CN107116218A - A kind of use low-melting alloy is easy to the method that metal 3D printing removes support - Google Patents

A kind of use low-melting alloy is easy to the method that metal 3D printing removes support Download PDF

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CN107116218A
CN107116218A CN201710343621.3A CN201710343621A CN107116218A CN 107116218 A CN107116218 A CN 107116218A CN 201710343621 A CN201710343621 A CN 201710343621A CN 107116218 A CN107116218 A CN 107116218A
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printing
low
metal
melting alloy
easy
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任冰
万熠
孟祥旗
曹恩源
王宏卫
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Shandong University
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Shandong University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/40Structures for supporting workpieces or articles during manufacture and removed afterwards
    • B22F10/43Structures for supporting workpieces or articles during manufacture and removed afterwards characterised by material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/60Treatment of workpieces or articles after build-up
    • B22F10/64Treatment of workpieces or articles after build-up by thermal means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/50Means for feeding of material, e.g. heads
    • B22F12/53Nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/50Means for feeding of material, e.g. heads
    • B22F12/55Two or more means for feeding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/70Recycling
    • B22F10/73Recycling of powder
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Powder Metallurgy (AREA)

Abstract

It is easy to the method that metal 3D printing removes support the invention discloses a kind of use low-melting alloy, using double nozzle printing systems, main jet head supply subject material, main component for printed product, secondary shower nozzle supplies low melting point alloy, for the support member of printed product, when being heat-treated after finished product printing shaping, backing material is melted.Present invention can apply to the 3D printing method of direct metal fusing, low-melting alloy auxiliary supporting material can be removed while Technology for Heating Processing is carried out, therefore relative to original processing in whole process, new process procedure is not increased, it can be saved the plenty of time compared to other post processing modes, use manpower and material resources sparingly cost, and can obtain more preferable surface quality.Meanwhile, the low-melting alloy after fusing can more meet the principle of green manufacturing with recycling.

Description

一种使用低熔点合金便于金属3D打印去除支撑的方法A method to facilitate support removal in metal 3D printing using low melting point alloys

技术领域technical field

本发明涉及一种金属3D打印技术,具体说涉及一种便于金属3D打印后期去除支撑材料的方法。The invention relates to a metal 3D printing technology, in particular to a method for removing supporting materials in the later stage of metal 3D printing.

背景技术Background technique

3D打印技术通过层层叠加的原理,在制造形状复杂的工件时具有突出的优势。用于金属组件3D打印的方式可以分为两种,直接能量沉积和粉末床熔化式式,其中直接能量沉积式是使用喷头供给粉末或线材的方式,在喷头处利用激光或电子束的能量形成熔池,直接熔覆原材料,并按预定路径层层堆叠获得成型金属。相比粉末床熔化式,直接能量沉积式具备更高的打印速度,在采用多喷头供给系统时可以实现多种材料的同时打印,因此具有广泛的应用前景。3D printing technology has outstanding advantages in the manufacture of workpieces with complex shapes through the principle of layer-by-layer superposition. The methods for 3D printing of metal components can be divided into two types, direct energy deposition and powder bed fusion. Among them, the direct energy deposition method uses the nozzle to supply powder or wire, and the energy of the laser or electron beam is used at the nozzle to form The molten pool is directly cladding the raw materials, and stacking them layer by layer according to the predetermined path to obtain the formed metal. Compared with the powder bed fusion type, the direct energy deposition type has a higher printing speed, and can realize simultaneous printing of multiple materials when using a multi-nozzle supply system, so it has a wide range of application prospects.

但是直接能量沉积式也存在较大缺陷,因为是层层叠加的原理,相比粉末床熔化式在打印镂空或悬垂结构时能够实现的悬垂角度较小,容易出现坍塌,这时,添加支撑材料是一种有效的手段。但是在打印完成后支撑材料的去除往往会带来非期望的麻烦。塑料或其他聚合物材料制品的支撑,因为硬度较低,可以借助钳子等工具去除,或者使用可溶性材料作为支撑,工件打印完后浸泡在溶解液中,支撑材料会被溶解。但是在金属材料的3d打印工艺中,用钳子去除支撑材料很耗费时间,去除效果也不够理想,还需要后期打磨,并且至今没有发现水溶性金属可以作为辅助支撑材料。However, the direct energy deposition method also has major defects, because it is based on the principle of layer-by-layer superposition. Compared with the powder bed fusion method, the overhang angle that can be achieved when printing hollow or overhanging structures is smaller, and it is prone to collapse. At this time, adding support materials is an effective means. But the removal of support material after printing is often undesired. The support of plastic or other polymer material products can be removed with tools such as pliers because of its low hardness, or use soluble materials as supports, and the support materials will be dissolved after the workpiece is soaked in the solution after printing. However, in the 3D printing process of metal materials, it is time-consuming to remove the support material with pliers, the removal effect is not ideal, and it needs to be polished later, and so far no water-soluble metal can be used as an auxiliary support material.

因为不能很好处理支撑材料的去除,目前打印含有较大悬垂角度的悬垂结构时,一般应用可倾斜工作台、五轴平台或机械手臂,提高可实现的最大悬垂角度上限,但相比三坐标式,需要增加复杂的手动路径规划,并且造价高昂。Because the removal of support materials cannot be handled well, when printing overhanging structures with large overhang angles, tiltable worktables, five-axis platforms or robotic arms are generally used to increase the upper limit of the maximum overhang angle that can be achieved, but compared with three-coordinate In this way, complex manual path planning needs to be added, and the cost is high.

Owen J.Hildreth等人在打印不锈钢材料时使用低碳钢作为支撑材料,并用电化学腐蚀的方法将支撑材料溶解掉,该成果发表在《3D Printing and AdditiveManufacturing》杂志“Dissolvable Metal Supports for 3D Direct Metal Printing”一文中。但是该方法需要选择合适的辅助材料和溶解剂,操作较复杂,依然需要较长时间,并且打印时使用的支撑材料越多,溶解所消耗的时间也越长。除此之外,支撑材料和溶解剂不能循环利用,不符合绿色制造的理念。Owen J.Hildreth and others used low-carbon steel as a support material when printing stainless steel materials, and used electrochemical corrosion to dissolve the support material. The results were published in the journal "Dissolvable Metal Supports for 3D Direct Metal Printing" article. However, this method needs to select appropriate auxiliary materials and dissolving agents, the operation is more complicated, and it still takes a long time, and the more support materials are used in printing, the longer the dissolution time will be. In addition, support materials and solvents cannot be recycled, which is not in line with the concept of green manufacturing.

发明内容Contents of the invention

本发明的目的在于提供一种更加简单快捷的用于直接能量沉积式金属3D打印后期去除辅助支撑的方法,该方法能够在不增加工艺环节的前提下去除支撑,并且实现支撑材料的回收利用。The purpose of the present invention is to provide a simpler and quicker method for removing auxiliary supports in the later stage of direct energy deposition metal 3D printing, which can remove supports without increasing the process steps, and realize the recycling of support materials.

本发明采用的技术方案如下:The technical scheme that the present invention adopts is as follows:

一种使用低熔点合金便于金属3D打印去除支撑的方法,采用双喷头打印系统,主喷头供给主体材料,用于打印产品的主体构件,副喷头供给低熔点合金材料,用于打印产品的支撑件,在成品打印成型后进行热处理时,将支撑件融化。A method of using low-melting-point alloys to facilitate the removal of supports in metal 3D printing. A dual-nozzle printing system is adopted. The main nozzle supplies the main material for printing the main components of the product, and the sub-nozzle supplies low-melting point alloy materials for printing the support of the product. , when the heat treatment is carried out after the finished product is printed and formed, the support is melted.

进一步的,在打印之前,首先使用上位机软件,根据待成型工件的结构添加辅助支撑,然后生成包含每一层打印路径的切片数据,并上传到打印机上。Further, before printing, first use the host computer software to add auxiliary supports according to the structure of the workpiece to be formed, and then generate slice data including the printing path of each layer, and upload it to the printer.

进一步的,打印机根据切片数据,自动执行预定路径和切换所需的喷头,在打印主体材料时移动主喷头,在打印支撑材料时移动副喷头;层层熔化并凝固完成毛坯制作。Further, the printer automatically executes the predetermined path and switches the required nozzles according to the slicing data, moves the main nozzle when printing the main material, and moves the auxiliary nozzle when printing the supporting material; layers are melted and solidified to complete the rough production.

进一步的,由于金属在3D打印过程中冷却速度较快,会产生残余应力,因此通常需要进行热处理。而低熔点合金的最大特点就是熔点低(232℃以下),不同的金属材料选用的热处理温度各有差异,但远高于此温度,因此在对成品进行热处理的同时就可以将其熔化并去除掉。采用的支撑材料的熔点低于工件在进行热处理时的热处理温度。Furthermore, due to the rapid cooling of metals during the 3D printing process, residual stress will be generated, so heat treatment is usually required. The biggest feature of low-melting point alloys is their low melting point (below 232°C). Different metal materials have different heat treatment temperatures, but they are much higher than this temperature. Therefore, they can be melted and removed while heat-treating the finished product. Lose. The melting point of the support material used is lower than the heat treatment temperature of the workpiece during heat treatment.

进一步的,所述的支撑材料的选择根据所述的主体材料进行选择,要求支撑材料的熔点低于主体材料。Further, the selection of the supporting material is based on the main material, and it is required that the melting point of the supporting material is lower than that of the main material.

进一步的,所述的支撑材料采用低熔点合金。Further, the support material adopts low melting point alloy.

进一步的,在低熔点合金熔化后用容器收集,由于熔凝过程只发生物理变化,材料化学性质并未改变,因此可以回收后重新制造粉末或线材原料,实现材料再利用。Furthermore, after the low-melting point alloy is melted, it is collected in a container. Since the melting process only undergoes physical changes and the chemical properties of the material do not change, it can be recycled to remanufacture powder or wire raw materials to realize material reuse.

本发明能够实现的有益效果:The beneficial effect that the present invention can realize:

本发明可应用于直接金属熔化的3D打印方式,低熔点合金辅助支撑材料可以在进行热处理工艺的同时被去除掉,因此整个过程中相对于原先的处理,并不增加新的工艺环节,相比其他后处理方式能够节约大量时间,节约人力物力成本,并且可以获得更好的表面质量。同时,熔化后的低熔点合金可以回收再利用,更符合绿色制造的原理。The invention can be applied to the 3D printing method of direct metal melting, and the low-melting point alloy auxiliary support material can be removed while performing the heat treatment process. Therefore, compared with the original process, no new process links are added in the whole process. Other post-processing methods can save a lot of time, save manpower and material costs, and can obtain better surface quality. At the same time, the melted low melting point alloy can be recycled and reused, which is more in line with the principle of green manufacturing.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本申请的进一步理解,本申请的示意性实施例及其说明用于解释本申请,并不构成对本申请的不当限定。The accompanying drawings constituting a part of the present application are used to provide further understanding of the present application, and the schematic embodiments and descriptions of the present application are used to explain the present application, and do not constitute improper limitations to the present application.

图1悬垂结构示意图;Figure 1 Schematic diagram of the suspension structure;

图2支撑结构示意图;Fig. 2 schematic diagram of support structure;

图中:1工件,2低熔点合金辅助支撑,3基板。In the figure: 1 workpiece, 2 low melting point alloy auxiliary support, 3 substrate.

具体实施方式detailed description

下应该指出,以下详细说明都是例示性的,旨在对本申请提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本申请所属技术领域的普通技术人员通常理解的相同含义。It should be pointed out that the following detailed descriptions are all exemplary and are intended to provide further explanation to the present application. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.

需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本申请的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terminology used here is only for describing specific implementations, and is not intended to limit the exemplary implementations according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural, and it should also be understood that when the terms "comprising" and/or "comprising" are used in this specification, they mean There are features, steps, operations, means, components and/or combinations thereof.

本发明公开的使用低熔点合金便于金属3D打印去除支撑的方法,采用双喷头打印系统,主喷头供给主体材料,用于打印产品的主体构件,副喷头供给低熔点合金材料,用于打印产品的支撑件,在成品打印成型后进行热处理时,将支撑材料融化;具体的如图1、2所示,工件1和低熔点合金辅助支撑均在基板3上形成,通过工件1通过低熔点合金辅助支撑2支撑,在后续的工艺处理时,低熔点合金辅助支撑2将被融化掉;具体的工艺过程如下:The method disclosed in the present invention uses a low-melting-point alloy to facilitate metal 3D printing to remove supports. A dual-nozzle printing system is adopted. The main nozzle supplies the main body material for printing the main components of the product, and the sub-nozzle supplies the low-melting point alloy material for printing the product. The support member melts the support material during heat treatment after the finished product is printed and formed; specifically, as shown in Figures 1 and 2, the workpiece 1 and the low-melting point alloy auxiliary support are formed on the substrate 3, and the workpiece 1 is assisted by the low-melting point alloy. Support 2 support, in the subsequent process, the low melting point alloy auxiliary support 2 will be melted; the specific process is as follows:

1.在打印之前,首先使用上位机软件,根据待成型工件的结构添加辅助支撑,然后生成包含每一层打印路径的切片数据,并上传到打印机上。1. Before printing, first use the host computer software to add auxiliary supports according to the structure of the workpiece to be formed, and then generate slice data including the printing path of each layer and upload it to the printer.

2.打印机根据切片数据,自动执行预定路径和切换所需的喷头,在打印主体材料时移动主喷头,在打印支撑材料时移动副喷头;层层熔化并凝固完成毛坯制作。2. According to the slicing data, the printer automatically executes the predetermined path and switches the required nozzles, moves the main nozzle when printing the main material, and moves the auxiliary nozzle when printing the supporting material; layers are melted and solidified to complete the rough production.

3.由于金属在3D打印过程中冷却速度较快,会产生残余应力,因此通常需要进行热处理。而低熔点合金的最大特点就是熔点低(232℃以下),不同的金属材料选用的热处理温度各有差异,但远高于此温度,因此在对成品进行热处理的同时就可以将其熔化并去除掉。3. Due to the rapid cooling of metal during the 3D printing process, residual stress will be generated, so heat treatment is usually required. The biggest feature of low melting point alloys is their low melting point (below 232°C). Different metal materials have different heat treatment temperatures, but they are much higher than this temperature. Therefore, they can be melted and removed while heat treating the finished product. Lose.

4.低熔点合金回收再利用。在低熔点合金熔化后用容器收集,由于熔凝过程只发生物理变化,材料化学性质并未改变,因此可以回收后重新制造粉末或线材原料,实现材料再利用。4. Recycling and reuse of low melting point alloys. After the low-melting point alloy is melted, it is collected in a container. Since the melting process only undergoes physical changes and the chemical properties of the material have not changed, it can be recycled to remanufacture powder or wire raw materials to realize material reuse.

下面以打印不锈钢拱形主体工件、使用200℃铋锡低熔点合金作辅助支撑为例,本发明的步骤如下:The following is an example of printing a stainless steel arched main body workpiece and using a 200°C bismuth-tin low-melting point alloy as an auxiliary support. The steps of the present invention are as follows:

1.准备316L不锈钢和铋锡低熔点合金粉末,将316L不锈钢配备到主喷头系统里面,将铋锡低熔点合金粉末配备到副喷头供给系统里面。1. Prepare 316L stainless steel and bismuth-tin low-melting point alloy powder, equip 316L stainless steel into the main nozzle system, and equip bismuth-tin low-melting point alloy powder into the auxiliary nozzle supply system.

2.将工件模型上传到上位机,完成切片,将切片数据导入打印机,开始打印。2. Upload the workpiece model to the host computer, complete the slicing, import the slicing data into the printer, and start printing.

3.打印完毕后将带支撑的工件用锡纸包裹放入加热炉中进行热处理,摆放成合理位置以便低熔点合金熔化后可自然流下并收集;设置热处理的加热温度为600℃,保温时间2小时;开始进行热处理。3. After printing, wrap the supported workpiece with tin foil and put it into the heating furnace for heat treatment, and place it in a reasonable position so that the low-melting point alloy can flow down and collect naturally after melting; set the heating temperature for heat treatment to 600°C, and the holding time for 2 hours; start heat treatment.

4.热处理结束后取出工件,分离工件、基板,在低熔点合金熔化后用容器收集,由于熔凝过程只发生物理变化,材料化学性质并未改变,因此可以回收铋锡低熔点合金后重新制造粉末或线材原料,实现材料再利用。4. After the heat treatment, take out the workpiece, separate the workpiece and the substrate, and collect it in a container after the low-melting point alloy is melted. Since only physical changes occur during the melting process, the chemical properties of the material have not changed, so the bismuth-tin low-melting point alloy can be recycled and remanufactured Powder or wire raw materials to realize material reuse.

上述虽然结合附图对本发明的具体实施方式进行了描述,但并非对本发明保护范围的限制,所属领域技术人员应该明白,在本发明的技术方案的基础上,本领域技术人员不需要付出创造性劳动即可做出的各种修改或变形仍在本发明的保护范围以内。Although the specific implementation of the present invention has been described above in conjunction with the accompanying drawings, it does not limit the protection scope of the present invention. Those skilled in the art should understand that on the basis of the technical solution of the present invention, those skilled in the art do not need to pay creative work Various modifications or variations that can be made are still within the protection scope of the present invention.

Claims (7)

1. a kind of use low-melting alloy is easy to the method that metal 3D printing removes support, it is characterised in that beaten using double shower nozzles Print system, main jet head supply subject material, for the main component of printed product, secondary shower nozzle supplies low melting point alloy, uses In the support member of printed product, when being heat-treated after finished product printing shaping, backing material is melted.
2. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 1, it is characterised in that Before the printing, first by upper computer software, Auxiliary support is added according to the structure of workpiece to be formed, then generation is comprising every The slice of data of one layer of printing path, and upload on printer.
3. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 1, it is characterised in that Printer is according to slice of data, and the automatic shower nozzle performed needed for predefined paths and switching moves main jet in type body material Head, the prismatic pair shower nozzle when printing backing material;Melt layer by layer and solidify completion blank and make.
4. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 1, it is characterised in that The fusing point of the backing material of use is less than heat treatment temperature of the workpiece when being heat-treated.
5. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 1, it is characterised in that The selection of described backing material is selected according to described material of main part, it is desirable to which the fusing point of backing material is less than main body material Material.
6. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 1, it is characterised in that Described backing material uses low-melting alloy.
7. it is easy to the method that metal 3D printing removes support using low-melting alloy as claimed in claim 6, it is characterised in that Described low-melting alloy uses container collection after being melted down, and powder or wire feedstock are remanufactured after recovery, realizes that material is sharp again With.
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CN113927375A (en) * 2021-09-15 2022-01-14 蓝箭航天空间科技股份有限公司 An automatic de-support method based on 3D metal printing
CN113927375B (en) * 2021-09-15 2022-07-22 蓝箭航天空间科技股份有限公司 An automatic de-support method based on 3D metal printing
CN114274505A (en) * 2021-12-23 2022-04-05 山东大学 A method and system for generating a sandwich plate fused deposition printing support structure
CN114274505B (en) * 2021-12-23 2022-08-30 山东大学 Sandwich plate fused deposition printing support structure generation method and system
CN115195106A (en) * 2022-06-30 2022-10-18 上海酷鹰机器人科技有限公司 Printing process for vertical stacking molding

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Application publication date: 20170901