CN107096554A - A kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst - Google Patents
A kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst Download PDFInfo
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- CN107096554A CN107096554A CN201710201102.3A CN201710201102A CN107096554A CN 107096554 A CN107096554 A CN 107096554A CN 201710201102 A CN201710201102 A CN 201710201102A CN 107096554 A CN107096554 A CN 107096554A
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- Prior art keywords
- silver
- phosphate
- phosphoric acid
- cobalt
- colloid
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- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 title claims abstract description 25
- 229940019931 silver phosphate Drugs 0.000 title claims abstract description 17
- 229910000161 silver phosphate Inorganic materials 0.000 title claims abstract description 17
- 229910000152 cobalt phosphate Inorganic materials 0.000 title claims abstract description 16
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 title claims abstract description 16
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000084 colloidal system Substances 0.000 claims abstract description 24
- NDYNABNWLRVCDO-UHFFFAOYSA-N phosphoric acid silver Chemical compound [Ag].P(O)(O)(O)=O NDYNABNWLRVCDO-UHFFFAOYSA-N 0.000 claims abstract description 19
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 17
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 11
- REERVHLUKHFRQT-UHFFFAOYSA-N cobalt phosphoric acid Chemical compound [Co].P(O)(O)(O)=O REERVHLUKHFRQT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001981 cobalt nitrate Inorganic materials 0.000 claims abstract description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims abstract description 6
- 150000002500 ions Chemical class 0.000 claims abstract description 6
- 239000002105 nanoparticle Substances 0.000 claims abstract description 6
- XRRQZKOZJFDXON-UHFFFAOYSA-N nitric acid;silver Chemical compound [Ag].O[N+]([O-])=O XRRQZKOZJFDXON-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 5
- 238000004821 distillation Methods 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 16
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 238000005215 recombination Methods 0.000 abstract description 2
- 230000006798 recombination Effects 0.000 abstract description 2
- 238000007654 immersion Methods 0.000 abstract 1
- 238000004042 decolorization Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000001699 photocatalysis Effects 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- -1 Disodium hydrogen Chemical class 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
The present invention discloses the preparation method that a kind of cobalt phosphate aids in silver phosphate photocatalyst, comprises the following steps that：Silver nitrate and disodium phosphate soln are mixed, yellow green colloid substance is formed, 3~4h is persistently stirred, disodium hydrogen phosphate and nitric acid silver reaction in whipping process generate phosphoric acid silver colloid；Phosphoric acid silver colloid is placed in pellicle bag, with distillation water washing 3~4 times, get rid of dissociated ion, the phosphoric acid silver colloid is added in the cobalt nitrate solution that 60~80mL concentration is 1~2mol/L again, immersion 1~3 day, in silver orthophosphate particle surface formation phosphoric acid cobalt nano-particle, a kind of cobalt phosphate auxiliary silver phosphate photocatalyst is made.This method is the cocatalyst in major catalyst surface recombination, greatly improves the stability and catalytic efficiency of major catalyst.
Description
Technical field
The present invention relates to the preparation method that a kind of cobalt phosphate aids in silver phosphate photocatalyst, belong in environmental protection at sewage
Manage technical field.
Background technology
Traditional method for treating water efficiency is low, cost is high, there are secondary pollution problems, and waste water control always cannot be well
Solution.The development and application of nanometer technology are likely to thoroughly solve this problem.Start within 1972 to find TiO2Oxidation activity
Higher, chemical stability is good, harmless to the human body, and cost is low, pollution-free, has a wide range of application, thus is most paid attention to, but TiO2
Larger (such as anatase TiO of energy gap2Energy gap Eg=3.2eV), be only capable of absorb ultraviolet region (wavelength is less than
Light 387nm), the utilization ratio to solar energy is relatively low.
In contaminant degradation and production of energy field, conductor photocatalysis is one of most promising method.Work as energy
Amount will produce point of electron-hole pair when being more than or equal to the photon irradiation of semiconductor energy gap in photocatalyst surface
From this is the initial basic step of light-catalyzed reaction.In order to find efficient photochemical catalyst, numerous studies work is all concentrated on
In the influence factor for studying photocatalytic activity.In June, 2010, material research institution researcher has found that silver orthophosphate has light
The effect of catalyst, and photooxidation effect is to be currently known more than the decades of times of various photochemical catalysts.But due to silver orthophosphate itself
Unstable, easy self-reversal, causes catalyst degradation performance to reduce rapidly in photocatalysis.And it is that a nothing is stopped to improve photocatalysis effect
The work in border.
Silver compound photochemical catalyst has the advantages that the big extensive attention by scientists of absorption region, and co-catalyst
Introducing can greatly improve the catalytic performance and stability of raw catalyst, therefore appendix co-catalyst is also to improve catalyst performance
One of important means of energy.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to propose a kind of cobalt phosphate auxiliary silver phosphate photocatalyst
Preparation method, this method is the cocatalyst in major catalyst surface recombination, greatly improves the stability of major catalyst and urges
Change efficiency.
The technical solution adopted by the present invention is to use following steps：
1) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid is weighed
Disodium hydrogen, is configured to 20mmol/L disodium phosphate soln；
2) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, continued
3~4h is stirred, disodium hydrogen phosphate and nitric acid silver reaction in whipping process generate phosphoric acid silver colloid；
3) phosphoric acid silver colloid is placed in pellicle bag, with water washing is distilled 3~4 times, gets rid of dissociated ion, then should
Phosphoric acid silver colloid is added in the cobalt nitrate solution that 60~80mL concentration is 1~2mol/L, is soaked 1~3 day, in phosphoric acid Argent grain
Surface forms phosphoric acid cobalt nano-particle, and one kind is made in separation of solid and liquid, deionized water washing solid 2~3 times, 75~105 DEG C of drying
Cobalt phosphate aids in silver phosphate photocatalyst.
The beneficial effects of the invention are as follows：(1) this method utilizes the difference of solubility product constant, in phosphoric acid silver surface formation solubility
The smaller phosphoric acid cobalt granule of product constant.
(2) cobalt phosphate auxiliary silver phosphate catalyst, synergy, can improve the stability of silver orthophosphate and improve catalysis effect
Really.
Embodiment
Embodiment 1
24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates are weighed, configured
Into 20mmol/L disodium phosphate soln；Both the above solution is mixed under 400 revs/min of rotating speed, yellow green is formed
Colloid substance, persistently stirs 4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；By phosphoric acid
Silver colloid is placed in pellicle bag, with water washing is distilled 4 times, gets rid of dissociated ion, then the phosphoric acid silver colloid is added to
80mL concentration is in 2mol/L cobalt nitrate solution, soaks 3 days, in silver orthophosphate particle surface formation phosphoric acid cobalt nano-particle, Gu
Liquid is separated, deionized water washing solid 3 times, and a kind of cobalt phosphate auxiliary silver phosphate photocatalyst is made in 105 DEG C of drying.
Aid in silver phosphate photocatalyst 0.3g to be added to the acid red that 500mL concentration is 30mg/L obtained cobalt phosphate to give up
In water, under the irradiation of 300w Metal halogen lamps, 30min is reacted, percent of decolourization is 96.1%, can be reused after catalyst separation.
Embodiment 2
20mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6mmol disodium hydrogen phosphates is weighed, matches somebody with somebody
It is set to 20mmol/L disodium phosphate soln；Both the above solution is mixed under 350 revs/min of rotating speed, formed yellowish green
Color colloid substance, persistently stirs 3h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；By phosphorus
Sour silver colloid is placed in pellicle bag, with water washing is distilled 3 times, gets rid of dissociated ion, then the phosphoric acid silver colloid is added to
60mL concentration is in 1mol/L cobalt nitrate solution, soaks 1 day, in silver orthophosphate particle surface formation phosphoric acid cobalt nano-particle, Gu
Liquid is separated, deionized water washing solid 2 times, and a kind of cobalt phosphate auxiliary silver phosphate photocatalyst is made in 75 DEG C of drying.
Aid in silver phosphate photocatalyst 0.3g to be added to the gold orange 7 that 500mL concentration is 30mg/L obtained cobalt phosphate to give up
In water, under the irradiation of 300w Metal halogen lamps, 30min is reacted, percent of decolourization is 97.4%, after catalyst separation under the same conditions again
Recycling four times, percent of decolourization is respectively 97.1%, 96.7%, 96.5%, 96.2%.
For identical waste water under the same conditions, the degradation efficiency of pure phosphoric acid silver is 89.2%, in phase after separation
Reused four times with conditions of, percent of decolourization is respectively 87.5%, 83.2%, 77.6%, 70.5%.
By under the auxiliary of cobalt phosphate, the efficiency and stability of silver phosphate catalyst have large increase.
Embodiment 3
24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates are weighed, configured
Into 20mmol/L disodium phosphate soln；Both the above solution is mixed under 400 revs/min of rotating speed, yellow green is formed
Colloid substance, persistently stirs 4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process, generates phosphoric acid silver colloid；By phosphoric acid
Silver colloid is placed in pellicle bag, with water washing is distilled 4 times, gets rid of dissociated ion, then the phosphoric acid silver colloid is added to
60mL concentration is in 2mol/L cobalt nitrate solution, soaks 3 days, in silver orthophosphate particle surface formation phosphoric acid cobalt nano-particle, Gu
Liquid is separated, deionized water washing solid 3 times, and a kind of cobalt phosphate auxiliary silver phosphate photocatalyst is made in 95 DEG C of drying.
Silver phosphate photocatalyst 0.3g is aided in be added to the rose red b that 500mL concentration is 30mg/L obtained cobalt phosphate
In waste water, under the irradiation of 300w Metal halogen lamps, 30min is reacted, percent of decolourization is 98.1%, can be reused after catalyst separation.
Claims (1)
1. a kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst, it is characterized in that in turn including the following steps：
1) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid hydrogen two is weighed
Sodium, is configured to 20mmol/L disodium phosphate soln；
2) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, lasting stirring
3~4h, disodium hydrogen phosphate and nitric acid silver reaction in whipping process generate phosphoric acid silver colloid；
3) phosphoric acid silver colloid is placed in pellicle bag, with distillation water washing 3~4 times, gets rid of dissociated ion, then by the phosphoric acid
Silver colloid is added in the cobalt nitrate solution that 60~80mL concentration is 1~2mol/L, is soaked 1~3 day, in silver orthophosphate particle surface
Phosphoric acid cobalt nano-particle is formed, a kind of phosphoric acid is made in separation of solid and liquid, deionized water washing solid 2~3 times, 75~105 DEG C of drying
Cobalt aids in silver phosphate photocatalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201102.3A CN107096554A (en) | 2017-03-30 | 2017-03-30 | A kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201102.3A CN107096554A (en) | 2017-03-30 | 2017-03-30 | A kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107096554A true CN107096554A (en) | 2017-08-29 |
Family
ID=59675732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710201102.3A Pending CN107096554A (en) | 2017-03-30 | 2017-03-30 | A kind of cobalt phosphate aids in the preparation method of silver phosphate photocatalyst |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107096554A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000042415A (en) * | 1998-08-04 | 2000-02-15 | Nissan Motor Co Ltd | Catalyst for exhaust gas purification using hydrocarbon reforming material |
| CN104014355A (en) * | 2014-06-19 | 2014-09-03 | 中国矿业大学 | Preparation method of visible-light catalyst |
| CN105170166A (en) * | 2015-09-21 | 2015-12-23 | 天津工业大学 | Cobalt/silver phosphate photocatalytic material and synthesizing method thereof |
-
2017
- 2017-03-30 CN CN201710201102.3A patent/CN107096554A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000042415A (en) * | 1998-08-04 | 2000-02-15 | Nissan Motor Co Ltd | Catalyst for exhaust gas purification using hydrocarbon reforming material |
| CN104014355A (en) * | 2014-06-19 | 2014-09-03 | 中国矿业大学 | Preparation method of visible-light catalyst |
| CN105170166A (en) * | 2015-09-21 | 2015-12-23 | 天津工业大学 | Cobalt/silver phosphate photocatalytic material and synthesizing method thereof |
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Application publication date: 20170829 |