CN107099075A - A kind of insect-sticking plate baseboard material of environment-friendly degradable and preparation method thereof - Google Patents
A kind of insect-sticking plate baseboard material of environment-friendly degradable and preparation method thereof Download PDFInfo
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- CN107099075A CN107099075A CN201610099842.6A CN201610099842A CN107099075A CN 107099075 A CN107099075 A CN 107099075A CN 201610099842 A CN201610099842 A CN 201610099842A CN 107099075 A CN107099075 A CN 107099075A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses insect-sticking plate baseboard material of a kind of environment-friendly degradable and preparation method thereof, the insect-sticking plate baseboard material, by weight percentage, including following components：Plastics homopolymer 65%~70%；Plastics 70428%~13%；Mineral powder 16%~20%；Natto bacterium powder 0.3%~0.5%；Titanium dioxide 0.1%~0.2%；Yellow agent 0.2%~0.4%；Dispersant 2%~5%；Ultraviolet-resistant absorbent 0.2%~0.3%；The baseboard material phototaxis is good, can be also held up under solar exposure, the extreme weather such as heavy rain six months it is colour-fast, start aging, natural degradation after six months.The baseboard material is cheap, convenient and practical, prepares simply, can largely be produced using traditional maturation process, and burn nontoxic, low-carbon emission reduction.
Description
Technical field
The present invention relates to insect-sticking plate baseboard material of a kind of environment-friendly degradable and preparation method thereof, belong to energy-conserving and environment-protective material
Field.
Background technology
The preventing and treating of insect is a very important link in agricultural production, and insect-sticking plate is a kind of special pest control
Product, compared to the mode of traditional chemical prevention insect pest, the mode of its physical control insect pest possesses significant advantage, without agriculture
Medicine is remained, and does not influence crop growth, therefore insect-sticking plate is widely used.The baseboard material of insect-sticking plate is the main of insect-sticking plate
Part, it is a kind of plastic material, and in the market is commonly called as " yellow plate ", and the insect-sticking plate baseboard material of in the market is usually present in recent years
Following shortcoming：1st, becoming, luminosity is poor, and attraction insect effect is not good；2nd, expose to the weather for a long time and easily cause colour fading, cause deinsectization
Evil effect is unstable, lacks of staying power；3rd, more importantly it is a kind of conventional plastic, and recycling value is not high, in natural ring
It is difficult to degrade again under border, serious pollution is caused to natural environment, belongs to white pollution.
The content of the invention
For defect present in above prior art, the invention provides a kind of insect-sticking plate bottom plate of environment-friendly degradable
Material and preparation method thereof, the baseboard material phototaxis is good, can also keep long under solar exposure, the extreme weather such as heavy rain
It is colour-fast up to six months, start aging, natural degradation after six months.The baseboard material is cheap, convenient and practical, prepares letter
It is single, can largely it be produced using traditional maturation process, burn nontoxic, low-carbon emission reduction.
Therefore, the technical solution adopted in the present invention is：A kind of insect-sticking plate baseboard material of environment-friendly degradable, the mythimna separata
Plate baseboard material, by weight percentage, including following components：
Plastics homopolymer 65%~70%；
Plastics 7,042 8%~13%；
Mineral powder 16%~20%；
Natto bacterium powder 0.3%~0.5%；
Titanium dioxide 0.1%~0.2%；
Yellow agent 0.2%~0.4%；
Dispersant 2%~5%；
Ultraviolet-resistant absorbent 0.2%~0.3%；
Described plastics homopolymer using the former grain of polyethylene plastic cement, polypropylene plastics collagen grain, the former grain of verelite plastic rubber and
The mixture of one or both of polyvinyl chloride plastic collagen grain；
Described mineral powder is the special mineral powder of plastics；Described dispersant is plastics dispersant special.
Further, the mineral powder is generally using the mixing of one or both of quartz powder, glass-cermic powder.
Further, generally using paraffin, Tissuemat E, OPE, polypropylene wax, aliphatic acid, soap,
Mixture more than one or both of fatty acid amide and fatty acid ester.
A kind of preparation method of the insect-sticking plate baseboard material of environment-friendly degradable, the preparation method comprises the following steps：
By 65%~70% plastics homopolymer, the mineral powder of 8%~13% plastics 7042,16%~20%, 0.3%
~0.5% natto bacterium powder, 0.1%~0.2% titanium dioxide, 0.2%~0.4% yellow agent, 2%~5% dispersant,
0.2%~0.3% ultraviolet-resistant absorbent mixture is mixed evenly；
Heating and temperature control is at 60 degrees Celsius；
Extruder is then added to, point three sections of temperature controls, first section is 160 degrees Celsius, and stage casing is 180 degrees Celsius, and back segment is
200 degrees Celsius, it is extruded into material；
Cutting is in blocks.
The insect-sticking plate baseboard material of the above-mentioned environment-friendly degradable prepared needs to meet following items performance detection：
The beneficial effects of the invention are as follows：
(1) the environment-friendly degradable insect-sticking plate baseboard material that provides of the present invention is made a living thing degradation function agent with natto bacterium powder, when
Environment-friendly degradable insect-sticking plate baseboard material is contacted after appropriate time with moisture content, makes to be evenly distributed Bacillus natto activation in the plastic, and
Generation biological decomposition, so as to realize natural degradation.
(2) it is equal with plastics homopolymer in the present invention also so that titanium dioxide is auxiliary material and is incorporated ultraviolet-resistant absorbent
Even mixing is combined as a whole.Titanium dioxide can increase substantially the heat resistance of environment-friendly degradable insect-sticking plate baseboard material, light resistance, resistance to
Hou Xing, making the physical and chemical performance of baseboard material is improved, and the mechanical strength of reinforcing material increases the service life.Uvioresistant
Light absorbers can make environment-friendly degradable insect-sticking plate baseboard material absorb the ultraviolet part in sunlight and fluorescence light source, play light stable
The effect of agent, can protect and weaken destruction of the sunlight to color.The addition of titanium dioxide and ultraviolet-resistant absorbent makes environmentally friendly drop
Solution insect-sticking plate baseboard material becomes luminosity enhancing, and can also keep stable under high temperature and solar exposure, colour-fast, makes deinsectization effect
It is more stable more longlasting.
(3) addition natural ore powder is auxiliary material and is incorporated dispersant in the present invention, is uniformly mixed with plastics homopolymer
Conjunction is combined as a whole.Mineral powder plays a part of accelerating disintegration, when environment-friendly degradable insect-sticking plate baseboard material is contacted suitably with moisture content
After time, make to be evenly distributed after natto bacterium powder activation in the plastic, mineral powder is disintegrated therewith, loses original between plastic molecules
Molecule link, and occur the phenomenon of biological decomposition, form a large amount of holes, and then reach the purpose of waste plastic fast decoupled.
Even if being buried in nature, natural decomposition can be accelerated, increase effective utilization space of landfill site.It it also avoid because can not
The natural pollution degraded and caused, such as because of burial and caused by soil pollution, the problem of air pollution caused by incineration etc., with
This reaches specific environmental benefit.
(4) the environment-friendly degradable insect-sticking plate baseboard material burning that the present invention is provided emits white cigarette, after low-carbon emission reduction, completely burning into
For can back to nature white powder.
(5) the environment-friendly degradable insect-sticking plate baseboard material cost that provides of the present invention is low, production method is simple and convenient, does not change viscous
The outward appearance and occupation mode of worm plate, it is not necessary to change production equipment.
Embodiment
Following embodiments describe the present invention in detail, but do not limit the scope of the invention.But protection scope of the present invention is simultaneously
It is non-to be limited only to following examples.Person of an ordinary skill in the technical field, can be real according to present disclosure
The existing purpose of the present invention.
Embodiment 1
A kind of environment-friendly degradable insect-sticking plate baseboard material, its constituent includes plastics homopolymer, and described constituent is also
Including natto bacterium powder, titanium dioxide, yellow agent, dispersant, mineral powder, ultraviolet-resistant absorbent.Main constituents in the present invention
For plastics homopolymer, part natto bacterium powder is distributed in plastics, and the natto bacterium powder after appropriate time is contacted with moisture content is lived
Change, destruction and the intermolecular link of the former grain of plastics form substantial amounts of hole, so that plastics are decomposed.It is heretofore described
Constituent also include mineral powder and dispersant, addition dispersant can enable each group fully dispersed equal into composition in the preparation
It is even.And mineral powder is added in plastics, then after the activation of natto bacterium powder, the mineral powder being distributed in plastics, which is played, accelerates disintegration
Effect, and then reach the purpose of waste plastic fast decoupled.In addition, mineral powder can not only substantially reduce the cost of baseboard material,
The popularization for making it be more beneficial for efforts at environmental protection, while by itself possessing natural cooling styling, can be reduced when burning
Burning-point, reduces burning time, waste plastic is easier complete burning.Heretofore described constituent titanium dioxide, addition
Titanium dioxide can improve the heat resistance, light resistance, weatherability of baseboard material, be changed the physical and chemical performance of baseboard material
Kind, the mechanical strength of reinforcing material increases the service life.Heretofore described constituent ultraviolet-resistant absorbent.Addition
Ultraviolet-resistant absorbent can make baseboard material absorb the ultraviolet part in sunlight and fluorescence light source, play the work of light stabilizer
With, it can protect and weaken destruction of the sunlight to color, and material will not change in itself.
A kind of environment-friendly degradable insect-sticking plate baseboard material, its constituent and percentage by weight are：
The mineral powder 18% of 70% plastics of plastics homopolymer 7,042 9.1%
The yellow agent 0.3% of 0.3% titanium dioxide of natto bacterium powder 0.1%
The ultraviolet-resistant absorbent 0.2% of dispersant 2%
Described plastics homopolymer using the former grain of polyethylene plastic cement, polypropylene plastics collagen grain, the former grain of verelite plastic rubber and
The mixture of one or both of polyvinyl chloride plastic collagen grain.
Described mineral powder is the special mineral powder of plastics, generally using one or both of quartz powder, glass-cermic powder
Mixing.
Described dispersant is plastics dispersant special, generally using paraffin, Tissuemat E, OPE, poly- third
Mixture more than one or both of alkene wax, aliphatic acid, soap, fatty acid amide and fatty acid ester.
The present invention be it is uniform with various constituent heating stirrings, temperature control at 60 degrees Celsius, after be then added to extrusion
Machine, point three sections of temperature controls, first section is 160 degrees Celsius, and stage casing is 180 degrees Celsius, and back segment is 200 degrees Celsius, is extruded into material,
Cut again in flakes.
Embodiment 2
A kind of environment-friendly degradable insect-sticking plate baseboard material, its constituent and percentage by weight are：
The mineral powder 18% of 65% plastics of plastics homopolymer 7,042 12%
The yellow agent 0.4% of 0.5% titanium dioxide of natto bacterium powder 0.2%
The ultraviolet-resistant absorbent 0.3% of dispersant 3.6%
Described plastics homopolymer using the former grain of polyethylene plastic cement, polypropylene plastics collagen grain, the former grain of verelite plastic rubber and
The mixture of one or both of polyvinyl chloride plastic collagen grain.
Described mineral powder is the special mineral powder of plastics, generally using one or both of quartz powder, glass-cermic powder
Mixing.
Described dispersant is plastics dispersant special, generally using paraffin, Tissuemat E, OPE, poly- third
Mixture more than one or both of alkene wax, aliphatic acid, soap, fatty acid amide and fatty acid ester.
A kind of preparation method be the same as Example 1 of the environment-friendly degradable insect-sticking plate baseboard material.
Embodiment 3
A kind of environment-friendly degradable insect-sticking plate baseboard material, its constituent and percentage by weight are：
The mineral powder 18% of 68% plastics of plastics homopolymer 7,042 10%
The yellow agent 0.3% of 0.3% titanium dioxide of natto bacterium powder 0.1%
The ultraviolet-resistant absorbent 0.2% of dispersant 3.1%
Described plastics homopolymer using the former grain of polyethylene plastic cement, polypropylene plastics collagen grain, the former grain of verelite plastic rubber and
The mixture of one or both of polyvinyl chloride plastic collagen grain.
Described mineral powder is the special mineral powder of plastics, generally using one or both of quartz powder, glass-cermic powder
Mixing.
Described dispersant is plastics dispersant special, generally using paraffin, Tissuemat E, OPE, poly- third
Mixture more than one or both of alkene wax, aliphatic acid, soap, fatty acid amide and fatty acid ester.
A kind of preparation method be the same as Example 1 of the environment-friendly degradable insect-sticking plate baseboard material.
After testing, a kind of environment-friendly degradable insect-sticking plate baseboard material under above-described embodiment 1-3 ratios has following excellent
Point：
(1) it is to be made a living thing degradation function agent with natto bacterium powder, when environment-friendly degradable insect-sticking plate baseboard material contacts suitable with moisture content
After the time, make to be evenly distributed Bacillus natto activation in the plastic, and occur biological decomposition, so as to realize natural degradation.
(2) it is equal with plastics homopolymer in the present invention also so that titanium dioxide is auxiliary material and is incorporated ultraviolet-resistant absorbent
Even mixing is combined as a whole.Titanium dioxide can increase substantially the heat resistance of environment-friendly degradable insect-sticking plate baseboard material, light resistance, resistance to
Hou Xing, making the physical and chemical performance of baseboard material is improved, and the mechanical strength of reinforcing material increases the service life.Uvioresistant
Light absorbers can make environment-friendly degradable insect-sticking plate baseboard material absorb the ultraviolet part in sunlight and fluorescence light source, play light stable
The effect of agent, can protect and weaken destruction of the sunlight to color.The addition of titanium dioxide and ultraviolet-resistant absorbent makes environmentally friendly drop
Solution insect-sticking plate baseboard material becomes luminosity enhancing, and can also keep stable under high temperature and solar exposure, colour-fast, makes deinsectization effect
It is more stable more longlasting.
(3) addition natural ore powder is auxiliary material and is incorporated dispersant in the present invention, is uniformly mixed with plastics homopolymer
Conjunction is combined as a whole.Mineral powder plays a part of accelerating disintegration, when environment-friendly degradable insect-sticking plate baseboard material is contacted suitably with moisture content
After time, make to be evenly distributed after natto bacterium powder activation in the plastic, mineral powder is disintegrated therewith, loses original between plastic molecules
Molecule link, and occur the phenomenon of biological decomposition, form a large amount of holes, and then reach the purpose of waste plastic fast decoupled.
Even if being buried in nature, natural decomposition can be accelerated, increase effective utilization space of landfill site.It it also avoid because can not
The natural pollution degraded and caused, such as because of burial and caused by soil pollution, the problem of air pollution caused by incineration etc., with
This reaches specific environmental benefit.
(4) the environment-friendly degradable insect-sticking plate baseboard material burning that the present invention is provided emits white cigarette, after low-carbon emission reduction, completely burning into
For can back to nature white powder.
(5) the environment-friendly degradable insect-sticking plate baseboard material cost that provides of the present invention is low, production method is simple and convenient, does not change viscous
The outward appearance and occupation mode of worm plate, it is not necessary to change production equipment.
Claims (4)
1. a kind of insect-sticking plate baseboard material of environment-friendly degradable, it is characterised in that：The insect-sticking plate baseboard material, by weight percentage
Than meter, including following components：
Plastics homopolymer 65%~70%；
Plastics 7,042 8%~13%；
Mineral powder 16%~20%；
Natto bacterium powder 0.3%~0.5%；
Titanium dioxide 0.1%~0.2%；
Yellow agent 0.2%~0.4%；
Dispersant 2%~5%；
Ultraviolet-resistant absorbent 0.2%~0.3%；
Described plastics homopolymer is using the former grain of polyethylene plastic cement, polypropylene plastics collagen grain, the former grain of verelite plastic rubber and polychlorostyrene
The mixture of one or both of ethene plastic cement original grain；
Described mineral powder is the special mineral powder of plastics；Described dispersant is plastics dispersant special.
2. a kind of insect-sticking plate baseboard material of environment-friendly degradable according to claim 1, it is characterised in that：
The mineral powder is generally using the mixing of one or both of quartz powder, glass-cermic powder.
3. a kind of insect-sticking plate baseboard material of environment-friendly degradable according to claim 1, it is characterised in that：Generally use stone
One kind in wax, Tissuemat E, OPE, polypropylene wax, aliphatic acid, soap, fatty acid amide and fatty acid ester
Or two or more mixtures.
4. a kind of preparation method of the insect-sticking plate baseboard material of environment-friendly degradable as claimed in claim 1, it is characterised in that：Institute
Preparation method is stated to comprise the following steps：
By 65%~70% plastics homopolymer, the mineral powder of 8%~13% plastics 7042,16%~20%, 0.3%~
0.5% natto bacterium powder, 0.1%~0.2% titanium dioxide, 0.2%~0.4% yellow agent, 2%~5% dispersant,
0.2%~0.3% ultraviolet-resistant absorbent mixture is placed in heating in dispersator and is mixed evenly；
Heating and temperature control is at 60 degrees Celsius；
Extruder is then added to, point three sections of temperature controls, first section is 160 degrees Celsius, stage casing is 180 degrees Celsius, and back segment is taken the photograph for 200
Family name's degree, is extruded into material；
Cutting is in blocks.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610099842.6A CN107099075A (en) | 2016-02-23 | 2016-02-23 | A kind of insect-sticking plate baseboard material of environment-friendly degradable and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610099842.6A CN107099075A (en) | 2016-02-23 | 2016-02-23 | A kind of insect-sticking plate baseboard material of environment-friendly degradable and preparation method thereof |
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| CN107099075A true CN107099075A (en) | 2017-08-29 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112005991A (en) * | 2020-09-11 | 2020-12-01 | 西南大学 | Environment-friendly reusable double-sided pest sticking plate and processing method thereof |
Citations (2)
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| CN101851364A (en) * | 2010-06-12 | 2010-10-06 | 东莞市川森环保塑料有限公司 | Biodegradable SEP environmental-friendly plastic |
| CN102492203A (en) * | 2011-12-06 | 2012-06-13 | 东莞市川森环保塑料有限公司 | Light-biological double-degradation agricultural film |
-
2016
- 2016-02-23 CN CN201610099842.6A patent/CN107099075A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851364A (en) * | 2010-06-12 | 2010-10-06 | 东莞市川森环保塑料有限公司 | Biodegradable SEP environmental-friendly plastic |
| CN102492203A (en) * | 2011-12-06 | 2012-06-13 | 东莞市川森环保塑料有限公司 | Light-biological double-degradation agricultural film |
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| 刘程 等: "《表面活性剂应用手册》", 31 August 1995, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112005991A (en) * | 2020-09-11 | 2020-12-01 | 西南大学 | Environment-friendly reusable double-sided pest sticking plate and processing method thereof |
| CN112005991B (en) * | 2020-09-11 | 2021-12-21 | 西南大学 | Environment-friendly reusable double-sided pest sticking plate and processing method thereof |
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