CN107123498A - Novel magnetic materials - Google Patents
Novel magnetic materials Download PDFInfo
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- CN107123498A CN107123498A CN201710516107.5A CN201710516107A CN107123498A CN 107123498 A CN107123498 A CN 107123498A CN 201710516107 A CN201710516107 A CN 201710516107A CN 107123498 A CN107123498 A CN 107123498A
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- magnetic
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- magnetic materials
- iron
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/047—Alloys characterised by their composition
- H01F1/053—Alloys characterised by their composition containing rare earth metals
- H01F1/055—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
- H01F1/057—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
Abstract
The present invention relates to novel magnetic materials, belong to field of functional materials.Present invention solves the technical problem that there is provided a kind of inexpensive novel magnetic materials.Magnetic material of the present invention, is made up of the component of following atomic percent:Nd:2~7at%;Nb:2~7at%;Dy:1~5at%;Si:3~10at%;B:8~12at%;Zn:1~3at%;Ag:1~5at%;Remaining is iron.Magnetic material of the present invention, adds a small amount of Nd, Nb and Dy, on the premise of without Co, it is ensured that material has high Curie temperature, under the high temperature conditions using also having higher magnetic conductivity, reduces the cost of magnetic material.
Description
Technical field
The present invention relates to novel magnetic materials, belong to field of functional materials.
Background technology
With the development of science and technology, magnetic alloy in electric power, electronics, computer, automatically control and the emerging technology such as electrooptics
In field, there is increasingly extensive application.Magnetic material can be divided into soft magnetic material and hard magnetic by the difficulty or ease of degaussing after magnetization
Material.Easily remove the material of magnetic soft magnetic material after magnetization, it is not easy to which the material of degaussing is retentive material.It is general next
Say that soft magnetic material remanent magnetism is smaller, retentive material remanent magnetism is larger.
Wherein, soft magnetic materials is often used as producing the product with soft magnetic characteristic such as high frequency transformer, choke coil and magnetic head.
Existing soft magnetic materials mainly uses ferrite material for matrix to prepare, and there is such material resistivity height, high-frequency vortex to damage
The advantages of consuming small.But, because the saturation induction density of material is relatively low, temperature characterisitic is poor, and its Curie temperature is 450 DEG C of left sides
The right side, under the high temperature conditions, the performance of material drastically decline even magnetic and disappeared, and therefore, this kind of material is not suitable for making under high temperature
With.
For disadvantages described above, this area scientific research personnel has done substantial amounts of research.At present, a kind of conventional method is in alloy
Middle addition Co elements, change the high temperature magnetic characteristic of material using α-FeCo, it is still had at a higher temperature preferable
Magnetic.
Such as, to disclose a kind of high temperature that can be used at high temperature non-for the patent of invention of Application No. 200410029900.5
Brilliant, microcrystalline soft magnetic alloy material, using FeCoMSiB as base material, the alloy employs 10~60% Co elements, has at high temperature
There is very high high temperature soft magnetic characteristic.
The patent of invention of Application No. 201611077360.7 discloses a kind of magnetic alloy powder material, with
FeCoMSiBTi is base material, and the alloy employs 20~25% Co, is to be used for preferable hot properties and storage magnetic characteristic
Make the preferred magnetic material of magnetic head.
Above patent is that the soft magnetic characteristic under high temperature is improved by adding Co.But, because metal Co belongs in China
In narrow resources, largely dependent on import, therefore, Co prices are higher, and substantial amounts of metal Co contents are added in the alloy, undoubtedly can
Substantial increase prepares cost so that the alloy can not be applied to industrialized production.
Therefore, a kind of lower-cost resistant to elevated temperatures novel magnetic alloy material is needed badly.
The content of the invention
For disadvantages described above, present invention solves the technical problem that being to provide a kind of inexpensive novel magnetic materials, the material
Material still has preferable magnetic under the high temperature conditions.
Magnetic material of the present invention, is made up of the component of following atomic percent:Nd:2~7at%;Nb:2~7at%;Dy:
1~5at%;Si:3~10at%;B:8~12at%;Zn:1~3at%;Ag:1~5at%;Remaining is iron.
It is preferred that, it is made up of the component of following atomic percent:Nd:3~6at%;Nb:3~6at%;Dy:2~
4at%;Si:4~8at%;B:9~11at%;Zn:1~3at%;Ag:2~5at%;Remaining is iron.
Preferably, it is made up of the component of following atomic percent:Nd:4at%;Nb:4at%;Dy:2at%;
Si:6at%;B:10at%;Zn:2at%;Ag:3at%;Remaining is iron.
Novel magnetic materials of the present invention, add a small amount of Nd, Nb and Dy, on the premise of without Co, it is ensured that material
Material has high Curie temperature, under the high temperature conditions using also having higher magnetic conductivity, reduces the cost of magnetic material, makes
It can be used in industrialized production.
Embodiment
Novel magnetic materials of the present invention, are made up of the component of following atomic percent:Nd:2~7at%;Nb:2~
7at%;Dy:1~5at%;Si:3~10at%;B:8~12at%;Zn:1~3at%;Ag:1~5at%;Remaining is iron.
It is preferred that, it is made up of the component of following atomic percent:Nd:3~6at%;Nb:3~6at%;Dy:2~
4at%;Si:4~8at%;B:9~11at%;Zn:1~3at%;Ag:2~5at%;Remaining is iron.
Preferably, it is made up of the component of following atomic percent:Nd:4at%;Nb:4at%;Dy:2at%;
Si:6at%;B:10at%;Zn:2at%;Ag:3at%;Remaining is iron.
Novel magnetic materials of the present invention, can be prepared, such as using conventional smelting process:Carried out using vaccum sensitive stove
Melting.When smelting, vaccum sensitive stove is added after raw material is prepared, after carrying out vacuum melting under argon gas protection, by abundant
Stirring, casting, produce alloy material.
The embodiment of the present invention is further described with reference to embodiment, not therefore by present invention limit
System is among described scope of embodiments.
Embodiment 1
Novel magnetic materials, are made up of the component of following atomic percent:Nd:2at%;Nb:7at%;Dy:5at%;
Si:3at%;B:12at%;Zn:1at%;Ag:1at%;Remaining is iron.
The material has higher Curie temperature, and (650 DEG C) also have higher magnetic conductivity under the high temperature conditions.
Embodiment 2
Novel magnetic materials, are made up of the component of following atomic percent:Nd:7at%;Nb:2at%;Dy:1at%;
Si:10at%;B:8at%;Zn:3at%;Ag:5at%;Remaining is iron.
The material has higher Curie temperature, and (650 DEG C) also have higher magnetic conductivity under the high temperature conditions.
Embodiment 3
Novel magnetic materials, are made up of the component of following atomic percent:Nd:4at%;Nb:4at%;Dy:2at%;
Si:6at%;B:10at%;Zn:2at%;Ag:3at%;Remaining is iron.
The material has higher Curie temperature, and (650 DEG C) also have higher magnetic conductivity under the high temperature conditions.
Embodiment 4
Novel magnetic materials, are made up of the component of following atomic percent:Nd:3at%;Nb:6at%;Dy:2at%;
Si:4at%;B:9at%;Zn:3at%;Ag:5at%;Remaining is iron.
The material has higher Curie temperature, and (650 DEG C) also have higher magnetic conductivity under the high temperature conditions.
Embodiment 5
Novel magnetic materials, are made up of the component of following atomic percent:Nd:6at%;Nb:3at%;Dy:4at%;
Si:8at%;B:11at%;Zn:1at%;Ag:2at%;Remaining is iron.
The material has higher Curie temperature, and (650 DEG C) also have higher magnetic conductivity under the high temperature conditions.
Claims (3)
1. novel magnetic materials, it is characterised in that be made up of the component of following atomic percent:Nd:2~7at%;Nb:2~
7at%;Dy:1~5at%;Si:3~10at%;B:8~12at%;Zn:1~3at%;Ag:1~5at%;Remaining is iron.
2. novel magnetic materials according to claim 1, it is characterised in that be made up of the component of following atomic percent:
Nd:3~6at%;Nb:3~6at%;Dy:2~4at%;Si:4~8at%;B:9~11at%;Zn:1~3at%;Ag:2
~5at%;Remaining is iron.
3. novel magnetic materials according to claim 2, it is characterised in that be made up of the component of following atomic percent:
Nd:4at%;Nb:4at%;Dy:2at%;Si:6at%;B:10at%;Zn:2at%;Ag:3at%;Remaining is iron.
Priority Applications (1)
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CN201710516107.5A CN107123498A (en) | 2017-06-29 | 2017-06-29 | Novel magnetic materials |
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CN201710516107.5A CN107123498A (en) | 2017-06-29 | 2017-06-29 | Novel magnetic materials |
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CN201710516107.5A Pending CN107123498A (en) | 2017-06-29 | 2017-06-29 | Novel magnetic materials |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1172862A (en) * | 1996-07-15 | 1998-02-11 | 阿尔卑斯电气株式会社 | Method for manufacturing iron-base soft magnetic alloy |
CN1253364A (en) * | 1998-11-10 | 2000-05-17 | 阿尔卑斯电气株式会社 | High saturation magnetic flux density low iron loss ferrous soft magnetic alloy and magnetic core using same and manufacturing method |
JP2005325429A (en) * | 2004-05-17 | 2005-11-24 | Nec Tokin Corp | Soft magnetic yoke, and electromagnetic actuator using the same |
-
2017
- 2017-06-29 CN CN201710516107.5A patent/CN107123498A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1172862A (en) * | 1996-07-15 | 1998-02-11 | 阿尔卑斯电气株式会社 | Method for manufacturing iron-base soft magnetic alloy |
CN1253364A (en) * | 1998-11-10 | 2000-05-17 | 阿尔卑斯电气株式会社 | High saturation magnetic flux density low iron loss ferrous soft magnetic alloy and magnetic core using same and manufacturing method |
JP2005325429A (en) * | 2004-05-17 | 2005-11-24 | Nec Tokin Corp | Soft magnetic yoke, and electromagnetic actuator using the same |
Non-Patent Citations (2)
Title |
---|
K.KAMARAJU等: "Magnetic properties of iron-rich Nd2-yDyyFe17-xSix mixed rare-earth system", 《JOURNAL OF APPLIED PHYSICS》 * |
N. CHAU等: "The effect of Zn, Ag and Au substitution of Cu in Finemet on the crystallization and magnetic properties", 《JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS》 * |
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Application publication date: 20170901 |
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