CN107116103A - A kind of copper alloy tube surface quality improves and control method - Google Patents

A kind of copper alloy tube surface quality improves and control method Download PDF

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Publication number
CN107116103A
CN107116103A CN201710351510.7A CN201710351510A CN107116103A CN 107116103 A CN107116103 A CN 107116103A CN 201710351510 A CN201710351510 A CN 201710351510A CN 107116103 A CN107116103 A CN 107116103A
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CN
China
Prior art keywords
parts
copper alloy
alloy tube
water
clear water
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Pending
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CN201710351510.7A
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Chinese (zh)
Inventor
郑晓飞
杜小秋
孙军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Tongcheng Alloy Copper Pipe Co Ltd
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Zhejiang Tongcheng Alloy Copper Pipe Co Ltd
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Application filed by Zhejiang Tongcheng Alloy Copper Pipe Co Ltd filed Critical Zhejiang Tongcheng Alloy Copper Pipe Co Ltd
Priority to CN201710351510.7A priority Critical patent/CN107116103A/en
Publication of CN107116103A publication Critical patent/CN107116103A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C1/00Manufacture of metal sheets, metal wire, metal rods, metal tubes by drawing
    • B21C1/16Metal drawing by machines or apparatus in which the drawing action is effected by other means than drums, e.g. by a longitudinally-moved carriage pulling or pushing the work or stock for making metal sheets, bars, or tubes
    • B21C1/22Metal drawing by machines or apparatus in which the drawing action is effected by other means than drums, e.g. by a longitudinally-moved carriage pulling or pushing the work or stock for making metal sheets, bars, or tubes specially adapted for making tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C3/00Profiling tools for metal drawing; Combinations of dies and mandrels
    • B21C3/02Dies; Selection of material therefor; Cleaning thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C43/00Devices for cleaning metal products combined with or specially adapted for use with machines or apparatus provided for in this subclass
    • B21C43/02Devices for cleaning metal products combined with or specially adapted for use with machines or apparatus provided for in this subclass combined with or specially adapted for use in connection with drawing or winding machines or apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00Cooling, heating or lubricating drawing material
    • B21C9/02Selection of compositions therefor

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Extraction Processes (AREA)
  • Lubricants (AREA)

Abstract

Improve the present invention relates to a kind of copper alloy tube surface quality and control method, it includes following processing step during manufacturing:(1)Degreasing aqueous solution soaks;(2)Clear water is rinsed;(3)It is dustless to be transported without bump injury;(4)Compressed air is purged online;(5)Drawing mould lubricates strong flushing;(6)Blanking in tubing water after drawing.In this method, by using different control methods, the quality on copper alloy tube surface is effectively improved, it is to avoid debris influences compo pipe Surface Machining treatment effect, easy to use, and the alloy copper pipe surface flaw for producing preparation is few, and using effect is good, long lifespan.

Description

A kind of copper alloy tube surface quality improves and control method
Technical field
Improve the present invention relates to a kind of copper alloy tube surface quality and control method, belong to copper alloy tube manufacturing technology neck Domain.
Background technology
Traditional copper alloy tube production technology is to use extrusion, is extruded by the strand ingot of semi-continuous casting or continuously casting Into pipe, then by drawing or cold rolling it is processed into tubing.And after casting and roll process is introduced into, casting and roll process produces wide in red copper tubing General application, practice have shown that the performance of casting and roll process production red copper tubing is stable and manufacturing cost is relatively low, can meet air conditioner refrigerating device Etc. the rigors of industry.At present, horizontal continuous casting tube blank, through planetary rolling cogging, again two even draw, the then production of disk drawn tube Technology is most advanced efficient production procedure, and steady quality, total manufacturing cost is relatively low.But, these in production by making During making, some collisions can be introduced unavoidably, and either some debris occur is attached to copper pipe surface, treated in subsequent high temperature Cheng Zhong, introduces defect, influences copper alloy tube surface quality.
Patent No. CN03149757.8 patent《The method that planet tube grimper manufactures copper and copper alloy tube》(Publication number For:1221336)A kind of method for disclosing utilization planet tube grimper manufacture copper and copper alloy tube, this method utilizes planetary rolling Machine is rolled to the pipe of copper and copper alloy, and specific step is, pipe surface mechanical process;Pipe is 701 DEG C~850 Deformation speed is carried out between DEG C rolling temperature to roll to form rolled parts;Three steps such as finally make rolled parts quickly cool down, should Method has the advantages that process is few, lumber recovery is high, manufacturing cost is low and tubing article steady quality.But, it is not disclosed For the subsequent cleaning processes of copper pipe, but washing method is washed down using conventional acid.
Patent No. CN03149786.1 patent《A kind of hot-rolling method for manufacturing copper and copper alloy tube》(Publication No.: 1221337)A kind of hot-rolling method for manufacturing copper and copper-alloy pipe-material is disclosed, using planet tube grimper to copper and the pipe of copper alloy Base carries out hot rolling, and specific step is, pipe surface mechanical process;Pipe on-line heating is to higher than recrystallization initial temperature; Pipe carries out deformation of the single pass elongation percentage more than 5 and with 10m/min-30m/min between 701 DEG C~850 DEG C rolling temperatures Mill speed hot rolling formed rolled parts;Four steps such as finally make rolled parts quickly cool down.With technical scheme disclosed above Similar, these methods are that on the milling method of concentration, follow-up cleaning program of becoming a useful person is not directed to, and in the operation of rolling, does not have There is waste recovery and recycle function, its lumber recovery is not high.
In Patent No. CN200410010338.1《A kind of manufacture method of precision superlong copper alloy pipe》Disclose one The manufacture method of precision superlong copper alloy pipe is planted, it includes carrying out horizontal casting copper alloy tube surface machining removal of impurities, will The pipe of surface machining removal of impurities imports rolling equipment, and rolling deformation is carried out using differential temperature rotation rolling method, what the differential temperature rotation was rolled Method is:Pipe deflection is controlled to be less than 20%, the heat energy produced by self-deformation makes pipe be warming up to 380-500 DEG C, with Increasing deflection afterwards makes blank temperature be rapidly heated the roll forming in the range of 720-880 DEG C to more than 80%, then in anaerobic Less than 50 DEG C are quickly cooled under environment tube rolling is made, then drawn using bigeminy and high speed disk stretcher is stretched through multi-pass Into trimmed size, coil pipe, straight tube or mosquito-repellent incense coil pipe is made finally by on-line continuous annealing and eddy current inspection.This method, has Manufacturing process is few, easy temperature control system, product precision high, be easy to large-scale production, injury device, cost is difficult in production low Advantage.
Make a general survey of above-mentioned various rolling copper alloy tube methods, no matter which kind of method, its uncontrollable surface quality, it is impossible to it is real The now quality control on more preferable copper alloy tube surface, it is necessary to improved using suitable mode, conveniently better control over copper Compo pipe surface quality, improves product quality, reduces the defect in copper alloy tube production process, improves the use longevity of copper alloy tube Life.
The content of the invention
Improve it is an object of the invention to provide a kind of copper alloy tube surface quality and control method, preferably to improve The quality control effect on copper alloy tube surface, it is to avoid copper alloy tube introduces unnecessary impurity during manufacturing, and facilitates root According to needing to use.
To achieve these goals, technical scheme is as follows.
A kind of copper alloy tube surface quality improves and control method, and it includes following processing step during manufacturing:
(1)Degreasing aqueous solution soaks:Using the aqueous solution containing various ingredients for copper alloy tube production blank immersion, realize de- Fat processing, and reduce the production of copper alloy tube and collide with;
(2)Clear water is rinsed:After degreasing, rinsed using clear water, remove surface irregularities, and realize that clear water is used after filtering, clear water is real Existing heat treatment;
(3)It is dustless to be transported without bump injury:Realize that dustless nothing is collided with operating, is provided with closing on transiting vehicle in transport process Lid, and be provided with dedusting fan and give dedusting;Flannelette is provided between copper alloy tube, prevents from mutually colliding between tubing;
(4)Compressed air is purged online:It is online using the compressed air through drying process when copper alloy tube is transported between process Purging, it is to avoid introduce dust and debris;
(5)Drawing mould lubricates strong flushing:Strong flushing is carried out using lubricant for drawing mould, drawing mould table is removed The debris in face, and conveniently handled for drawing mould surface lubrication;
(6)Blanking in tubing water after drawing:Using side position stretching-machine, fallen directly into after facilitating side position blanking, tubing blanking in water, To reduce the probability mutually collided.
Further, above-mentioned steps(1)In, used degreasing aqueous solution is composed of the following components:Hexadecyldimethylamine Base amine-oxides, ethoxylated dodecyl alcohol sodium sulphate, isopropanol, sodium alkyl benzene sulfonate, coconutalkyl ethanol diamides and water, Above-mentioned each component according to the mass fraction, be respectively:10~25 parts of octadecyldimethyl amine-oxides, ethoxylated dodecyl alcohol sulphur Sour 12~24 parts of sodium, 8~20 parts of isopropanol, 20~40 parts of sodium alkyl benzene sulfonate, 10~18 parts of coconutalkyl ethanol diamides, 100~240 parts of water;Degreasing agent is prepared into after said components mixing to be used in mixed way.
Further, above-mentioned steps(5)In, used lubricant is mixed by the component materials of following mass fraction and made It is standby to form:8~16 parts of sodium polyphosphate, 5~10 parts of zinc oxide, 12~25 parts of molybdenum disulfide, 12~20 parts of amido silicon oil, nitridation 15~26 parts of boron powder, 10~30 parts of makrolon, 1000~2000 parts of base oil.
Further, above-mentioned steps(2)In, clear water heating-up temperature is 60~90 DEG C.
The beneficial effect of the invention is:In this method, by using different control methods, copper alloy is effectively improved The quality of pipe surface, it is to avoid debris influences compo pipe Surface Machining treatment effect, easy to use, produces the alloy copper pipe prepared Surface blemish is few, and using effect is good, long lifespan.
Embodiment
The embodiment of the present invention is described with reference to embodiment, to be better understood from the present invention.
Embodiment 1
Copper alloy tube surface quality in the present embodiment improves and control method, and it is walked during manufacturing comprising following technique Suddenly:
(1)Degreasing aqueous solution soaks:Soaked using the aqueous solution containing various ingredients for copper alloy tube production embryo material, it is real Show ungrease treatment, and reduce the production of copper alloy tube and collide with;Used degreasing aqueous solution, it is composed of the following components:Octadecane Base dimethyl ammonium, ethoxylated dodecyl alcohol sodium sulphate, isopropanol, sodium alkyl benzene sulfonate, the acyl of coconutalkyl ethanol two Amine and water, above-mentioned each component according to the mass fraction, be respectively:10 parts of octadecyldimethyl amine-oxides, lauryl alcohol polyethylene glycol oxide 12 parts of ether sodium sulfate, 8 parts of isopropanol, 20 parts of sodium alkyl benzene sulfonate, 10 parts of coconutalkyl ethanol diamides, 100 parts of water;It is above-mentioned Degreasing agent is prepared into after component mixing to be used in mixed way.
(2)Clear water is rinsed:After degreasing, rinsed using clear water, remove surface irregularities, and realize that clear water is used after filtering, clearly Water realizes heat treatment;Clear water heating-up temperature is 60 DEG C.
(3)It is dustless to be transported without bump injury:Realize that dustless nothing is collided with operating, is provided with envelope on transiting vehicle in transport process The lid closed, and be provided with dedusting fan and give dedusting;Flannelette is provided between copper alloy tube, prevents from mutually touching between tubing Hit;
(4)Compressed air is purged online:It is online using the compressed air through drying process when copper alloy tube is transported between process Purging, it is to avoid introduce dust and debris;
(5)Drawing mould lubricates strong flushing:Strong flushing is carried out using lubricant for drawing mould, drawing mould table is removed The debris in face, and conveniently handled for drawing mould surface lubrication;Used lubricant, by the component thing of following mass fraction Material, which is mixed with, to be formed:8 parts of sodium polyphosphate, 5 parts of zinc oxide, 12 parts of molybdenum disulfide, 12 parts of amido silicon oil, boron nitride powder 15 Part, 10 parts of makrolon, 1000 parts of base oil.
(6)Blanking in tubing water after drawing:Using side position stretching-machine, fallen directly into after facilitating side position blanking, tubing blanking In water, to reduce the probability mutually collided.
Embodiment 2
Copper alloy tube surface quality in the present embodiment improves and control method, and it is walked during manufacturing comprising following technique Suddenly:
(1)Degreasing aqueous solution soaks:Soaked using the aqueous solution containing various ingredients for copper alloy tube production embryo material, it is real Show ungrease treatment, and reduce the production of copper alloy tube and collide with;Used degreasing aqueous solution, it is composed of the following components:Octadecane Base dimethyl ammonium, ethoxylated dodecyl alcohol sodium sulphate, isopropanol, sodium alkyl benzene sulfonate, the acyl of coconutalkyl ethanol two Amine and water, above-mentioned each component according to the mass fraction, be respectively:15 parts of octadecyldimethyl amine-oxides, lauryl alcohol polyethylene glycol oxide 18 parts of ether sodium sulfate, 14 parts of isopropanol, 30 parts of sodium alkyl benzene sulfonate, 14 parts of coconutalkyl ethanol diamides, 170 parts of water;On It is prepared into degreasing agent after stating component mixing and is used in mixed way.
(2)Clear water is rinsed:After degreasing, rinsed using clear water, remove surface irregularities, and realize that clear water is used after filtering, clearly Water realizes heat treatment;Clear water heating-up temperature is 75 DEG C.
(3)It is dustless to be transported without bump injury:Realize that dustless nothing is collided with operating, is provided with envelope on transiting vehicle in transport process The lid closed, and be provided with dedusting fan and give dedusting;Flannelette is provided between copper alloy tube, prevents from mutually touching between tubing Hit;
(4)Compressed air is purged online:It is online using the compressed air through drying process when copper alloy tube is transported between process Purging, it is to avoid introduce dust and debris;
(5)Drawing mould lubricates strong flushing:Strong flushing is carried out using lubricant for drawing mould, drawing mould table is removed The debris in face, and conveniently handled for drawing mould surface lubrication;Used lubricant, by the component thing of following mass fraction Material, which is mixed with, to be formed:12 parts of sodium polyphosphate, 8 parts of zinc oxide, 18 parts of molybdenum disulfide, 16 parts of amido silicon oil, boron nitride powder 20 parts, 20 parts of makrolon, 1500 parts of base oil.
(6)Blanking in tubing water after drawing:Using side position stretching-machine, fallen directly into after facilitating side position blanking, tubing blanking In water, to reduce the probability mutually collided.
Embodiment 3
Copper alloy tube surface quality in the present embodiment improves and control method, and it is walked during manufacturing comprising following technique Suddenly:
(1)Degreasing aqueous solution soaks:Soaked using the aqueous solution containing various ingredients for copper alloy tube production embryo material, it is real Show ungrease treatment, and reduce the production of copper alloy tube and collide with;Used degreasing aqueous solution, it is composed of the following components:Octadecane Base dimethyl ammonium, ethoxylated dodecyl alcohol sodium sulphate, isopropanol, sodium alkyl benzene sulfonate, the acyl of coconutalkyl ethanol two Amine and water, above-mentioned each component according to the mass fraction, be respectively:25 parts of octadecyldimethyl amine-oxides, lauryl alcohol polyethylene glycol oxide 24 parts of ether sodium sulfate, 20 parts of isopropanol, 40 parts of sodium alkyl benzene sulfonate, 18 parts of coconutalkyl ethanol diamides, 240 parts of water;On It is prepared into degreasing agent after stating component mixing and is used in mixed way.
(2)Clear water is rinsed:After degreasing, rinsed using clear water, remove surface irregularities, and realize that clear water is used after filtering, clearly Water realizes heat treatment;Clear water heating-up temperature is 90 DEG C.
(3)It is dustless to be transported without bump injury:Realize that dustless nothing is collided with operating, is provided with envelope on transiting vehicle in transport process The lid closed, and be provided with dedusting fan and give dedusting;Flannelette is provided between copper alloy tube, prevents from mutually touching between tubing Hit;
(4)Compressed air is purged online:It is online using the compressed air through drying process when copper alloy tube is transported between process Purging, it is to avoid introduce dust and debris;
(5)Drawing mould lubricates strong flushing:Strong flushing is carried out using lubricant for drawing mould, drawing mould table is removed The debris in face, and conveniently handled for drawing mould surface lubrication;Used lubricant, by the component thing of following mass fraction Material, which is mixed with, to be formed:16 parts of sodium polyphosphate, 10 parts of zinc oxide, 25 parts of molybdenum disulfide, 20 parts of amido silicon oil, boron nitride powder 26 parts, 30 parts of makrolon, 2000 parts of base oil.
(6)Blanking in tubing water after drawing:Using side position stretching-machine, fallen directly into after facilitating side position blanking, tubing blanking In water, to reduce the probability mutually collided.

Claims (4)

1. a kind of copper alloy tube surface quality improves and control method, it is characterised in that:It includes following during manufacturing Processing step:
(1)Degreasing aqueous solution soaks:Soaked using the aqueous solution containing various ingredients for copper alloy tube production embryo material, it is real Show ungrease treatment, and reduce the production of copper alloy tube and collide with;
(2)Clear water is rinsed:After degreasing, rinsed using clear water, remove surface irregularities, and realize that clear water is used after filtering, clear water is real Existing heat treatment;
(3)It is dustless to be transported without bump injury:Realize that dustless nothing is collided with operating, is provided with closing on transiting vehicle in transport process Lid, and be provided with dedusting fan and give dedusting;Flannelette is provided between copper alloy tube, prevents from mutually colliding between tubing;
(4)Compressed air is purged online:It is online using the compressed air through drying process when copper alloy tube is transported between process Purging, it is to avoid introduce dust and debris;
(5)Drawing mould lubricates strong flushing:Strong flushing is carried out using lubricant for drawing mould, drawing mould table is removed The debris in face, and conveniently handled for drawing mould surface lubrication;
(6)Blanking in tubing water after drawing:Using side position stretching-machine, fallen directly into after facilitating side position blanking, tubing blanking in water, To reduce the probability mutually collided.
2. copper alloy tube surface quality according to claim 1 improves and control method, it is characterised in that:The step (1)In, used degreasing aqueous solution is composed of the following components:Octadecyldimethyl amine-oxides, ethoxylated dodecyl alcohol Sodium sulphate, isopropanol, sodium alkyl benzene sulfonate, coconutalkyl ethanol diamides and water, above-mentioned each component according to the mass fraction, divide It is not:10~25 parts of octadecyldimethyl amine-oxides, 12~24 parts of ethoxylated dodecyl alcohol sodium sulphate, isopropanol 8~20 Part, 20~40 parts of sodium alkyl benzene sulfonate, 10~18 parts of coconutalkyl ethanol diamides, 100~240 parts of water;Said components are mixed Degreasing agent is prepared into after conjunction to be used in mixed way.
3. copper alloy tube surface quality according to claim 1 improves and control method, it is characterised in that:The above-mentioned step Suddenly(5)In, used lubricant is mixed with by the component materials of following mass fraction and formed:Sodium polyphosphate 8~16 Part, 5~10 parts of zinc oxide, 12~25 parts of molybdenum disulfide, 12~20 parts of amido silicon oil, 15~26 parts of boron nitride powder, poly- carbonic acid 10~30 parts of ester, 1000~2000 parts of base oil.
4. copper alloy tube surface quality according to claim 1 improves and control method, it is characterised in that:The above-mentioned step Suddenly(2)In, clear water heating-up temperature is 60~90 DEG C.
CN201710351510.7A 2017-05-18 2017-05-18 A kind of copper alloy tube surface quality improves and control method Pending CN107116103A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110899350A (en) * 2019-12-24 2020-03-24 新乡市金龙精密铜管制造有限公司 Production process for online production of hydrophilic copper straight pipe

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110899350A (en) * 2019-12-24 2020-03-24 新乡市金龙精密铜管制造有限公司 Production process for online production of hydrophilic copper straight pipe
CN110899350B (en) * 2019-12-24 2021-09-14 新乡市金龙精密铜管制造有限公司 Production process for online production of hydrophilic copper straight pipe

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Application publication date: 20170901