CN107081404A - A kind of lead-acid accumulator cast welding releasing agent - Google Patents
A kind of lead-acid accumulator cast welding releasing agent Download PDFInfo
- Publication number
- CN107081404A CN107081404A CN201710210991.XA CN201710210991A CN107081404A CN 107081404 A CN107081404 A CN 107081404A CN 201710210991 A CN201710210991 A CN 201710210991A CN 107081404 A CN107081404 A CN 107081404A
- Authority
- CN
- China
- Prior art keywords
- lead
- acid accumulator
- agent
- releasing agent
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 54
- 239000002253 acid Substances 0.000 title claims abstract description 39
- 238000003466 welding Methods 0.000 title claims abstract description 37
- 239000013556 antirust agent Substances 0.000 claims abstract description 33
- 239000000314 lubricant Substances 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 27
- 239000000654 additive Substances 0.000 claims abstract description 23
- 230000000996 additive effect Effects 0.000 claims abstract description 23
- 239000012459 cleaning agent Substances 0.000 claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000003879 lubricant additive Substances 0.000 claims abstract description 17
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 239000001993 wax Substances 0.000 claims description 23
- 150000002148 esters Chemical class 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- -1 methyl glycol fatty acid ester Chemical class 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 claims description 3
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004200 microcrystalline wax Substances 0.000 claims description 3
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 3
- 229950004053 octoxinol Drugs 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 229950008882 polysorbate Drugs 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 2
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 2
- 229940068041 phytic acid Drugs 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- 125000005586 carbonic acid group Chemical group 0.000 claims 1
- 125000005456 glyceride group Chemical group 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 15
- 229910000464 lead oxide Inorganic materials 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 230000028161 membrane depolarization Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 6
- 239000006210 lotion Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 210000000481 breast Anatomy 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 2
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D25/00—Special casting characterised by the nature of the product
- B22D25/02—Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
- B22D25/04—Casting metal electric battery plates or the like
Abstract
The invention belongs to technical field of mold release.The invention discloses a kind of lead-acid accumulator cast welding releasing agent, it is made by lubricant, surface cleaning agent, wax additive, lubricant additive, long-chain fatty alcohol APEO, emulsifying agent, antirust agent and solvent.The lead oxides that lead-acid accumulator cast welding produced by the present invention can be effectively gone in depolarization group surface and mold cavity with releasing agent, make die cavity and pole group surface completely smooth, realize the good bus-bar welding effect of lead-acid accumulator, its high-rate discharge ability is improved, so that it is guaranteed that its longer service life；It can promote the mobility of lead liquid in cast welding, reduce the adhesion between lead liquid and mould, it is easy to be stripped；It effectively can carry out a kind of protection to mould, generate one layer of oxidation-resistant film, extend die life；It can also ensure that service life of lead accumulator and performance are unaffected.
Description
Technical field
The present invention relates to technical field of mold release, more particularly, to a kind of lead-acid accumulator cast welding releasing agent.
Background technology
Polar plate of lead acid storage battery welding in recent years is eliminated substantially using manual mode, and provisions of the relevant regulations issued by the State accumulator plate
Machine automatic cast welding must be used with bus-bar welding.Cast welding mode is typically all：Positive plate, the dividing plate folded（Glass fibers
Tie up separator paper）, negative plate pole plate group, after lug is cleared up, insertion cast welded mold is filled in the die cavity of lead liquid, passes through lead liquid
500 DEG C or so of temperature, makes lug surface melting, then it is cold it is dynamic make lead liquid solidification forming, then by pole plate group and cast welded mold phase
Separation, just realizes multi-disc pole plate and connects together, and the purpose of mould spraying releasing agent helps pole group and mould after welding
Separation, it is ensured that the smooth full light of bus-bar.Also it is exclusively used in lead-acid accumulator cast welding releasing process without a class in the prior art
In releasing agent, but use some analogous technical fields in releasing agent carry out assisted demoulding operation, due to not being special
Releasing agent will produce a series of problems, such as be difficult to clean off the impurity such as the lead oxide of lead acid accumulator pole group surface attachment, meeting
Cause loose contact and reduce the life-span of battery；Although and some releasing agents can understand the lead oxide of accumulator pole group surface attachment
Deng impurity, but damage is also caused in itself to pole group, influence the life-span of battery；Because these releasing agents are not lead-acid accumulator castings
The special releasing agent of releasing process is welded, its usage amount is also larger, virtually adds manufacturing cost；Cast welding operating temperature typically exists
400~500 DEG C, using effect is poor at such a temperature for existing conventional releasing agent, because resistance to elevated temperatures is not good, releasing agent
Evaporation rate is too fast, causes continually to need manually to add releasing agent, causes manpower to waste.
The content of the invention
To solve the above problems, ensure that service life of lead accumulator is unaffected and can realize the invention provides one kind
Effectively remove the lead-acid accumulator cast welding releasing agent of bus-bar surface oxidation lead.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：3.0~8.0wt% of lubricant,
The wt % of surface cleaning agent 2.0~3.0, the wt % of wax additive 0.8~1.0, the wt % of lubricant additive 0.2~0.5, length
The wt % of chain fatty alcohol APEO 0.5~1.0, the wt % of emulsifying agent 0.1~0.3, antirust agent 0.01~0.05 wt %, it is remaining
Measure as solvent.
Surface cleaning agent is dissolved in after water in alkalescence in technical solution of the present invention, can effectively dissolve the oxide of lead, but not
Mould can be made to sustain damage, mould bus-bar die cavity is remained complete, promote the full light in bus-bar surface after welding.
Lubricant can form one layer after being mixed with lubricant additive, long-chain fatty alcohol APEO, wax additive in die cavity
Film, performance is stable in weakly alkaline solution, bus-bar is smoothed out with die cavity in the demoulding, prevents the demoulding has some setbacks from causing to conflux
Row pulls.
Preferably, lubricant is one kind in mineral oil, vegetable oil or artificial oil.
This mineral oil, vegetable oil and artificial oil have more excellent oxidation stability, resistance to emulsion.
Preferably, surface cleaning agent is one kind in sodium carbonate, sodium hydroxide or triethanolamine.
Above-mentioned surface cleaner all has weakly alkaline material to be dissolved in after water, and the materials such as steel, iron, nickel are not worked,
And there is larger corrosivity to its alloy, the lead oxides in mould bus-bar die cavity can be made to depart from mold cavity surface, make type
Chamber surface is complete, also promotes the full light in bus-bar surface.
Preferably, wax additive is OPE, atoleine, microcrystalline wax, natural paraffin wax or polyethylene
One kind in wax.
Above-mentioned wax additive has higher melt and with low viscosity, and it can promote lead liquid to have well after adding
Mobility, can reduce the adhesion between lead liquid and mould, it is easy to be stripped.
Preferably, lubricant additive is one in AEO, fatty acid sorbitan or polysorbate
Kind.
Preferably, emulsifying agent is one kind in glyceryl monooleate, Octoxinol or methyl glycol fatty acid ester.
Preferably, antirust agent is polynary esters antirust agent.
Preferably, polynary esters antirust agent is triethanolamine borate, pentaerythritol ester, sorbitan gear oleate
Or one kind in inositol hexaphosphate.
Preferably, solvent is water.
Preferably, the lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 140~160 DEG C；
c）Solvent is heated to 90~100 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent is closed after adding
Heating；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
Therefore, the invention has the advantages that：
（1）The lead oxides that can effectively go in depolarization group surface and mold cavity, make die cavity and pole group surface completely smooth,
The good bus-bar welding effect of lead-acid accumulator is realized, its high-rate discharge ability is improved, so that it is guaranteed that its longer use longevity
Life；
（2）The mobility of lead liquid can be promoted during cast welding, the adhesion between lead liquid and mould is reduced, it is easy to be stripped；
（3）A kind of protection effectively can be carried out to mould, generate one layer of oxidation-resistant film, extend die life；
（4）Ensure that service life of lead accumulator and performance are unaffected.
Embodiment
Technical scheme is further described with reference to embodiment.
Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on this
Embodiment in invention, all other reality that those of ordinary skill in the art are obtained under the premise of creative work is not made
Example is applied, the scope of protection of the invention is belonged to.
Embodiment 1
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：Lubricant 3.0wt%, surface are clear
Lotion 2.0wt%, wax additive 0.8wt%, lubricant additive 0.2wt%, long-chain fatty alcohol APEO 0.5wt%, breast
Agent 0.1wt%, antirust agent 0.01wt%, solvent 93.39wt%；
Wherein, lubricant is mineral oil；Surface cleaning agent is sodium carbonate；Wax additive is OPE；Lubricant adds
Plus agent is AEO；Emulsifying agent is glyceryl monooleate；Antirust agent is polynary esters antirust agent, and polynary esters are prevented
Rust agent is triethanolamine borate；Solvent is water.
Above-mentioned lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 140 DEG C；
c）Solvent is heated to 90 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent closes heating after adding；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
Embodiment 2
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：Lubricant 4.0wt%, surface are clear
Lotion 2.2wt%, wax additive 0.85wt%, lubricant additive 0.3wt%, long-chain fatty alcohol APEO 0.6wt%, breast
Agent 0.15wt%, antirust agent 0.02wt%, solvent 91.88wt%；
Wherein, lubricant is mineral oil；Surface cleaning agent is sodium hydroxide；Wax additive is atoleine；Lubricant is added
Agent is AEO；Emulsifying agent is methyl glycol fatty acid ester；Antirust agent is polynary esters antirust agent, and polynary esters are prevented
Rust agent is pentaerythritol ester；Solvent is water.
Above-mentioned lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 145 DEG C；
c）Solvent is heated to 93 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent closes heating after adding；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
Embodiment 3
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：Lubricant 5.5wt%, surface are clear
Lotion 2.5wt%, wax additive 0.9wt%, lubricant additive 0.35wt%, long-chain fatty alcohol APEO 0.75wt%,
Emulsifying agent 0.2wt%, antirust agent 0.03wt%, solvent 89.77wt%；
Wherein, lubricant is vegetable oil；Surface cleaning agent is sodium hydroxide；Wax additive is microcrystalline wax；Lubricant is added
Agent is fatty acid sorbitan；Emulsifying agent is Octoxinol；Antirust agent is polynary esters antirust agent, and polynary esters antirust agent is three second
Hydramine borate；Solvent is water.
Above-mentioned lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 150 DEG C；
c）Solvent is heated to 95 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent closes heating after adding；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
Embodiment 4
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：Lubricant 6.5wt%, surface are clear
Lotion 2.7wt%, wax additive 0.95wt%, lubricant additive 0.4wt%, long-chain fatty alcohol APEO 0.8wt%, breast
Agent 0.25wt%, antirust agent 0.04wt%, solvent 88.36wt%；
Wherein, lubricant is artificial oil；Surface cleaning agent is triethanolamine；Wax additive is natural paraffin wax；Lubricant is added
Agent is fatty acid sorbitan；Emulsifying agent is methyl glycol fatty acid ester；Antirust agent is polynary esters antirust agent, polynary esters antirust agent
Oleate is kept off for sorbitan；Solvent is water.
Above-mentioned lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 155 DEG C；
c）Solvent is heated to 97 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent closes heating after adding；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
Embodiment 5
A kind of lead-acid accumulator cast welding releasing agent, is made by the raw material of following percetage by weight：Lubricant 8.0wt%, surface are clear
Lotion 3.0wt%, wax additive 1.0wt%, lubricant additive 0.5wt%, long-chain fatty alcohol APEO 1.0wt%, breast
Agent 0.3wt%, antirust agent 0.05wt%, solvent 86.15wt%；
Wherein, lubricant is artificial oil；Surface cleaning agent is triethanolamine；Wax additive is Tissuemat E；Lubricant is added
Agent is polysorbate；Emulsifying agent is methyl glycol fatty acid ester；Antirust agent is polynary esters antirust agent, and polynary esters antirust agent is flesh
The phosphate of alcohol six；Solvent is water.
Above-mentioned lead-acid accumulator cast welding is made with releasing agent by following steps：
a）It is fitted into after wax additive is mixed with surface cleaning agent in preparing tank, is heated to being completely dissolved；
b）Long-chain fatty alcohol APEO, emulsifying agent, lubricant and lubricant additive are added in step a obtained mixed
Close in liquid and stir, and heating makes temperature control at 140~160 DEG C；
c）Solvent is heated to 90~100 DEG C, is slowly added into afterwards in mixed liquor made from step b, solvent is closed after adding
Heating；
d）Antirust agent is added into mixed liquor made from step c and is stirred, lead-acid accumulator cast welding releasing agent is made.
It should be appreciated that to those skilled in the art, can according to the above description be improved or be become
Change, and all these modifications and variations should all belong to the protection domain of appended claims of the present invention.
Claims (9)
1. a kind of lead-acid accumulator cast welding releasing agent, it is characterised in that be made by the raw material of following percetage by weight：Lubricant
3.0~8.0wt%, the wt % of surface cleaning agent 2.0~3.0, the wt % of wax additive 0.8~1.0, lubricant additive 0.2~
0.5 wt %, the wt % of long-chain fatty alcohol APEO 0.5~1.0, the wt % of emulsifying agent 0.1~0.3, antirust agent 0.01~
0.05 wt %, surplus is solvent.
2. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that：Described lubricant is mineral
One kind in oil, vegetable oil or artificial oil.
3. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that：The surface cleaning agent is carbonic acid
One kind in sodium, sodium hydroxide or triethanolamine.
4. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that：The wax additive is oxidation
One kind in Tissuemat E, atoleine, microcrystalline wax, natural paraffin wax or Tissuemat E.
5. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that the lubricant additive is fat
One kind in fat alcohol APEO, fatty acid sorbitan or polysorbate.
6. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that：Described emulsifying agent is single oleic acid
One kind in glyceride, Octoxinol or methyl glycol fatty acid ester.
7. a kind of lead-acid accumulator releasing agent according to claim 1, it is characterised in that：Described antirust agent is polyester
Class antirust agent.
8. a kind of lead-acid accumulator releasing agent according to claim 7, it is characterised in that：Described polynary esters antirust agent
For one kind in triethanolamine borate, pentaerythritol ester, sorbitan gear oleate or inositol hexaphosphate.
9. a kind of lead-acid accumulator releasing agent according to claims 1 to 8, it is characterised in that：Described solvent is water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710210991.XA CN107081404B (en) | 2017-03-31 | 2017-03-31 | A kind of lead-acid accumulator cast welding release agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710210991.XA CN107081404B (en) | 2017-03-31 | 2017-03-31 | A kind of lead-acid accumulator cast welding release agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107081404A true CN107081404A (en) | 2017-08-22 |
| CN107081404B CN107081404B (en) | 2019-08-06 |
Family
ID=59614902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710210991.XA Active CN107081404B (en) | 2017-03-31 | 2017-03-31 | A kind of lead-acid accumulator cast welding release agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107081404B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109175224A (en) * | 2018-09-06 | 2019-01-11 | 安美科技股份有限公司 | A kind of not aqueous zinc alloy diecasting release agent of silicate-containing oil |
| WO2019148066A1 (en) | 2018-01-29 | 2019-08-01 | Purdue Research Foundation | Compositions for use as lubricants in die casting methods of using the same, and products produced therewith |
| CN112589074A (en) * | 2020-11-11 | 2021-04-02 | 天能电池集团股份有限公司 | Maintenance method of storage battery cast-weld mold |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133025A (en) * | 1976-04-30 | 1977-11-08 | Shin Kobe Electric Machinery | Slipping agent for casting |
| JPS5339924A (en) * | 1976-09-25 | 1978-04-12 | Matsushita Electric Ind Co Ltd | Demoulding agent for casting |
| CN1165060A (en) * | 1996-05-10 | 1997-11-19 | 赵洪昌 | Water-soluble mold-release agent and its preparation method |
| CN1563302A (en) * | 2004-01-20 | 2005-01-12 | 李波 | Water-soluble environmental protective dedicated liquid in favor of die set synthetically |
| CN101152662A (en) * | 2006-10-01 | 2008-04-02 | 福建省测试技术研究所 | Heat resisting lubricating agent |
| CN101812362A (en) * | 2009-12-18 | 2010-08-25 | 河南省绿韵建材有限公司 | Emulsified paraffin release agent and manufacturing method thereof |
| CN102527927A (en) * | 2012-02-27 | 2012-07-04 | 超威电源有限公司 | Grid mould release agent |
| CN102873265A (en) * | 2012-09-10 | 2013-01-16 | 超威电源有限公司 | Release agent used for pouring lead-acid storage battery grid and preparation method of release agent |
| CN103305325A (en) * | 2013-05-30 | 2013-09-18 | 超威电源有限公司 | Release agent and preparation method thereof |
| CN103624211A (en) * | 2013-11-26 | 2014-03-12 | 河南超威电源有限公司 | Storage battery grid mold release agent and preparation method thereof |
-
2017
- 2017-03-31 CN CN201710210991.XA patent/CN107081404B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133025A (en) * | 1976-04-30 | 1977-11-08 | Shin Kobe Electric Machinery | Slipping agent for casting |
| JPS5339924A (en) * | 1976-09-25 | 1978-04-12 | Matsushita Electric Ind Co Ltd | Demoulding agent for casting |
| CN1165060A (en) * | 1996-05-10 | 1997-11-19 | 赵洪昌 | Water-soluble mold-release agent and its preparation method |
| CN1563302A (en) * | 2004-01-20 | 2005-01-12 | 李波 | Water-soluble environmental protective dedicated liquid in favor of die set synthetically |
| CN101152662A (en) * | 2006-10-01 | 2008-04-02 | 福建省测试技术研究所 | Heat resisting lubricating agent |
| CN101812362A (en) * | 2009-12-18 | 2010-08-25 | 河南省绿韵建材有限公司 | Emulsified paraffin release agent and manufacturing method thereof |
| CN102527927A (en) * | 2012-02-27 | 2012-07-04 | 超威电源有限公司 | Grid mould release agent |
| CN102873265A (en) * | 2012-09-10 | 2013-01-16 | 超威电源有限公司 | Release agent used for pouring lead-acid storage battery grid and preparation method of release agent |
| CN103305325A (en) * | 2013-05-30 | 2013-09-18 | 超威电源有限公司 | Release agent and preparation method thereof |
| CN103624211A (en) * | 2013-11-26 | 2014-03-12 | 河南超威电源有限公司 | Storage battery grid mold release agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019148066A1 (en) | 2018-01-29 | 2019-08-01 | Purdue Research Foundation | Compositions for use as lubricants in die casting methods of using the same, and products produced therewith |
| CN109175224A (en) * | 2018-09-06 | 2019-01-11 | 安美科技股份有限公司 | A kind of not aqueous zinc alloy diecasting release agent of silicate-containing oil |
| CN112589074A (en) * | 2020-11-11 | 2021-04-02 | 天能电池集团股份有限公司 | Maintenance method of storage battery cast-weld mold |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107081404B (en) | 2019-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107081404B (en) | A kind of lead-acid accumulator cast welding release agent | |
| CN107999692B (en) | Die-casting aluminum alloy water-based release agent and preparation method thereof | |
| CN103305325B (en) | Release agent and preparation method thereof | |
| CN106099118A (en) | A kind of anode plate for lead acid accumulator grid alloy | |
| CN105463483A (en) | Aluminum product surface treatment method | |
| CN108637521B (en) | Tin wire capable of welding stainless steel material at low temperature and preparation method thereof | |
| CN102303123B (en) | Lead shot production method | |
| CN107723429A (en) | A kind of low oil smoke overspeed quenching oil and preparation method thereof | |
| EP1888310A1 (en) | Die casting moulding release agents | |
| CN104973887A (en) | Scabbling agent and preparation method thereof | |
| CN107446654A (en) | Abrasion is automatic to repair micro lubricating oil and preparation method thereof | |
| CN103088347B (en) | Storage tank coil pipe aluminium alloy sacrificial anode material and preparation method thereof | |
| CN106867634A (en) | A kind of preparation method of environmentally friendly antiwear hydraulic oil | |
| AU2012237021B2 (en) | Methods for die casting metals using phase separable fluids | |
| CN104152219A (en) | Grease for engineering machinery and preparation method thereof | |
| CN1063122A (en) | Washing liquor used for water-base crude oil | |
| CN101126045B (en) | Preparation technique for general purpose lithium-base grease | |
| WO1992007673A1 (en) | Parting agent for die casting | |
| CN106675706A (en) | Heavy-duty exposed gear lubricating grease for steel ball coal mill and preparation method of heavy-duty exposed gear lubricating grease | |
| CN101921546A (en) | Self-bright liquid shoe cream | |
| CN104450029A (en) | Anti-oxidation thixotropy anti-rusting oil | |
| CN102703915A (en) | Degreasing agent for pre-treatment of anodic oxidation of aluminum and alloy thereof and preparation and using methods for degreasing agent | |
| CN102311855B (en) | Aviation lubricating oil composition | |
| CN202367185U (en) | One-furnace and four-machine type plate casting machine | |
| CN107541640A (en) | The alloy pig and preparation method of a kind of yttrium containing magnesium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 313100 Zhejiang city of Huzhou province Changxing County pheasant emerging urban industrial park Patentee after: Chaowei Power Group Co.,Ltd. Address before: 313100 Zhejiang city of Huzhou province Changxing County pheasant emerging urban industrial park Patentee before: CHILWEE POWER Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A release agent for lead-acid battery casting and welding Effective date of registration: 20220720 Granted publication date: 20190806 Pledgee: Agricultural Bank of China Limited by Share Ltd. Changxing County branch Pledgor: Chaowei Power Group Co.,Ltd. Registration number: Y2022330001465 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231023 Granted publication date: 20190806 Pledgee: Agricultural Bank of China Limited by Share Ltd. Changxing County branch Pledgor: Chaowei Power Group Co.,Ltd. Registration number: Y2022330001465 |