CN107083051A - A kind of nylon fly net master batch and preparation method thereof - Google Patents
A kind of nylon fly net master batch and preparation method thereof Download PDFInfo
- Publication number
- CN107083051A CN107083051A CN201710289283.XA CN201710289283A CN107083051A CN 107083051 A CN107083051 A CN 107083051A CN 201710289283 A CN201710289283 A CN 201710289283A CN 107083051 A CN107083051 A CN 107083051A
- Authority
- CN
- China
- Prior art keywords
- nylon
- parts
- master batch
- fly net
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of nylon fly net master batch and preparation method thereof, master batch raw material includes：Nylon, hydroxy silicon oil 16, hydroxy ethyl fiber, stearic acid, polyethylene, polyvinyl butyral resin, Tissuemat E, bulking agent, antioxidant, ultra-violet absorber, barium stearate and plasticizer.The present invention is modified using hydroxyethyl cellulose to nylon, and hydroxy silicon oil is used to strengthen the compatibility between nylon molecules and hydroxyethyl cellulose molecule；Modified nylon molecules are combined with polyethylene, polyvinyl butyral resin, Tissuemat E and master batch are made, and under action of ultraviolet radiation, hydroxyethyl cellulose can degrade, so as to improve the air permeability of nylon wire.
Description
Technical field
The invention belongs to nylon master-batch techniques field, and in particular to a kind of nylon fly net master batch and preparation method thereof.
Background technology
After nylon yarn appearance, because it is better and more robust than the toughness of plastic gauze, permeability, about upper
The nineties in century, nylon yarn is largely applied in Protected production, prevents and treats a variety of pest and disease damages.The method that nylon gauze is used
A lot,（1）Screen window is made, the pre- pest control on the window of attached-greenhouse；（2）Covered the ventilation in various protecting fields
Insect is worked as in mouth, Kong Shang, screening；（3）It is directly made to solarium, pre- pest control.It can not only be prevented and treated with insect prevention, also by insect prevention
The virosis that worm passes.Application nylon gauze turns into one of nuisanceless, green agriculture and the most frequently used measure of organic agriculture at present.
Doing fly net using nylon gauze needs to consider suitable mesh, if the density of general grenadine is up to more than 30 mesh,
Summer high temperature season is possible to because of improper ventilation, is made warm indoor temperature too high, is caused blade to be burnt.Sunshade is generally used at present
Net, which is covered in above ceiling, to cool, and to avoid canopy temperature too high, also needs to increase output if necessary, alleviates plant blade face and burn
Wound.
The content of the invention
The technical problem of solution：It is an object of the invention to provide a kind of nylon fly net master batch and preparation method thereof.
Technical scheme：A kind of nylon fly net master batch, raw material includes in parts by weight：30-40 parts of nylon, hydroxyl silicon
It is oily 1-6 parts, 2-9 parts of hydroxy ethyl fiber, 0.8-3.2 parts of stearic acid, 5-10 parts of polyethylene, 2-7 parts of polyvinyl butyral resin, poly- second
1-5 parts of alkene wax, 0.7-1.5 parts of bulking agent, 1-2 parts of antioxidant, 0.8-2.4 parts of ultra-violet absorber, barium stearate 1.4-2.7
Part, 2-7 parts of plasticizer.
Further, the bulking agent is ethylene acrylic acid co polymer, ethylene ethyl acrylate or maleic anhydride grafting second
One kind in alkene acetate ethylene copolymer.
Further, the plasticizer is the one or several kinds in ethylene glycol, propane diols, sorbierite or glycerine.
Further, the ultra-violet absorber is UV-531.
The preparation method of above-mentioned nylon fly net master batch, comprises the following steps：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch.
Further, the extrusion temperature of extrusion molding is 180-210 DEG C in step 3.
Beneficial effect：The present invention is modified using hydroxyethyl cellulose to nylon, and hydroxy silicon oil is used to strengthen nylon point
Compatibility between son and hydroxyethyl cellulose molecule；Modified nylon molecules and polyethylene, polyvinyl butyral resin, poly- second
Alkene wax is compound to be made master batch, and under action of ultraviolet radiation, hydroxyethyl cellulose can degrade, so as to improve the ventilation of nylon wire
Property.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Obviously, described embodiment is only embodiment of the invention a part of, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
For a further understanding of the present invention, with reference to embodiment, the present invention will be described in detail, wherein, such as without special
Illustrate, the various reaction reagents being related in embodiment can be commercially available by commercial channel.
Embodiment 1
A kind of nylon fly net master batch, raw material includes in parts by weight：30 parts of nylon, 1 part of hydroxy silicon oil, hydroxy ethyl fiber 2
Part, 0.8 part of stearic acid, 5 parts of polyethylene, 2 parts of polyvinyl butyral resin, 1 part of Tissuemat E, 0.7 part of bulking agent, 1 part of antioxidant,
0.8 part of ultra-violet absorber, 1.4 parts of barium stearate, 2 parts of plasticizer.
The bulking agent is ethylene acrylic acid co polymer, and the plasticizer is ethylene glycol, the ultra-violet absorber
For UV-531.
The preparation method of above-mentioned nylon fly net master batch, comprises the following steps：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch, the extrusion temperature of extrusion molding is 180-210 DEG C.
Nylon gauze is made in gained master batch, mesh number is being used 20 days in 30 mesh or so, the light transmittance of gauze up to 85%
Afterwards, gauze mesh number is 20 mesh.
Embodiment 2
A kind of nylon fly net master batch, raw material includes in parts by weight：33 parts of nylon, 2 parts of hydroxy silicon oil, hydroxy ethyl fiber 4
Part, 1.3 parts of stearic acid, 7 parts of polyethylene, 4 parts of polyvinyl butyral resin, 3 parts of Tissuemat E, 1.1 parts of bulking agent, antioxidant 1.4
Part, 1.5 parts of ultra-violet absorber, 1.8 parts of barium stearate, 4 parts of plasticizer.
The bulking agent is ethylene ethyl acrylate, and the plasticizer is propane diols, and the ultra-violet absorber is
UV-531。
The preparation method of above-mentioned nylon fly net master batch, comprises the following steps：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch, the extrusion temperature of extrusion molding is 180-210 DEG C.
Nylon gauze is made in gained master batch, mesh number is being used 20 days in 30 mesh or so, the light transmittance of gauze up to 85%
Afterwards, gauze mesh number is 20 mesh.
Embodiment 3
A kind of nylon fly net master batch, raw material includes in parts by weight：37 parts of nylon, 3 parts of hydroxy silicon oil, hydroxy ethyl fiber 8
Part, 2.7 parts of stearic acid, 8 parts of polyethylene, 6 parts of polyvinyl butyral resin, 4 parts of Tissuemat E, 1.3 parts of bulking agent, antioxidant 1.8
Part, 1.8 parts of ultra-violet absorber, 2.2 parts of barium stearate, 6 parts of plasticizer.
The bulking agent is ethylene-vinylacetate grafting maleic anhydride copolymer, and the plasticizer is sorbierite, institute
Ultra-violet absorber is stated for UV-531.
The preparation method of above-mentioned nylon fly net master batch, comprises the following steps：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch, the extrusion temperature of extrusion molding is 180-210 DEG C.
Nylon gauze is made in gained master batch, mesh number is being used 20 days in 30 mesh or so, the light transmittance of gauze up to 85%
Afterwards, gauze mesh number is 20 mesh.
Embodiment 4
A kind of nylon fly net master batch, raw material includes in parts by weight：40 parts of nylon, 6 parts of hydroxy silicon oil, hydroxy ethyl fiber 9
Part, 3.2 parts of stearic acid, 10 parts of polyethylene, 7 parts of polyvinyl butyral resin, 5 parts of Tissuemat E, 1.5 parts of bulking agent, antioxidant 2
Part, 2.4 parts of ultra-violet absorber, 2.7 parts of barium stearate, 7 parts of plasticizer.
The bulking agent is ethylene acrylic acid co polymer, and the plasticizer is ethylene glycol, the ultra-violet absorber
For UV-531.
The preparation method of above-mentioned nylon fly net master batch, comprises the following steps：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch, the extrusion temperature of extrusion molding is 180-210 DEG C.
Nylon gauze is made in gained master batch, mesh number is being used 20 days in 30 mesh or so, the light transmittance of gauze up to 85%
Afterwards, gauze mesh number is 20 mesh.
Claims (6)
1. a kind of nylon fly net master batch, it is characterised in that：Raw material includes in parts by weight：30-40 parts of nylon, hydroxy silicon oil
1-6 parts, 2-9 parts of hydroxy ethyl fiber, 0.8-3.2 parts of stearic acid, 5-10 parts of polyethylene, 2-7 parts of polyvinyl butyral resin, polyethylene
1-5 parts of wax, 0.7-1.5 parts of bulking agent, 1-2 parts of antioxidant, 0.8-2.4 parts of ultra-violet absorber, 1.4-2.7 parts of barium stearate,
2-7 parts of plasticizer.
2. nylon fly net master batch according to claim 1, it is characterised in that：The bulking agent is common for ethylene acrylic
One kind in polymers, ethylene ethyl acrylate or ethylene-vinylacetate grafting maleic anhydride copolymer.
3. nylon fly net master batch according to claim 1, it is characterised in that：The plasticizer is ethylene glycol, the third two
One or several kinds in alcohol, sorbierite or glycerine.
4. nylon fly net master batch according to claim 1, it is characterised in that：The ultra-violet absorber is UV-
531。
5. the preparation method of the nylon fly net master batch described in any one of Claims 1-4, it is characterised in that：Including following
Step：
Step 1, nylon, hydroxy silicon oil, hydroxyethyl cellulose are mixed, 250-260 DEG C, stirring is heated under vacuum
20-30min, is cooled to 150-160 DEG C, adds stearic acid, stirs 30-40min, obtains modification of nylon；
Step 2, modification of nylon, polyethylene, polyvinyl butyral resin, Tissuemat E and bulking agent are added and mixed, mixed
Thing；
Step 3, antioxidant, ultra-violet absorber, barium stearate, plasticizer are well mixed, extruded in double screw extruder
Shaping, obtains master batch.
6. the preparation method of nylon fly net master batch according to claim 5, it is characterised in that：It is extruded into step 3
The extrusion temperature of type is 180-210 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289283.XA CN107083051A (en) | 2017-04-27 | 2017-04-27 | A kind of nylon fly net master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289283.XA CN107083051A (en) | 2017-04-27 | 2017-04-27 | A kind of nylon fly net master batch and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107083051A true CN107083051A (en) | 2017-08-22 |
Family
ID=59611996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710289283.XA Pending CN107083051A (en) | 2017-04-27 | 2017-04-27 | A kind of nylon fly net master batch and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107083051A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002176863A (en) * | 2000-12-15 | 2002-06-25 | Kanebo Ltd | Agricultural net |
| CN1761718A (en) * | 2003-03-14 | 2006-04-19 | 纳幕尔杜邦公司 | Polymeric amide and polyvinyl butyral acetal composition and have raising surface property blend and by the goods of its manufacturing |
| CN102388775A (en) * | 2011-08-02 | 2012-03-28 | 赵霖霖 | Net shed for breeding entomoplily cross pollinated cultivate plants |
| CN103351614A (en) * | 2013-07-09 | 2013-10-16 | 宁波伊德尔新材料有限公司 | Easily-degradable and environment-friendly nylon |
-
2017
- 2017-04-27 CN CN201710289283.XA patent/CN107083051A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002176863A (en) * | 2000-12-15 | 2002-06-25 | Kanebo Ltd | Agricultural net |
| CN1761718A (en) * | 2003-03-14 | 2006-04-19 | 纳幕尔杜邦公司 | Polymeric amide and polyvinyl butyral acetal composition and have raising surface property blend and by the goods of its manufacturing |
| CN102388775A (en) * | 2011-08-02 | 2012-03-28 | 赵霖霖 | Net shed for breeding entomoplily cross pollinated cultivate plants |
| CN103351614A (en) * | 2013-07-09 | 2013-10-16 | 宁波伊德尔新材料有限公司 | Easily-degradable and environment-friendly nylon |
Non-Patent Citations (3)
| Title |
|---|
| 张再仁: "银链牌蔬菜防虫网", 《湖南农业》 * |
| 李明远: "利用尼龙纱网防治病虫害常见的问题及其对策", 《农业工程技术（温室园艺）》 * |
| 陈全胜 等: "《设施园艺》", 31 August 2010, 华中师范大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6522788B2 (en) | Biodegradable polyester composition | |
| CN109535675A (en) | The hydrolysis light of resistance to UV aging biodegradable plastic mulch and preparation method thereof | |
| JP3064611B2 (en) | Agricultural coating film | |
| CN105330962A (en) | Preparation method of super-tough antibacterial masterbatch with high concentration | |
| WO2018227941A1 (en) | Structurally uniform, highly gas-permeable microporous membrane for filtration and preparation process thereof, flat filter element and gas filtration article | |
| CN108059727B (en) | Heat-insulating plastic mulching film with black coating and preparation method thereof | |
| CN105295191A (en) | Bamboo fiber-reinforced material and preparation method therefor | |
| CN106519311A (en) | Thermoplastic starch-polyvinyl alcohol fogging-resistance film and preparation method thereof | |
| CN106479132B (en) | A kind of degradation of plastic film master batch and the preparation method and application thereof | |
| CN106883566A (en) | A kind of biodegradable films and preparation method thereof | |
| CN107083051A (en) | A kind of nylon fly net master batch and preparation method thereof | |
| CN107556611A (en) | It is a kind of suitable for conversion film of vegetables greenhouse cultivation and preparation method thereof | |
| CN109251488B (en) | Biodegradable light conversion film and preparation method thereof | |
| CN107298791A (en) | A kind of manufacturing process of fire-retardant antifog anti-aging awning film | |
| CN106046603A (en) | Weather-resistant PVC (polyvinyl chloride) | |
| CN105001558A (en) | Farm-oriented anti-atomization polyvinyl chloride film and preparation method thereof | |
| JPH08308401A (en) | Fluorescent film for agriculture of which weatherability is excellent | |
| CN108587209A (en) | A kind of novel wood-plastic floor and preparation method thereof | |
| CN107556612A (en) | A kind of plastic sheeting and preparation method thereof | |
| CN107726251A (en) | A kind of light fixture | |
| CN109181167A (en) | The method for preparing agricultural canopy film master batch using automobile-used acoustical cotton corner dead meal | |
| CN107325512A (en) | A kind of anti-aging PC sunlight boards and preparation method thereof | |
| CN106995548A (en) | A kind of preparation method of multi-functional color masterbatch | |
| KR102036284B1 (en) | Manufacturing method of polyethylene terephthalate film | |
| CN113004665A (en) | Antibacterial insect-preventing degradable agricultural mulching film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170822 |
|
| RJ01 | Rejection of invention patent application after publication |