CN107090105A - A kind of anti-skidding sole for children - Google Patents
A kind of anti-skidding sole for children Download PDFInfo
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- CN107090105A CN107090105A CN201710422711.1A CN201710422711A CN107090105A CN 107090105 A CN107090105 A CN 107090105A CN 201710422711 A CN201710422711 A CN 201710422711A CN 107090105 A CN107090105 A CN 107090105A
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- sole
- attapulgite
- nano magnesia
- magnesia
- children
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of anti-skidding sole for children, it is made up of following component：Natural rubber, butadiene-styrene rubber, filler, stearic acid, plasticizer, foaming agent, polyvinyl resin, calcium sulfate crystal whiskers, modified Nano magnesia, the activation attapulgite present invention is by adding modified oxidized magnesium and activating the synergy of attapulgite, the wet-sliding resistant performance for the sole for children being made is enabled to be significantly improved, pass through the surface modification treatment carried out to magnesia, obtain causing the hydrophily increase of magnesia, when sole is in friction, modified oxidized magnesium easier can puncture moisture film, reduce discharge moisture film area, sole is enabled to faster more directly to be in contact with rubbing surface, pass through the synergy of the attapulgite of activation, stronger adhesive attraction can be produced, dramatically increase the coefficient of friction of sole, so as to, so that after sole is directly contacted with rubbing surface, it ensure that larger coefficient of friction, so as to improve the non-skid property of sole.
Description
Technical field
The invention belongs to children's shoes technical field, and in particular to a kind of anti-skidding sole for children.
Background technology
Children are the special colonies of a class, it is necessary to meticulous protection.General footwear sole is all to use en-block construction, whole
Block sole is all using same soft or hard material, moreover, generally all harder.However, the center of gravity of people all falls in heel, walk
The weight of the overwhelming majority is all undertaken by heel during road.So, the children in the growth stage, the especially baby of age very little, children
Youngster, concentrating on the entire weight of heel relatively easily makes it sustain damage, particularly step on hard thing when, for children's shoes come
Say, there is sole good wear-resisting antiskid performance to be even more important, and preferably children can be avoided to fall down.
The content of the invention
The purpose of the present invention is that there is provided a kind of anti-skidding sole for children the problem of being directed to existing.
The present invention is achieved by the following technical solutions：
A kind of anti-skidding sole for children, is made up of following component by weight：Natural rubber 80-100, butadiene-styrene rubber 15-18, fill out
Fill agent 40-60, stearic acid 3-6, plasticizer 1-3, foaming agent 2-4, polyvinyl resin 6-8, calcium sulfate crystal whiskers 5-7, modified Nano
Magnesia 3.5-5, activation attapulgite 0.7-1；
The modified Nano magnesia is made as first being surface-treated nano magnesia using silane coupler, then again will place
Nano magnesia after reason reacts with methyl acrylate under persulfate initiation system, then by suction filtration drying, obtains.
Further, the modified Nano preparation method of magnesia is：A certain amount of coupling agent kh-570 is added to suitable
Measure in ethanol, obtain the coupling agent alcoholic solution that mass fraction is 4.2%, mass fraction is added dropwise molten for 5% aqueous acetic acid regulation
Liquid pH to 3-5, at 20 DEG C, is incubated 2 hours, then adds nano magnesia into coupling agent alcoholic solution, heating water bath to 80
DEG C, 1.5 hours are incubated, is then filtered by vacuum, surface clean 10min is carried out to nano magnesia using deionized water, dried
Do to constant weight, then nano magnesia and dodecyl sodium sulfate are pressed 5：It is ground after the mixing of 1 mass ratio, grinds 30min,
Compound is obtained, the deionized water of 3-5 times of its quality is added into compound, methyl acrylate is then added dropwise again, dripping quantity is
The 40% of mixture quality, after stirring, then adds the ammonium persulfate of mixture quality 1.5%, is heated to 80 DEG C, insulation 2 is small
When, suction filtration is then carried out, then be dried in vacuo at 100 DEG C, produce.
Further, the activation preparation method of attapulgite is：By the concave convex rod that a certain amount of granularity is 800-900 mesh
Soil is hybridly prepared into the attapulgite water slurry that mass concentration is 5.5% with water, adds the polyethylene of attapulgite quality 1.2%
Alcohol, is added in homogenizer under 2800r/min rotating speeds and stirred 3 hours, then adjusted the pH of suspension using ammoniacal liquor
To 8.6,40 DEG C are heated to, after 120r/min rotating speeds stirring 30min, 15-20min is stood, then using 300W ultrasonications
2min, then adds the ammonium persulfate of suspension quality 0.18%, is stirred 2 hours with 100r/min rotating speeds, then carries out vacuum and takes out
Filter, is dried using vacuum drying chamber at 100 DEG C, produced.
Further, the filler is white carbon.
Further, the plasticizer is trimethyl citrate.
Further, the foaming agent is the middle temperature foaming agents of DX-74MT.
The present invention has advantages below compared with prior art：The present invention is by adding modified oxidized magnesium and activation attapulgite
Synergy, enable to the wet-sliding resistant performance for the sole for children being made to be significantly improved, by being carried out to magnesia
Surface modification treatment, obtain cause magnesia hydrophily increase, when sole friction when, modified oxidized magnesium can be easier
Puncture moisture film, reduce discharge moisture film area, enable to sole to be faster more directly in contact with rubbing surface, pass through the recessed of activation
The synergy of convex rod soil, can produce stronger adhesive attraction, dramatically increase the coefficient of friction of sole, so that so that sole
After directly being contacted with rubbing surface, it is ensured that larger coefficient of friction, it is bigger that adhesion friction during actual contact becomes, so as to improve
The non-skid property of sole.
Embodiment
Embodiment 1
A kind of anti-skidding sole for children, is made up of following component by weight：Natural rubber 80, butadiene-styrene rubber 15, filler 40,
Stearic acid 3, plasticizer 1, foaming agent 2, polyvinyl resin 6, calcium sulfate crystal whiskers 5, modified Nano magnesia 3.5, activation concave convex rod
Soil 0.7；
The modified Nano magnesia is made as first being surface-treated nano magnesia using silane coupler, then again will place
Nano magnesia after reason reacts with methyl acrylate under persulfate initiation system, then by suction filtration drying, obtains.
The modified Nano preparation method of magnesia is：A certain amount of coupling agent kh-570 is added in ethanol in proper amount,
The coupling agent alcoholic solution that mass fraction is 4.2% is obtained, mass fraction is added dropwise and adjusts pH value of solution to 3 for 5% aqueous acetic acid,
At 20 DEG C, 2 hours are incubated, nano magnesia is then added into coupling agent alcoholic solution, heating water bath is to 80 DEG C, and insulation 1.5 is small
When, then it is filtered by vacuum, surface clean 10min is carried out to nano magnesia using deionized water, dried to constant weight, then will
Nano magnesia presses 5 with dodecyl sodium sulfate：It is ground after the mixing of 1 mass ratio, grinds 30min, obtain compound, to
The deionized water of 3-5 times of its quality is added in compound, methyl acrylate is then added dropwise again, dripping quantity is mixture quality
40%, after stirring, then the ammonium persulfate of mixture quality 1.5% is added, be heated to 80 DEG C, be incubated 2 hours, then taken out
Filter, then be dried in vacuo at 100 DEG C, produce.
It is described activation preparation method of attapulgite be：A certain amount of granularity is mixed for the attapulgite of 800 mesh with water and matched somebody with somebody
The attapulgite water slurry that mass concentration is 5.5% is made, adds the polyvinyl alcohol of attapulgite quality 1.2%, is added to height
Stirred in fast mixer under 2800r/min rotating speeds 3 hours, then the pH of suspension is adjusted to 8.6 using ammoniacal liquor, is heated to
40 DEG C, after 120r/min rotating speeds stirring 30min, 15min is stood, then using 300W ultrasonication 2min, then add outstanding
The ammonium persulfate of supernatant liquid quality 0.18%, is stirred 2 hours with 100r/min rotating speeds, is then filtered by vacuum, is adopted at 100 DEG C
It is dried, is produced with vacuum drying chamber.
The filler is white carbon.
The plasticizer is trimethyl citrate.
The foaming agent is the middle temperature foaming agents of DX-74MT.
Embodiment 2
A kind of anti-skidding sole for children, is made up of following component by weight：Natural rubber 100, butadiene-styrene rubber 18, filler
60th, stearic acid 3-6, plasticizer 3, foaming agent 4, polyvinyl resin 8, calcium sulfate crystal whiskers 7, modified Nano magnesia 5, activation are concavo-convex
Rod soil 1；
The modified Nano magnesia is made as first being surface-treated nano magnesia using silane coupler, then again will place
Nano magnesia after reason reacts with methyl acrylate under persulfate initiation system, then by suction filtration drying, obtains.
The modified Nano preparation method of magnesia is：A certain amount of coupling agent kh-570 is added in ethanol in proper amount,
The coupling agent alcoholic solution that mass fraction is 4.2% is obtained, mass fraction is added dropwise and adjusts pH value of solution to 5 for 5% aqueous acetic acid,
At 20 DEG C, 2 hours are incubated, nano magnesia is then added into coupling agent alcoholic solution, heating water bath is to 80 DEG C, and insulation 1.5 is small
When, then it is filtered by vacuum, surface clean 10min is carried out to nano magnesia using deionized water, dried to constant weight, then will
Nano magnesia presses 5 with dodecyl sodium sulfate：It is ground after the mixing of 1 mass ratio, grinds 30min, obtain compound, to
The deionized water of 5 times of its quality is added in compound, methyl acrylate is then added dropwise again, dripping quantity is the 40% of mixture quality,
After stirring, then the ammonium persulfate of mixture quality 1.5% is added, is heated to 80 DEG C, be incubated 2 hours, then carry out suction filtration,
It is dried in vacuo, is produced at 100 DEG C again.
It is described activation preparation method of attapulgite be：A certain amount of granularity is mixed for the attapulgite of 900 mesh with water and matched somebody with somebody
The attapulgite water slurry that mass concentration is 5.5% is made, adds the polyvinyl alcohol of attapulgite quality 1.2%, is added to height
Stirred in fast mixer under 2800r/min rotating speeds 3 hours, then the pH of suspension is adjusted to 8.6 using ammoniacal liquor, is heated to
40 DEG C, after 120r/min rotating speeds stirring 30min, 20min is stood, then using 300W ultrasonication 2min, then add outstanding
The ammonium persulfate of supernatant liquid quality 0.18%, is stirred 2 hours with 100r/min rotating speeds, is then filtered by vacuum, is adopted at 100 DEG C
It is dried, is produced with vacuum drying chamber.
The filler is white carbon.
The plasticizer is trimethyl citrate.
The foaming agent is the middle temperature foaming agents of DX-74MT.
Embodiment 3
A kind of anti-skidding sole for children, is made up of following component by weight：Natural rubber 90, butadiene-styrene rubber 16, filler 50,
Stearic acid 5, plasticizer 2, foaming agent 3, polyvinyl resin 7, calcium sulfate crystal whiskers 6, modified Nano magnesia 4.0, activation concave convex rod
Soil 0.8；
The modified Nano magnesia is made as first being surface-treated nano magnesia using silane coupler, then again will place
Nano magnesia after reason reacts with methyl acrylate under persulfate initiation system, then by suction filtration drying, obtains.
The modified Nano preparation method of magnesia is：A certain amount of coupling agent kh-570 is added in ethanol in proper amount,
The coupling agent alcoholic solution that mass fraction is 4.2% is obtained, mass fraction is added dropwise and adjusts pH value of solution to 4 for 5% aqueous acetic acid,
At 20 DEG C, 2 hours are incubated, nano magnesia is then added into coupling agent alcoholic solution, heating water bath is to 80 DEG C, and insulation 1.5 is small
When, then it is filtered by vacuum, surface clean 10min is carried out to nano magnesia using deionized water, dried to constant weight, then will
Nano magnesia presses 5 with dodecyl sodium sulfate：It is ground after the mixing of 1 mass ratio, grinds 30min, obtain compound, to
The deionized water of 3-5 times of its quality is added in compound, methyl acrylate is then added dropwise again, dripping quantity is mixture quality
40%, after stirring, then the ammonium persulfate of mixture quality 1.5% is added, be heated to 80 DEG C, be incubated 2 hours, then taken out
Filter, then be dried in vacuo at 100 DEG C, produce.
It is described activation preparation method of attapulgite be：A certain amount of granularity is mixed for the attapulgite of 850 mesh with water and matched somebody with somebody
The attapulgite water slurry that mass concentration is 5.5% is made, adds the polyvinyl alcohol of attapulgite quality 1.2%, is added to height
Stirred in fast mixer under 2800r/min rotating speeds 3 hours, then the pH of suspension is adjusted to 8.6 using ammoniacal liquor, is heated to
40 DEG C, after 120r/min rotating speeds stirring 30min, 18min is stood, then using 300W ultrasonication 2min, then add outstanding
The ammonium persulfate of supernatant liquid quality 0.18%, is stirred 2 hours with 100r/min rotating speeds, is then filtered by vacuum, is adopted at 100 DEG C
It is dried, is produced with vacuum drying chamber.
The filler is white carbon.
The plasticizer is trimethyl citrate.
The foaming agent is the middle temperature foaming agents of DX-74MT.
Comparative example 1：Differed only in embodiment 1 using common unmodified magnesia.
Comparative example 2：Differed only in embodiment 1 using the attapulgite without activation process.
Comparative example 3：Differed only in embodiment 1 and magnesia is replaced with into zinc oxide, method of modifying is constant.
Comparative example 4：Differed only in embodiment 1 and attapulgite is replaced with into bentonite, activation method is constant
Experiment：
（1）PVvalue testing
According to People's Republic of China (PRC) chemical industry standard GH/T 2729-1995, using Labthink Instruments Co., Ltd.
It is embodiment and comparative example that MXD-01A friction coefficient instruments, which test kinematics and static friction coefficient, sample of the sheet rubber under dry, wet condition,
The material for sole of shoe of preparation, it is the sample that length × width × height size is 63mm × 63mm × 2mm that uniform sizes, which are made, and draw speed is
150mm/min, test sliding distance is 140mm, tests 5 times, averages；
Table 1
As can be seen from Table 1, modified oxidized magnesium has to cooperate with activation attapulgite improves the anti-skidding action effect of sole, by oxygen
Change zinc to replace magnesia or bentonite replacement attapulgite is substantially reduced into the skidproof effect of sole, using common magnesia
Or raising of the common attapulgite to sole skidproof effect is also limited.
Claims (6)
1. a kind of anti-skidding sole for children, it is characterised in that be made up by weight of following component：Natural rubber 80-100, fourth
Benzene rubber 15-18, filler 40-60, stearic acid 3-6, plasticizer 1-3, foaming agent 2-4, polyvinyl resin 6-8, calcium sulfate are brilliant
Must 5-7, modified Nano magnesia 3.5-5, activation attapulgite 0.7-1；
The modified Nano magnesia is made as first being surface-treated nano magnesia using silane coupler, then again will place
Nano magnesia after reason reacts with methyl acrylate under persulfate initiation system, then by suction filtration drying, obtains.
2. a kind of anti-skidding sole for children according to claim 1, it is characterised in that the modified Nano magnesia preparation side
Method is：A certain amount of coupling agent kh-570 is added in ethanol in proper amount, the coupling agent alcoholic solution that mass fraction is 4.2% is obtained,
Mass fraction is added dropwise and adjusts pH value of solution to 3-5 for 5% aqueous acetic acid, at 20 DEG C, is incubated 2 hours, then adds nano oxygen
Change magnesium into coupling agent alcoholic solution, heating water bath is incubated 1.5 hours, be then filtered by vacuum, using deionized water to 80 DEG C
Surface clean 10min is carried out to nano magnesia, dried to constant weight, then nano magnesia and dodecyl sodium sulfate are pressed 5：1
It is ground after mass ratio mixing, grinds 30min, obtain compound, the deionization of 3-5 times of its quality is added into compound
Water, is then added dropwise methyl acrylate again, and dripping quantity is the 40% of mixture quality, after stirring, then adds mixture quality
1.5% ammonium persulfate, is heated to 80 DEG C, is incubated 2 hours, then carries out suction filtration, then is dried in vacuo at 100 DEG C, i.e.,
.
3. a kind of anti-skidding sole for children according to claim 1, it is characterised in that the activation preparation method of attapulgite
For：Attapulgite and water that a certain amount of granularity is 800-900 mesh are hybridly prepared into the attapulgite that mass concentration is 5.5%
Water slurry, adds the polyvinyl alcohol of attapulgite quality 1.2%, is added in homogenizer and is stirred under 2800r/min rotating speeds
Mix 3 hours, then the pH of suspension is adjusted to 8.6 using ammoniacal liquor, 40 DEG C are heated to, 30min is stirred with 120r/min rotating speeds
Afterwards, 15-20min is stood, then using 300W ultrasonication 2min, then adds the ammonium persulfate of suspension quality 0.18%, with
100r/min rotating speeds are stirred 2 hours, are then filtered by vacuum, are dried, produced using vacuum drying chamber at 100 DEG C.
4. a kind of anti-skidding sole for children according to claim 1, it is characterised in that the filler is white carbon.
5. a kind of anti-skidding sole for children according to claim 1, it is characterised in that the plasticizer is citric acid front three
Ester.
6. a kind of anti-skidding sole for children according to claim 1, it is characterised in that the foaming agent is DX-74MT
Middle temperature foaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710422711.1A CN107090105B (en) | 2017-06-07 | 2017-06-07 | A kind of anti-skidding sole for children |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710422711.1A CN107090105B (en) | 2017-06-07 | 2017-06-07 | A kind of anti-skidding sole for children |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107090105A true CN107090105A (en) | 2017-08-25 |
| CN107090105B CN107090105B (en) | 2018-03-09 |
Family
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| CN201710422711.1A Expired - Fee Related CN107090105B (en) | 2017-06-07 | 2017-06-07 | A kind of anti-skidding sole for children |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659278A (en) * | 2018-06-19 | 2018-10-16 | 明光市天淼新能源科技有限公司 | A kind of production method of anti-skidding polymer composite |
| CN108822355A (en) * | 2018-07-12 | 2018-11-16 | 合肥连森裕腾新材料科技开发有限公司 | A kind of anti-skidding nanocomposite |
| CN110643084A (en) * | 2019-10-22 | 2020-01-03 | 温州职业技术学院 | Enhancement mode antiskid sole and antiskid shoes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143039A (en) * | 2007-11-01 | 2008-03-19 | 青岛亨达集团有限公司 | Rubber and wood powder mixed non-slip sole material |
| CN102863663A (en) * | 2012-10-23 | 2013-01-09 | 南通市黄海电机有限公司 | High abrasion resistance polymer rubber sole |
| CN104672515A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Antiskid wear-resistant sole material and preparation method thereof |
-
2017
- 2017-06-07 CN CN201710422711.1A patent/CN107090105B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143039A (en) * | 2007-11-01 | 2008-03-19 | 青岛亨达集团有限公司 | Rubber and wood powder mixed non-slip sole material |
| CN102863663A (en) * | 2012-10-23 | 2013-01-09 | 南通市黄海电机有限公司 | High abrasion resistance polymer rubber sole |
| CN104672515A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Antiskid wear-resistant sole material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659278A (en) * | 2018-06-19 | 2018-10-16 | 明光市天淼新能源科技有限公司 | A kind of production method of anti-skidding polymer composite |
| CN108822355A (en) * | 2018-07-12 | 2018-11-16 | 合肥连森裕腾新材料科技开发有限公司 | A kind of anti-skidding nanocomposite |
| CN110643084A (en) * | 2019-10-22 | 2020-01-03 | 温州职业技术学院 | Enhancement mode antiskid sole and antiskid shoes |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107090105B (en) | 2018-03-09 |
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