CN107106436A - Liquid skin cleansing composition - Google Patents
Liquid skin cleansing composition Download PDFInfo
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- CN107106436A CN107106436A CN201580070724.6A CN201580070724A CN107106436A CN 107106436 A CN107106436 A CN 107106436A CN 201580070724 A CN201580070724 A CN 201580070724A CN 107106436 A CN107106436 A CN 107106436A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Abstract
There is provided a kind of liquid skin cleansing composition, said composition contains the mass % of at least one kind of mass % of copolymer 0.04 containing dimethyl diallyl ammonium chloride and in acrylic acid and acrylamide of the mass % of (A) (A1) laruate and (A2) myristate, the mass % of (B) alkyl amine oxide compound 1~4 and (C)~0.12；(A1) it is 1.5~6 with the mass ratio (A1/A2) of (A2), and total content (A1+A2) is the mass % of 4 mass %~10；(C) in composition, the dimethyl diallyl ammonium chloride (c1) and the mol ratio (c1 of at least any one (c2) in the acrylic acid and acrylamide：C2 it is) 20：80~70：30, and viscosity of the copolymer solution when solids content is 39 mass %~45 mass % is 1,200mPas~6,000mPas at 25 DEG C；(A) mass ratio (A/C) with (C) is 65~170, and said composition is filled in bubbling container.
Description
Technical field
The present invention relates to liquid skin cleansing composition.
Background technology
In the past, for skin cleaning agent composite used in cleaning finger, it is desirable to for being attached to spot on hand, spy
It is not that greasy soils or fishlike smell that the difficulty brought by the food materials such as the meat in culinary art or fish is washed etc. have good cleaning strength, someone
Various technical schemes in terms of proposing for improveing these.
For example, it is proposed that a kind of technical scheme of finger cleansing composition, the finger cleansing composition contains both sexes
Surfactant and soap, the cleaning strength of greasy soils is excellent and there is soft salubrious flushing to feel to skin, and
And be difficult to remaining stink on hand.(for example, with reference to patent document 1)
In addition, it is also proposed that a kind of technical scheme of skin cleaning agent composite, the skin cleaning agent composite contains aliphatic acid
Or its salt, quaternary ammonium salt and cation property copolymer, when foaming, the exquisiteness (creamy property) of foam and flushing
Flatness (smoothness) with clean after moist feeling (moisten feeling) it is excellent, and can suppress flushing when
Stick-slip sense (slimy feeling), refreshingly clearing skin.(for example, with reference to patent document 2)
In addition, it is proposed that a kind of technical scheme of cleansing composition, the cleansing composition contains higher fatty acid salt, fat
The ethylene oxide adduct of sour single ethanol amide type nonionic surfactant and Semi-polar surfactants so that senior fat
The salubrious sense of fat acid is improved, while foaming properties (foaming characteristic, froth texture (foam quality), foam volume) are excellent.(example
Such as, referring to patent document 3)
However, in skin cleaning agent composite described in above-mentioned prior art literature, due to the high liquid skin of cleaning strength
Skin cleansing composition is main flow, therefore there is following problem：Stimulation to skin is too strong, produces stick-slip sense when rinsing, rises
Bubble trouble, the skin after cleaning produces viscosity.On the other hand, if weakening cleaning for aforesaid liquid skin cleaning agent composite
, then there is following opposite problem in power：The greasy soils or fishlike smell being attached in culinary art on finger can not fully be cleaned.
Accordingly, it is desirable to provide a kind of liquid skin cleansing composition for having both following all properties：Head retention is excellent
It is different, without grease spot, no fishlike smell, stick-slip sense during no flushing, without the excitement to skin, the viscosity of the skin after no flushing
And without the blocking under low temperature environment.
Prior art literature
Patent document
Patent document 1：Japanese Patent Laid-Open 2006-182698 publications
Patent document 2：Japanese Patent Laid-Open 2005-154360 publications
Patent document 3：Japanese Patent Laid-Open 2004-204087 publications
The content of the invention
The invention problem to be solved
The problem of the present invention is the above-mentioned various problems for solving to exist in the past, realizes following purpose.That is, this hair
Bright purpose is to provide a kind of liquid skin cleansing composition for having both following all properties：Head retention is excellent, nothing
Greasy soils, no fishlike smell, no stick-slip sense when rinsing, without to the excitement of skin, the viscosity of the skin after no flushing and
Without the blocking under low temperature environment.In addition, in the present invention, above-mentioned " low temperature environment " means about 5 DEG C.
The method for solving problem
In order to solve above-mentioned problem, as a result the present inventors has found after furtheing investigate repeatedly：In order to improve in culinary art
In be attached to the cleaning strengths of greasy soils or fishlike smell on finger, by allocating alkyl amine oxide compound, be further used in combination
The soap and specific cation property copolymer being made up of laruate and myristate, can obtain following liquid skin
Cleansing composition：To the cleaning strengths of greasy soils or fishlike smell while high also without stick-slip sense when rinsing, it is possible to achieve it is clear
It is refreshing to clean.
Based on above-mentioned discovery, after the present inventor is furtherd investigate, as a result find, following liquid skin remover combination
Thing had both by the cooperative effect of following each compositions excellent head retention, without grease spot, without fishlike smell, without rinse when
Stick-slip sense, without to the excitement of skin, without the skin after flushing viscosity and without under low temperature environment block this all property
Energy：The liquid skin cleansing composition contains the aliphatic acid that (A) is made up of (A1) laruate and (A2) myristate
The mass % of salt, the mass % of (B) alkyl amine oxide compound 1~4 and (C) is containing dimethyl diallyl ammonium chloride and is selected from
The mass % of at least one kind of mass % of copolymer 0.04 in acrylic acid and acrylamide~0.12；The aliphatic acid of above-mentioned (A) composition
The mass ratio (A/C) of salt and the copolymer of above-mentioned (C) composition is 65~170, and the liquid skin cleansing composition is filled in
In bubbling container.
The present invention is completed based on the above-mentioned discovery by the present inventor, is used as the following institute of the method for solving above-mentioned problem
Show.That is,
A kind of liquid skin cleansing compositions of the ＞ of ＜ 1, it is characterised in that
The composition contains：(A) soap, (B) alkyl oxygen being made up of (A1) laruate and (A2) myristate
Change the mass % of amines 1 mass %~4 and (C) containing dimethyl diallyl ammonium chloride and selected from acrylic acid and propylene
The mass % of at least one kind of mass % of copolymer 0.04 in acid amides~0.12；
The mass ratio (A1/A2) of the laruate of above-mentioned (A1) composition and the myristate of above-mentioned (A2) composition is 1.5~6,
And total content (A1+A2) of the laruate of above-mentioned (A1) composition and the myristate of above-mentioned (A2) composition is 4 matter
Measure the mass % of %~10；
In the copolymer of above-mentioned (C) composition, above-mentioned dimethyl diallyl ammonium chloride (c1) and aforesaid propylene acid and acrylamide
In at least any one (c2) mol ratio (c1：C2 it is) 20：80~70：30, and above-mentioned copolymer solution contains in solid
Viscosity when amount is 39 mass %~45 mass % is 1,200mPas~6,000mPas at 25 DEG C；
The mass ratio (A/C) of the soap of above-mentioned (A) composition and the copolymer of above-mentioned (C) composition is 65~170, the combination
Thing is filled in bubbling container.
Liquid skin cleansing compositions of the ＞ of ＜ 2 according to the above-mentioned ＞ of ＜ 1, it is characterised in that the alkyl oxygen of (B) composition
Change amines is lauryl dimethyl amine oxide.
Invention effect
According to the present invention it is possible to solve conventional above-mentioned various problems and realize that above-mentioned purpose is following all there is provided having both
The liquid skin cleansing composition of performance：Head retention is excellent, without grease spot, no fishlike smell, stick-slip during no flushing
Sense, without to the excitement of skin, the viscosity of the skin after no flushing, and without the blocking under low temperature environment.
Embodiment
(liquid skin cleansing composition)
The liquid skin cleansing composition of the present invention contains (A) soap, (B) alkyl amine oxide compound and (C) and contained
There are dimethyl diallyl ammonium chloride and at least one kind of copolymer in acrylic acid and acrylamide, further optionally
Contain other compositions.
＜ (A) soaps ＞
Above-mentioned soap is in order at following purpose and contained：Improve cleaning strength, head retention, without grease spot, without fish
Fishy smell, without rinse when stick-slip sense, without the blocking under low temperature environment and without the excitement to skin.
The soap of above-mentioned (A) composition is made up of (A1) laruate with (A2) myristate.
As above-mentioned (A1) composition laruate and above-mentioned (A2) composition myristate counter ion, for example, can enumerate
Go out：The alkali metal such as sodium, potassium；Triethanolamine etc..Among these, from without grease spot, without fishlike smell, head retention, without flushing
When stick-slip sense and without the blocking under low temperature environment from the point of view of, preferred potassium.
From head retention, without grease spot, without fishlike smell, without stick-slip sense when rinsing, without the blocking under low temperature environment and nothing
From the point of view of the excitement of skin, in terms of the total amount of liquid skin cleansing composition, the laurate of above-mentioned (A1) composition
Total content (A1+A2) of the myristate of salt and above-mentioned (A2) composition is the mass % of 4 mass %~10, preferably 5 matter
Measure the mass % of %~9.
If above-mentioned total content (A1+A2) is less than 4 mass %, there is head retention, without grease spot and without fishlike smell
The situation of reduction, if total content (A1+A2) is more than 10 mass %, it sometimes appear that to the excitement and low temperature of skin
Blocking under environment.
From without stick-slip sense when rinsing, without grease spot, without fishlike smell, head retention and without the excitement to skin
Angle considers that in terms of the total amount of liquid skin cleansing composition, the content of the laruate of above-mentioned (A1) composition is preferably 2.5
The mass % of quality %~8.0 mass %, more preferably 3.4 mass %~7.0.If above-mentioned content is less than 2.5 mass %,
Stick-slip sense is produced during flushing, it sometimes appear that without grease spot and without fishlike smell deterioration, if above-mentioned content be more than 8.0 matter
% is measured, then it sometimes appear that head retention reduction and a problem that to the excitement of skin.
From head retention, without grease spot, without fishlike smell, without stick-slip sense when rinsing and the angle without the blocking under low temperature environment
Degree considers that in terms of the total amount of liquid skin cleansing composition, the content of the myristate of above-mentioned (A2) composition is preferably 0.6
The mass % of quality %~2.5 mass %, more preferably 0.9 mass %~2.0.If above-mentioned content is less than 0.6 mass %, deposit
Head retention, without grease spot and without fishlike smell deteriorate situation, if above-mentioned content be more than 2.5 mass %, sometimes
A problem that blocking under stick-slip sense and low temperature environment when flushing occurs.
From without stick-slip sense when rinsing, without grease spot, without fishlike smell, head retention, without to the excitement of skin and
From the point of view of the blocking under low temperature environment, the myristate of the laruate of above-mentioned (A1) composition and above-mentioned (A2) composition
Mass ratio (A1/A2) be 1.5~6, preferably 2~5.If above-mentioned mass ratio (A1/A2) is less than 1.5, it sometimes appear that
Without stick-slip sense when rinsing, without grease spot, without fishlike smell and without the blocking deterioration under low temperature environment, if above-mentioned mass ratio
(A1/A2) it is more than 6, then it sometimes appear that head retention reduction and a problem that to the excitement of skin.
In addition, there is no particular restriction for the soap of above-mentioned (A) composition, it can be allocated as soap, can also be to tune
Neutralization reaction is brought it about with aliphatic acid and potassium hydroxide, triethanolamine, MEA etc. is added in groove respectively and as fat
Hydrochlorate.
＜ (B) alkyl amine oxide compound ＞
Abovementioned alkyl amine oxide compounds are in order at following purpose and contained：Improve without grease spot, without fishlike smell, without right
The excitement of skin and without rinse when stick-slip sense.
As the alkyl amine oxide compound of above-mentioned (B) composition, for example, alkyl dimethyl amine oxide, dihydroxy second can be included
Base lauryl amine oxide etc..
As abovementioned alkyl dimethyl amine, for example, lauryl dimethyl amine oxide, myristyl dimethyl oxygen can be included
Change amine, cocodimethyl amine oxide, oleyl dimethyl amine oxide etc..These can be used alone, can also 2 kinds with
On be used in combination.
Among these, from without grease spot and without fishlike smell from the point of view of, preferred lauryl dimethyl amine oxide.
From the point of view of from without grease spot, without fishlike smell, without the excitement to skin and without stick-slip sense when rinsing, with liquid
The total amount meter of skin cleaning agent composite, the content of the alkyl amine oxide compound of above-mentioned (B) composition is the matter of 1 mass %~4
Measure %, the mass % of preferably 1 mass %~3.If above-mentioned content be less than 1 mass %, it sometimes appear that without grease spot and
Without fishlike smell reduction, if above-mentioned content is more than 4 mass %, it sometimes appear that stick-slip when excitement to skin and flushing
A problem that sense.
＜ (C) dimethyl diallyl ammonium chlorides and at least one kind of copolymer ＞ in acrylic acid and acrylamide
Above-mentioned at least one kind of containing dimethyl diallyl ammonium chloride and in acrylic acid and acrylamide is used as monomeric unit
Copolymer be following purpose and contain：Improve without stick-slip sense when rinsing, head retention, without under low temperature environment
Block and the viscosity without the skin after flushing.
As the copolymer of above-mentioned (C) composition, the copolymer represented by following formulas (1) is suitable.
[changing 1]
And in above-mentioned formula (1), n, m and z represent the mol ratio of each monomeric unit, n+m+z=100, n is preferably 0~40.M is excellent
Elect 20~70 as.Z is preferably 0~80, and more preferably 0~76.Come from addition, the copolymer represented by above-mentioned formula (1) is included
In n unit of acrylic acid and the z unit from acrylamide at least any one.
The copolymer represented by above-mentioned formula (1) can be by making in following monomer B and following monomer A and following monomer C
At least any one copolymerization and synthesize.
As above-mentioned monomer A, the acrylic acid (AA) represented by following structural formula can be included.
[changing 2]
As above-mentioned monomer B, the dimethyl diallyl ammonium chloride (DADMAC) represented by following structural formula can be included.
[changing 3]
As above-mentioned monomer C, the acrylamide (AM) represented by following structural formula can be included.
[changing 4]
In the copolymer of above-mentioned (C) composition, (c1) dimethyl diallyl ammonium chloride and (c2) acrylic acid and acryloyl
At least mol ratio (the c1 of any one in amine：C2 it is) 20：80~70：30, preferably 20：80~35：65.If above-mentioned diformazan
Base diallyl ammonium chloride is less than 20 moles relative at least ratio of any one in aforesaid propylene acid and acrylamide, then
It sometimes appear that stick-slip sense is produced when rinsing, if the ratio is more than 70 moles, it sometimes appear that head retention variation,
Blocking is produced when using at low ambient temperatures.
The ratio of each monomeric unit in above-mentioned (C) composition can be by nuclear magnetic resonance (NMR) under following measuring conditions
Measure.
[measuring condition]
Solvent：Heavy water (D2O)
Measuring instrument：JNM-LA300 (300MH, Jeol Ltd.'s manufacture)
There is no particular restriction for the weight average molecular weight of the copolymer of above-mentioned (C) composition, can suitably be selected according to purpose,
But from the point of view of from head retention and without stick-slip sense when rinsing, preferably 100,000~1,000,000, more preferably
100,000~500,000.If above-mentioned weight average molecular weight is less than 100,000, then it sometimes appear that producing stick-slip when rinsing
Sense, if above-mentioned weight average molecular weight is more than 1,000,000, then it sometimes appear that head retention is reduced.
The weight average molecular weight of the copolymer of above-mentioned (C) composition can for example pass through SEC-MALLS-RI system (measuring conditions：Chromatogram
Post：The TSKgel α series α-M chromatographic columns 30cm of TOSOH Co., Ltd's manufacture；Solvent：The sodium nitrate 0.3M aqueous solution) it is measured.
From the point of view of from head retention and without stick-slip sense when rinsing, the copolymer solution of above-mentioned (C) composition is solid
Viscosity when body content is 39 mass %~45 mass % is 1,200mPas~6,000mPas at 25 DEG C.In addition, on
It is preferably 1 at 25 DEG C to state viscosity of the copolymer solution of (C) composition when solids content is 41 mass %~45 mass %,
200mPas~4,500mPas.In addition, the copolymer solution of above-mentioned (C) composition is the matter of 39 mass %~43 in solids content
Viscosity when measuring % is preferably 3,000mPas~6,000mPas at 25 DEG C, more preferably 1,200mPas~4,
500mPa·s。
If above-mentioned viscosity is less than 1,200mPas, then it sometimes appear that stick-slip sense is produced when rinsing, if above-mentioned viscosity is big
In 6,000mPas, then it sometimes appear that head retention is reduced.
Above-mentioned viscosity can for example use Brookfield viscosimeters RVF (manufacture of Brookfield companies) or Brookfield to glue
Degree meter LVF (manufacture of Brookfield companies) is measured.
As the copolymer of above-mentioned (C) composition, commercially available product can be used, as the commercially available product, following material can be included
Deng.
(the Components Names of Merquat 3940：Acrylic acid dimethyl diallyl ammonium chloride acrylamide copolymer；
Display Name：Polyquaternium -39 (Polyquaternium-39), the manufacture of Lu Borun (Lubrizol) company, solids content：41
The mass % of quality %~45, the viscosity at 25 DEG C：1,500mPas~4,500mPas, weight average molecular weight：150,000,
N in above-mentioned formula (1)：m：Z=31：29：40, mol ratio (c1：C2)=29：71)：Above-mentioned viscosity can for example be used
Brookfield Digital Viscometers RVF (manufacture of Brookfield companies), the turning using main shaft (spindle) 3 at 25 DEG C
Sub (Rotor) is measured under conditions of 60 revs/min.
(the Components Names of Merquat 280：Acrylic acid dimethyl diallyl ammonium chloride copolymer；Display Name：It is poly-
Quaternary ammonium salt -22 (Polyquaternium-22), Lubrizol Corp.'s manufacture, solids content：The mass % of 39 mass %~43, viscosity：
3,000mPas~6,000mPas, weight average molecular weight：450,000, the n in above-mentioned formula (1)：m：Z=35：65：0, rub
You are than (c1：C2)=65：35)：Above-mentioned viscosity can for example use Brookfield Digital Viscometers LVF, and (Brookfield is public
Department's manufacture), be measured using the rotor of main shaft 4, under conditions of 60 revs/min at 25 DEG C.
(above-mentioned Merquat 280 low pH types, do not contain anti-corrosion formulation, Components Name to Merquat 281：Propylene
Sour dimethyl diallyl ammonium chloride copolymer, display Name：Merquat 280 (Polyquaternium-22), Lu Borun
Company manufactures, solids content：The mass % of 39 mass %~43, viscosity：4,000mPas~15,000mPas, Weight-average molecular
Amount：450,000)：Above-mentioned viscosity can for example use Brookfield Digital Viscometers LVF (manufacture of Brookfield companies),
It is measured at 25 DEG C using the rotor of main shaft 4, under conditions of 60 revs/min.
(the Components Names of Merquat 740：Dimethyl diallyl ammonium chloride acrylamide copolymer；Display Name：
Polyquaternium -7 (Polyquaternium-7), Lubrizol Corp.'s manufacture, solids content：The mass % of 41 mass %~45,25
Viscosity at DEG C：1,200mPas~4,500mPas, weight average molecular weight：120,000, the n in above-mentioned formula (1)：m：Z=
0：24：76, mol ratio (c1：C2)=24：76)：Above-mentioned viscosity can for example use Brookfield Digital Viscometers RVF
(manufacture of Brookfield companies), it is measured using the rotor of main shaft 3, under conditions of 60 revs/min at 25 DEG C.
Salcare Super 7AT1 (display Names：Polyquaternium -7 (Polyquaternium-7), BASF AG's system
Make, solids content：The mass % of 39 mass %~41, viscosity：3,500mPas~6,000mPas, weight average molecular weight：150,
000, the n in above-mentioned formula (1)：m：Z=0：25：75, mol ratio (c1：C2)=25：75)：Above-mentioned viscosity can for example be used
Brookfield Digital Viscometers RVF (manufacture of Brookfield companies), at 25 DEG C using main shaft 3 rotor, 10 turns/
It is measured under conditions of minute.
Among these, from the point of view of without stick-slip sense when rinsing, the suitable mol ratio using in above-mentioned formula (1)
(n：m：Z)=0：24：76th, solids content is that the mass % of 41 mass %~45, the viscosity at 25 DEG C are 1,200mPas~4,
500mPas Merquat 740 (polyquaternium -7).
In addition, above-mentioned " polyquaternium -39 ", above-mentioned " Merquat 280 " and above-mentioned " polyquaternium -7 " is Japanese cosmetic work
Composition display Name as defined in industry federation.
From without stick-slip sense when rinsing, head retention, the viscosity without the skin after flushing and without stifled under low temperature environment
From the point of view of plug, in terms of the total amount of liquid skin cleansing composition, the content of the copolymer of above-mentioned (C) composition is 0.04 matter
Measure the mass % of %~0.12 mass %, preferably 0.05 mass %~0.1.If above-mentioned content is less than 0.04 mass %, have
When occur during flushing stick-slip sense and head retention a problem that reduce, if above-mentioned content is more than 0.12 mass %,
Then it sometimes appear that rinse after skin viscosity and low temperature environment under blocking a problem that.
＜ mass ratioes (A/C) ＞
From without the viscosity after cleaning, without grease spot, without fishlike smell, without stick-slip sense when rinsing and without the excitement to skin
Angle consideration, the content (quality %) of the soap of above-mentioned (A) composition and the content (matter of the copolymer of above-mentioned (C) composition
Measure %) mass ratio (A/C) be 65~170, preferably 67~150.If above-mentioned mass ratio (A/C) is less than 65, sometimes
There is the viscosity of skin after rinsing, without grease spot and without fishlike smell reduction, if the mass ratio is more than 170, sometimes
Stick-slip sense when rinsing and the excitement to skin.
The other composition ＞ of ＜
, can also be in addition to above-mentioned (A)~above-mentioned (C) each composition in the liquid skin cleansing composition of the present invention
Other compositions are optionally allocated in the range of the effect for not undermining the present invention.
As above-mentioned other compositions, for example, it can include：It is the alcohols such as water, oil component, silicone, lower alcohol or higher alcohol, polynary
Medicament, bactericide, preservative, the hydrogen such as alcohols, lanolin derivative, protein derivatives, acrylic resin dispersion liquid, vitamin
The pH adjusting agents such as potassium oxide, citric acid, hydrochloric acid, triethanolamine, antioxidant, metal-chelator, ultra-violet absorber, animals and plants
The chelating agents such as extract or derivatives thereof, ethylenediamine tetra-acetic acid, pigment, spices, pigment, inorganic particle, clay mineral, nylon,
Water-insoluble high-molecular compound powder such as polyethylene etc..These can be used alone, can also two or more be used in combination.
The manufacture method ＞ of ＜ liquid skin cleansing compositions
As the manufacture method of aforesaid liquid skin cleaning agent composite, it is not particularly limited, can be suitably carried out according to purpose
Selection, for example can by above-mentioned (A) composition, above-mentioned (B) composition and above-mentioned (C) composition, and further optionally it is above-mentioned its
Its composition is mixed and manufactured.Preferably, the water in above-mentioned other compositions is mixed into as surplus, so that whole aforesaid liquids
Skin cleaning agent composite is changed into 100 mass %.
Aforesaid liquid skin cleaning agent composite can also be used and is modulated.As said apparatus, it is not particularly limited, can be with
Suitably selected, for example, can be included equipped with the stirring with shearing force and the agitating paddle that can integrally mix according to purpose
Device etc..
As above-mentioned agitating paddle, and be not particularly limited, can suitably be selected according to purpose, can for example include propeller,
Turbine, disperser etc..
The present invention liquid skin cleansing composition be filled in bubbling container, spued with blister, the liquid of leave
Body skin cleaning agent composite.Due to being blister, so used than gel or the easy of spray form, can be in the feelings without water
Simply sterilized and cleaned under condition.Possesses leave liquid skin cleansing composition, with being equipped with furthermore it is also possible to be made
The Bactericidal cleaner product of the liquid skin cleansing composition and the bubbling container spued with blister.
Above-mentioned leave refers to, the liquid skin cleansing composition of blister is taken in hand, is being spread out in sterilization
Clean object such as hand, whole body on skin after, be rinsed and use without water etc..As above-mentioned application method, have no
It is particularly limited to, can be suitably selected according to purpose, following methods can be included：For several times, 1g is taken with blister in appropriate amount within 1st
~15g is on hand, making it throughout sterilizing peace and quiet object such as hand, whole body.
＜ bubbling containers ＞
As above-mentioned bubbling container, apneumatic pattern foam discharge container can be included.As above-mentioned apneumatic pattern foam discharge container, only
Aforesaid liquid skin cleaning agent composite can be mixed with air, be spued, be not particularly limited with foamed state, can
Suitably to be selected according to purpose, for example, it can include the extruding foaming appearance for the foam that can be spued by using hand extruding body portion
Device, the pump bubbling container for the foam that can be spued by pressing nozzle portion etc..As such bubbling container, for example, it can use big
Manufactured with Zhi Guan Co., Ltd., the container etc. of Yoshino Kogyosho Co., Ltd's manufacture.
Above-mentioned apneumatic pattern foam discharge container generally have formed foam Porous film body (material be preferably nylon, polyester,
The plastic materials such as polyolefin), its liquid skin cleansing composition is by the Porous film body so as to form foam.As above-mentioned
The sieve mesh (mesh) of Porous film body, is not particularly limited, and can suitably be selected according to purpose, for example preferably 100 mesh
More than, more than more preferably 100 mesh below 400 mesh, more than more preferably 200 mesh below 350 mesh.
As the number of above-mentioned Porous film body, it is not particularly limited, can be suitably selected according to purpose, from raising foam
From the point of view of performance, preferably 2~4.More specifically, Japanese Patent Laid-Open 7- can suitably be used
No. 315463 publications, Japanese Patent Laid-Open 8-230961 publications and Japanese Patent Laid-Open 2005-193972 publications
Described in bubbling container.
- viscosity-
Aforesaid liquid skin cleaning agent composite use by Pressing pump can spue foam pump bubbling container and 2 200
During mesh, there is no particular restriction for the viscosity of the aforesaid liquid skin cleaning agent composite under the temperature conditionss used, can be according to mesh
Appropriate selection, and the viscosity at 25 DEG C is preferably 1mPas~20mPas, more preferably 1mPas~10mPas.
Above-mentioned viscosity can for example be carried out as follows measure：Using BL types viscosimeter (Co., Ltd.'s Tokyo gauge is manufactured) in sample temperature
At 25 DEG C of degree, in the case where above-mentioned viscosity is less than 10mPas, 1 is determined with BL adapters (adapter), rotating speed 60rpm
Viscosity after minute, and in the case where above-mentioned viscosity is 10mPas~20mPas, surveyed with rotor 1, rotating speed 60rpm
Viscosity after fixed 1 minute.
-pH-
From the point of view of from head retention, without grease spot and without fishlike smell, the pH of aforesaid liquid skin cleaning agent composite
Preferably 9.5~11.0, more preferably 9.8~10.6.
Above-mentioned pH for example can be in medicine part outer article raw material specification 2006 ordinary test method pH mensurations, at 25 DEG C
It is measured.
＜ purposes ＞
As the liquid skin cleansing composition of the present invention, because it has both excellent head retention, without grease spot, without fish
Fishy smell, without stick-slip sense when rinsing, without the viscosity to the excitement of skin, without the skin after flushing and without stifled under low temperature environment
This all properties is filled in, so can for example be suitably used for bath soap, hand soaps, foam hand soaps, liquid hand soap, face cleaning production
Product, hand soaps for kitchen use etc..
Embodiment
Hereinafter, the present invention is specifically described by enumerating embodiments of the invention, but the invention is not limited in this
A little embodiments.In addition, the content of each composition is the value for being converted into sterling.
(embodiment 1~32 and comparative example 1~19)
- modulation of liquid skin cleansing composition-
Modulate and be made up of each shown in following tables and embodiment 1~32 and ratio that amount (quality %) is constituted according to conventional method
Compared with the liquid skin cleansing composition (hand soaps) of example 1~19.Using potassium hydroxide by each liquid skin cleansing composition
PH (25 DEG C) be adjusted to 10.In addition, the pH mensurations of ordinary test methods of the pH in medicine part outer article raw material specification 2006,
It is measured at 25 DEG C.
- making of container dress liquid skin cleansing composition-
Each liquid skin cleansing composition of the embodiment 1~32 obtained and comparative example 1~18 is filled in and pumps up bubble appearance
Device (a) [net：200 2, mesh, Yoshino Kogyosho Co., Ltd is manufactured (with Japanese Patent Laid-Open 2005-193972 publications
The pump used in embodiment 2 is identical)] in, pump bubbling container dress liquid skin cleansing composition is made.By the liquid of comparative example 19
Body skin cleaning agent composite is filled in the container (b) with distributor (dispenser), and [discharge-amount 1mL, nozzle diameter is (interior
Footpath) 3.5mm, the manufacture of Canyon Co., Ltd.] in, make the container dress liquid skin cleansing composition with distributor.
- evaluate-
Then, liquid skin cleansing composition is filled for each container obtained, according to as follows, evaluates " without grease dirt
Stain ", " no fishlike smell ", " head retention ", while rinsing " no stick-slip sense ", " without the excitement to skin ", " after no flushing
The viscosity of skin " and " blocking under no low temperature environment ".Result is remembered in the following table in the lump.
＜ without grease spots ＞
10 star's butter 1g of professional judging panel (male 2, women 8) fill two hands, are soaked with water after two hands, and each container is filled into liquid
1 pressing (about 1g) of body skin cleaning agent composite is taken in hand, after mutually rubbing hands 20 seconds, uses the flowing water of 2L flow velocitys per minute
After (25 DEG C) are rinsed 1 minute, according to following metewand evaluations " without grease spot ".As a result the scoring of professional judging panel 10 is asked for
Average value, is judged according to following determinating references.
[metewand]
4 points：The viscosity of greasy soils is not felt completely
3 points：Although feeling and being somewhat attached with greasy soils, acceptable degree
2 points：Somewhat feel the viscosity of greasy soils
1 point：Feel the viscosity of greasy soils
[determinating reference]
◎：More than 3.5 points, less than 4.0 points
○：More than 3.0 points, less than 3.5 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
＜ is without fishlike smell ＞
Live fish (mackerel piece) 1g is spread out full two hands by professional judging panel 10 (male 2, women 8), is soaked with water after two hands, will be each
1 pressing (about 1g) of container dress liquid skin cleansing composition is taken in hand, after mutually rubbing hands 20 seconds, is flowed using 2L per minute
The flowing water (25 DEG C) of speed is rinsed 1 minute, after towel, is heard in two fishlike smell remained on hand, is evaluated according to following
Benchmark evaluation " no fishlike smell ".As a result the grade average of 10 professional judging panels is asked for, is judged according to following determinating references.
[metewand]
5 points：Fishlike smell is not felt completely
4 points：Extremely slightly feel fishlike smell
3 points：Although somewhat feeling fishlike smell, the degree having no problem
2 points：Feel fishlike smell
1 point：Fishlike smell is not almost removed
[determinating reference]
◎：More than 4.0 points, less than 5.0 points
○：More than 3.0 points, less than 4.0 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
＜ head retentions ＞
Each container is filled 1 pressing of liquid skin cleansing composition (about by professional judging panel 10 (male 2, women 8)
1g) it is taken in hand, by the foam volume after just mutually rubbing hands 10 times with mutually rubbing the bubble after being stood again 10 seconds after two hand 10 times with the hands
Foam amount is compared, and " head retention " is judged according to following metewands.As a result the scoring for asking for 10 professional judging panels is averaged
Value, is judged according to following determinating references.
[metewand]
5 points：Foam volume does not change completely
4 points：Foam volume has almost no change
3 points：Foam volume is somewhat reduced
2 points：Foam volume is reduced a considerable amount ofly
1 point：On hand without residual foam
[determinating reference]
◎：More than 4.0 points, less than 5.0 points
○：More than 3.0 points, less than 4.0 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
＜ is without stick-slip sense ＞ when rinsing
Each container is filled liquid skin remover group by professional judging panel 10 (male 2, women 8) after two hands are soaked with water
1 pressing (about 1g) of compound is taken in hand, is mutually rubbed two hands with the hands after 20 seconds, is rushed using the flowing water (25 DEG C) of 2L flow velocitys per minute
Wash after 1 minute, according to following metewand evaluations " stick-slip sense during no flushing ".As a result the scoring for asking for 10 professional judging panels is put down
Average, is judged according to following determinating references.
[metewand]
5 points：Stick-slip sense during flushing is not felt completely
4 points：Extremely slightly feel stick-slip sense during flushing
3 points：Although somewhat feeling stick-slip sense during flushing, the degree having no problem
2 points：Feel stick-slip sense during flushing
1 point：Stick-slip sense during flushing is not almost removed
[determinating reference]
◎：More than 4.0 points, less than 5.0 points
○：More than 3.0 points, less than 4.0 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
＜ is without the excitement ＞ to skin
Feel oneself be sensitive flesh professional judging panel 10 (male 2, women 8) by each container fill liquid skin remover group
1 pressing (about 1g) of compound is taken in hand, is mutually rubbed two hands with the hands after 10 seconds, is rushed using the flowing water (25 DEG C) of 2L flow velocitys per minute
Wash 1 minute, after towel, evaluate burning sensation according to following metewands or itch etc. " without the stimulation to skin
Sense ".As a result the grade average of 10 professional judging panels is asked for, is judged according to following determinating references.
[metewand]
5 points：The excitement to skin is not felt completely
4 points：The excitement to skin is not almost felt
3 points：Somewhat feel the excitement to skin
2 points：Slightly feel the excitement to skin
1 point：The strong excitement felt to skin
[determinating reference]
◎：More than 4.5 points, less than 5.0 points
○：More than 4.0 points, less than 4.5 points
△：More than 3.0 points, less than 4.0 points
×：Less than 3.0 points
Sticky ＞s of the ＜ without the skin after flushing
Each container is filled 1 pressing of liquid skin cleansing composition (about by professional judging panel 10 (male 2, women 8)
1g) it is taken in hand, mutually rubs two hands with the hands after 10 seconds, 1 minute, towel are rinsed using the flowing water (25 DEG C) of 2L flow velocitys per minute
Afterwards, according to following metewand evaluations " viscosity of the skin after no flushing ".As a result the scoring for asking for 10 professional judging panels is averaged
Value, is judged according to following determinating references.
[metewand]
5 points：The viscosity of skin is not felt completely
4 points：The viscosity of skin is not almost felt
3 points：Although extremely slightly feeling the viscosity of skin, the degree having no problem
2 points：Feel the viscosity of skin
1 point：Greatly feel the viscosity of skin
[determinating reference]
◎：More than 4.0 points, less than 5.0 points
○：More than 3.0 points, less than 4.0 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
＜ is without the blocking ＞ under low temperature environment
Each liquid skin cleansing composition of embodiment 1~33 and comparative example 1~18 is filled in pump bubbling container (a),
It is each to make 5 bottles of pump bubbling container dress liquid skin cleansing compositions for each liquid skin cleansing composition.In addition,
In comparative example 19, make the 5 bottles of container with distributor being filled in the container (b) with distributor dress liquid skins and clean
Agent composition.
At 5 DEG C, above-mentioned each pump bubbling container is filled into each liquid skin cleansing composition and above-mentioned each dispenser container fills liquid
Body skin cleaning agent composite is preserved 1 month in the dark.During preservation, with the ratio of 1 week 1 time, No. 5 pump bubbling containers of pressing
The pump of pump or container with distributor, on the easy pressing of the pump of the 1st time, 1 professional judging panel is according to following evaluation bases
Standard is evaluated.As a result the grade average of 1 month is asked for, is judged based on following determinating references.In addition, if above-mentioned
Exist in sieve mesh in pump bubbling container and block, then the action of pump becomes heavy, it becomes difficult to press.
[metewand]
5 points：Can extremely swimmingly Pressing pump
4 points：Can swimmingly Pressing pump
3 points：Can somewhat swimmingly Pressing pump
2 points：Pump is heavy, may only somewhat press
1 point：Can not Pressing pump
[determinating reference]
◎：More than 4.0 points, less than 5.0 points
○：More than 3.0 points, less than 4.0 points
△：More than 2.0 points, less than 3.0 points
×：Less than 2.0 points
[table 1]
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
[table 8]
[table 9]
[table 10]
[table 11]
(embodiment 33)
Hereinafter, the suitable allotment embodiment of display liquid skin cleansing composition (hand soaps).
[table 12]
In addition, the composition used in the liquid skin cleansing composition of embodiment 1~33 and comparative example 1~19 is specific
Content is as shown in following tables 13 and table 14.
[table 13]
- (C) composition and (C) compare composition-
[table 14]
*1：Brookfield viscosimeters RVF (manufacture of Brookfield companies), main shaft No. 3,60 revs/min, 25 DEG C
*2：Brookfield viscosimeters RVF (manufacture of Brookfield companies), main shaft No. 4,60 revs/min, 25 DEG C
Industrial utilizability
The liquid skin cleansing composition of the present invention, because it has both excellent head retention, without grease spot, without fish
Fishy smell, without stick-slip sense when rinsing, without the viscosity to the excitement of skin, without the skin after flushing and without stifled under low temperature environment
The all properties of plug, so for example suitably as body soap, hand soaps, foam hand soaps, liquid hand soap, face cleaning product, kitchen
Room hand soaps etc..
Claims (2)
1. a kind of liquid skin cleansing composition, it is characterised in that
The composition contains：(A) soap being made up of (A1) laruate and (A2) myristate, (B) alkyl oxygen
Change the mass % of amines 1 mass %~4, and (C) is containing dimethyl diallyl ammonium chloride and selected from acrylic acid and propylene
The mass % of at least one kind of mass % of copolymer 0.04 in acid amides~0.12；
The mass ratio of the laruate of (A1) composition and the myristate of (A2) composition is that A1/A2 is 1.5~6,
And total content (A1+A2) of the laruate of (A1) composition and the myristate of (A2) composition is 4 matter
Measure the mass % of %~10；
In the copolymer of (C) composition, the dimethyl diallyl ammonium chloride (c1) and the acrylic acid and acrylamide
In the mol ratio of at least any one (c2) be c1：C2 is 20：80~70：30, and the copolymer solution contains in solid
Viscosity when amount is 39 mass %~45 mass % is 1,200mPas~6,000mPas at 25 DEG C；
The mass ratio of the soap of (A) composition and the copolymer of (C) composition is that A/C is 65~170,
The composition is filled in bubbling container.
2. liquid skin cleansing composition according to claim 1, it is characterised in that the alkyl amine oxide of B component
Compound is lauryl dimethyl amine oxide.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014262272 | 2014-12-25 | ||
| JP2014-262272 | 2014-12-25 | ||
| PCT/JP2015/080081 WO2016103892A1 (en) | 2014-12-25 | 2015-10-26 | Liquid skin cleansing agent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107106436A true CN107106436A (en) | 2017-08-29 |
| CN107106436B CN107106436B (en) | 2020-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580070724.6A Active CN107106436B (en) | 2014-12-25 | 2015-10-26 | Liquid skin cleansing composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6739349B2 (en) |
| KR (1) | KR102448653B1 (en) |
| CN (1) | CN107106436B (en) |
| MY (1) | MY194702A (en) |
| WO (1) | WO2016103892A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111093608A (en) * | 2017-09-19 | 2020-05-01 | 株式会社资生堂 | Cleaning agent composition |
| CN111295179A (en) * | 2017-11-16 | 2020-06-16 | 狮王株式会社 | Liquid skin cleanser composition |
| CN113661232A (en) * | 2019-04-12 | 2021-11-16 | 狮王株式会社 | Liquid skin detergent composition |
| CN117279611A (en) * | 2021-06-16 | 2023-12-22 | 狮王株式会社 | Liquid skin cleanser composition |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY192590A (en) * | 2016-05-31 | 2022-08-29 | Lion Corp | Liquid skin-cleansing agent composition |
| JP7291009B2 (en) * | 2019-06-14 | 2023-06-14 | ライオン株式会社 | Liquid skin cleanser composition |
| JP2021107355A (en) * | 2019-12-27 | 2021-07-29 | 日油株式会社 | Cleaning agent composition for foamer |
| JP7463038B2 (en) | 2020-05-21 | 2024-04-08 | 株式会社マンダム | Liquid skin cleansing composition |
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|---|---|---|---|---|
| JPH0753991A (en) * | 1993-08-09 | 1995-02-28 | New Japan Chem Co Ltd | Liquid detergent composition |
| WO2014003114A1 (en) * | 2012-06-29 | 2014-01-03 | ライオン株式会社 | Liquid skin cleanser product |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4114054B2 (en) | 2002-12-26 | 2008-07-09 | ライオン株式会社 | Cleaning composition |
| JP2005154360A (en) | 2003-11-27 | 2005-06-16 | Lion Corp | Skin cleansing agent composition |
| JP4812298B2 (en) | 2004-12-27 | 2011-11-09 | ライオン株式会社 | Hand cleaning composition |
| JP2007146029A (en) * | 2005-11-29 | 2007-06-14 | Lion Corp | Detergent composition |
| JP5071631B2 (en) * | 2006-06-26 | 2012-11-14 | ライオン株式会社 | Solid detergent composition |
| JP5502408B2 (en) * | 2009-09-17 | 2014-05-28 | ライオン株式会社 | Shampoo composition |
| JP2014009195A (en) * | 2012-06-29 | 2014-01-20 | Lion Corp | Liquid skin-cleansing agent product |
| JP2014076975A (en) * | 2012-10-12 | 2014-05-01 | Lion Corp | Skin detergent composition |
| JP6162066B2 (en) * | 2013-03-29 | 2017-07-12 | ライオン株式会社 | Skin cleanser composition in former container |
-
2015
- 2015-10-26 WO PCT/JP2015/080081 patent/WO2016103892A1/en active Application Filing
- 2015-10-26 JP JP2016565990A patent/JP6739349B2/en active Active
- 2015-10-26 MY MYPI2017702142A patent/MY194702A/en unknown
- 2015-10-26 CN CN201580070724.6A patent/CN107106436B/en active Active
- 2015-10-26 KR KR1020177007860A patent/KR102448653B1/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0753991A (en) * | 1993-08-09 | 1995-02-28 | New Japan Chem Co Ltd | Liquid detergent composition |
| WO2014003114A1 (en) * | 2012-06-29 | 2014-01-03 | ライオン株式会社 | Liquid skin cleanser product |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111093608A (en) * | 2017-09-19 | 2020-05-01 | 株式会社资生堂 | Cleaning agent composition |
| CN111093608B (en) * | 2017-09-19 | 2023-05-30 | 株式会社资生堂 | Cleaning agent composition |
| CN111295179A (en) * | 2017-11-16 | 2020-06-16 | 狮王株式会社 | Liquid skin cleanser composition |
| CN111295179B (en) * | 2017-11-16 | 2023-09-26 | 狮王株式会社 | Liquid skin cleanser composition |
| CN113661232A (en) * | 2019-04-12 | 2021-11-16 | 狮王株式会社 | Liquid skin detergent composition |
| CN117279611A (en) * | 2021-06-16 | 2023-12-22 | 狮王株式会社 | Liquid skin cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107106436B (en) | 2020-10-27 |
| WO2016103892A1 (en) | 2016-06-30 |
| MY194702A (en) | 2022-12-15 |
| JP6739349B2 (en) | 2020-08-12 |
| KR20170098791A (en) | 2017-08-30 |
| KR102448653B1 (en) | 2022-09-29 |
| JPWO2016103892A1 (en) | 2017-10-05 |
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