CN107120663B - A kind of organic contamination soil and solid waste combination treatment method - Google Patents

A kind of organic contamination soil and solid waste combination treatment method Download PDF

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Publication number
CN107120663B
CN107120663B CN201710260164.1A CN201710260164A CN107120663B CN 107120663 B CN107120663 B CN 107120663B CN 201710260164 A CN201710260164 A CN 201710260164A CN 107120663 B CN107120663 B CN 107120663B
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rotary furnace
solid waste
cement kiln
organic contamination
furnace
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CN107120663A (en
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李春萍
张青锋
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Golmud Hongyang Environmental Protection Technology Co. Ltd.
Jinyuan environmental protection Co., Ltd.
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Golmud Hongyang Environmental Protection Technology Co Ltd
Golden Round Cement Ltd By Share Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/06Reclamation of contaminated soil thermally
    • B09C1/065Reclamation of contaminated soil thermally by pyrolysis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of organic contamination soil and solid waste combination treatment method, processing unit includes the first rotary furnace, vertical incinerator, the second rotary furnace;Solid waste is added from the top of the first rotary furnace, introduces low temperature exhaust gas from bottom and is used for drying solid waste;It will be delivered in vertical incinerator by dry solid waste, introduce cement kiln smoke-box tail gas, cement kiln tertiary air into incinerator respectively, and be added by raw material part;The second rotary furnace will be inputted from top after the sieving of organic contamination soil;The tail gas that vertical incinerator generates is delivered in the second rotary furnace and carries out heat exchange with organic contamination soil, the exhaust gas of generation is discharged by air-introduced machine.This method combines organic polluted soil with solid waste such as domestic waste, sludge, aging rubbish, it not only can use the thermal energy during solid waste incineration, treated, and contaminated soil can also produce building materials, achieve the purpose that while handling soil and solid waste, reduces the cost individually handled.

Description

A kind of organic contamination soil and solid waste combination treatment method
Technical field
The present invention relates to solid waste recycling field, in particular for organic polluted soil and domestic waste, The solid waste joint processing technologies such as sludge, aging rubbish, hazardous waste.
Background technique
Soil is material base for the survival of mankind, is an important part of the human ecological environment.With industrial or agricultural Development and urbanization process expansion, agriculturally being widely used of fertilizer and pesticide, poisonous and harmful substance is invaded in industrial wastewater Farmland, solid waste stack the leakage etc. for filling caused poisonous and harmful substance, and various pollutants matter is made to exist by different approaches It is constantly accumulated in soil, purification capacity of soil day hastens towards saturation, and soil quality is decreased obviously, and China's soil pollution situation has started pair Sustainable Use of Soil Resources constitutes a threat to agricultural product ecological safety.According to statistics, the whole nation is by organic pollutant (pesticide, petroleum Hydrocarbon and PAHs) pollution farmland up to 3.6 × 107hm2, these contaminated sites show that type is more, pollution sources are complicated, harm is wide The features such as, the grain that loses every year by soil pollution of the whole nation is up to 1.2 × 1010kg.Soil pollution does not only result in quality of agricultural product Decline, is detrimental to health, also results in atmosphere and water body environment pollution.Soil pollution have typical time bomb property, one Denier large area outburst, it will influence difficult to the appraisal is caused on national sustainable development, therefore, how rationally to dispose contaminated soil At being an urgent problem to be solved currently, it is very urgent to carry out the research of contaminated soil disposal technology.The recovery technique of contaminated soil is ground Study carefully the emphasis for becoming countries in the world research, also an important topic and research direction of the China in environment protection field.
At present mainly there is the processing technique of POPs Polluted Soil in the country: Thermal desorption technology, high-level oxidation technology and biology Extracting, biological prosthetic etc..But each technology has certain limitation, and the atmosphere pollution after Thermal desorption can not be ignored.Therefore, originally Invention reaches a variety of organic contaminations by the way of by Polluted Soil and solid waste Combined Treatment for POPs contaminated soil The purpose that object is handled simultaneously.
Summary of the invention
Handling organic polluted soil simultaneously the technical problem to be solved in the present invention is to provide one kind (includes: polycyclic aromatic hydrocarbon, stone The multiple pollutants such as petroleum hydrocarbon, organic agricultural chemicals) with the method for solid waste.The present invention by following scheme to organic contamination soil into Row processing:
A kind of organic contamination soil and solid waste combination treatment method, processing unit packet used in the processing method Include the first rotary furnace, the vertical incinerator connecting with the tapping channel of the first rotary furnace, the exhaust passage company with vertical incinerator The second rotary furnace connect;The bottom of first rotary furnace is provided with low temperature exhaust gas import, and the top of the first rotary furnace is equipped with solid Body waste import;Cement kiln smoke-box inlet exhaust gas, vertical incinerator are equipped at the lower part 1/6~1/8 of the vertical incinerator Lower part 1/2~1/3 at be equipped with cement kiln wind inlet three times, be equipped at the lower part 1/9~1/10 of vertical incinerator hot raw material into Mouthful, the bottom of vertical incinerator is exported equipped with raw material;The top of second rotary furnace is equipped with Polluted Soil import, the second rotary furnace Bottom be equipped with slag-drip opening, the side wall of the second rotary furnace is equipped with outlet port;It the treating method comprises following steps:
A, solid waste is added from the top of the first rotary furnace, introduces low temperature exhaust gas from the bottom of the first rotary furnace and is used for The dry solid waste, the introducing temperature of the low temperature exhaust gas is 100~300 DEG C, air quantity is 20000~50000Nm3/ H, the revolving speed of the first rotary furnace are 10~30r/h, and drying time is 30~60 minutes;
B, it will be delivered in vertical incinerator by dry solid waste, introduce cement kiln cigarette into incinerator respectively Room tail gas, cement kiln tertiary air, and 600~800 DEG C of the raw material from cement kiln precalcining system level V preheater are added Powder;The cement kiln smoke-box exhaust temperature of introducing be 1000~1200 DEG C, cement kiln smoke-box tail gas air quantity be 10000~ 30000Nm3/ h, cement kiln smoke-box tail gas oxygen content are 2%~4%;Air temperature is 700~900 DEG C to the cement kiln of introducing three times, Cement kiln tertiary air air quantity is 20000~50000Nm3/ h, cement kiln tertiary air oxygen content are 18%~21%;
C, organic contamination soil is crossed into 15~80mm rotary screen, screenings inputs the second rotary furnace from top;By vertical burning The tail gas that furnace generates, which is delivered in the second rotary furnace, carries out heat exchange with organic contamination soil, and the revolving speed of the second rotary furnace is 10~ 30r/h, the exhaust gas generated in the second rotary furnace pass through air-introduced machine discharge from the second revolution furnace sidewall discharge, exhaust gas.
Further, the tail gas or tail gas or kiln after cogeneration that the low temperature exhaust gas is cement plant grate-cooler low-temperature zone The tail gas that last row is put.
Further, the exhaust gas that air-introduced machine is drawn respectively enters ozone+Ultraviolet Oxidation equipment, 1~5%NaOH solution absorbs After be incorporated to cement kiln end bag dust arrester installation, qualified discharge after processing.
Further, first rotary furnace is steel structure, and liner fire proofing material, draw ratio is 10~15:1, inclination Angle is 3~5 °.
Further, second rotary furnace is steel structure, and liner fire proofing material, draw ratio is 3~5:1, inclination angle Degree is 1~3 °.
Further, the solid waste is delivered in the first rotary furnace by helix transporting device.
Further, the screenings after the sieving of organic contamination soil is delivered in the second rotary furnace by helix transporting device.
Beneficial effects of the present invention:
This method utilizes incinerator for solid rubbish, by organic polluted soil and domestic waste, sludge, aging rubbish The solid waste such as rubbish, hazardous waste combine, and not only can use the thermal energy during solid waste incineration, after gained processing Contaminated soil can also produce building materials, achieve the purpose that while handling soil and solid waste, substantially reduce and individually handle Cost.
Invention is described in detail with reference to the accompanying drawings and examples.
Detailed description of the invention
Fig. 1 present invention process flow diagram.
Specific embodiment
As shown in Figure 1, a kind of organic contamination soil and solid waste combination treatment method, used in the processing method Processing unit includes the first rotary furnace, the vertical incinerator connecting with the tapping channel of the first rotary furnace and vertical incinerator Second rotary furnace of exhaust passage (top of tertiary air entrance) connection;The bottom of first rotary furnace is provided with low temperature exhaust gas The top of import, the first rotary furnace is equipped with solid waste import;Water is equipped at the lower part 1/6~1/8 of the vertical incinerator Stall smoke-box inlet exhaust gas is equipped with cement kiln wind inlet three times at the lower part 1/2~1/3 of vertical incinerator, vertical incinerator Hot raw meal inlet is equipped at lower part 1/9~1/10, the bottom of vertical incinerator is exported equipped with raw material;The top of second rotary furnace End is equipped with Polluted Soil import, and the bottom of the second rotary furnace is equipped with slag-drip opening, and the side wall of the second rotary furnace is equipped with outlet port;Institute State processing method the following steps are included:
A, solid waste is added from the top of the first rotary furnace, introduces low temperature exhaust gas from the bottom of the first rotary furnace and is used for The dry solid waste, the introducing temperature of the low temperature exhaust gas is 100~300 DEG C, air quantity is 20000~50000Nm3/ H, the revolving speed of the first rotary furnace are 10~30r/h, and drying time is 30~60 minutes;The low temperature exhaust gas is cement plant grate-cooler The tail gas of low-temperature zone or the tail gas after cogeneration or kiln tail discharged tail gas;
B, it will be delivered in vertical incinerator by dry solid waste, introduce cement kiln cigarette into incinerator respectively Room tail gas, cement kiln tertiary air, and hot raw material are added (has the elephant trunk of refractory material that will come from cement kiln predecomposition using inside block The 10~20% of the total amount of 600~800 degree of raw meal powders of system level V preheater introduce vertical incinerator lower part 1/9~1/10 Place);The cement kiln smoke-box exhaust temperature of introducing be 1000~1200 DEG C, cement kiln smoke-box tail gas air quantity be 10000~ 30000Nm3/ h, cement kiln smoke-box tail gas oxygen content are 2%~4%;Air temperature is 700~900 DEG C to the cement kiln of introducing three times, Cement kiln tertiary air air quantity is 20000~50000Nm3/ h, cement kiln tertiary air oxygen content are 18%~21%;Cement kiln smoke-box Tail gas due to oxygen content it is low, pyrolysis is played to the solid waste after drying;Tertiary air oxygen content is high, plays the role of dual firing chamber, So that solid waste full combustion, hot raw material play the role of fluidized bed, prevent the heat molten types material such as plastics in solid waste bonding, frame Bridge.
C, organic contamination soil is crossed into 15~80mm rotary screen, screenings inputs the second rotary furnace from top;By vertical burning The tail gas that furnace generates, which is delivered in the second rotary furnace, carries out heat exchange with organic contamination soil, and the revolving speed of the second rotary furnace is 10~ 30r/h, the exhaust gas generated in vertical incinerator pass through air-introduced machine discharge from furnace sidewall discharge, exhaust gas is burned.
D, the exhaust gas that air-introduced machine is drawn respectively enters ozone+Ultraviolet Oxidation equipment, 1~5%NaOH solution is incorporated to after absorbing Cement kiln end bag dust arrester installation, qualified discharge after processing.Its activity of treated Polluted Soil is high, can be used as non-burning brick, permeable The building materials ingredient such as brick uses, and additive amount can reach 30% or more.First rotary furnace is steel structure, liner fire proofing material, major diameter Than for 10~15:1, tilt angle is 3~5 °.Second rotary furnace is steel structure, and liner fire proofing material, draw ratio is 3~5: 1, tilt angle is 1~3 °.Solid waste is delivered in the first rotary furnace by helix transporting device.The sieving of organic contamination soil Screenings afterwards is delivered in the second rotary furnace by helix transporting device.
Embodiment 1
The tail gas part of cement plant grate-cooler low-temperature zone is introduced into the first rotary furnace bottom end, the first rotary furnace draw ratio is 10:1, tilt angle are 3 °, steel structure, liner fire proofing material, and the exhaust temperature of extraction is 180 DEG C, air quantity 20000Nm3/ H, solid waste are added above the first rotary furnace by helical feed.The revolving speed for keeping the first rotary furnace is 10r/h, when dry materials Between be 30 minutes;It will be sent into vertical incinerator by dry solid waste by spiral.There is the resistance to of refractory material using inside block High temperature air hose draws part of cement kiln smoke-box tail gas and part tertiary air, and cement kiln smoke-box tail gas is sent into vertical incinerator lower part At 1/7, the technological parameter of tail gas are as follows: temperature is 1000 DEG C, air quantity 15000Nm3/ h, oxygen content 2%;Tertiary air is sent into vertical At formula incinerator lower part 1/2, technological parameter are as follows: temperature is 700 DEG C, air quantity 20000Nm3/ h, oxygen content 20%.Separately Outside, there is the elephant trunk of refractory material will be from 700 DEG C of raw meal powder total amounts of precalcining system level V preheater using inside block 15% introduces at vertical incinerator lower part 1/9.In one the second rotary furnace of the rear end of vertical incinerator series connection.Second revolution furnace superintendent Diameter ratio is 3:1, and tilt angle is 2 °, and the second rotary furnace is steel structure, liner fire proofing material.Organic contamination soil is crossed into 20mm rolling Shaft screen, screenings are transported to the second rotary furnace top using screw conveyor.The tail gas that vertical incinerator is generated is sent into second Rotary furnace, the approach axis of incineration tail gas and the discharge direction of exhaust gas (flue gas) are in the same direction.The revolving speed for keeping the second rotary furnace is Exhaust gas after 10r/h, with Polluted Soil heat exchange is discharged from air-introduced machine;The gas feeding that air-introduced machine is drawn is respectively enterd into ozone+purple External oxidation equipment, 1%NaOH solution are incorporated to cement kiln end bag dust arrester installation, qualified discharge after processing after absorbing.It is treated Polluted Soil prepares non-burning brick, additive amount 45%.The compound national standard of the brick produced.
Embodiment 2
Carry out burning the improvement of parameter again on the basis of embodiment 1.
It will be sent into vertical incinerator by dry solid waste by spiral.There is the high temperature resistant of refractory material using internal block Air hose draws part of cement kiln smoke-box tail gas and part tertiary air, and cement kiln smoke-box tail gas is sent into vertical incinerator lower part 1/8 Place, the technological parameter of tail gas are as follows: temperature is 1200 DEG C, air quantity 30000Nm3/ h, oxygen content 2.5%;Tertiary air is sent into vertical At formula incinerator lower part 1/3, technological parameter are as follows: temperature is 700 DEG C, air quantity 30000Nm3/ h, oxygen content 20%.Separately Outside, the elephant trunk of refractory material draws the 20% of 800 DEG C of raw meal powder total amounts of precalcining system level V preheater using inside block Enter at vertical incinerator lower part 1/9.In one the second rotary furnace of the rear end of vertical incinerator series connection.Second rotary furnace draw ratio is 4:1, tilt angle are 2.5 °, and the second rotary furnace is steel structure, liner fire proofing material.Organic contamination soil is crossed into 15mm roller Sieve, screenings are transported to the second rotary furnace top using screw conveyor.The tail gas that vertical incinerator is generated is sent into second time Converter, the approach axis of incineration tail gas and the discharge direction of exhaust gas are in the same direction.The revolving speed for keeping the second rotary furnace is 15r/h, with Exhaust gas after Polluted Soil heat exchange is discharged from air-introduced machine;The gas feeding that air-introduced machine is drawn is respectively enterd ozone+Ultraviolet Oxidation to set Standby, 1.5%NaOH solution is incorporated to cement kiln end bag dust arrester installation, qualified discharge after processing after absorbing.Treated Polluted Soil Prepare non-burning brick, additive amount 33%.The compound national standard of the brick produced.

Claims (7)

1. a kind of organic contamination soil and solid waste combination treatment method, it is characterised in that: used in the processing method Processing unit includes the first rotary furnace, the vertical incinerator connecting with the tapping channel of the first rotary furnace and vertical incinerator Second rotary furnace of exhaust passage connection;The bottom of first rotary furnace is provided with low temperature exhaust gas import, the first rotary furnace Top is equipped with solid waste import;It is equipped with cement kiln smoke-box inlet exhaust gas at the lower part 1/6 ~ 1/8 of the vertical incinerator, stands It is equipped with cement kiln wind inlet three times at the lower part 1/2 ~ 1/3 of formula incinerator, is equipped with heat at the lower part 1/9 ~ 1/10 of vertical incinerator The bottom of raw meal inlet, vertical incinerator is exported equipped with raw material;The top of second rotary furnace be equipped with Polluted Soil import, second The bottom of rotary furnace is equipped with slag-drip opening, and the side wall of the second rotary furnace is equipped with outlet port;It the treating method comprises following step It is rapid:
A, solid waste is added from the top of the first rotary furnace, introduces low temperature exhaust gas for doing from the bottom of the first rotary furnace The dry solid waste, the introducing temperature of the low temperature exhaust gas is 100 ~ 300 DEG C, air quantity is 20000 ~ 50000Nm3/ h, the The revolving speed of single-revolution furnace is 10 ~ 30r/h, and drying time is 30 ~ 60 minutes;
B, it will be delivered in vertical incinerator by dry solid waste, introduce cement kiln smoke-box tail into incinerator respectively Gas and water stall tertiary air, and 600 ~ 800 DEG C of the raw meal powder from cement kiln precalcining system level V preheater is added;Draw The cement kiln smoke-box exhaust temperature entered is 1000 ~ 1200 DEG C, and cement kiln smoke-box tail gas air quantity is 10000 ~ 30000Nm3/ h, water Stall smoke-box tail gas oxygen content is 2% ~ 4%;Air temperature is 700 ~ 900 DEG C to the cement kiln of introducing three times, cement kiln tertiary air air quantity For 20000 ~ 50000Nm3/ h, cement kiln tertiary air oxygen content are 18% ~ 21%;
C, organic contamination soil is crossed into 15 ~ 80mm rotary screen, screenings inputs the second rotary furnace from top;Vertical incinerator is generated Tail gas be delivered in the second rotary furnace and carry out heat exchange with organic contamination soil, the revolving speed of the second rotary furnace is 10 ~ 30r/h, the The exhaust gas generated in two-revolution furnace is discharged from the second revolution furnace sidewall discharge, exhaust gas by air-introduced machine.
2. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: described low Warm tail gas can the tail gas using cement plant grate-cooler low-temperature zone or tail gas or kiln tail discharged tail gas three after cogeneration Any one of person.
3. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: air-introduced machine The exhaust gas of extraction respectively enters ozone+Ultraviolet Oxidation equipment, 1 ~ 5%NaOH solution is incorporated to cement kiln end bag dust arrester installation after absorbing, Qualified discharge after processing.
4. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: described the Single-revolution furnace is steel structure, and liner fire proofing material, draw ratio is 10 ~ 15:1, and tilt angle is 3 ~ 5 °.
5. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: described the Two-revolution furnace is steel structure, and liner fire proofing material, draw ratio is 3 ~ 5:1, and tilt angle is 1 ~ 3 °.
6. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: described solid Body waste is delivered in the first rotary furnace by helix transporting device.
7. organic contamination soil according to claim 1 and solid waste combination treatment method, it is characterised in that: organic dirt Screenings after dye soil sieving is delivered in the second rotary furnace by helix transporting device.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107790480A (en) * 2017-10-26 2018-03-13 天津中材工程研究中心有限公司 It is a kind of to utilize the method for transforming cement kiln processing Polluted Soil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004000985A (en) * 2001-03-09 2004-01-08 Mitsubishi Materials Corp Processing method of organic matter contaminated soil
JP2005270874A (en) * 2004-03-25 2005-10-06 Sumitomo Osaka Cement Co Ltd Treatment method of polluted soil and apparatus thereof
CN103936311A (en) * 2014-04-14 2014-07-23 北京建筑材料科学研究总院有限公司 Method of combination of joint treatment of organic polluted soil and municipal wastes with cement kiln
CN105731839A (en) * 2016-01-15 2016-07-06 浙江环立环保科技有限公司 Treatment method of cement kiln incineration polluted soil

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004000985A (en) * 2001-03-09 2004-01-08 Mitsubishi Materials Corp Processing method of organic matter contaminated soil
JP2005270874A (en) * 2004-03-25 2005-10-06 Sumitomo Osaka Cement Co Ltd Treatment method of polluted soil and apparatus thereof
CN103936311A (en) * 2014-04-14 2014-07-23 北京建筑材料科学研究总院有限公司 Method of combination of joint treatment of organic polluted soil and municipal wastes with cement kiln
CN105731839A (en) * 2016-01-15 2016-07-06 浙江环立环保科技有限公司 Treatment method of cement kiln incineration polluted soil

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Address after: Room 906, building 3, fengdanbailu phase I, CITIC City, Jingyue Development Zone, Changchun City, Jilin Province 130000

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Patentee after: Jinyuan environmental protection Co., Ltd.

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Patentee before: Golden round cement Limited by Share Ltd