CN107083520A - A kind of low-alloy high-strength steel plate and its production method - Google Patents

A kind of low-alloy high-strength steel plate and its production method Download PDF

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Publication number
CN107083520A
CN107083520A CN201710142782.6A CN201710142782A CN107083520A CN 107083520 A CN107083520 A CN 107083520A CN 201710142782 A CN201710142782 A CN 201710142782A CN 107083520 A CN107083520 A CN 107083520A
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CN
China
Prior art keywords
low
steel plate
strength steel
alloy high
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710142782.6A
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Chinese (zh)
Inventor
夏明生
刘立学
刘春雨
王云阁
郭志凯
李梦英
李桂兰
刘丽萍
关淑巧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Original Assignee
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tangshan Iron and Steel Group Co Ltd, HBIS Co Ltd Tangshan Branch filed Critical Tangshan Iron and Steel Group Co Ltd
Priority to CN201710142782.6A priority Critical patent/CN107083520A/en
Publication of CN107083520A publication Critical patent/CN107083520A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/02Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of sheets
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium

Abstract

The invention discloses a kind of low-alloy high-strength steel plate and its production method, it includes hot rolling, cold rolling, annealing and smooth process, and the weight/mass percentage composition of the steel plate composition is:C 0.08~0.10%, Mn 0.8~1.0%, Nb 0.045~0.060%, Als 200~500ppm, P≤0.025%, S≤0.010%, N≤50ppm, remaining is iron and inevitable impurity.This steel plate is designed using low-carbon, and the intensity of material is controlled by Mn solution strengthening, Nb precipitation strengths and refined crystalline strengthening;And it is few to be added without precious alloy, alloying element content, the characteristics of with low cost.This method passes through the low cost production of the optimum organization reality of the procedure parameters such as hot-rolling coiling temperature, cold rolling reduction ratio, continuous annealing process annealing temperature, smooth elongation percentage low-alloy high-strength steel;While the high performance low-alloy high-strength steel of production is required to meet the difference of client, cost is reduced, with significant economic benefit.

Description

A kind of low-alloy high-strength steel plate and its production method
Technical field
The invention belongs to metal material field, especially a kind of low-alloy high-strength steel plate and its production method.
Background technology
The raising required with vehicle safety performance, more and more using with good strong modeling in body of a motor car manufacture Long-pending high-strength steel.On the one hand car body weight is mitigated on the premise of vehicle safety performance is not lost;On the other hand reduction automobile is oily Consumption and reduction environmental pollution;Therefore, use of the high-strength steel in body of a motor car manufacture is more and more, especially in some safety members In structural member production.And traditional micro-alloyed high strength steel is due to good yield tensile ratio and welding performance, in automobile zero Still widely used in part manufacture, such steel grade is mainly by adding the solution strengthening elements such as Mn and Si and Nb, V and Ti etc. Micro alloying element improves the strength of materials, is provided simultaneously with certain forming property;But the cost that also result in such steel is higher.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of inexpensive low-alloy high-strength steel plate;Present invention also offers A kind of production method of low-alloy high-strength steel plate.
In order to solve the above technical problems, the weight/mass percentage composition of present component is:C 0.08~0.10%, Mn 0.8~ 1.0%, Nb 0.045~0.060%, Als 200~500ppm, P≤0.025%, S≤0.010%, N≤50ppm, remaining is iron With inevitable impurity.
In the present invention:
C:Carbon is most basic element in steel, and as the interstitial atom in steel, very important work is played to the intensity for improving steel With the yield strength and tensile strength influence on steel are maximum.Under normal circumstances, the intensity of steel is higher, and elongation percentage is lower, therefore carbon Content is controlled between 0.08~0.10%.
Mn:Solution strengthening element, ferritic intensity can be improved by typically often adding the Mn of 1% (mass percent) content 40MPa, it is generally the case that the fire check produced for Al killed steel in order to avoid S, generally require by Mn/S control 20 and with On;Simultaneously during Cooling Austenite Transformation, the transformation to bainite and pearlite can be postponed.
P:In the present invention, P is impurity element, control it is more low better.
Al:Deoxidant element, in order to which effectively deoxidation generally controls Als in 200~500ppm.
N:For objectionable impurities elements, diffusion velocity is fast in the ferrite of room temperature, it is easy to cause room-temperature aging, in order that Final products have a good forming property, N content control is in 50ppm and following in the present invention.
S:Objectionable impurities elements, it is more low better to control, and present invention control is 0.010% and less.
Nb:For carbide, nitride or carbonitride-forming elements, in hot rolling, recrystallization can be suppressed, hot rolling is refined And after annealing finished product crystal grain, while can mutually improve the toughness of material by forming precipitated phase, improve intensity.
The inventive method includes hot rolling, cold rolling, annealing and smooth process, and the weight/mass percentage composition of the steel plate composition is as above It is described.
Hot-rolled process described in the inventive method:1250~1320 DEG C of heating-up temperature, the heat time is 120~180 minutes, heat It is 870 ± 10 DEG C to roll finishing temperature, and coiling temperature is 560~680 DEG C.
Cold rolling process described in the inventive method:Cold rolling reduction ratio control is 50~80%.
Annealing operation described in the inventive method:Annealing soak temperature is 730~820 DEG C, and soaking time is 60~250s;It hurry up Cold start temperature is 670 ± 30 DEG C, and overaging temperature is 350 ± 50 DEG C, finally enters water cooling.
Smooth process described in the inventive method:Using smooth elongation control pattern, smooth elongation percentage is 1.0~1.5%.
It is using the beneficial effect produced by above-mentioned technical proposal:The present invention passes through Mn solid solution using low-carbon design Reinforcing, Nb precipitation strengths and refined crystalline strengthening control the intensity of material;And it is few to be added without precious alloy, alloying element content, The characteristics of with low cost.
The inventive method was waited by hot-rolling coiling temperature, cold rolling reduction ratio, continuous annealing process annealing temperature, smooth elongation percentage The real low cost production of low-alloy high-strength steel of the optimum organization of journey parameter;Producing high performance low-alloy high-strength steel to meet While the difference of client is required, cost is reduced, with significant economic benefit.
Embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
Embodiment 1-8:The production method of this low-alloy high-strength steel plate include steel-making, LF refining, continuous casting, hot rolling, it is cold rolling and Continuous annealing process, the technique of each operation is as described below.
(1)Steel making working procedure:Using 100 tons of top and bottom combined blown converter, by bessemerizing in reduction carbon and phosphorus, tapping process Pushing off the slag is carried out using mop, using sial complex deoxidization, manganese and niobium are configured to middle limit.
(2)LF stoves are refined and continuous casting working procedure:The FeO added in lime, the progress slag making deoxidization desulfuration operation of magnalium calcium iron, slag + MnO mass percents content is less than 1%, adds ferro-niobium and metal ferromanganese is finely adjusted to composition, while Calcium treatment is carried out, to folder Debris is denatured, quiet after Calcium treatment to blow 7~15 minutes, help inclusion floating, continuous casting working procedure casting rate be 1.0~ 1.5m/min, slab thickness is 230mm, and superheat of liquid steel is controlled at 15~30 DEG C;The weight/mass percentage composition of gained strand composition For:C 0.08~0.10%, Mn 0.8~1.0%, Nb 0.045~0.060%, Als 200~500ppm, P≤0.025%, S≤ 0.010%, N≤50ppm, remaining is iron and inevitable impurity.The specific composition proportion of strand of each embodiment is shown in Table 1.
Table 1:The chemical composition of each embodiment(wt%)
In table 1, surplus is iron and inevitable impurity.
(3)Hot rolling and cold rolling process:In hot-rolled process, 1250~1320 DEG C of heating-up temperature, the heat time is 120~180 Minute, hot rolling finishing temperature is 870 ± 10 DEG C, and coiling temperature is 560~680 DEG C.Cold rolling reduction ratio control in cold rolling process 50~80%.The specific process parameter of hot rolling and cold rolling process is shown in Table 2 in each embodiment
Table 2:Hot rolling and the technological parameter of cold rolling process
(4)Annealing and smooth process:In annealing operation, annealing soak temperature is 730~820 DEG C, and soaking time is 60~250s, Rapid cooling start temperature is 670 ± 30 DEG C, and overaging temperature is 350 ± 50 DEG C, finally enters to be water-cooled to room temperature.Smooth process is used Smooth elongation control pattern, smooth elongation percentage 1.0~1.5%.The specific process parameter of each embodiment annealing and smooth process is shown in Table 3.
Table 3:Annealing and the technological parameter of smooth process
Thickness in table 3 refers to the thickness of steel plate obtained by annealing operation.
(5)After testing, the mechanical performance of high-strength steel sheet is shown in Table 4 obtained by each embodiment.
Table 4:The mechanical performance of high-strength steel sheet
From table 4, the performance of high-strength steel sheet is stable obtained by this method.

Claims (6)

1. a kind of low-alloy high-strength steel plate, it is characterised in that the weight/mass percentage composition of its composition is:C 0.08~0.10%, Mn 0.8~1.0%, Nb 0.045~0.060%, Als 200~500ppm, P≤0.025%, S≤0.010%, N≤50ppm, remaining For iron and inevitable impurity.
2. a kind of production method of low-alloy high-strength steel plate, it is characterised in that:It includes hot rolling, cold rolling, annealing and smooth process, The weight/mass percentage composition of the steel plate composition is:C 0.08~0.10%, Mn 0.8~1.0%, Nb 0.045~0.060%, Als 200~500ppm, P≤0.025%, S≤0.010%, N≤50ppm, remaining is iron and inevitable impurity.
3. a kind of production method of low-alloy high-strength steel plate according to claim 3, it is characterised in that the Hot-roller Sequence:1250~1320 DEG C of heating-up temperature, the heat time is 120~180 minutes, and hot rolling finishing temperature is 870 ± 10 DEG C, batches temperature Spend for 560~680 DEG C.
4. a kind of production method of low-alloy high-strength steel plate according to claim 3, it is characterised in that the Cold-roller Sequence:Cold rolling reduction ratio control is 50~80%.
5. a kind of production method of low-alloy high-strength steel plate according to claim 3, it is characterised in that the lehr attendant Sequence:Annealing soak temperature is 730~820 DEG C, and soaking time is 60~250s;Rapid cooling start temperature is 670 ± 30 DEG C, overaging Temperature is 350 ± 50 DEG C, finally enters water cooling.
6. a kind of production method of low-alloy high-strength steel plate according to claim 2-5 any one, it is characterised in that The smooth process:Using smooth elongation control pattern, smooth elongation percentage is 1.0~1.5%.
CN201710142782.6A 2017-03-10 2017-03-10 A kind of low-alloy high-strength steel plate and its production method Pending CN107083520A (en)

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CN201710142782.6A CN107083520A (en) 2017-03-10 2017-03-10 A kind of low-alloy high-strength steel plate and its production method

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Application Number Priority Date Filing Date Title
CN201710142782.6A CN107083520A (en) 2017-03-10 2017-03-10 A kind of low-alloy high-strength steel plate and its production method

Publications (1)

Publication Number Publication Date
CN107083520A true CN107083520A (en) 2017-08-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904478A (en) * 2017-10-12 2018-04-13 首钢集团有限公司 Reduce the manufacture method of cold rolling low-alloy high-strength steel ferritic-pearlitic type segregation
CN109576467A (en) * 2019-01-08 2019-04-05 邯郸钢铁集团有限责任公司 Improve the control method of the logical volume performance uniformity of low-alloy high-strength steel containing Nb
CN109735768A (en) * 2019-02-15 2019-05-10 邯郸钢铁集团有限责任公司 A kind of 650MPa level low alloy high-strength steel and its production method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105714186A (en) * 2016-04-01 2016-06-29 唐山钢铁集团有限责任公司 Continuous annealing low-alloy and high-strength steel plate and production method thereof
CN105950967A (en) * 2016-06-30 2016-09-21 唐山钢铁集团有限责任公司 Method for producing 500MPa level low alloy and high strength steel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105714186A (en) * 2016-04-01 2016-06-29 唐山钢铁集团有限责任公司 Continuous annealing low-alloy and high-strength steel plate and production method thereof
CN105950967A (en) * 2016-06-30 2016-09-21 唐山钢铁集团有限责任公司 Method for producing 500MPa level low alloy and high strength steel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904478A (en) * 2017-10-12 2018-04-13 首钢集团有限公司 Reduce the manufacture method of cold rolling low-alloy high-strength steel ferritic-pearlitic type segregation
CN109576467A (en) * 2019-01-08 2019-04-05 邯郸钢铁集团有限责任公司 Improve the control method of the logical volume performance uniformity of low-alloy high-strength steel containing Nb
CN109576467B (en) * 2019-01-08 2021-03-09 邯郸钢铁集团有限责任公司 Control method for improving uniformity of coiling performance of Nb-containing low-alloy high-strength steel
CN109735768A (en) * 2019-02-15 2019-05-10 邯郸钢铁集团有限责任公司 A kind of 650MPa level low alloy high-strength steel and its production method

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Application publication date: 20170822