CN107082883A - A kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof - Google Patents
A kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof Download PDFInfo
- Publication number
- CN107082883A CN107082883A CN201710296190.XA CN201710296190A CN107082883A CN 107082883 A CN107082883 A CN 107082883A CN 201710296190 A CN201710296190 A CN 201710296190A CN 107082883 A CN107082883 A CN 107082883A
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- CN
- China
- Prior art keywords
- solvent
- organic siliconresin
- pearl ink
- resist modification
- heat resist
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof, heat resist modification organic siliconresin includes following components by weight percentage：Hydroxyl saturated polyester resin 50%~70%；Organic siliconresin 10%~30%；Solvent 5%~20%；Auxiliary agent 1%~5%.The present invention has synthesized excellent adhesive force, bend-resistance, resistant to elevated temperatures modified organic silicone resin with conventional method, and is configured to white and black pearl ink with the modified organic silicone resin, has reached the requirement of industry high level.
Description
Technical field
The present invention relates to organic siliconresin, and in particular to a kind of heat resist modification organic siliconresin and pearl ink and its system
Preparation Method.
Background technology
How improving the adhesive force of PI ink (pearl ink) and improving resistance to temperature is always an insoluble problem.This
Invention has synthesized a kind of excellent adhesive force, bend-resistance, resistant to elevated temperatures modified organic silicone resin with conventional method, and organic with this
Silicones has prepared white and black pearl ink, has reached the requirement of industry high level.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of heat resist modification organic siliconresin and pearl ink and its system
Preparation Method, improves the adhesive force and resistance to temperature of pearl ink.
The present invention be solve the technical scheme that is used of above-mentioned technical problem for：
A kind of heat resist modification organic siliconresin, by weight percentage including following components：
Embodiments in accordance with the present invention, the solvent is set to propylene glycol methyl ether acetate.
Embodiments in accordance with the present invention, the auxiliary agent is set to butyl titanate or organotin.
A kind of heat resist modification preparation method for organic silicon resin, including step：
(1) hydroxyl saturated polyester resin and solvent are added in kettle；
(2) in 100 DEG C~180 DEG C temperature ranges, organic siliconresin and auxiliary agent are added slowly；
(3) 2 hours are incubated；
(4) discharged when being cooled to less than 80 DEG C.
A kind of pearl ink, by weight percentage including following components：
A kind of pearl ink preparation method, including step：
(1) modified organic silicone resin, titanium dioxide and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes
End；
(2) by below powder mull to 10 μm of fineness；
(3) amino resins, levelling agent, coupling agent and solvent are added.
A kind of pearl ink, by weight percentage including following components：
A kind of pearl ink preparation method, including step：
(1) modified organic silicone resin, carbon black and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes；
(2) by below powder mull to 10 μm of fineness；
(3) amino resins, levelling agent, coupling agent and solvent are added.
Beneficial effects of the present invention：The present invention has synthesized excellent adhesive force, bend-resistance with conventional method, resistant to elevated temperatures changed
Property organic siliconresin, and be configured to the modified organic silicone resin white and black pearl ink, reached that industry high level will
Ask.
Embodiment
The present invention is described in further detail below according to embodiment:
Heat resist modification organic siliconresin of the present invention, by weight percentage including following components：
The solvent is set to propylene glycol methyl ether acetate.The auxiliary agent is set to butyl titanate or organotin.
Heat resist modification preparation method for organic silicon resin of the present invention, including step：
(1) hydroxyl saturated polyester resin and solvent are added in kettle；
(2) in 100 DEG C~180 DEG C temperature ranges, organic siliconresin and auxiliary agent are added slowly；
(3) 2 hours are incubated；
(4) discharged when being cooled to less than 80 DEG C.
Pearl ink of the present invention, by weight percentage including following components：
As above pearl ink preparation method, including step：
(1) modified organic silicone resin, titanium dioxide and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes
End；
(2) by below powder mull to 10 μm of fineness；
(3) amino resins, levelling agent, coupling agent and solvent are added.
Pearl ink of the present invention, by weight percentage including following components：
As above pearl ink preparation method, including step：
(1) modified organic silicone resin, carbon black and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes；
(2) by below powder mull to 10 μm of fineness；
(3) amino resins, levelling agent, coupling agent and solvent are added.
Embodiment 1：
(1) 70 parts of hydroxyl saturated polyester resins and 14 parts of propylene glycol methyl ether acetates are added in kettle；
(2) in 100 DEG C~180 DEG C temperature ranges, 15 parts of organic siliconresins and 1 part of butyl titanate are added slowly；
(3) 2 hours are incubated；
(4) discharging obtains modified organic silicone resin when being cooled to less than 80 DEG C.
Embodiment 2：
(1) 1 part of 60 parts of modified organic silicone resin, 30 parts of titanium dioxide and defoamer are added in a mixing bowl, 15 is disperseed at a high speed
Minute obtains powder；
(2) by below powder mull to 10 μm of fineness；
(3) 1 part of 6 parts of amino resins, 1 part of levelling agent, 1 part of coupling agent and solvent propylene glycol methyl ether acetate are added.
Embodiment 3:
(1) 2 parts of 70 parts of modified organic silicone resin, 15 parts of carbon black and defoamer are added in a mixing bowl, it is scattered 15 points at a high speed
Clock obtains powder；
(2) by below powder mull to 10 μm of fineness；
(3) 1 part of 9 parts of amino resins, 1 part of levelling agent, 1 part of coupling agent and solvent propylene glycol methyl ether acetate are added.
Those skilled in the art do not depart from the essence and spirit of the present invention, can have various deformation scheme to realize the present invention,
Preferable feasible embodiment of the invention is the foregoing is only, not thereby limits to the interest field of the present invention, it is all with this
Within the equivalent structure change that description of the invention content is made, the interest field for being both contained in the present invention.
Claims (8)
1. a kind of heat resist modification organic siliconresin, it is characterised in that by weight percentage including following components：
Hydroxyl saturated polyester resin 50%~70%
Organic siliconresin 10%~30%
Solvent 5%~20%
Auxiliary agent 1%~5%.
2. heat resist modification organic siliconresin according to claim 1, it is characterised in that：The solvent is set to propane diols first
Ether acetate.
3. heat resist modification organic siliconresin according to claim 1, it is characterised in that：The auxiliary agent is set to butyl titanate
Or organotin.
4. a kind of heat resist modification preparation method for organic silicon resin, it is characterised in that including step：
（1）Hydroxyl saturated polyester resin and solvent are added in kettle；
（2）In 100 DEG C~180 DEG C temperature ranges, organic siliconresin and auxiliary agent are added slowly；
（3）Insulation 2 hours；
（4）Discharged when being cooled to less than 80 DEG C.
5. a kind of pearl ink, it is characterised in that by weight percentage including following components：
Modified organic silicone resin 40%~60% as described in claims 1 to 3 is any
Titanium dioxide 30%~50%
Amino resins 2%~10%
Defoamer 1%~3%
Levelling agent 1%~3%
Coupling agent 1%~3%
Solvent 1%~10%.
6. a kind of pearl ink preparation method, it is characterised in that including step：
（1）Modified organic silicone resin, titanium dioxide and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes；
（2）Below powder mull to 10 μm of fineness；
（3）Add amino resins, levelling agent, coupling agent and solvent.
7. a kind of pearl ink, it is characterised in that by weight percentage including following components：
Modified organic silicone resin 50%~70% as described in claims 1 to 3 is any
Carbon black 10%~20%
Amino resins 2%~10%
Defoamer 1%~3%
Levelling agent 1%~3%
Coupling agent 1%~3%
Solvent 1%~10%.
8. a kind of pearl ink preparation method, it is characterised in that including step：
（1）Modified organic silicone resin, carbon black and defoamer are added in a mixing bowl, it is scattered at a high speed to obtain powder within 15 minutes；
（2）Below powder mull to 10 μm of fineness；
（3）Add amino resins, levelling agent, coupling agent and solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710296190.XA CN107082883A (en) | 2017-04-28 | 2017-04-28 | A kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710296190.XA CN107082883A (en) | 2017-04-28 | 2017-04-28 | A kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107082883A true CN107082883A (en) | 2017-08-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710296190.XA Pending CN107082883A (en) | 2017-04-28 | 2017-04-28 | A kind of heat resist modification organic siliconresin and pearl ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116239914A (en) * | 2022-09-09 | 2023-06-09 | 广东东溢新材料科技有限公司 | Water-based white ink and preparation method and application thereof |
| WO2023129472A1 (en) * | 2021-12-30 | 2023-07-06 | Sun Chemical Corporation | High opacity white ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050250891A1 (en) * | 2002-05-29 | 2005-11-10 | Tomohiro Matuki | Water-based coating material for rubber product |
| CN105348540A (en) * | 2015-11-30 | 2016-02-24 | 东莞市俊怡化工科技有限公司 | Water-based room temperature air-dried organosilicone modified resin and preparation method thereof and paint |
| CN105949951A (en) * | 2016-06-11 | 2016-09-21 | 刘平 | Water-borne heat conducting paint for radiator and preparing method thereof |
-
2017
- 2017-04-28 CN CN201710296190.XA patent/CN107082883A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050250891A1 (en) * | 2002-05-29 | 2005-11-10 | Tomohiro Matuki | Water-based coating material for rubber product |
| CN105348540A (en) * | 2015-11-30 | 2016-02-24 | 东莞市俊怡化工科技有限公司 | Water-based room temperature air-dried organosilicone modified resin and preparation method thereof and paint |
| CN105949951A (en) * | 2016-06-11 | 2016-09-21 | 刘平 | Water-borne heat conducting paint for radiator and preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023129472A1 (en) * | 2021-12-30 | 2023-07-06 | Sun Chemical Corporation | High opacity white ink |
| CN116239914A (en) * | 2022-09-09 | 2023-06-09 | 广东东溢新材料科技有限公司 | Water-based white ink and preparation method and application thereof |
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170822 |
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| RJ01 | Rejection of invention patent application after publication |