulose ethers and xanthans, and lignin fibre is by plant Stalk passes through the organic fiber that chemical treatment is obtained.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 9:1:1 composition.
Embodiment 3
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:200 parts of Portland cement, zeolite 60 parts of powder, 600 parts of ferronickel slag sand, 900 parts of river sand, 0.3 part of water-retaining admixture, 1 part of slow setting early strength agent, emulsifier op-10 0.2 Part.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin fibre, carboxymethyl SE-cellulose ether and xanthans by weight 2:1:1 Composition.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 8:2:1 composition.
Embodiment 4
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:190 parts of Portland cement, zeolite 70 parts of powder, 550 parts of ferronickel slag sand, 950 parts of river sand, 0.4 part of water-retaining admixture, 1.5 parts of slow setting early strength agent, emulsifier op-10 0.21 part.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin fibre, ethoxyl methyl cellulose ether and xanthans by weight 1:2:1 group Into lignin fibre therein is to pass through the organic fiber that chemical treatment is obtained by straw.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 6:2:1 composition.
Embodiment 5
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:220 parts of Portland cement, zeolite 40 parts of powder, 650 parts of ferronickel slag sand, 850 parts of river sand, 0.45 part of water-retaining admixture, 1.2 parts of slow setting early strength agent, emulsifier op-10 0.25 part.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin, carboxymethyl SE-cellulose ether and xanthans by weight 3:1:1 composition.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 5:1:1 composition.
Comparative example 1
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:200 parts of Portland cement, zeolite 60 parts of powder, 1500 parts of river sand, 0.3 part of water-retaining admixture, 1 part of slow setting early strength agent, 0.2 part of emulsifier op-10.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin fibre, carboxymethyl SE-cellulose ether and xanthans by weight 2:1:1 Composition.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 8:2:1 composition.
Comparative example 2
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:260 parts of Portland cement, ferronickel 600 parts of slag sand, 900 parts of river sand, 0.3 part of water-retaining admixture, 1 part of slow setting early strength agent, 0.2 part of emulsifier op-10.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin fibre, carboxymethyl SE-cellulose ether and xanthans by weight 2:1:1 Composition.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 8:2:1 composition.
Comparative example 3
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:200 parts of Portland cement, zeolite 60 parts of powder, 600 parts of ferronickel slag sand, 900 parts of river sand, 0.3 part of hydroxypropyl methyl cellulose, 1 part of slow setting early strength agent, polyoxyethylene nonylphenol ether- 10 0.2 parts.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The slow setting early strength agent is by sodium sulphate, calcium saccharate and dimethylethanolamine by weight 8:2:1 composition.
Comparative example 4
A kind of low-cost environmental-protecting mortar, is made up of the raw material of following parts by weight:200 parts of Portland cement, zeolite 60 parts of powder, 600 parts of ferronickel slag sand, 900 parts of river sand, 0.3 part of water-retaining admixture, 0.2 part of emulsifier op-10.
The zeolite powder is milled to 45um by natural zeolite powder and tailed over to be obtained less than 12%.
The ferronickel slag sand is that the waste residue produced in smelting ferronickel alloy process is crushed to sand grains footpath and obtained less than 4.75mm Arrive.
The water-retaining admixture is by lignin fibre, carboxymethyl SE-cellulose ether and xanthans by weight 2:1:1 Composition.
Performance test
According to JGJ/T 70-2009《Building mortar basic performance tests method standard》It is strong that defined method carries out mortar Degree, denseness, delamination degree, the test of tensile bond strength;According to GB/T 14684-2011《Building sand》In quick alkali-silicon Acid reaction method of testing carries out expansion rate test.As a result it see the table below 1.
The mortar performance test result of table 1

Claims (6)

1. a kind of low-cost environmental-protecting mortar, it is characterised in that be made up of the raw material of following parts by weight:Portland cement 150-230 parts, 30-80 parts of zeolite powder, 500-700 parts of ferronickel slag sand, 700-1000 parts of river sand, 0.2-0.5 parts of water-retaining admixture, 0.5-2 parts of slow setting early strength agent, 0.15-0.3 parts of emulsifier op-10.
2. low-cost environmental-protecting mortar according to claim 1, it is characterised in that the water-retaining admixture is fine by lignin Dimension, cellulose ether and xanthans composition.
3. low-cost environmental-protecting mortar according to claim 2, it is characterised in that the cellulose ether is carboxymethyl sulfoethyl Cellulose ether or ethoxyl methyl cellulose ether.
4. low-cost environmental-protecting mortar according to claim 2, it is characterised in that the lignin fibre is by straw The organic fiber obtained by chemical treatment.
5. low-cost environmental-protecting mortar according to claim 2, it is characterised in that the water-retaining admixture is fine by lignin Dimension, carboxymethyl SE-cellulose ether and xanthans are by weight 1-3:1-2:1 composition.
6. low-cost environmental-protecting mortar according to claim 1, it is characterised in that the slow setting early strength agent is by sodium sulphate, sugarcane Be saccharified calcium and dimethylethanolamine 1-9 by weight:1-3:1 composition.
CN201710490171.0A 2017-06-25 2017-06-25 A kind of low-cost environmental-protecting mortar Active CN107140916B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915449A (en) * 2017-12-14 2018-04-17 盐城工学院 A kind of dry-mixed masonry mortar and preparation method thereof
CN110028943A (en) * 2019-03-27 2019-07-19 深圳地球村环保产业有限公司 A kind of preparation method of the compound water shutoff agent of saline-alkali tolerant
CN111362654A (en) * 2020-03-19 2020-07-03 河南锦亿建材有限公司 Dry-mixed mortar for stair treads and preparation method thereof
CN111566070A (en) * 2018-01-10 2020-08-21 三井住友建设株式会社 Mortar and preparation method thereof

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CN103626440A (en) * 2013-12-04 2014-03-12 桂林理工大学 Dry-mixed mortar prepared from hot furnace slag and preparation method of dry-mixed mortar

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915449A (en) * 2017-12-14 2018-04-17 盐城工学院 A kind of dry-mixed masonry mortar and preparation method thereof
CN111566070A (en) * 2018-01-10 2020-08-21 三井住友建设株式会社 Mortar and preparation method thereof
CN110028943A (en) * 2019-03-27 2019-07-19 深圳地球村环保产业有限公司 A kind of preparation method of the compound water shutoff agent of saline-alkali tolerant
CN111362654A (en) * 2020-03-19 2020-07-03 河南锦亿建材有限公司 Dry-mixed mortar for stair treads and preparation method thereof
CN111362654B (en) * 2020-03-19 2022-07-19 河南锦亿建材有限公司 Dry-mixed mortar for stair treads and preparation method thereof

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Denomination of invention: A Low cost Environmental friendly Mortar

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