CN107103834A - A kind of foldable label material - Google Patents

A kind of foldable label material Download PDF

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Publication number
CN107103834A
CN107103834A CN201710162231.6A CN201710162231A CN107103834A CN 107103834 A CN107103834 A CN 107103834A CN 201710162231 A CN201710162231 A CN 201710162231A CN 107103834 A CN107103834 A CN 107103834A
Authority
CN
China
Prior art keywords
parts
layer
glue layer
bisphenol
epoxy resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710162231.6A
Other languages
Chinese (zh)
Inventor
舒杰广
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU SIP HI-TECH PRECISION ELECTRONICS Co Ltd
Original Assignee
SUZHOU SIP HI-TECH PRECISION ELECTRONICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU SIP HI-TECH PRECISION ELECTRONICS Co Ltd filed Critical SUZHOU SIP HI-TECH PRECISION ELECTRONICS Co Ltd
Priority to CN201710162231.6A priority Critical patent/CN107103834A/en
Publication of CN107103834A publication Critical patent/CN107103834A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive
    • G09F2003/0233Resistance to humidity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Epoxy Resins (AREA)

Abstract

The present invention discloses a kind of foldable label material, it include release layer, formed the release layer any surface tack coat, formed another surface of the tack coat the first false proof layer, formed the described first false proof layer surface substrate layer and formed the base material layer surface the second false proof layer, the tack coat includes the first glue layer and the second glue layer being disposed adjacent, the material of the substrate layer is PET, and the adhesion strength of second glue layer is more than the adhesion strength of first glue layer.The foldable label material of the present invention, by being arranged to glue layer to include the first glue layer and the second glue layer, can so utilize the difference of different glue layer cohesive forces, realize being partially stripped and folding for label material, simple in construction, cost is relatively low, simple production process.

Description

A kind of foldable label material
Technical field
The present invention relates to a kind of label material, and in particular to a kind of foldable label material.
Background technology
Folding tag is the information bar formed by the paper folded along two vertical directions.Letter is printed on this paper Breath, these information are probably the information relevant with drug products or medicinal material.Folding tag is probably the top for sticking to medicament reservoir In portion or side, the carton that holding medicine container can also be loosely inserted into.After consumer's purchase drug products, Ke Yizhan Open foldable label, to read the information being printed thereon.With developing rapidly for science and technology, folding tag has also obtained technology Improve, but present label dry glue is slow, water proofing property is poor, not foldable, without effect of heat insulation;And label construction is complicated, material Material is expensive, brings very inconvenient to user.
The content of the invention
For above-mentioned technical deficiency, it is an object of the invention to provide a kind of foldable label material.
In order to solve the above technical problems, the present invention is adopted the following technical scheme that:A kind of foldable label material, it include from Type layer, formed the release layer any surface tack coat, formed another surface of the tack coat the first false proof layer, shape Into the substrate layer in the described first false proof layer surface and formation in the second false proof layer of the base material layer surface, the tack coat Including the first glue layer and the second glue layer being disposed adjacent, the material of the substrate layer is PET, second glue layer it is viscous Knotting strength is more than the adhesion strength of first glue layer.
Optimally, second glue layer includes the component of following parts by weight:
30-50 parts of bisphenol A type epoxy resin;
10-30 parts of bisphenol f type epoxy resin;
5-10 parts of triphenylmethane triisocyanate;
1-5 parts of aerosil;
1-5 parts of Boron Trifluoride Ethylamine;
1-5 parts of silane coupler kh550.
Further, first glue layer includes the component of following parts by weight:
30-50 parts of bisphenol A type epoxy resin;
10-30 parts of bisphenol f type epoxy resin;
5-10 parts of triphenylmethane triisocyanate;
1-5 parts of aerosil.
The beneficial effects of the present invention are:The foldable label material of the present invention, by being arranged to glue layer to include first Glue layer and the second glue layer, can so utilize the difference of different glue layer cohesive forces, realize being partially stripped for label material And folding, simple in construction, cost is relatively low, simple production process.
Brief description of the drawings
Fig. 1 is the structural representation of foldable label material of the invention.
Embodiment
The present invention is described in detail below with reference to shown embodiment:
Embodiment 1
The present embodiment provides a kind of foldable label material, as shown in figure 1, it includes release layer 1, formed in release layer 1 The tack coat 2 of any surface, formed another surface of tack coat 2 the first false proof layer 3, formed on the surface of the first false proof layer 3 Substrate layer 4 and the second false proof layer 5 on the surface of substrate layer 4 is formed, tack coat 2 includes the He of the first glue layer 21 that is disposed adjacent Second glue layer 22, the material of substrate layer 4 is PET, and the adhesion strength of the second glue layer 22 is more than the bonding of the first glue layer 21 Intensity.
Wherein, the second glue layer 22 includes the component of following parts by weight:
30 parts of bisphenol A type epoxy resin (E12);
30 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
10 parts of triphenylmethane triisocyanate;
5 parts of aerosil (average grain diameter 200nm);
5 parts of Boron Trifluoride Ethylamine;
5 parts of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
30 parts of bisphenol A type epoxy resin (E12);
30 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
10 parts of triphenylmethane triisocyanate;
5 parts of aerosil (average grain diameter 200nm).
Embodiment 2
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 1, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
50 parts of bisphenol A type epoxy resin (E12);
10 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
5 parts of triphenylmethane triisocyanate;
1 part of aerosil (average grain diameter 200nm);
1 part of Boron Trifluoride Ethylamine;
1 part of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
50 parts of bisphenol A type epoxy resin (E12);
10 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
5 parts of triphenylmethane triisocyanate;
1 part of aerosil (average grain diameter 200nm).
Embodiment 3
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 1, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm);
2 parts of Boron Trifluoride Ethylamine;
2 parts of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm).
Comparative example 1
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 3, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of methyl diphenylene diisocyanate;
3 parts of aerosil (average grain diameter 200nm);
2 parts of Boron Trifluoride Ethylamine;
2 parts of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of methyl diphenylene diisocyanate;
3 parts of aerosil (average grain diameter 200nm).
Comparative example 2
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 3, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
3 parts of aerosil (average grain diameter 200nm);
2 parts of Boron Trifluoride Ethylamine;
2 parts of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
3 parts of aerosil (average grain diameter 200nm).
Comparative example 3
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 3, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm);
2 parts of silane coupler kh550.
First glue layer 21 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm).
Comparative example 4
The present embodiment provides a kind of foldable label material, and its structure is consistent with embodiment 3, unlike:First The component of the glue layer 22 of glue layer 21 and second is inconsistent, is specially:
Second glue layer 22 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm);
2 parts of Boron Trifluoride Ethylamine.
First glue layer 21 includes the component of following parts by weight:
40 parts of bisphenol A type epoxy resin (E12);
20 parts of bisphenol f type epoxy resin (Chongqing forever magnificent chemical industry);
8 parts of triphenylmethane triisocyanate;
3 parts of aerosil (average grain diameter 200nm).
Foldable label material made from embodiment 1-3, comparative example 1-4 is carried out forming test, its result is listed in table 1 In.
The performance test table of foldable label material made from the embodiment 1-3 of table 1, comparative example 1-4
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all according to the present invention The equivalent change or modification that spirit is made, should all be included within the scope of the present invention.

Claims (3)

1. a kind of foldable label material, it includes release layer(1), formed in the release layer(1)The tack coat of any surface (2), formed in the tack coat(2)First false proof layer on another surface(3), formed in first false proof layer(3)Surface Substrate layer(4)And formed in the substrate layer(4)Second false proof layer on surface(5), it is characterised in that:The tack coat(2) Including the first glue layer being disposed adjacent(21)With the second glue layer(22), the substrate layer(4)Material be PET, described the Two glue layers(22)Adhesion strength be more than first glue layer(21)Adhesion strength.
2. foldable label material according to claim 1, it is characterised in that second glue layer(22)Including following The component of parts by weight:
30-50 parts of bisphenol A type epoxy resin;
10-30 parts of bisphenol f type epoxy resin;
5-10 parts of triphenylmethane triisocyanate;
1-5 parts of aerosil;
1-5 parts of Boron Trifluoride Ethylamine;
1-5 parts of silane coupler kh550.
3. foldable label material according to claim 2, it is characterised in that:First glue layer(21)Including following The component of parts by weight:
30-50 parts of bisphenol A type epoxy resin;
10-30 parts of bisphenol f type epoxy resin;
5-10 parts of triphenylmethane triisocyanate;
1-5 parts of aerosil.
CN201710162231.6A 2017-03-17 2017-03-17 A kind of foldable label material Pending CN107103834A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710162231.6A CN107103834A (en) 2017-03-17 2017-03-17 A kind of foldable label material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710162231.6A CN107103834A (en) 2017-03-17 2017-03-17 A kind of foldable label material

Publications (1)

Publication Number Publication Date
CN107103834A true CN107103834A (en) 2017-08-29

Family

ID=59675906

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710162231.6A Pending CN107103834A (en) 2017-03-17 2017-03-17 A kind of foldable label material

Country Status (1)

Country Link
CN (1) CN107103834A (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1158107A (en) * 1994-05-20 1997-08-27 明尼苏达州采矿制造公司 Decal assembly and method of making
CN1823139A (en) * 2003-07-18 2006-08-23 小西株式会社 Curable resin composition and moisture-curing adhesive composition
CN201590199U (en) * 2009-12-11 2010-09-22 武汉威杜信息材料科技有限公司 Combined type anti-counterfeiting label
CN201740540U (en) * 2010-05-28 2011-02-09 艾博生物医药(杭州)有限公司 Detection device with covering element
CN204189380U (en) * 2014-10-28 2015-03-04 王清萍 Double anti-forge label
CN104409013A (en) * 2014-12-02 2015-03-11 东莞新能德科技有限公司 Tag with handle
CN204833311U (en) * 2015-08-11 2015-12-02 明尼苏达矿业制造医用器材(上海)有限公司 Can trace back label and label group
CN205899967U (en) * 2016-05-26 2017-01-18 苏州工业园区高泰电子有限公司 Former material of antifalsification label
CN206194284U (en) * 2016-11-10 2017-05-24 苏州工业园区高泰电子有限公司 Collapsible label material

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1158107A (en) * 1994-05-20 1997-08-27 明尼苏达州采矿制造公司 Decal assembly and method of making
CN1823139A (en) * 2003-07-18 2006-08-23 小西株式会社 Curable resin composition and moisture-curing adhesive composition
CN201590199U (en) * 2009-12-11 2010-09-22 武汉威杜信息材料科技有限公司 Combined type anti-counterfeiting label
CN201740540U (en) * 2010-05-28 2011-02-09 艾博生物医药(杭州)有限公司 Detection device with covering element
CN204189380U (en) * 2014-10-28 2015-03-04 王清萍 Double anti-forge label
CN104409013A (en) * 2014-12-02 2015-03-11 东莞新能德科技有限公司 Tag with handle
CN204833311U (en) * 2015-08-11 2015-12-02 明尼苏达矿业制造医用器材(上海)有限公司 Can trace back label and label group
CN205899967U (en) * 2016-05-26 2017-01-18 苏州工业园区高泰电子有限公司 Former material of antifalsification label
CN206194284U (en) * 2016-11-10 2017-05-24 苏州工业园区高泰电子有限公司 Collapsible label material

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CB02 Change of applicant information

Address after: 215000 No. 2 Lantern Street, Suzhou Industrial Park, Suzhou City, Jiangsu Province

Applicant after: Suzhou Gaotai Electronic Technology Co., Ltd.

Address before: 215000 No. 2 Lantern Street, Suzhou Industrial Park, Jiangsu Province

Applicant before: SUZHOU SIP HI-TECH PRECISION ELECTRONICS CO., LTD.

CB02 Change of applicant information
RJ01 Rejection of invention patent application after publication

Application publication date: 20170829

RJ01 Rejection of invention patent application after publication