CN107083108A - A kind of compound oil ink and preparation method thereof - Google Patents
A kind of compound oil ink and preparation method thereof Download PDFInfo
- Publication number
- CN107083108A CN107083108A CN201710501327.0A CN201710501327A CN107083108A CN 107083108 A CN107083108 A CN 107083108A CN 201710501327 A CN201710501327 A CN 201710501327A CN 107083108 A CN107083108 A CN 107083108A
- Authority
- CN
- China
- Prior art keywords
- mixture
- polyurethane resin
- scattered
- compound oil
- oil ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 90
- 239000000203 mixture Substances 0.000 claims abstract description 82
- 238000010790 dilution Methods 0.000 claims abstract description 56
- 239000012895 dilution Substances 0.000 claims abstract description 56
- 238000004132 cross linking Methods 0.000 claims abstract description 46
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical class CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000019441 ethanol Nutrition 0.000 claims abstract description 24
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical class CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 235000019439 ethyl acetate Nutrition 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 12
- -1 propyl alcohols Chemical class 0.000 claims abstract description 12
- 125000005909 ethyl alcohol group Chemical group 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 7
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 4
- 238000004821 distillation Methods 0.000 claims abstract 2
- 238000000227 grinding Methods 0.000 claims description 63
- 239000012153 distilled water Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000011049 filling Methods 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 238000001514 detection method Methods 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 12
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 5
- 150000002367 halogens Chemical class 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 description 17
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 229940126062 Compound A Drugs 0.000 description 4
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of compound oil ink and preparation method thereof, by mass percentage, the compound oil ink includes the compound oil ink：Polyurethane resin dispensing A, urethane resin compound B and crosslinking coagent；The polyurethane resin dispensing A includes：10% 30% benzene-free ketone-free polyurethane resins, 1% 10%UK resins, 1% 20% pigment, 0.5% 5% wax powders, 10% 30% n-propyl acetates, 1% 20% normal propyl alcohols；The polyurethane resin dispensing B includes：1% 20% benzene-free ketone-free polyurethane resins, 5% 25% ethyl acetates, 1% 10% absolute ethyl alcohols and 1% 6% distillation aqueous mixtures；The crosslinking coagent includes：0.5% 5% crosslinking coagents.Above-mentioned compound oil ink main material uses benzene-free ketone-free polyurethane resin, after testing without halogen and heavy metal, meet the requirement of environmental protection.In terminal processes, do not pollute the environment.And the dissolubility of benzene-free ketone-free polyurethane resin is good, after printing-ink dilution 10%, printing reaches other existing printing ink concentrations, thus client's printing rate of transform improves 10%, can fully improve ink and redissolve performance.
Description
Technical field
The present invention relates to technical field of ink, more particularly to a kind of compound oil ink and preparation method thereof.
Background technology
Compound oil ink technology is will be common（Oiliness）Ink and UV curing technologies are combined, and common ink composition is consolidated with UV
Change material mixing with after two or more anti-forgery ink is mixed according to a certain percentage, so that it may develop with new capability
Compound oil ink be also known as inner-printing ink or mixed ink.Compound oil ink has the characteristics that：Smell is small；It is beautiful in colour, unglazed
Pool；Conjunctiva is softer；Not abrasion-resistant；Piece peel strength is big；Beneficial to compound etc..
Existing compound oil ink is used as ink adhesive, and organic pigment point using the molten polyurethane resin of ester and the matching of chlorine vinegar
Grinding is dissipated, the requirement of later stage combined strength bination is reached.However, vinyl chloride-vinyl acetate resin difficulty is difficult to dissolve, the compound oil ink of preparation redissolves poor performance,
Client's printing rate of transform is low.
The content of the invention
Based on this, it is necessary in view of the above-mentioned problems, providing a kind of compound oil ink and preparation method thereof.
A kind of compound oil ink, the compound oil ink by mass percentage, including：Polyurethane resin dispensing A, urethane resin
Dispensing B and crosslinking coagent；The polyurethane resin dispensing A includes：10%-30% benzene-free ketone-free polyurethane resins, 1%-10%UK trees
Fat, 1%-20% pigment, 0.5%-5% wax powders, 10%-30% n-propyl acetates, 1%-20% normal propyl alcohols；The polyurethane resin dispensing B
Including：1%-20% benzene-free ketone-free polyurethane resins, 5%-25% ethyl acetates, 1%-10% absolute ethyl alcohols and the mixing of 1%-6% distilled water
Thing；The crosslinking coagent includes：0.5%-5% crosslinking coagents.
Preferably, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：10%-20% is without benzene
Without ketone polyurethane resin, 1%-5%UK resins, 1%-10% pigment, 1%-5% wax powders, 10%-20% n-propyl acetates, 1%-10% positive third
Alcohol；The polyurethane resin dispensing B includes：5%-15% benzene-free ketone-free polyurethane resins, 50%-20% ethyl acetates, 1%-5% without
Water-ethanol and 1%-3% distilled water；The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
Preferably, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：10% benzene-free ketone-free
Polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% wax powders, 20% n-propyl acetate, 1%-10% normal propyl alcohols；The poly- ammonia
Ester resin compound B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and 1%-3% distilled water；
The crosslinking coagent includes：2% carbonic ester crosslinking coagent.
Preferably, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：20% benzene-free ketone-free
Polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% wax powders, 20% n-propyl acetate, 1%-10% normal propyl alcohols；The poly- ammonia
Ester resin compound B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and 1%-3% distilled water；
The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
A kind of preparation method of compound oil ink, the compound oil ink by mass percentage, including：By above-mentioned formula ratio
Polyurethane resin dispensing A mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；Detect the thin of the mixture after grinding
Degree；The fineness to be checked for measuring the mixture after the grinding is added above-mentioned less than 25 microns on the mixture after the grinding
The polyurethane resin dispensing B of formula ratio carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking of above-mentioned formula ratio is added dropwise
Auxiliary agent；Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, metal bucket is used
It is filling to the mixture progress after filtering, obtain compound oil ink.
Preferably, the compound oil ink by mass percentage, including：By the polyurethane resin dispensing A of above-mentioned formula ratio
Mixing is scattered, and grinds, and grinding temperature is controlled below 45 degree；The fineness of mixture after detection grinding；It is to be checked measure it is described
The fineness of mixture after grinding is less than the polyurethane tree that above-mentioned formula ratio is added on 25 microns, the mixture after the grinding
Fat dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10
Minute, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, using metal bucket to the mixing after filtering
Thing progress is filling, obtains compound oil ink.
Preferably, the compound oil ink by mass percentage, including：By the polyurethane resin dispensing A of above-mentioned formula ratio
Mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；The fineness of mixture after detection grinding；It is to be checked measure it is described
The fineness of mixture after grinding is less than the polyurethane tree that above-mentioned formula ratio is added on 15 microns, the mixture after the grinding
Fat dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10
Minute, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, using metal bucket to the mixing after filtering
Thing progress is filling, obtains compound oil ink.
Preferably, the compound oil ink by mass percentage, including：By the polyurethane resin dispensing A of above-mentioned formula ratio
Mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；The fineness of mixture after detection grinding；It is to be checked measure it is described
The fineness of mixture after grinding is less than the polyurethane tree that above-mentioned formula ratio is added on 25 microns, the mixture after the grinding
Fat dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10
Minute, viscosity was controlled at 20-30 seconds.The mixture of the scattered dilution is filtered, using metal bucket to the mixing after filtering
Thing progress is filling, obtains compound oil ink.
Preferably, the compound oil ink by mass percentage, including：By the polyurethane resin dispensing A of above-mentioned formula ratio
Mixing is scattered, and grinds, and grinding temperature is controlled below 45 degree；The fineness of mixture after detection grinding；It is to be checked measure it is described
The fineness of mixture after grinding is less than the polyurethane tree that above-mentioned formula ratio is added on 15 microns, the mixture after the grinding
Fat dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10
Minute, viscosity was controlled at 20-30 seconds.The mixture of the scattered dilution is filtered, using metal bucket to the mixing after filtering
Thing progress is filling, obtains compound oil ink.
Preferably, the step of being filtered to the mixture of the scattered dilution includes：Using high-pressure filteration machine to described
The mixture of scattered dilution is filtered.
Above-mentioned compound oil ink main material uses benzene-free ketone-free polyurethane resin, after testing without halogen and a huge sum of money
Category, meet the requirement of environmental protection.In terminal processes, do not pollute the environment., can and the dissolubility of benzene-free ketone-free polyurethane resin is good
Fully improve ink and redissolve performance, after printing-ink dilution 10%, printing reaches other existing printing ink concentrations, client's printing
The rate of transform improves 10%, embodies more excellent shallow reticulated printing effect.In addition, doing slow curing auxiliary agent, ink printing residual using distilled water
Without macromolecule solvent, printing total residual controls 2 milligrams/square, and the national examination criterias of GT-9685 are fully achieved.
Embodiment
The main material that the compound oil ink of this programme is used is benzene-free ketone-free polyurethane resin, when detecting residual, through inspection
Survey and be free of halogen and heavy metal, meet the requirement of environmental protection.And polyurethane resin dissolubility preferably, benzene-free ketone-free polyurethane resin it is molten
Solution property is good, can fully improve ink and redissolve performance, and after printing-ink dilution 10%, printing reaches that other existing ink are dense
Degree, client's printing rate of transform improves 10%, embodies more excellent shallow reticulated printing effect.In addition, slow curing auxiliary agent is done using distilled water,
Ink printing residual is free of macromolecule solvent, and printing total residual controls 2 milligrams/square, and GT-9685 countries detection mark is fully achieved
It is accurate.
A kind of compound oil ink, the compound oil ink by mass percentage, including：Polyurethane resin dispensing A, urethane resin
Dispensing B and crosslinking coagent；The polyurethane resin dispensing A includes：10%-30% benzene-free ketone-free polyurethane resins, 1%-10%UK trees
Fat, 1%-20% pigment, 0.5%-5% wax powders, 10%-30% n-propyl acetates, 1%-20% normal propyl alcohols；The polyurethane resin dispensing B
Including：1%-20% benzene-free ketone-free polyurethane resins, 5%-25% ethyl acetates, 1%-10% absolute ethyl alcohols and the mixing of 1%-6% distilled water
Thing；The crosslinking coagent includes：0.5%-5% crosslinking coagents.
Wherein, benzene-free ketone-free polyurethane resin can be good at reaching as ink adhesive, and the scattered grinding of organic pigment
To the requirement of later stage combined strength bination.Benzene-free ketone-free polyurethane resin is the main material of shown compound oil ink, through being examined to compound oil ink
Residual is surveyed, after testing without halogen and heavy metal.In addition, polyurethane resin dissolubility is preferably, this compound oil ink is substantially increased
Ink redissolves performance, after printing-ink dilution 10%, and printing reaches other existing printing ink concentrations, and client's printing rate of transform is carried
It is high by 10%, embody more excellent shallow reticulated printing effect.
As a preferred embodiment, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：
10%-20% benzene-free ketone-free polyurethane resins, 1%-5%UK resins, 1%-10% pigment, 1%-5% wax powders, 10%-20% n-propyl acetates,
1%-10% normal propyl alcohols；The polyurethane resin dispensing B includes：5%-15% benzene-free ketone-free polyurethane resins, 50%-20% acetic acid second
Ester, 1%-5% absolute ethyl alcohols and 1%-3% distilled water；The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
As a preferred embodiment, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：
10% benzene-free ketone-free polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% wax powders, 20% n-propyl acetate, 1%-10% positive third
Alcohol；The polyurethane resin dispensing B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and
1%-3% distilled water；The crosslinking coagent includes：2% carbonic ester crosslinking coagent.
As a preferred embodiment, by mass percentage, the polyurethane resin dispensing A includes the compound oil ink：
20% benzene-free ketone-free polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% wax powders, 20% n-propyl acetate, 1%-10% positive third
Alcohol；The polyurethane resin dispensing B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and
1%-3% distilled water；The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
Wherein, the order of addition of 10% polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and 1%-3% distilled water is not
Limit.3% distilled water is used as slow curing auxiliary agent so that ink printing residual is free of macromolecule solvent, 2 milligrams of printing total residual control/flat
Side, is fully achieved the national examination criterias of GT-9685.
A kind of preparation method of compound oil ink, the compound oil ink by mass percentage, including：By above-mentioned formula ratio
Polyurethane resin dispensing A mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；Detect the thin of the mixture after grinding
Degree；The fineness to be checked for measuring the mixture after the grinding is added above-mentioned less than 25 microns on the mixture after the grinding
The polyurethane resin dispensing B of formula ratio carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking of above-mentioned formula ratio is added dropwise
Auxiliary agent；Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, metal bucket is used
It is filling to the mixture progress after filtering, obtain compound oil ink.
As a preferred embodiment, the compound oil ink by mass percentage, including：By the polyurethane of above-mentioned formula ratio
Resin compound A mixing is scattered, and grinds, and grinding temperature is controlled below 45 degree；The fineness of mixture after detection grinding；Treat
The fineness of the mixture after the grinding is detected less than 25 microns, above-mentioned formula ratio is added on the mixture after the grinding
Polyurethane resin dispensing B carry out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；
Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, using metal bucket to mistake
Mixture progress after filter is filling, obtains compound oil ink.
As a preferred embodiment, the compound oil ink by mass percentage, including：By the polyurethane of above-mentioned formula ratio
Resin compound A mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；The fineness of mixture after detection grinding；It is to be checked
The fineness of the mixture after the grinding is measured less than 15 microns, above-mentioned formula ratio is added on the mixture after the grinding
Polyurethane resin dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；After
Continuous scattered 10 minutes, viscosity was controlled at 10-40 seconds.The mixture of the scattered dilution is filtered, using metal bucket to filtering
Mixture progress afterwards is filling, obtains compound oil ink.
As a preferred embodiment, the compound oil ink by mass percentage, including：By the polyurethane of above-mentioned formula ratio
Resin compound A mixing is scattered, and grinds, and grinding temperature is controlled below 55 degree；The fineness of mixture after detection grinding；Treat
The fineness of the mixture after the grinding is detected less than 25 microns, above-mentioned formula ratio is added on the mixture after the grinding
Polyurethane resin dispensing B carry out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；
Continue scattered 10 minutes, viscosity was controlled at 20-30 seconds.The mixture of the scattered dilution is filtered, using metal bucket to mistake
Mixture progress after filter is filling, obtains compound oil ink.
As a preferred embodiment, the compound oil ink by mass percentage, including：By the polyurethane of above-mentioned formula ratio
Resin compound A mixing is scattered, and grinds, and grinding temperature is controlled below 45 degree；The fineness of mixture after detection grinding；It is to be checked
The fineness of the mixture after the grinding is measured less than 15 microns, above-mentioned formula ratio is added on the mixture after the grinding
Polyurethane resin dispensing B carries out scattered dilution 20 minutes；After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；After
Continuous scattered 10 minutes, viscosity was controlled at 20-30 seconds.The mixture of the scattered dilution is filtered, using metal bucket to filtering
Mixture progress afterwards is filling, obtains compound oil ink.
Wherein, carbonic ester crosslinking coagent can improve intensity, heat resistance, wearability, solvent resistance.
As a preferred embodiment, the viscosity for applying the scattered rear mixture of four glasss of measurements is used.Apply four glasss be domestic application most
A kind of extensive flow cup, under the conditions of certain temperature, the time that measurement quantitative sample all flows out from the hole of specified diameter.
As a preferred embodiment, the step of being filtered to the mixture of the scattered dilution includes：Pressed through using height
Filter is filtered to the mixture of the scattered dilution.Further, using high-pressure filteration machine to the scattered dilution
Mixture is filtered twice, to remove grinding impurity.
Compound oil ink prepared by above-mentioned preparation method, main material uses benzene-free ketone-free polyurethane resin, after testing
Without halogen and heavy metal, meet the requirement of environmental protection.In terminal processes, do not pollute the environment.And polyurethane resin dissolubility compared with
Good, the preparation method of this compound oil ink substantially increases ink and redissolves performance, and client's printing rate of transform improves 10%, embodied more excellent
Different shallow reticulated printing effect.In addition, making slow curing auxiliary agent using distilled water, ink printing residual is free of macromolecule solvent, and printing is total
Residual 2 milligrams/square of control, are fully achieved the national examination criterias of GT-9685.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of compound oil ink, the compound oil ink is by mass percentage, it is characterised in that including：Polyurethane resin dispensing
A, urethane resin compound B and crosslinking coagent；
The polyurethane resin dispensing A includes：10%-30% benzene-free ketone-free polyurethane resins, 1%-10%UK resins, 1%-20% face
Material, 0.5%-5% wax powders, 10%-30% n-propyl acetates, 1%-20% normal propyl alcohols；
The polyurethane resin dispensing B includes：1%-20% benzene-free ketone-free polyurethane resins, 5%-25% ethyl acetates, 1%-10% without
Water-ethanol and 1%-6% distillation aqueous mixtures；
The crosslinking coagent includes：0.5%-5% crosslinking coagents.
2. compound oil ink according to claim 1, the compound oil ink is by mass percentage, it is characterised in that
The polyurethane resin dispensing A includes：10%-20% benzene-free ketone-free polyurethane resins, 1%-5%UK resins, 1%-10% pigment,
1%-5% wax powders, 10%-20% n-propyl acetates, 1%-10% normal propyl alcohols；
The polyurethane resin dispensing B includes：5%-15% benzene-free ketone-free polyurethane resins, 50%-20% ethyl acetates, 1%-5% without
Water-ethanol and 1%-3% distilled water；
The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
3. compound oil ink according to claim 1, the compound oil ink is by mass percentage, it is characterised in that
The polyurethane resin dispensing A includes：10% benzene-free ketone-free polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% waxes
Powder, 20% n-propyl acetate, 1%-10% normal propyl alcohols；
The polyurethane resin dispensing B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and
1%-3% distilled water；
The crosslinking coagent includes：2% carbonic ester crosslinking coagent.
4. compound oil ink according to claim 1, the compound oil ink is by mass percentage, it is characterised in that
The polyurethane resin dispensing A includes：20% benzene-free ketone-free polyurethane resin, 5%UK resins, 1%-10% pigment, 1%-5% waxes
Powder, 20% n-propyl acetate, 1%-10% normal propyl alcohols；
The polyurethane resin dispensing B includes：10% benzene-free ketone-free polyurethane resin, 15% ethyl acetate, 1%-5% absolute ethyl alcohols and
1%-3% distilled water；
The crosslinking coagent includes：1%-5% carbonic ester crosslinking coagents.
5. the preparation method of a kind of compound oil ink according to claim 1-4 any one, it is characterised in that described compound
Ink by mass percentage, including：
The polyurethane resin dispensing A of above-mentioned formula ratio is mixed scattered, and ground, grinding temperature is controlled below 55 degree；
The fineness of mixture after detection grinding；The fineness to be checked for measuring the mixture after the grinding is less than 25 microns, in institute
State and the polyurethane resin dispensing B of above-mentioned formula ratio is added on the mixture after grinding carry out scattered dilution 20 minutes；
After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds；
The mixture of the scattered dilution is filtered, it is filling to the mixture progress after filtering using metal bucket, obtain compound oil ink.
6. preparation method according to claim 5, it is characterised in that the compound oil ink by mass percentage, including：
The polyurethane resin dispensing A of above-mentioned formula ratio is mixed scattered, and ground, grinding temperature is controlled below 45 degree；
The fineness of mixture after detection grinding；The fineness to be checked for measuring the mixture after the grinding is less than 25 microns, in institute
State and the polyurethane resin dispensing B of above-mentioned formula ratio is added on the mixture after grinding carry out scattered dilution 20 minutes；
After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds；
The mixture of the scattered dilution is filtered, it is filling to the mixture progress after filtering using metal bucket, obtain compound oil ink.
7. preparation method according to claim 5, it is characterised in that the compound oil ink by mass percentage, including：
The polyurethane resin dispensing A of above-mentioned formula ratio is mixed scattered, and ground, grinding temperature is controlled below 55 degree；
The fineness of mixture after detection grinding；The fineness to be checked for measuring the mixture after the grinding is less than 15 microns, in institute
State and the polyurethane resin dispensing B of above-mentioned formula ratio is added on the mixture after grinding carry out scattered dilution 20 minutes；
After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10 minutes, viscosity was controlled at 10-40 seconds；
The mixture of the scattered dilution is filtered, it is filling to the mixture progress after filtering using metal bucket, obtain compound oil ink.
8. preparation method according to claim 5, it is characterised in that the compound oil ink by mass percentage, including：
The polyurethane resin dispensing A of above-mentioned formula ratio is mixed scattered, and ground, grinding temperature is controlled below 55 degree；
The fineness of mixture after detection grinding；The fineness to be checked for measuring the mixture after the grinding is less than 25 microns, in institute
State and the polyurethane resin dispensing B of above-mentioned formula ratio is added on the mixture after grinding carry out scattered dilution 20 minutes；
After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10 minutes, viscosity was controlled at 20-30 seconds；
The mixture of the scattered dilution is filtered, it is filling to the mixture progress after filtering using metal bucket, obtain compound oil ink.
9. preparation method according to claim 5, it is characterised in that the compound oil ink by mass percentage, including：
The polyurethane resin dispensing A of above-mentioned formula ratio is mixed scattered, and ground, grinding temperature is controlled below 45 degree；
The fineness of mixture after detection grinding；The fineness to be checked for measuring the mixture after the grinding is less than 15 microns, in institute
State and the polyurethane resin dispensing B of above-mentioned formula ratio is added on the mixture after grinding carry out scattered dilution 20 minutes；
After the completion of scattered dilution, the crosslinking coagent of above-mentioned formula ratio is added dropwise；Continue scattered 10 minutes, viscosity was controlled at 20-30 seconds；
The mixture of the scattered dilution is filtered, it is filling to the mixture progress after filtering using metal bucket, obtain compound oil ink.
10. preparation method according to claim 5, it is characterised in that filtered to the mixture of the scattered dilution
The step of include：
The mixture of the scattered dilution is filtered using high-pressure filteration machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710501327.0A CN107083108A (en) | 2017-06-27 | 2017-06-27 | A kind of compound oil ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710501327.0A CN107083108A (en) | 2017-06-27 | 2017-06-27 | A kind of compound oil ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107083108A true CN107083108A (en) | 2017-08-22 |
Family
ID=59605922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710501327.0A Pending CN107083108A (en) | 2017-06-27 | 2017-06-27 | A kind of compound oil ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107083108A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341223A (en) * | 2005-12-20 | 2009-01-07 | 帝斯曼知识产权资产管理有限公司 | Radiation curable composition |
-
2017
- 2017-06-27 CN CN201710501327.0A patent/CN107083108A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341223A (en) * | 2005-12-20 | 2009-01-07 | 帝斯曼知识产权资产管理有限公司 | Radiation curable composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964917B (en) | Water-based offset print anti-forgery ink and method for preparing same | |
| CN104263069B (en) | A kind of aqueous thermosetting glass printing ink and preparation method thereof | |
| CN109321030B (en) | Water-based plastic inner printing ink and water-based plastic surface printing ink | |
| CN107129185B (en) | A kind of lacquer and preparation method thereof | |
| CN102796420A (en) | Water-based ink color painting pigment with shading effect used on rice paper | |
| DE102014015151A1 (en) | PVD metallic effect pigment powder | |
| CN109443864A (en) | The method for making sample of titanium dioxide weatherability detection | |
| CN107083108A (en) | A kind of compound oil ink and preparation method thereof | |
| CN106596585A (en) | Quick detection method of emulsion paint film cracking | |
| US2870037A (en) | Process for treating grass | |
| CN106987207B (en) | A kind of environment-friendly spray coating type wood wax oil and its preparation method and application | |
| CN103666088B (en) | Special aqueous gold ink for tipping paper, preparation method and application thereof | |
| CN102558966A (en) | Dye-based emulsion ink and producing method thereof | |
| CN106978075B (en) | A kind of environment-friendly spray coating type white wood wax oil and its preparation method and application | |
| CN108084773A (en) | A kind of plastic film intaglio plate table printing ink and preparation method thereof | |
| CN103308357A (en) | Lead-containing paint coating standard substance and preparation method thereof | |
| JPH01203482A (en) | Proving ink | |
| CN114384022B (en) | Method for testing application stability of powder coating composition in electrostatic spraying process | |
| CN105717238A (en) | Method for detecting nuciferine in lotus leaf through liquid chromatography | |
| CN105542567B (en) | A kind of instant ink stick of effervesce and preparation method thereof | |
| CN107525847A (en) | The quick determination method of colouring agent is disabled in a kind of wax crayon and Decal | |
| CN105372181B (en) | The detection method of compatibility of the aqueous color paste in emulsion paint | |
| CN111289687B (en) | Method for adjusting and testing alkali resistance of polymer emulsion for architectural coating | |
| Xue et al. | Study on the characterization technology of hiding power of powder coating | |
| CN106995660A (en) | A kind of novel rare-earth oil colour and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180614 Address after: 528400 one of 13 Fu Ting Road, Gaoping industrial area, Zhongshan, Guangdong. Applicant after: Zhongshan feilite Chemical Co., Ltd. Address before: 528000 Shunde District, Foshan, Guangdong, Daliang, Daliang Yan Nian Road, Shunde, 104 garden shop Applicant before: Guangdong Environmental Protection Technology Co., Ltd. Shunde desert forest |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20181109 Address after: 052360 No. 227, Fumin Hutong village, Xinji Town, Xinji, Shijiazhuang, Hebei Applicant after: Zhang Chunming Address before: 528400 one of 13 Fu Ting Road, Gaoping industrial area, Zhongshan, Guangdong. Applicant before: Zhongshan feilite Chemical Co., Ltd. |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20190130 Address after: 312000 Shangyu Economic and Technological Development Zone, Hangzhou Bay, Shangyu District, Shaoxing City, Zhejiang Province Applicant after: Shaoxing Fulinhan Nanomaterials Co., Ltd. Address before: 052360 No. 227, Fumin Hutong village, Xinji Town, Xinji, Shijiazhuang, Hebei Applicant before: Zhang Chunming |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200427 Address after: 052360 Fumin Hutong 227, YueErying Village, Xinji Town, Shijiazhuang City, Hebei Province Applicant after: Zhang Chunming Address before: 312000 Hangzhou Bay Shangyu economic and Technological Development Zone, Shangyu District, Zhejiang, Shaoxing Applicant before: Shaoxing Fulinhan Nanomaterials Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170822 |
|
| RJ01 | Rejection of invention patent application after publication |