CN107083562A - The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth - Google Patents
The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth Download PDFInfo
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- CN107083562A CN107083562A CN201710265473.8A CN201710265473A CN107083562A CN 107083562 A CN107083562 A CN 107083562A CN 201710265473 A CN201710265473 A CN 201710265473A CN 107083562 A CN107083562 A CN 107083562A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/02—Electrophoretic coating characterised by the process with inorganic material
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D13/00—Friction clutches
- F16D13/58—Details
- F16D13/60—Clutching elements
- F16D13/64—Clutch-plates; Clutch-lamellae
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
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Abstract
The invention discloses a kind of method that graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, the step such as its preparation for including graphene oxide water solution, nanodiamond liquid dispersion, composite fiber surface electrophoretic deposition graphene oxide and Nano diamond.Graphene oxide and Nano diamond are successively uniformly distributed in composite fibre each fiber surface and formed between the fibers and bridged by the present invention using the electrophoresis precipitation method, it is heat-treated again, being bonded for graphene oxide, Nano diamond and composite fibre can be realized, improve the adhesive force of graphene oxide, Nano diamond in composite fiber surface, modified composite fibre is enabled to inherit the high thermal conductivity of graphene and the super wear resistance of Nano diamond, can be with more preferable heat conductivility with stronger uniform wearability.
Description
Technical field
The present invention relates to fibrous material field, and in particular to a kind of graphene oxide and Nano diamond be modified automobile from
The method of clutch dough sheet complex fabric cloth.
Background technology
Car clutch face sheet is the component materials that vehicle performs transmission agency by rubbing action, is the one of friction material
Kind, it is very important breaking piece in automobile, the realization for the feature, security and comfortableness of automobile has
Material impact.Conventional car clutch face sheet mainly has the raw materials such as binding agent, reinforcing fiber and filler grain to be made.Its
In, reinforcing fiber is the important component of clutch surface, and main load bearing unit plays skeleton function, material is had necessarily strong
Degree and toughness, the mechanism such as can experience a shock, shear, stretching and occurring without crack fracture, collapse the mechanical damage such as scarce, to material
The performance important such as fretting wear.The main development direction of the current reinforcing fiber of composite fibre stone, from performance and
Complementary two or more the fiber composite enhancing of price, can not only reduce cost, additionally it is possible to play respective advantage, more
Fill a vacancy sunken, improve performance.
Ren Zengmao is at it《Complex-fiber Non-asbestos Winding Clutch Facing is developed》Elaborated in one text according to glass
They are twisted together one by fiber 50%-60%, Kafra fiber 0%-20%, carbon fiber 0%-10%, other fibers 0%-10% ratio
Rise, a kind of mixed type composite fibre is made as reinforcing fiber to substitute asbestos fibre, while being set from performance is preferably modified
Fat, rubber and its complex, frictional property regulator etc. do binding agent and filler, and a kind of friction and wear behavior answering well is made
Condensating fiber type non-asbestos winding form clutch plate.But as automobile is towards high speed, heavily loaded, comfortable safe development, it is right
The performance requirement of clutch surface used in automobile also more and more higher, this requires composite fibre needs higher more stable
Coefficient of friction, stronger anti-wear performance and more preferable heat conductivility.
Therefore, graphene oxide and Nano diamond are successively uniformly distributed in compound by the present invention using the electrophoresis precipitation method
Each fiber surface and bridge joint is formed between the fibers in fiber, then be heat-treated, it is possible to achieve graphene oxide, receive
Rice diamond is bonded with composite fibre, improves the adhesive force of graphene oxide, Nano diamond in composite fiber surface so that
Modified composite fibre inherits the high thermal conductivity of graphene and the super wear resistance energy of Nano diamond, with stronger etc. resistance to
Grind performance and more preferable heat conductivility.
The content of the invention
Car clutch face sheet is modified with again it is an object of the invention to provide a kind of graphene oxide and Nano diamond
The method of condensating fiber cloth, can significantly improve the anti-wear performance and heat conductivility of complex fabric cloth.
To achieve the above object, the present invention is adopted the following technical scheme that:
The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, including following step
Suddenly:
(1)By graphene oxide add water ultrasonic agitation be made mass concentration be 0.5-1.0mg/mL graphene oxide water solution,
It is stand-by;
(2)According to mass ratio 15-18:0.3-0.5:0.4-0.6:0.01 mixes absolute ethyl alcohol, acetone, iodine, Nano diamond
Uniformly, ultrasonic disperse produces nanodiamond liquid dispersion, stand-by;
(3)Using complex fabric cloth as anode, two pieces of an equal amount of stainless steel plates as to electrode runs parallel as compound
Fiber both sides are as electrophoretic apparatus, and electrode distance is 1-2cm, then adds step(1)Obtained graphene oxide water solution is made
For electrophoresis liquid, DC voltage control takes out complex fabric cloth after 15-20V, electrophoretic deposition 30-40min, in 1-2L/minN2Protect
Shield atmosphere,(2-3)×10-3Pa vacuum protections and 280-360 DEG C of temperature conditionss high-temperature process 4-7h, fiber cloth cooling to be composite
It is reentered into after to room temperature in electrophoretic apparatus, adds step(2)Obtained nanodiamond liquid dispersion is used as electrophoresis liquid, direct current
Voltage control takes out complex fabric cloth after 40-50V, electrophoretic deposition 5-10min, in 2-3L/minN2Protective atmosphere,(1-2)×
10-3Pa vacuum protections and 350-400 DEG C of temperature conditionss high-temperature process 2-5h, are cooled to room temperature, produce graphene oxide and receive
Rice diamond modified composite fiber cloth.
Step(1)Described graphene oxide is made using Hummers methods.
Step(1)Described ultrasonic power is 200-300W, and ultrasonic time is 5-10min.
Step(2)Described Nano diamond is made by explosion method, and particle diameter is 1-10nmm.
Step(2)Described ultrasonic power is 150-250W, and ultrasonic time is 10-15min.
Step(3)Composite fibre in described complex fabric cloth is selected from glass fibre, aramid fiber, acrylic fiber, carbon
Two or more fiber milling in fiber, copper fiber, steel fibre, sepiolite fibre, potassium titanate fibre, alumina silicate fibre
Form.
Beneficial effects of the present invention:
Graphene oxide and Nano diamond are successively uniformly distributed in composite fibre often by the present invention using the electrophoresis precipitation method
A piece fiber surface and formation bridge joint, then be heat-treated between the fibers, it is possible to achieve graphene oxide, Nano diamond
With being bonded for composite fibre, the adhesive force of graphene oxide, Nano diamond in composite fiber surface is improved so that modified
Composite fibre inherits the high thermal conductivity of graphene and the super wear resistance energy of Nano diamond, with stronger uniform wearability can and
More preferable heat conductivility.
Embodiment
Embodiment 1
The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, including following step
Suddenly:
(1)By graphene oxide add water ultrasonic agitation be made mass concentration be 0.5mg/mL graphene oxide water solution, it is stand-by;
(2)According to mass ratio 15:0.3:0.4:0.01 is well mixed absolute ethyl alcohol, acetone, iodine, Nano diamond, ultrasound point
Dissipate and produce nanodiamond liquid dispersion, it is stand-by;
(3)Using complex fabric cloth as anode, two pieces of an equal amount of stainless steel plates as to electrode runs parallel as compound
Fiber both sides are as electrophoretic apparatus, and electrode distance is 1cm, then adds step(1)Obtained graphene oxide water solution conduct
Electrophoresis liquid, DC voltage control takes out complex fabric cloth after 15V, electrophoretic deposition 40min, in 1L/minN2Protective atmosphere, 2 ×
10-3Pa vacuum protections and 280 DEG C of temperature conditionss high-temperature process 7h, fiber cloth to be composite, which is cooled to after room temperature, is reentered into electrophoresis
In device, step is added(2)Obtained nanodiamond liquid dispersion sinks as electrophoresis liquid, DC voltage control in 40V, electrophoresis
Complex fabric cloth is taken out after product 10min, in 2L/minN2Protective atmosphere, 1 × 10-3Pa vacuum protections and 350 DEG C of temperature conditionss
High-temperature process 5h, is cooled to room temperature, produces graphene oxide and Nano diamond modified composite fiber cloth.
Step(1)Described graphene oxide is made using Hummers methods.
Step(1)Described ultrasonic power is 200W, and ultrasonic time is 10min.
Step(2)Described Nano diamond is made by explosion method, and particle diameter is 1nmm.
Step(2)Described ultrasonic power is 150W, and ultrasonic time is 15min.
Step(3)Composite fibre in described complex fabric cloth is glass fibre, two kinds of fiber millings of aramid fiber and
Into.
Embodiment 2
The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, including following step
Suddenly:
(1)By graphene oxide add water ultrasonic agitation be made mass concentration be 0.8mg/mL graphene oxide water solution, it is stand-by;
(2)According to mass ratio 16:0.4:0.5:0.01 is well mixed absolute ethyl alcohol, acetone, iodine, Nano diamond, ultrasound point
Dissipate and produce nanodiamond liquid dispersion, it is stand-by;
(3)Using complex fabric cloth as anode, two pieces of an equal amount of stainless steel plates as to electrode runs parallel as compound
Fiber both sides are as electrophoretic apparatus, and electrode distance is 1.5cm, then adds step(1)Obtained graphene oxide water solution is made
For electrophoresis liquid, DC voltage control takes out complex fabric cloth after 18V, electrophoretic deposition 35min, in 1.5L/minN2Protect gas
Atmosphere, 2.5 × 10-3Pa vacuum protections and 320 DEG C of temperature conditionss high-temperature process 6h, fiber cloth to be composite are cooled to after room temperature again
It is put into electrophoretic apparatus, adds step(2)Obtained nanodiamond liquid dispersion exists as electrophoresis liquid, DC voltage control
Complex fabric cloth is taken out after 45V, electrophoretic deposition 8min, in 2.5L/minN2Protective atmosphere, 1.5 × 10-3Pa vacuum protections and
380 DEG C of temperature conditionss high-temperature process 4h, are cooled to room temperature, produce graphene oxide and Nano diamond modified composite fiber cloth.
Step(1)Described graphene oxide is made using Hummers methods.
Step(1)Described ultrasonic power is 250W, and ultrasonic time is 8min.
Step(2)Described Nano diamond is made by explosion method, and particle diameter is 5nmm.
Step(2)Described ultrasonic power is 200W, and ultrasonic time is 12min.
Step(3)Composite fibre in described complex fabric cloth is glass fibre, acrylic fiber, three kinds of fibers of copper fiber
It is twisted to form.
Embodiment 3
The method that a kind of graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, including following step
Suddenly:
(1)By graphene oxide add water ultrasonic agitation be made mass concentration be 1.0mg/mL graphene oxide water solution, it is stand-by;
(2)According to mass ratio 18:0.5:0.6:0.01 is well mixed absolute ethyl alcohol, acetone, iodine, Nano diamond, ultrasound point
Dissipate and produce nanodiamond liquid dispersion, it is stand-by;
(3)Using complex fabric cloth as anode, two pieces of an equal amount of stainless steel plates as to electrode runs parallel as compound
Fiber both sides are as electrophoretic apparatus, and electrode distance is 2cm, then adds step(1)Obtained graphene oxide water solution conduct
Electrophoresis liquid, DC voltage control takes out complex fabric cloth after 20V, electrophoretic deposition 30min, in 2L/minN2Protective atmosphere, 3 ×
10-3Pa vacuum protections and 360 DEG C of temperature conditionss high-temperature process 4h, fiber cloth to be composite, which is cooled to after room temperature, is reentered into electrophoresis
In device, step is added(2)Obtained nanodiamond liquid dispersion sinks as electrophoresis liquid, DC voltage control in 50V, electrophoresis
Complex fabric cloth is taken out after product 5min, in 3L/minN2Protective atmosphere, 2 × 10-3Pa vacuum protections and 400 DEG C of temperature conditionss height
Temperature processing 2h, is cooled to room temperature, produces graphene oxide and Nano diamond modified composite fiber cloth.
Step(1)Described graphene oxide is made using Hummers methods.
Step(1)Described ultrasonic power is 300W, and ultrasonic time is 5min.
Step(2)Described Nano diamond is made by explosion method, and particle diameter is 10nmm.
Step(2)Described ultrasonic power is 250W, and ultrasonic time is 10min.
Step(3)Composite fibre in described complex fabric cloth is aramid fiber, carbon fiber, steel fibre, potassium titanate are fine
Four kinds of fiber millings of dimension are formed.
Claims (6)
1. a kind of method that graphene oxide and Nano diamond are modified car clutch face sheet complex fabric cloth, its feature exists
In comprising the following steps:
(1)By graphene oxide add water ultrasonic agitation be made mass concentration be 0.5-1.0mg/mL graphene oxide water solution,
It is stand-by;
(2)According to mass ratio 15-18:0.3-0.5:0.4-0.6:0.01 mixes absolute ethyl alcohol, acetone, iodine, Nano diamond
Uniformly, ultrasonic disperse produces nanodiamond liquid dispersion, stand-by;
(3)Using complex fabric cloth as anode, two pieces of an equal amount of stainless steel plates as to electrode runs parallel as compound
Fiber both sides are as electrophoretic apparatus, and electrode distance is 1-2cm, then adds step(1)Obtained graphene oxide water solution is made
For electrophoresis liquid, DC voltage control takes out complex fabric cloth after 15-20V, electrophoretic deposition 30-40min, in 1-2L/minN2Protect
Shield atmosphere,(2-3)×10-3Pa vacuum protections and 280-360 DEG C of temperature conditionss high-temperature process 4-7h, fiber cloth cooling to be composite
It is reentered into after to room temperature in electrophoretic apparatus, adds step(2)Obtained nanodiamond liquid dispersion is used as electrophoresis liquid, direct current
Voltage control takes out complex fabric cloth after 40-50V, electrophoretic deposition 5-10min, in 2-3L/minN2Protective atmosphere,(1-2)×
10-3Pa vacuum protections and 350-400 DEG C of temperature conditionss high-temperature process 2-5h, are cooled to room temperature, produce graphene oxide and receive
Rice diamond modified composite fiber cloth.
2. a kind of graphene oxide according to claim 1 and Nano diamond are modified car clutch face sheet with compound fibre
The method for tieing up cloth, it is characterised in that step(1)Described graphene oxide is made using Hummers methods.
3. a kind of graphene oxide according to claim 1 and Nano diamond are modified car clutch face sheet with compound fibre
The method for tieing up cloth, it is characterised in that step(1)Described ultrasonic power is 200-300W, and ultrasonic time is 5-10min.
4. a kind of graphene oxide according to claim 1 and Nano diamond are modified car clutch face sheet with compound fibre
The method for tieing up cloth, it is characterised in that step(2)Described Nano diamond is made by explosion method, and particle diameter is 1-10nmm.
5. a kind of graphene oxide according to claim 1 and Nano diamond are modified car clutch face sheet with compound fibre
The method for tieing up cloth, it is characterised in that step(2)Described ultrasonic power is 150-250W, and ultrasonic time is 10-15min.
6. a kind of graphene oxide according to claim 1 and Nano diamond are modified car clutch face sheet with compound fibre
The method for tieing up cloth, it is characterised in that step(3)It is fine that composite fibre in described complex fabric cloth is selected from glass fibre, aramid fiber
Two kinds or two in dimension, acrylic fiber, carbon fiber, copper fiber, steel fibre, sepiolite fibre, potassium titanate fibre, alumina silicate fibre
Above fiber milling is planted to form.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108046842A (en) * | 2017-11-17 | 2018-05-18 | 宿迁南航新材料与装备制造研究院有限公司 | A kind of preparation method of graphene enhancing ceramic fibre |
Citations (4)
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---|---|---|---|---|
CN1947990A (en) * | 2005-10-11 | 2007-04-18 | 江苏威特集团有限公司 | Novel wet type method for producing surface sheet of clutch of automobile |
CN101792571A (en) * | 2010-02-04 | 2010-08-04 | 浙江科马摩擦材料有限公司 | Novel non-rubber winding clutch facing |
CN103030921A (en) * | 2011-09-29 | 2013-04-10 | 浙江科马摩擦材料股份有限公司 | Clutch facing without rubber winding and preparation method thereof |
CN103351574A (en) * | 2013-06-03 | 2013-10-16 | 海盐华强树脂有限公司 | Method for preparing short fiber reinforced friction material through adopting long fibers |
-
2017
- 2017-04-21 CN CN201710265473.8A patent/CN107083562B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1947990A (en) * | 2005-10-11 | 2007-04-18 | 江苏威特集团有限公司 | Novel wet type method for producing surface sheet of clutch of automobile |
CN101792571A (en) * | 2010-02-04 | 2010-08-04 | 浙江科马摩擦材料有限公司 | Novel non-rubber winding clutch facing |
CN103030921A (en) * | 2011-09-29 | 2013-04-10 | 浙江科马摩擦材料股份有限公司 | Clutch facing without rubber winding and preparation method thereof |
CN103351574A (en) * | 2013-06-03 | 2013-10-16 | 海盐华强树脂有限公司 | Method for preparing short fiber reinforced friction material through adopting long fibers |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108046842A (en) * | 2017-11-17 | 2018-05-18 | 宿迁南航新材料与装备制造研究院有限公司 | A kind of preparation method of graphene enhancing ceramic fibre |
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