CN107140683A - The system that Nano lead sulfide is prepared based on hydro-thermal method - Google Patents
The system that Nano lead sulfide is prepared based on hydro-thermal method Download PDFInfo
- Publication number
- CN107140683A CN107140683A CN201710599190.7A CN201710599190A CN107140683A CN 107140683 A CN107140683 A CN 107140683A CN 201710599190 A CN201710599190 A CN 201710599190A CN 107140683 A CN107140683 A CN 107140683A
- Authority
- CN
- China
- Prior art keywords
- kettle
- transmission mechanism
- lead sulfide
- reactor
- nano lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229940056932 lead sulfide Drugs 0.000 title claims abstract description 37
- 229910052981 lead sulfide Inorganic materials 0.000 title claims abstract description 37
- 238000001027 hydrothermal synthesis Methods 0.000 title claims abstract description 13
- 230000005540 biological transmission Effects 0.000 claims abstract description 34
- 238000004140 cleaning Methods 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 230000008676 import Effects 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000002425 crystallisation Methods 0.000 abstract description 3
- 230000008025 crystallization Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000010411 cooking Methods 0.000 abstract 1
- 238000007689 inspection Methods 0.000 description 4
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012155 injection solvent Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002096 quantum dot Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G21/00—Compounds of lead
- C01G21/21—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to the system that Nano lead sulfide is prepared based on hydro-thermal method, the system includes reactor and transmission mechanism, heater box, incubator, normal temperature case and cleaning case are sequentially provided with along its transmission direction on transmission mechanism, reactor can complete the preparation of Nano lead sulfide via heater box, incubator, normal temperature case and cleaning case successively under the drive of transmission mechanism.The beneficial effects of the invention are as follows：Reaction substratess can be first put into reactor, solvent is being injected into kettle by inlet, realize that substratess are mixed with the uniform of solvent by agitator again, sealed again on kettle, the above-mentioned mixture being stirred is sequentially passed through into heater box heating, haybox cooking and the cooling of normal temperature case normal temperature, finally the Nano lead sulfide of advantages of good crystallization is rinsed, so as to prepare Nano lead sulfide, by the automated system of the present invention, the preparation efficiency of Nano lead sulfide can be improved and power is prepared into.
Description
Technical field
The present invention relates to Nano lead sulfide preparing technical field, and in particular to a kind of to be based on what hydro-thermal method prepared vulcanized lead
System.
Background technology
Nano lead sulfide is a kind of cube rock salt structure semi-conducting material, with narrow band gap and big Bohr's exciton half
Footpath.Nano lead sulfide is nanocrystalline to have strong quantum confined effect, and its three non-linear optical properties are stronger, and it is logical in near-infrared
Have in terms of news, photon switch, heat and bio-imaging, photoelectric device and solar cell and potentially apply.In recent years, receive
The generation of effective many excitons is detected in rice vulcanized lead quantum dot, most promising high-efficiency photovoltaic converting material is become.
The preparation method of Nano lead sulfide has a lot, and one way in which is to Nano lead sulfide system based on hydro-thermal method
Standby, it is usually to be prepared in laboratory or production that existing use hydro-thermal method, which prepares Nano lead sulfide, and behaviour by hand
Make frequent, once sealing is not good Nano lead sulfide can be caused to prepare failure, nowadays still without suitable automation equipment
The preparation to Nano lead sulfide can be realized.
Therefore, this area needs a kind of system for preparing Nano lead sulfide based on hydro-thermal method to solve the above problems.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of system that Nano lead sulfide is prepared based on hydro-thermal method,
Aim to provide a kind of automation Preparation equipment to prepare Nano lead sulfide, carried so as to realize on the premise of labour is saved
The preparation efficiency of high Nano lead sulfide and it is prepared into power.
In order to realize above-mentioned technical purpose, the present invention provides following technical scheme：
A kind of system that Nano lead sulfide is prepared based on hydro-thermal method, the system includes reactor and transmission mechanism, the biography
Heater box, incubator, normal temperature case and cleaning case are sequentially provided with along its transmission direction on transfer mechanism, the reactor can be in institute
State and received successively via the completion of the heater box, the incubator, the normal temperature case and the cleaning case under the drive of transmission mechanism
The preparation of rice vulcanized lead.
In the optimal technical scheme of said system, the reactor includes having chamber in kettle, the kettle, in institute
State in kettle, the bottom of the chamber is provided with agitator, the agitator can be stirred to the reactant in the kettle.
In the optimal technical scheme of said system, the kettle is provided with inlet, can be to by the inlet
Injection solvent in the kettle.
In the optimal technical scheme of said system, the both sides of the kettle are provided with slot, the slot and can inserted
Sealing plate, can be realized to the chamber by the sealing plate and sealed.
In the optimal technical scheme of said system, on the transmission mechanism, at the import of the heater box and go out
The first range sensor for detecting the reactor movement is respectively provided with mouthful.
In the optimal technical scheme of said system, on the transmission mechanism, at the import of the incubator and go out
The second distance sensor for detecting the reactor movement is respectively provided with mouthful.
In the optimal technical scheme of said system, on the transmission mechanism, at the import of the normal temperature case and go out
The 3rd range sensor for detecting the reactor movement is respectively provided with mouthful.
In the optimal technical scheme of said system, on the transmission mechanism, at the import of the cleaning case and go out
The 4th range sensor for detecting the reactor movement is respectively provided with mouthful.
In the optimal technical scheme of said system, divide in the heater box, in the incubator and in the cleaning case
She You not temperature sensor.
In the optimal technical scheme of said system, the system also includes the control being arranged on the transmission mechanism
Device, the controller respectively with the transmission mechanism, first range sensor, the second distance sensor, described
Three range sensors, the 4th range sensor and temperature sensor signal connection.
The invention provides a kind of system that Nano lead sulfide is prepared based on hydro-thermal method, its advantage is：Can be by
Reaction substratess are first put into reactor, and solvent is being injected into kettle by inlet, then by agitator realize substratess with it is molten
The uniform mixing of agent, then sealed on kettle, the above-mentioned mixture being stirred is sequentially passed through into heater box heating, incubator
The Nano lead sulfide of advantages of good crystallization, is finally rinsed by insulation and the cooling of normal temperature case normal temperature, so that Nano lead sulfide is prepared,
By the automated system of the present invention, the preparation efficiency of Nano lead sulfide can be improved and power is prepared into.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation of the system that Nano lead sulfide is prepared based on hydro-thermal method of the present invention；
Fig. 2 is the structural representation of the reactor of the present invention.
In figure：1st, reactor；2nd, transmission mechanism；3rd, heater box；4th, incubator；5th, normal temperature case；6th, cleaning case；7th, first away from
From sensor；8th, second distance sensor；9th, the 3rd range sensor；10th, the 4th range sensor；11st, kettle；12nd, chamber；
13rd, agitator；14th, inlet；15th, sealing plate；16th, controller.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical scheme will be carried out below
Detailed description.Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are resulting on the premise of creative work is not made to be owned
Other embodiment, belongs to the scope that the present invention is protected.
It should be noted that in the description of the invention, term " " center ", " on ", " under ", "left", "right", " vertical ",
The direction of instruction such as " level ", " interior ", " outer " or the term of position relationship are to be based on direction shown in the drawings or position relationship, this
Description is intended merely to facilitate, rather than indicates or imply that described device or element there must be specific orientation, with specific
Azimuth configuration and operation, therefore be not considered as limiting the invention.In addition, term " first ", " second ", " the 3rd " are only used
In description purpose, and it is not intended that indicating or implying relative importance.
In addition it is also necessary to explanation, in the description of the invention, unless otherwise clearly defined and limited, term " peace
Dress ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integratedly
Connection；Can be mechanical connection or electrical connection；Can be joined directly together, can also be indirectly connected to by intermediary,
It can be the connection of two element internals.To those skilled in the art, it can understand that above-mentioned term exists as the case may be
Concrete meaning in the present invention.
Referring to Fig. 1 and Fig. 2, Fig. 1 is the structural representation of the system that Nano lead sulfide is prepared based on hydro-thermal method of the present invention,
Fig. 2 is the structural representation of the reactor 1 of the present invention.As depicted in figs. 1 and 2, it is based on hydro-thermal legal system the invention provides one kind
The system of standby Nano lead sulfide, the system include on reactor 1 and transmission mechanism 2, the transmission mechanism 2 along its transmission direction according to
Secondary to be provided with heater box 3, incubator 4, normal temperature case 5 and cleaning case 6, the reactor 1 can (can be with the transmission mechanism 2
For conveyer belt) drive under completed successively via the heater box 3, the incubator 4, the normal temperature case 5 and the cleaning case 6
The preparation of Nano lead sulfide.The reactor 1 includes having chamber 12 in kettle 11, the kettle 11, in the kettle 11,
The bottom of the chamber 12 is provided with agitator 13, and the agitator 13 can be stirred to the reactant in the kettle 11.
The kettle 11 is provided with inlet 14, and solvent can be injected into the kettle 11 by the inlet 14.By above-mentioned
Structure design, can will reaction substratess first be put into the reactor 1, by the inlet 14 into the kettle 11
Solvent is injected, then realizes that substratess are mixed with the uniform of solvent by the agitator 13, then is sealed on the kettle 11,
The above-mentioned mixture being stirred sequentially passes through to the heater box 3 is heated, the incubator 4 is incubated and the normal temperature of normal temperature case 5
The Nano lead sulfide of advantages of good crystallization, is finally rinsed by cooling, so as to prepare Nano lead sulfide, passes through the automatic of the present invention
Change system, can improve the preparation efficiency of Nano lead sulfide and be prepared into power.
Preferably, the both sides of the kettle 11, which are provided with slot, the slot, can insert sealing plate 15, by described close
Shrouding 15 can be realized to the chamber 12 and sealed.The sealing of the kettle 11 can be improved by the sealing plate 15, from
And make that during reaction impurity will not be entered, so as to prepare the higher Nano lead sulfide of cleanliness.
Preferably, on the transmission mechanism 2, at the import of the heater box 3 and exit is respectively provided with inspection
Survey the first range sensor 7 that the reactor 1 is moved.
Preferably, on the transmission mechanism 2, at the import of the incubator 4 and exit is respectively provided with inspection
Survey the second distance sensor 8 that the reactor 1 is moved.
Preferably, on the transmission mechanism 2, at the import of the normal temperature case 5 and exit is respectively provided with inspection
Survey the 3rd range sensor 9 that the reactor 1 is moved.
Preferably, on the transmission mechanism 2, at the import of the cleaning case 6 and exit is respectively provided with inspection
Survey the 4th range sensor 10 that the reactor 1 is moved.
In above-mentioned design, pass through first range sensor 7, the second distance sensor 8, the 3rd distance
Sensor 9 and the 4th range sensor 10 can detect the shift position of the reactor 1 in real time, it is being entered described
It can control to be grasped accordingly in each casing in heater box 3, the incubator 4, the normal temperature case 5 or the cleaning case 6
Make.
Preferably, it is respectively equipped with temperature sensor in the heater box 3, in the incubator 4 and in the cleaning case 6.
Temperature that can in real time in detection case body by the temperature sensor in each casing, it is to avoid occur that temperature is improper and shadow
Ring the situation of the preparation of Nano lead sulfide.
Preferably, the system also includes the controller 16 being arranged on the transmission mechanism 2, and the controller 16 is distinguished
With the transmission mechanism 2, first range sensor 7, the second distance sensor 8, the 3rd range sensor 9,
4th range sensor 10 and temperature sensor signal connection.It can be controlled in real time entirely by the controller 16
The progress of equipment, makes its full automation, improves the preparation efficiency of Nano lead sulfide and is prepared into power.
In a kind of embodiment of the present invention, 120 can be carried out by 3 pairs of the heater box reactor 1
DEG C heating, and heating rate be 6 DEG C per minute, by the incubator 4 carry out 12 hours insulation, then in institute
State and natural cooling is carried out in normal temperature case 5, final cleaning is finally completed in the cleaning case 6 pure Nano lead sulfide is made.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of system that Nano lead sulfide is prepared based on hydro-thermal method, it is characterised in that the system includes reactor and transmission
Heater box, incubator, normal temperature case and cleaning case are sequentially provided with along its transmission direction on mechanism, the transmission mechanism, it is described anti-
Answer kettle can be under the drive of the transmission mechanism successively via the heater box, the incubator, the normal temperature case and described
Cleaning case completes the preparation of Nano lead sulfide.
2. system according to claim 1, it is characterised in that the reactor includes having chamber in kettle, the kettle
Room, in the kettle, the bottom of the chamber be provided with agitator, the agitator can enter to the reactant in the kettle
Row stirring.
3. system according to claim 2, it is characterised in that the kettle is provided with inlet, passes through the inlet
Solvent can be injected into the kettle.
4. system according to claim 3, it is characterised in that the both sides of the kettle are provided with slot, the slot interior energy
Sealing plate is enough inserted, the chamber can be realized and sealed by the sealing plate.
5. system according to any one of claim 1 to 4, it is characterised in that on the transmission mechanism, the heating
At the import of case and exit is respectively provided with the first range sensor for detecting the reactor movement.
6. system according to claim 5, it is characterised in that on the transmission mechanism, at the import of the incubator
And exit is respectively provided with the second distance sensor for detecting the reactor movement.
7. system according to claim 6, it is characterised in that on the transmission mechanism, at the import of the normal temperature case
And exit is respectively provided with the 3rd range sensor for detecting the reactor movement.
8. system according to claim 7, it is characterised in that on the transmission mechanism, at the import of the cleaning case
And exit is respectively provided with the 4th range sensor for detecting the reactor movement.
9. system according to claim 8, it is characterised in that the heater box is interior, the interior and described cleaning of the incubator
Temperature sensor is respectively equipped with case.
10. system according to claim 9, it is characterised in that the system also includes being arranged on the transmission mechanism
Controller, the controller respectively with the transmission mechanism, first range sensor, the second distance sensor,
3rd range sensor, the 4th range sensor and temperature sensor signal connection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710599190.7A CN107140683B (en) | 2017-07-21 | 2017-07-21 | System for preparing nano lead sulfide based on hydrothermal method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710599190.7A CN107140683B (en) | 2017-07-21 | 2017-07-21 | System for preparing nano lead sulfide based on hydrothermal method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107140683A true CN107140683A (en) | 2017-09-08 |
| CN107140683B CN107140683B (en) | 2023-10-24 |
Family
ID=59775830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710599190.7A Active CN107140683B (en) | 2017-07-21 | 2017-07-21 | System for preparing nano lead sulfide based on hydrothermal method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107140683B (en) |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134159A (en) * | 2006-08-30 | 2008-03-05 | 藤村通商株式会社 | Water-hot processing device and method by using the water or heat of the vapor |
| AU2009100701A4 (en) * | 2008-07-21 | 2009-10-22 | Jens Berkan | Mechanical cleaning device for a downstream gasifier |
| EP2390301A2 (en) * | 2010-05-31 | 2011-11-30 | EnBW Energie Baden-Württemberg AG | Reactor assembly and method for producing a carbon-enriched solid product by means of increasing the carbon content |
| CN202212386U (en) * | 2011-07-21 | 2012-05-09 | 重庆科本科技有限公司 | Workpiece cleaning machine |
| CN102989374A (en) * | 2012-11-19 | 2013-03-27 | 江苏三木集团有限公司 | Fully enclosed solid material feeding system and feeding method |
| CN103901222A (en) * | 2012-12-27 | 2014-07-02 | 深圳雷杜生命科学股份有限公司 | Reaction vessel transmission mechanism |
| CN104014289A (en) * | 2014-06-10 | 2014-09-03 | 中国石油大学(北京) | Reaction kettle heating device and hydrothermal reaction method |
| CN204222113U (en) * | 2014-10-28 | 2015-03-25 | 天津联创精艺模具有限公司 | A kind of mould automatic temp controller utilizing water circulation to carry out cooling and preheating |
| CN105084381A (en) * | 2015-09-23 | 2015-11-25 | 成都艾比科生物科技有限公司 | Production device with microporous structure molecular sieve |
| CN105478601A (en) * | 2016-02-23 | 2016-04-13 | 朱隆娅 | Multifunctional sealing plate mold system capable of achieving quick cleaning and automatic feeding |
| CN205700542U (en) * | 2016-04-29 | 2016-11-23 | 咸宁天安新型建材有限公司 | A kind of production system of concrete admixture |
| CN205761176U (en) * | 2016-07-04 | 2016-12-07 | 南安市博胤机械科技有限公司 | A kind of novel reaction kettle |
-
2017
- 2017-07-21 CN CN201710599190.7A patent/CN107140683B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134159A (en) * | 2006-08-30 | 2008-03-05 | 藤村通商株式会社 | Water-hot processing device and method by using the water or heat of the vapor |
| AU2009100701A4 (en) * | 2008-07-21 | 2009-10-22 | Jens Berkan | Mechanical cleaning device for a downstream gasifier |
| EP2390301A2 (en) * | 2010-05-31 | 2011-11-30 | EnBW Energie Baden-Württemberg AG | Reactor assembly and method for producing a carbon-enriched solid product by means of increasing the carbon content |
| CN202212386U (en) * | 2011-07-21 | 2012-05-09 | 重庆科本科技有限公司 | Workpiece cleaning machine |
| CN102989374A (en) * | 2012-11-19 | 2013-03-27 | 江苏三木集团有限公司 | Fully enclosed solid material feeding system and feeding method |
| CN103901222A (en) * | 2012-12-27 | 2014-07-02 | 深圳雷杜生命科学股份有限公司 | Reaction vessel transmission mechanism |
| CN104014289A (en) * | 2014-06-10 | 2014-09-03 | 中国石油大学(北京) | Reaction kettle heating device and hydrothermal reaction method |
| CN204222113U (en) * | 2014-10-28 | 2015-03-25 | 天津联创精艺模具有限公司 | A kind of mould automatic temp controller utilizing water circulation to carry out cooling and preheating |
| CN105084381A (en) * | 2015-09-23 | 2015-11-25 | 成都艾比科生物科技有限公司 | Production device with microporous structure molecular sieve |
| CN105478601A (en) * | 2016-02-23 | 2016-04-13 | 朱隆娅 | Multifunctional sealing plate mold system capable of achieving quick cleaning and automatic feeding |
| CN205700542U (en) * | 2016-04-29 | 2016-11-23 | 咸宁天安新型建材有限公司 | A kind of production system of concrete admixture |
| CN205761176U (en) * | 2016-07-04 | 2016-12-07 | 南安市博胤机械科技有限公司 | A kind of novel reaction kettle |
Non-Patent Citations (1)
| Title |
|---|
| 糜裕宏: "球状、立方状及空心立方状PbS纳米晶的控制合成及其形成机理" * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107140683B (en) | 2023-10-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ateba Mba et al. | Synthesis and crystallographic study of homeotypic LiVPO4F and LiVPO4O | |
| CN104362334B (en) | The preparation method of Lithium metasilicate coated lithium ion battery lithium-rich positive electrode | |
| CN205308324U (en) | Reaction system of preparation lithium ion secondary cell cathode material precursor | |
| CN104505505A (en) | Method for preparing lithium silicate coated lithium ion battery ternary layered anode material | |
| CN105261754A (en) | Preparation method of lithium ion conductor-coated lithium-ion battery lithium cobaltate cathode material | |
| CN104091941A (en) | Lithium-rich and manganese-based anode material of layered lithium battery and preparation method thereof | |
| CN107140683A (en) | The system that Nano lead sulfide is prepared based on hydro-thermal method | |
| CN207061886U (en) | The system that Nano lead sulfide is prepared based on hydro-thermal method | |
| CN102092699B (en) | Method for preparing lithium iron phosphate by sintering lithium iron phosphate precursor and microwave sintering equipment | |
| CN104538610B (en) | Preparation method of improved alkali metal ion-doped lithium titanate | |
| CN104591112B (en) | Manganese phosphate caesium lithium and preparation method and application | |
| CN204051685U (en) | Cefixime active ester synthesis reactor | |
| CN109295364A (en) | A kind of method and device preparing manganese-silicon using Mn-rich slag | |
| CN104269545A (en) | Preparation method of lithium-rich lamellar positive electrode material of lithium metatitanate-coated lithium ion battery | |
| CN104993107A (en) | Lithium ion battery cathode material Li4Ti5O12/rutile-TiO2 and preparation method thereof | |
| CN105576228A (en) | Method for preparing lithium manganate to serve as lithium-ion battery by sol-gel method | |
| CN201587859U (en) | Lithium iron phosphate micro-wave heating horizontal continuous production equipment | |
| CN208952664U (en) | A kind of High-efficiency silicon slag smelting furnace | |
| CN209481679U (en) | The constant temperature system provided multiple forms of energy to complement each other based on liquid charge material | |
| CN203598810U (en) | Lithium salt preparation device | |
| CN201598178U (en) | Ferric phosphate lithium microwave heating single-furnace continuous production equipment | |
| CN206173220U (en) | Mineral fibre quenching and tempering stove | |
| CN201587860U (en) | Lithium iron phosphate micro-wave heating staggered vertical continuous production equipment | |
| Benabed et al. | Synthesis, structure, and electrochemical properties of LiFeV2O7 | |
| CN207095169U (en) | A kind of energy-efficient interior heating, vacuum baking intelligence system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |