CN107099877A - One kind is without the antifouling fishing net of coating - Google Patents
One kind is without the antifouling fishing net of coating Download PDFInfo
- Publication number
- CN107099877A CN107099877A CN201710336266.7A CN201710336266A CN107099877A CN 107099877 A CN107099877 A CN 107099877A CN 201710336266 A CN201710336266 A CN 201710336266A CN 107099877 A CN107099877 A CN 107099877A
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- Prior art keywords
- parts
- fishing net
- coating
- antifouling
- polycarbosilane
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Paints Or Removers (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The present invention discloses one kind without the antifouling fishing net of coating, is made up of the component of following parts by weight：50 64 parts of polyvinyl resin, 14 16 parts of Polycarbosilane, 59 parts of butyl titanate, 57 parts of 1 sodium heptanesulfonate, 46 parts of lemon isopropyl propionate, 36 parts of 1 decyl mercaptan, 6 10 parts of piperonyl acetate, 25 parts of triisopropanolamine, 9 11 parts of heptyl paraben.Antifouling fishing net produced by the present invention, will add in fishing net with the material for suppressing fouling organism growth, can cause fishing net in the case of not brushing paint, with excellent antifouling capacity, the problem of solving the problem of environmental pollution and short anti-fouling effect that coating is brought.
Description
Technical field
The invention belongs to fishing net preparation field, and in particular to one kind is without the antifouling fishing net of coating.
Background technology
Fishing net has substantial amounts of fouling organism and multiplied in its superficial growth, excessive is stained because long period of soaking is in water
Biology can consume substantial amounts of nutriment in water body, can reduce the exchange velocity of water body inside and outside fishing net, can increase aquatic livestock trouble
The risk of upper infectious disease, and the material that some fouling organisms are excreted, corrosion can be caused to fishing net, fishing net has been had a strong impact on
Service life.At present, in order to increase the anti-fouling effect of fishing net, frequently with method be fishing net shaping after, fishing net surface apply
Upper antifouling paint, the adhesion amount of fouling organism on fishing net is reduced although this method can be to a certain extent, coating due to
Long period of soaking is in water, and its is easy to crack to come off, and then causes fishing net to lose antifouling ability, and some nonpolluting coatings can be right
The environment of water body and the health of aquatic livestock cause harm.
The content of the invention
In order to solve the above problems, the present invention provides one kind without the antifouling fishing net of coating.
The present invention is achieved by the following technical solutions.
One kind is made up without the antifouling fishing net of coating of the component of following parts by weight：50-64 parts of polyvinyl resin, Polycarbosilane
14-16 parts, 5-9 parts of butyl titanate, 5-7 parts of 1- sodium heptanesulfonates, 4-6 parts of lemon isopropyl propionate, 3-6 parts of 1- decyl mercaptans, acetic acid
6-10 parts of pepper ester, 2-5 parts of triisopropanolamine, 9-11 parts of heptyl paraben, preparation method comprises the following steps：（1）By poly- second
Olefine resin, Polycarbosilane are put into ball mill, and mechanical mixture is standby after 4-6 hours；（2）1- sodium heptanesulfonates, citric acid is different
Propyl ester, triisopropanolamine, heptyl paraben add step（1）In gained mixture, continue mechanical mixture standby after 1-2 hours；
（3）After 1- decyl mercaptans, piperonyl acetate, butyl titanate are mixed, and 0.05-0.07 times of addition mixed liquor gross weight is weighed thereto
Absolute ethyl alcohol, after stirring, add to step（2）In the compound of gained, pass through plastic extruder melting extrusion, melting
Extrusion temperature is 220-230 DEG C, and the fiber of melting extrusion is put into the ethanol solution that volume fraction is 10%, 2-4 times of drawing-off, so
Afterwards again at a temperature of 80-85 DEG C by 14-15 times of drawing of fiber, then wound, line processed, knitmesh, finished product.
Specifically, above-mentioned steps（1）The average grain diameter of mixture is 100-140 mesh after middle mechanical mixture.
Technical scheme more than, the beneficial effects of the invention are as follows：
Antifouling fishing net produced by the present invention, will add in fishing net with the material for suppressing fouling organism growth, can cause fishing net
In the case of not brushing paint, with excellent antifouling capacity, problem of environmental pollution and antifouling effect that coating is brought are solved
Really short the problem of.Wherein, by adding piperonyl acetate, triisopropanolamine, three kinds of antifoulant compositions of heptyl paraben, on the one hand its
Attachment of the fouling organism on fishing net surface that can effectively suppress in water body is multiplied, and on the other hand it can be with the article shaped in fishing net
Matter is combined closely, and is difficult to depart from fishing net during use, and its chemical stability is good, and the material being not easy in water body is anti-
Should, therefore it can cause fishing net to have permanent effective antifouling capacity；Polycarbosilane, 1- heptanesulfonic acids in fishing net composition
Sodium, 1- decyl mercaptans synergy, on the one hand can increase adhesion of the antifoulant composition in fishing net, on the other hand can reduce fishing net
Surface can so that the fouling organism being attached on fishing net is easily walked by rain drop erosion, can further lift the antifouling capacity of fishing net.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following examples are carried out to the present invention
It is further described.It should be appreciated that specific embodiment party example described herein is not used to limit only to explain the present invention
The fixed present invention.
Embodiment 1
One kind is made up without the antifouling fishing net of coating of the component of following parts by weight：50 parts of polyvinyl resin, 14 parts of Polycarbosilane, titanium
5 parts of acid butyl ester, 5 parts of 1- sodium heptanesulfonates, 4 parts of lemon isopropyl propionate, 3 parts of 1- decyl mercaptans, 6 parts of piperonyl acetate, three isopropanols
2 parts of amine, 9 parts of heptyl paraben, preparation method comprises the following steps：（1）Polyvinyl resin, Polycarbosilane are put into ball mill
In, mechanical mixture is standby after 4 hours；（2）1- sodium heptanesulfonates, lemon isopropyl propionate, triisopropanolamine, heptyl paraben are added
Enter step（1）In gained mixture, continue mechanical mixture standby after 1 hour；（3）By 1- decyl mercaptans, piperonyl acetate, metatitanic acid fourth
After ester mixing, and mixed liquor 0.05 times of heavy absolute ethyl alcohol of gross weight is added thereto, after stirring, add to step（2）
In the compound of gained, by plastic extruder melting extrusion, melting extrusion temperature is 220 DEG C, and the fiber of melting extrusion is put into
Volume fraction is in 10% ethanol solution, 2 times of drawing-off then again at a temperature of 80 DEG C by 14 times of drawing of fiber, is then carried out
Winding, line processed, knitmesh, finished product.
Specifically, above-mentioned steps（1）The average grain diameter of mixture is 100 mesh after middle mechanical mixture.
Embodiment 2
One kind is made up without the antifouling fishing net of coating of the component of following parts by weight：58 parts of polyvinyl resin, 15 parts of Polycarbosilane, titanium
7 parts of acid butyl ester, 6 parts of 1- sodium heptanesulfonates, 5 parts of lemon isopropyl propionate, 5 parts of 1- decyl mercaptans, 8 parts of piperonyl acetate, three isopropanols
3 parts of amine, 10 parts of heptyl paraben, preparation method comprises the following steps：（1）Polyvinyl resin, Polycarbosilane are put into ball mill
In, mechanical mixture is standby after 5 hours；（2）1- sodium heptanesulfonates, lemon isopropyl propionate, triisopropanolamine, heptyl paraben are added
Enter step（1）In gained mixture, continue mechanical mixture standby after 1 hour；（3）By 1- decyl mercaptans, piperonyl acetate, metatitanic acid fourth
After ester mixing, and mixed liquor 0.06 times of heavy absolute ethyl alcohol of gross weight is added thereto, after stirring, add to step（2）
In the compound of gained, by plastic extruder melting extrusion, melting extrusion temperature is 225 DEG C, and the fiber of melting extrusion is put into
Volume fraction is in 10% ethanol solution, 3 times of drawing-off then again at a temperature of 83 DEG C by 14 times of drawing of fiber, is then carried out
Winding, line processed, knitmesh, finished product.
Specifically, above-mentioned steps（1）The average grain diameter of mixture is 120 mesh after middle mechanical mixture.
Embodiment 3
One kind is made up without the antifouling fishing net of coating of the component of following parts by weight：64 parts of polyvinyl resin, 16 parts of Polycarbosilane, titanium
9 parts of acid butyl ester, 7 parts of 1- sodium heptanesulfonates, 6 parts of lemon isopropyl propionate, 6 parts of 1- decyl mercaptans, 10 parts of piperonyl acetate, three isopropanols
5 parts of amine, 11 parts of heptyl paraben, preparation method comprises the following steps：（1）Polyvinyl resin, Polycarbosilane are put into ball mill
In, mechanical mixture is standby after 6 hours；（2）1- sodium heptanesulfonates, lemon isopropyl propionate, triisopropanolamine, heptyl paraben are added
Enter step（1）In gained mixture, continue mechanical mixture standby after 2 hours；（3）By 1- decyl mercaptans, piperonyl acetate, metatitanic acid fourth
After ester mixing, and mixed liquor 0.07 times of heavy absolute ethyl alcohol of gross weight is added thereto, after stirring, add to step（2）
In the compound of gained, by plastic extruder melting extrusion, melting extrusion temperature is 230 DEG C, and the fiber of melting extrusion is put into
Volume fraction is in 10% ethanol solution, 4 times of drawing-off then again at a temperature of 85 DEG C by 15 times of drawing of fiber, is then carried out
Winding, line processed, knitmesh, finished product.
Specifically, above-mentioned steps（1）The average grain diameter of mixture is 140 mesh after middle mechanical mixture.
Comparative example 1
Piperonyl acetate, triisopropanolamine, heptyl paraben composition, remaining composition and the complete phase of embodiment 1 are not contained in fishing net
Together.
Comparative example 2
Polycarbosilane, 1- sodium heptanesulfonates, 1- decyl mercaptan compositions are not contained in fishing net, remaining composition is identical with embodiment 2.
Fishing net is made in the method provided respectively with an embodiment and comparative example, then by fishing net made from each group in Qingdao
Offshore sea waters carries out real extra large linked network experiment, and it is the commercially available common nonpolluting coating that scribbles to set the fishing net in control group, control group
Fishing net, during experiment, the ratio of the fishing net gross area, experiment knot are accounted for every the area for adhering to fouling organism on three months measurement fishing nets
Fruit is as shown in table 1：
The comparison of the different fishing net anti-fouling effects of table 1
| Project | 3 months | 6 months | 9 months | 12 months |
| Embodiment 1 | 2.6 | 4.4 | 8.8 | 10.1 |
| Comparative example 1 | 9.1 | 18.6 | 20.7 | 30.9 |
| Embodiment 2 | 2.2 | 4.0 | 8.5 | 9.7 |
| Comparative example 2 | 3.5 | 9.7 | 18.3 | 29.4 |
| Embodiment 3 | 2.1 | 3.9 | 7.9 | 9.6 |
| Control group | 3.7 | 9.8 | 18.9 | 34.1 |
From the anti-fouling effect of embodiment 1 and comparative example 1, piperonyl acetate, triisopropanolamine, heptyl paraben have notable
Anti-fouling effect, from embodiment 2 and comparative example 2, Polycarbosilane, 1- sodium heptanesulfonates, 1- decyl mercaptans can effectively prolong
The anti-fouling effect of long fishing net, from the fishing net in embodiment and control group, fishing net anti-fouling effect produced by the present invention is notable, and
Antifouling effective time is longer.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (2)
1. one kind is without the antifouling fishing net of coating, it is characterised in that be made up of the component of following parts by weight：50-64 parts of polyvinyl resin,
14-16 parts of Polycarbosilane, 5-9 parts of butyl titanate, 5-7 parts of 1- sodium heptanesulfonates, 4-6 parts of lemon isopropyl propionate, 1- decyl mercaptans 3-6
Part, 6-10 parts of piperonyl acetate, 2-5 parts of triisopropanolamine, 9-11 parts of heptyl paraben, preparation method comprises the following steps：（1）
Polyvinyl resin, Polycarbosilane are put into ball mill, mechanical mixture is standby after 4-6 hours；（2）By 1- sodium heptanesulfonates, lemon
Lemon isopropyl propionate, triisopropanolamine, heptyl paraben add step（1）In gained mixture, continue mechanical mixture after 1-2 hours
It is standby；（3）After 1- decyl mercaptans, piperonyl acetate, butyl titanate are mixed, and mixed liquor gross weight 0.05- is added thereto
0.07 times of heavy absolute ethyl alcohol, after stirring, is added to step（2）In the compound of gained, melted by plastic extruder
Extrusion, melting extrusion temperature is 220-230 DEG C, and the fiber of melting extrusion is put into the ethanol solution that volume fraction is 10%, drawing-off
2-4 times, then again at a temperature of 80-85 DEG C by 14-15 times of drawing of fiber, then wound, line processed, knitmesh, be made into
Product.
2. one kind according to claim 1 is without the antifouling fishing net of coating, it is characterised in that above-mentioned steps（1）Middle machinery is mixed
The average grain diameter of mixture is 100-140 mesh after conjunction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710336266.7A CN107099877A (en) | 2017-05-13 | 2017-05-13 | One kind is without the antifouling fishing net of coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710336266.7A CN107099877A (en) | 2017-05-13 | 2017-05-13 | One kind is without the antifouling fishing net of coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107099877A true CN107099877A (en) | 2017-08-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710336266.7A Pending CN107099877A (en) | 2017-05-13 | 2017-05-13 | One kind is without the antifouling fishing net of coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107099877A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685032A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1276965A (en) * | 2000-07-31 | 2000-12-20 | 江苏省化工研究所 | Fishnet capable of resisting contamination from marine organism |
| CN105801973A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Antifouling fishing net |
-
2017
- 2017-05-13 CN CN201710336266.7A patent/CN107099877A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1276965A (en) * | 2000-07-31 | 2000-12-20 | 江苏省化工研究所 | Fishnet capable of resisting contamination from marine organism |
| CN105801973A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Antifouling fishing net |
Non-Patent Citations (1)
| Title |
|---|
| 朱洪法: "《精细化工常用原材料手册》", 31 December 2003, 金盾出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685032A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
| CN110685032B (en) * | 2019-08-19 | 2022-04-19 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
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Application publication date: 20170829 |
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