CN107063941B - A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ - Google Patents

A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ Download PDF

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CN107063941B
CN107063941B CN201710217667.0A CN201710217667A CN107063941B CN 107063941 B CN107063941 B CN 107063941B CN 201710217667 A CN201710217667 A CN 201710217667A CN 107063941 B CN107063941 B CN 107063941B
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pyrolysis
water
movement
pressure
microscope carrier
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CN107063941A (en
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刘剑
梁卫国
李子文
高亚斌
廉浩杰
黎力
耿毅德
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Taiyuan University of Technology
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N13/00Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
    • G01N13/04Investigating osmotic effects
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • G01N2015/0023Investigating dispersion of liquids
    • G01N2015/0034Investigating dispersion of liquids in solids

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Abstract

A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ, belong to pyrolytic reaction pollutant diffusion And Movement technical field, it includes hydraulic analogue system, ground temperature crustal stress simulation system, pollutant diffusion And Movement simulation system, and the hydraulic analogue system is made of gas, gas booster pump, pressure regulator valve, pressure gauge, intake valve, water tank, water compensating valve, inlet valve;The ground temperature crustal stress simulation system, is made of insulating box, servo-pressing machine, pressure sensor;The pollutant diffusion And Movement simulation system, including water tank, pyrolysis rock stratum microscope carrier, infiltration liquid case, adjacent pervious bed microscope carrier, tapping valve, liquid trap, water compensating valve.The present invention overcomes existing experimental rig in no restrained condition, to test specimen without load, do not focus on ground temperature environment and Groundwater Flow state the shortcomings that and deficiency, in the underground water of hundreds of meters of underground depths oil shale and low-disintegration coal etc. in situ pyrolysis pollutant diffusion And Movement carry out feasibility test research.

Description

A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ
Technical field
A kind of experimental rig of simulation of present invention pyrolysis pollutant diffusion And Movement in underground water in situ, is mainly used for oily page The pyrolysis exploiting field groundwater pollution simulation research in situ such as rock and low-disintegration coal, spreads fortune for research Pyrolysis Contamination object in underground water It moves rule and test data is provided.
Background technique
In-situ heat solution exploitation be that pyrolyzation fluid is directly injected into buried target ore bed by heat injection well, using injection fluid with The physics chemical action occurred between ore bed useful constituent is pyrolyzed target ore bed useful constituent in situ, will finally have It is converted into fluid with component, a kind of mining methods on ground are then extracted by producing well.With traditional mining method phase Than not needing mineral products digging to earth's surface can obtain resource, having process flow few, at low cost, coefficient of mining is high, and land occupation is few The advantages of, it is the important way of the development and utilization such as the following oil shale and low-disintegration coal.
Although the exploitation of in-situ heat solution has above-mentioned advantage, pyrolysis meeting is so that the permeability of oil shale and low-disintegration coal occurs Great variety becomes pervious bed from water barrier, and the heavy metal generated in pyrolytic process, organic pollutant etc. can enter adjacent contain In water layer, underground water pollution is caused.Pyrolysis in situ descends water pollution research seldom over the ground at present, and is based primarily upon stagnant water and impregnates examination It tests, this has crustal stress and hydraulic condition grave fault with exploiting field in situ, and obtained experimental result differs larger with truth.Exploitation The pollutant diffusion And Movement experimental rig of energy simulated ground stress and hydraulic pressure reflects exploiting field underground water pollution in situ with heavy to true Want meaning.
Summary of the invention
Pyrolysis pollutant purpose of the experimental rig of diffusion And Movement in underground water is a kind of simulation of the present invention in situ, gram The defect and deficiency for taking traditional soak test method, providing a kind of can effectively simulate original ground temperature, crustal stress and hydraulic condition Under exploiting field underground water pollutant diffusion And Movement experimental rig, can be Transport of the research Pyrolysis Contamination object in underground water Reliable test data is provided.
A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ, it is characterised in that including hydraulic pressure Simulation system, ground temperature crustal stress simulation system, pollutant diffusion And Movement simulation system, the hydraulic analogue system is by gas, gas Body booster pump, pressure regulator valve, pressure gauge, intake valve, the first water tank, the second water tank, water compensating valve, inlet valve composition, gas pass through increasing Press pump is pressurized, and adjusts required pressure by pressure regulator valve and pressure gauge, passes through intake valve, the first water tank, inlet valve and pressure Power table is by water cycle factors into the second water tank;Water body supplements the water in the first water tank by water compensating valve.
The hydraulic analogue system is transmitted, not to test specimen load by the way that high pressure gas to be injected into water tank by pressure Same hydraulic pressure, to simulate the true groundwater environment of the preservations such as oil shale and low-disintegration coal layer.Gas is increased by booster pump Pressure, pressure needed for being adjusted by pressure regulator valve and pressure gauge, is passed hydraulic pressure by intake valve, the first water tank, inlet valve and pressure gauge It is handed in the second water tank.Water body supplements the water in the first water tank by water compensating valve.
The ground temperature crustal stress simulation system passes through the mild crustal stress condition of insulating box and servo-pressing machine simulation ground.Institute Ground temperature crustal stress simulation system is stated to be made of insulating box, servo-pressing machine, pressure sensor.By servo-pressing machine to being placed in heat Pyrolysis formation sample progress axis pressure and the confining pressure load in the microscope carrier of rock stratum are solved, is tried by pressure sensor pyrolysis rock stratum is applied to The axis pressure and confining pressure of part are precisely monitored, by servo-pressing machine to the permeable stratum sample being placed in adjacent pervious bed microscope carrier Axis pressure and confining pressure load are carried out, the axis for being applied to permeable stratum sample is pressed by pressure sensor and confining pressure is precisely supervised Control carries out heated at constant temperature to pyrolysis rock stratum test specimen and permeable stratum sample by insulating box.
Pollutant diffusion And Movement simulation system, by by with hydraulic pressure water body note be implanted sequentially pyrolysis rock stratum test specimen and thoroughly In water formation sample, to simulate diffusion And Movement of the Pyrolysis Contamination object in underground water.Pollutant diffusion And Movement simulation system is by water Case, pyrolysis rock stratum microscope carrier, infiltration liquid case, adjacent pervious bed microscope carrier, infiltration liquid case, tapping valve, liquid trap, water compensating valve, fastening spiral shell Bolt composition, pyrolysis rock stratum test specimen are placed in pyrolysis rock stratum microscope carrier, and pyrolysis rock stratum microscope carrier is using flange arrangement and close with fastening bolt Envelope, permeable stratum test specimen is placed in adjacent pervious bed microscope carrier, and adjacent pervious bed microscope carrier is using flange arrangement and close with fastening bolt Envelope, under the action of water pressure, water body enter pyrolysis rock stratum microscope carrier from water tank and form contaminated liquid, and contaminated liquid enters infiltration liquid case, passes through Tapping valve acquires penetrating fluid at different height position into liquid trap, under hydraulic pressure effect, is permeated the contaminated liquid of liquid case through phase Adjacent pervious bed microscope carrier enters in infiltration liquid case, is acquired penetrating fluid at different height position into liquid trap by tapping valve, Penetrating fluid is collected into liquid trap by tapping valve.Drain threshold velocity is identical as groundwater velocity, and main function is simulation ground The flowing running water characteristic being lauched, the main function of water compensating valve be to supplement the water body isometric through the taken contaminated liquid of tapping valve, with Reduce liquid volume in infiltration liquid case and changes bring error.
The present invention can press under the conditions of ground temperature test specimen loading axis and confining pressure, while simulated groundwater hydraulic condition, examination Part is having a size of 400 × 50mm of Φ, test specimen axis pressure and confining pressure 0-20MPa, hydraulic pressure 0-10MPa, 0-80 DEG C of test specimen environment temperature, simulation Buried depth reaches the geological environment of 800m.
A kind of above-mentioned simulation is pyrolyzed the experimental rig of pollutant diffusion And Movement in underground water in situ, which is characterized in that The pyrolysis rock stratum microscope carrier and adjacent pervious bed microscope carrier can load pyrolysis rock stratum test specimen and permeable stratum test specimen, sample dimensions respectively It is 400 × 50mm of Φ.
A kind of above-mentioned simulation is pyrolyzed the experimental rig of pollutant diffusion And Movement in underground water in situ, which is characterized in that The axis pressure loaded to test specimen and confining pressure are 0-20MPa, and hydraulic pressure 0-10MPa, temperature is 0-80 DEG C.
A kind of above-mentioned simulation is pyrolyzed the experimental rig of pollutant diffusion And Movement in underground water in situ, which is characterized in that Gas 1 in the hydraulic analogue system is using nitrogen.
A kind of above-mentioned simulation is pyrolyzed the test method of pollutant experimental rig of diffusion And Movement in underground water in situ, Device used by being characterized in that can constant-temperature high-pressure encapsulation test specimen, analog mineral products buried depth reaches the ground temperature crustal stress of 800m Pyrolysis rock stratum test specimen and permeable stratum test specimen are respectively placed in pyrolysis rock stratum microscope carrier and phase first by the device of hydraulic condition, this method In adjacent pervious bed microscope carrier, and it is sealed with fastening bolt;Water compensating valve, inlet valve are opened, water tank, infiltration liquid case is made to be full of water, Close water compensating valve;Servo-pressing machine is opened after temperature reaches setting value and stablizes 30min to incubator set point target temperature Axis pressure and confining pressure are applied to test specimen, pressure is controlled to setting value by pressure sensor;Hydraulic analogue system is opened to apply test specimen Add hydraulic pressure, so that hydraulic pressure is increased to setup pressure value by gas booster pump, pressure regulator valve, pressure gauge, intake valve;Tapping valve is opened, is made Drain threshold velocity is identical as groundwater velocity, and penetrating fluid is collected into liquid trap, on-test;Sampling time point is being set, Tapping valve is opened to collect contaminated liquid, when taking liquid, the old liquid that should first be vented in tapping valve and rinse, it is later, fast from each tapping valve Speed continuously takes sample three times, using the average value of three parallel contaminated liquid sample concentrations as the position contaminated liquid concentration value.Each After picking up contaminated liquid, changes bring error to reduce liquor capacity, imported and the bodies such as the amount of picking up by water compensating valve at once Long-pending water.Different location contaminated liquid ingredient and concentration is determined by analysis, the diffusion And Movement to Pyrolysis Contamination object in underground water is advised Rule is studied.
Pyrolysis pollutant experimental rig advantage of diffusion And Movement in underground water is a kind of simulation of the present invention in situ: with show There are device and method to compare, which has fully considered the ground temperature, crustal stress, ground water pressure condition of mineral products preservation, can be to examination Part loads the axis pressure and confining pressure of 0-20MPa respectively, applies the hydraulic pressure of 0-10MPa, 0-80 DEG C of test specimen environment temperature, analog 800m Geological conditions.The present invention is not only oil shale and low-disintegration coal, and pyrolysis pollutant diffusion And Movement in underground water tries in situ The significant innovation of proved recipe method and experimental rig, more other buried mineral products in-situ heat solution exploitation bring groundwater environment effects mention Feasible experimental study method is supplied.
Detailed description of the invention
Fig. 1 is the simulation test device structural schematic diagram of pyrolysis pollutant diffusion And Movement in underground water in situ.
Label in figure: 1 --- gas;2 --- gas booster pump;3 --- pressure regulator valve;4-1 --- first pressure gauge;4- 2 --- first pressure gauge;5 --- intake valve;6-1 --- the first water tank;6-2 --- the second water tank;7-1 --- the first moisturizing Valve;7-2 --- the second water compensating valve;7-3 --- third water compensating valve: 8 --- inlet valve;9 --- insulating box;10-1 --- first watches Take press machine;10-2 --- the second servo-pressing machine;11-1 --- first pressure sensor;11-2 --- second pressure sensing Device;12 --- pyrolysis rock stratum microscope carrier;13-1 --- the first infiltration liquid case;13-2 --- the second infiltration liquid case;14 --- it is adjacent Water layer microscope carrier;15 --- tapping valve;16 --- liquid trap;17 --- fastening bolt.
Specific embodiment
This experimental rig can be with the diffusion And Movement of oil shale in-situ Pyrolysis Contamination object in simulated groundwater, also analog underground Lignite is pyrolyzed the diffusion And Movement of pollutant in situ in water.
Shown in Fig. 1, a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ, it is characterised in that Including hydraulic analogue system, ground temperature crustal stress simulation system, pollutant diffusion And Movement simulation system, the hydraulic analogue system by Gas 1, gas booster pump 2, pressure regulator valve 3, first pressure gauge 4-1, intake valve 5, the first water tank 6-1, the first water compensating valve 7-1, into Water valve 8 forms;
Gas is pressurized by booster pump, and pressure needed for being adjusted by pressure regulator valve and pressure gauge, passes through intake valve, the One water tank, inlet valve and pressure gauge are by water cycle factors into the second water tank 6-2;Water body carries out the water in water tank by water compensating valve Supplement.
The ground temperature crustal stress simulation system, is made of insulating box 9, pressure sensor, servo-pressing machine.It is watched by first It takes press machine 10-1 and axis pressure and confining pressure load is carried out to the pyrolysis formation sample being placed in pyrolysis rock stratum microscope carrier 12, pass through the first pressure Force snesor 11-1 precisely monitors the axis pressure and confining pressure that are applied to pyrolysis rock stratum test specimen, passes through the second servo-pressing machine 10-2 carries out axis pressure to the permeable stratum sample being placed in adjacent pervious bed microscope carrier 14 and confining pressure loads, and is sensed by second pressure Device 11-2 to be applied to permeable stratum sample axis press and confining pressure precisely monitored, by insulating box to pyrolysis rock stratum test specimen with Permeable stratum sample carries out heated at constant temperature.
Embodiment 1: the diffusion And Movement of oil shale in-situ Pyrolysis Contamination object in simulated groundwater
The experimental rig of present embodiment is pyrolyzed the examination of pollutant diffusion And Movement in underground water using above-mentioned simulation in situ Experiment device.
It is as follows that operating procedure is embodied:
1, by having a size of 400 × 50mm of Φ pyrolysis oil shale test specimen and permeable stratum test specimen be respectively put into pyrolysis rock stratum carry It in platform 12 and adjacent pervious bed microscope carrier 14, is sealed with 17 pairs of pyrolysis rock stratum microscope carriers 12 of fastening bolt, adjacent permeable stratum carries Platform 14 is sealed.
2, first open water compensating valve 7-1, second open water compensating valve 7-2, third opens water compensating valve 7-3, inlet valve 8, make the One water tank 6-1, the second water tank 6-2, the first infiltration liquid case 13-1, the second infiltration liquid case 13-2 are full of water, close the first water compensating valve 7-1, the second water compensating valve 7-2, third water compensating valve 7-3.
3, according to required simulation oil shale layer buried depth and hydrogeologic condition, temperature ring where oil shale is calculated Border, ground stress environment and ground water pressure force environment set target temperature to insulating box 9, when temperature reaches setting value and stabilization It after 30min, opens servo-pressing machine and axis pressure and confining pressure is applied to test specimen, pressure is controlled to setting value by pressure sensor;It opens It opens hydraulic analogue system and hydraulic pressure is applied to test specimen, made by gas booster pump 2, pressure regulator valve 3, first pressure gauge 4-1, intake valve 5 Hydraulic pressure increases to setup pressure value.
4, according to practical hydrogeologic condition, groundwater velocity is selected, opens tapping valve 15, makes 15 flow velocity of tapping valve and ground Lower water flow velocity is identical, on-test.
5, sample time and sampling amount are set according to actual tests demand, when sampling, tapping valve 15 is opened and collects contaminated liquid Into liquid trap 16.
6, after picking up contaminated liquid every time, change bring error to reduce liquor capacity, pass through water compensating valve at once It imports and water that the amount of picking up is isometric.
7, different location contaminated liquid ingredient and concentration is determined by analysis, studies oil shale pyrolysis pollutant in underground water Diffusive migration rule.
Embodiment 2: lignite is pyrolyzed the diffusion And Movement of pollutant in situ in simulated groundwater
The experimental rig of present embodiment is pyrolyzed the examination of pollutant diffusion And Movement in underground water using above-mentioned simulation in situ Experiment device, it can satisfy the diffusion And Movement that lignite in simulated groundwater is pyrolyzed pollutant in situ, by that will be pyrolyzed lignite test specimen It is placed in microscope carrier, seals with permeable stratum test specimen, make equipment full of water, reach setting value to calorstat temperature and stablize 30min Afterwards, axis pressure, confining pressure and hydraulic pressure are applied to test specimen, opens bottom tapping valve 15, keeps its flow velocity identical as groundwater velocity.Hereafter, Tapping valve picks up contaminated liquid at different location on the right side of time opening, analyzes contaminated liquid ingredient and concentration, studies lignite Pyrolysis Contamination Diffusive migration rule of the object in underground water.
In conclusion present invention is mainly used for oil shale in underground water and low-disintegration coal etc., the diffusion of pyrolysis pollutant is transported in situ Move research.
The experimental rig can simulate the underground water under the conditions of different crustal stress conditions, temperature condition, groundwater pressure Middle Pyrolysis Contamination object diffusion And Movement problem, but embodiment of above is only used to illustrate the technical scheme of the present invention and not to limit it, Although by referring to embodiments of the present invention, invention has been described, and the scientific research technical staff of this field should Understand, various changes can be made to it in the form and details.

Claims (9)

1. a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ, it is characterised in that including hydraulic pressure mould Quasi- system, ground temperature crustal stress simulation system, pollutant diffusion And Movement simulation system, hydraulic analogue system and ground temperature crustal stress are simulated System connection, ground temperature crustal stress simulation system are connect with pollutant diffusion And Movement simulation system;The hydraulic analogue system is by gas Body, gas booster pump, pressure regulator valve, pressure gauge, intake valve, the first water tank, the second water tank, the first water compensating valve, inlet valve composition, gas Body is pressurized by booster pump, and adjusts required pressure by pressure regulator valve and first pressure gauge, passes through intake valve, the first water Case, inlet valve and second pressure gauge are by water cycle factors into the second water tank, and water body is by the first water compensating valve in the first water tank Water is supplemented;
The ground temperature crustal stress simulation system, is made of insulating box, servo-pressing machine, pressure sensor;Servo-pressing machine setting In insulating box;By servo-pressing machine respectively to be placed in pyrolysis rock stratum microscope carrier in pyrolysis rock stratum test specimen, be placed in it is adjacent permeable Permeable stratum test specimen in layer microscope carrier carries out axis pressure and confining pressure load;By pressure sensor respectively to be applied to pyrolysis rock stratum examination Part, the axis pressure of permeable stratum sample and confining pressure are precisely monitored, and are tried by insulating box pyrolysis rock stratum test specimen and permeable stratum Part carries out heated at constant temperature;
The pollutant diffusion And Movement simulation system, including the second water tank, pyrolysis rock stratum microscope carrier, infiltration liquid case, adjacent pervious bed Microscope carrier, tapping valve, liquid trap, the second water compensating valve, third water compensating valve;Second water tank, permeates liquid case, is adjacent at pyrolysis rock stratum microscope carrier Pervious bed microscope carrier is arranged in insulating box;Pyrolysis rock stratum test specimen is placed in pyrolysis rock stratum microscope carrier, and permeable stratum test specimen is placed in phase In adjacent pervious bed microscope carrier;Second water tank is located above pyrolysis rock stratum microscope carrier, and two infiltration liquid cases are arranged below in pyrolysis rock stratum microscope carrier, Adjacent pervious bed microscope carrier is equipped between two infiltration liquid cases;Each infiltration liquid case is respectively connected with several liquid traps;
Water body enters pyrolysis rock stratum microscope carrier through the second water tank and forms contaminated liquid, and contaminated liquid enters the first infiltration liquid case, passes through drain Valve acquires penetrating fluid at different height position into different liquid traps;Under the action of water pressure, the pollution of the first infiltration liquid case Liquid enters in the second infiltration liquid case through adjacent pervious bed microscope carrier, by tapping valve by penetrating fluid at different height position acquire to In different liquid traps.
2. the experimental rig of a kind of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, It is characterized in that the hydraulic analogue system is transmitted by the way that high pressure gas to be injected into water tank, and by pressure, not to test specimen load Same hydraulic pressure, to simulate the true groundwater environment of oil shale and low-disintegration coal layer preservation.
3. the experimental rig of a kind of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, It is characterized in the ground temperature crustal stress simulation system, the true of mineral products is simulated by insulating box and servo-pressing machine and buries ground temperature condition With crustal stress condition.
4. the experimental rig of a kind of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, Be characterized in the pollutant diffusion And Movement simulation system, by by with hydraulic pressure water body note be implanted sequentially pyrolysis rock stratum test specimen and In the sample of permeable stratum, diffusion And Movement of the Pyrolysis Contamination object in underground water is simulated.
5. the experimental rig of a kind of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, It is characterized in that it simulates the geological conditions that mineral products buried depth is 800m.
6. a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, It is characterized in that, it is 400mm that the pyrolysis rock stratum microscope carrier, which loads diameter, height is the pyrolysis rock stratum test specimen of 50mm.
7. a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ according to claim 1, It is characterized in that, it is 400mm that the adjacent pervious bed microscope carrier, which loads diameter, height is the permeable stratum test specimen of 50mm.
8. a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ described in accordance with the claim 1, It is characterized in that pressing to the axis that test specimen loads with confining pressure is 0-20MPa, it is 0-10MPa, water temperature temperature to the hydraulic pressure that test specimen loads Degree is 0-80 DEG C.
9. a kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ described in accordance with the claim 1, It is characterized in that the gas is using nitrogen.
CN201710217667.0A 2017-04-05 2017-04-05 A kind of experimental rig of simulation pyrolysis pollutant diffusion And Movement in underground water in situ Expired - Fee Related CN107063941B (en)

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