CN107057552A - A kind of leather surface treatment agent and preparation method thereof - Google Patents
A kind of leather surface treatment agent and preparation method thereof Download PDFInfo
- Publication number
- CN107057552A CN107057552A CN201710346840.7A CN201710346840A CN107057552A CN 107057552 A CN107057552 A CN 107057552A CN 201710346840 A CN201710346840 A CN 201710346840A CN 107057552 A CN107057552 A CN 107057552A
- Authority
- CN
- China
- Prior art keywords
- leather
- modified
- surface treatment
- treatment agent
- soybean oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
- C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention provides a kind of leather surface treatment agent and preparation method thereof.Modified colza and epoxidized soybean oil modified polyurethane resin in leather treatment provided by the present invention effectively can be permeated in leather, leather is set to absorb a certain amount of grease, it is strong to UV absorbing properties, resultant Leather is glossy after stuffing feels, it effectively prevent that leather is hardened, jackknifing, be worthy to be popularized and use；On the other hand, Al2O3Sol-gel modified Leather Waste micro mist forms a kind of polymer with double-layer nanometer layer so that the coating that the leather surface handled by the surface conditioning agent has, and with more stable lasting superpower water repellent, refuses oil, antifouling properties；Touch leather original surface nano-particle can and the bumps of original surface carry out the connection of deep combination, further increase coating and leather, greasy dirt or moisture is not penetrated into inside leather directly, substantially increase water repellent, refuse oil and antifouling property.
Description
Technical field
The present invention relates to leather processing preparation technique field, and in particular to a kind of leather surface treatment agent and its preparation side
Method.
Background technology
With the development of technology, leather and fur products has been realized in diversified production, enriches the life of people.Surface is applied
Decorations are the essential processes of leather processing, and it not only assigns leather beautiful outward appearance, it is often more important that obtain the physical property of leather
To lifting, as against weather, water resistance, softness, ventilative, permeable etc..In leather finish, in order to reach that high-quality cover with paint, lacquer, colour wash, etc. is imitated
Really, the fashion pursuit of people that consumer is continually changing is met, finish auxiliary is very crucial and indispensable.It can adjust covering with paint slurry
The levelability of material, improves the film forming of film forming agent, improves the physical property of finished leather, assigns the sense organ style of leather fashion.
But, existing leather surface treatment agent is coated in after leather surface, and its persistence is not good, easily causes the mill of coating
Damage, influence the attractive in appearance of leather and use.
Therefore, it is necessary to provide a kind of lasting water repellent, refuse oil, the leather surface treatment agent of antifouling properties and its preparation side
Method.
The content of the invention
In order to solve the above problems, the invention provides a kind of leather surface treatment agent and preparation method thereof.
In a first aspect, the invention provides a kind of leather surface treatment agent, the raw material of the leather surface treatment agent, by weight
Number meter is measured, including：15~25 parts of modified colza, 30~45 parts of epoxidized soybean oil modified polyurethane resin, deionized water 30
~45 parts, 1~4 part of silicone emulsion, 0.5~2 part of organic silicon defoamer, 1~5 part of polyurethane associative thickener, gelatin 0.1~
0.5 part, Al2O3Sol-gel modified 1~5 part of Leather Waste micro mist.
It is further preferred that in the raw material of the leather surface treatment agent, the modified colza and the epoxy soybean
The mass ratio of oil modified urethanes resin is 1:1~3.
It is further preferred that in the raw material of the leather surface treatment agent, the modified colza and the epoxy soybean
The mass ratio of oil modified urethanes resin is 1:1、1:1.5、1:2、1:2.5 or 1:3.
Preferably, the preparation method of the modified colza, comprises the following steps：According to rapeseed oil, ethylenediamine, three oxidations
The mass ratio of aluminium is 100:1.5~3:1~1.5 ratio, the mixture of rapeseed oil, ethylenediamine and alchlor is warming up to
100~120 DEG C, 3~4h of insulation reaction, the mass ratio according still further to acrylic acid and rapeseed oil is 5~10:100 ratio, adds third
Olefin(e) acid, is warming up to 125~135 DEG C, modified colza is made in 3~4h of insulation reaction.
It is further preferred that the condition of the ultrasonic processing method is：Frequency be 10~60kHz, power be 100~
500W。
Preferably, the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, comprises the following steps：
Take the raw material of the epoxidized soybean oil modified polyurethane resin of following portions by weight：It is 15~20 parts of polyisocyanates, many
First 20~35 parts of alcohol, 10~20 parts of epoxidized soybean oil, 10~15 parts of diethanol amine, 10~15 parts of the first chain extender, the second chain extension
5~7 parts of agent, 0.1~0.5 part of organic bismuth catalyst, 2~4 parts of organic solvent；After epoxidized soybean oil and diethanol amine are mixed,
50~60 DEG C are warming up under inert gas shielding, 2~3h of insulation reaction obtains the epoxidized soybean oil of open loop；Again by higher alcohols
After sulfosuccinate, PPG and the mixing of the epoxidized soybean oil of open loop, 75~85 DEG C are warming up to, 2~3h of insulation reaction,
Not higher than 60 DEG C are cooled to, the first chain extender, the second chain extender and organic bismuth catalyst and organic solvent is being added, 65~
85 DEG C of 3~4h of reaction, after cooling, neutralizing, add frozen water and emulsify at a high speed, 10~15min is reacted adding ethylenediamine dilution,
The polyurethane resin that epoxidized soybean oil is modified is made.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyalcohol bag
Include but be not limited to polytetramethylene ether diol, polycaprolactone polyol, polycarbonate polyol, PolyTHF ethoxylated polyhydric alcohol,
One or more in polyethylene oxide polyol, polyoxypropylene polyol and end hydroxy butadiene.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyalcohol
For polytetramethylene ether diol.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyisocyanic acid
Ester includes but is not limited to higher alcohols sulfosuccinate, toluene di-isocyanate(TDI), IPDI, diphenyl methane
Diisocyanate, hexamethylene diisocyanate, XDI, naphthalene -1,5- diisocyanate, polymethylene are more
Phenyl isocyanate, tetramethylxylylene diisocyanate, Methylcyclohexyl diisocyanate and dicyclohexyl methyl hydride two
One or more in isocyanates.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, many isocyanides
Acid esters is higher alcohols sulfosuccinate.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, first chain extension
Agent include but is not limited to dihydromethyl propionic acid, dimethylolpropionic acid, dihydroxymethyl valeric acid and dihydroxymethyl octanoic acid in one kind or
It is several.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, described first expands
Chain agent is dihydromethyl propionic acid.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, second chain extension
Agent include but is not limited to ethylene glycol, diglycol, 1,4- butanediols, 2,3- butanediols, 1,6-HD, neopentyl glycol,
One or more in diethylene glycol (DEG), glycerine, sorbierite, trimethylolpropane and hydroxymethyl-cyclohexane.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, described second expands
Chain agent is 1,4- butanediols.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organo-bismuth is urged
One kind that agent includes but is not limited in Coscat83, organo-bismuth 1610, organo-bismuth 2010, organo-bismuth 2810, organo-bismuth 2808
Or it is several.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organo-bismuth
Catalyst is organo-bismuth 1610.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organic solvent
Including but not limited to acetone.
Preferably, the Al2O3The preparation method of sol-gel modified Leather Waste micro mist, comprises the following steps:By Leather Waste
Micro mist is mixed with deionized water stirring, is instilled Alumina gel with 10~15d/min speed, is warming up to and is not less than 60 DEG C, insulation is stirred
1~2h of reaction is mixed, is dried with spray dryer and Al is made2O3Sol-gel modified Leather Waste micro mist, it is standby, wherein, the waste and old skin
It is 1 to remove from office micro mist, deionized water, the mass ratio of Alumina gel:3:0.25.
It is 0.05~2nm of average length, straight it is further preferred that the mass fraction of solid is 7~15% in the Alumina gel
0.005~2nm of footpath, in threadiness.
Second aspect, present invention also offers a kind of preparation method of leather surface treatment agent, comprises the following steps：
Take the raw material of the leather surface treatment agent of following portions by weight：15~25 parts of modified colza, epoxidized soybean oil change
Property 30~45 parts of polyurethane resin, 30~45 parts of deionized water, 1~4 part of silicone emulsion, 0.5~2 part of organic silicon defoamer, poly-
1~5 part of urethane association thickener, 0.1~0.5 part of gelatin, Al2O3Sol-gel modified 1~5 part of Leather Waste micro mist；
By modified colza, epoxidized soybean oil modified polyurethane resin, deionized water, silicone emulsion, organic silicon defoamer
0.5~2h is mixed, 30~40 DEG C are warming up to, added after gelatin, then first 5~30min of ultrasonication, ground, mistake
Filter, obtains emulsion；Polyurethane associative thickener is added, after mixing, Al is added2O3Sol-gel modified Leather Waste micro mist, then second
Secondary 10~60min of ultrasonication, is made leather surface treatment agent.
Preferably, in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the modified colza and institute
The mass ratio for stating epoxidized soybean oil modified polyurethane resin is 1:1~3.
Preferably, in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the modified colza and institute
The mass ratio for stating epoxidized soybean oil modified polyurethane resin is 1:1、1:1.5、1:2、1:2.5 or 1:3.
Preferably, in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the inert gas include but
It is not limited to the one or more in nitrogen, argon gas, argon gas, helium.
Preferably, the preparation method of the modified colza, comprises the following steps:According to rapeseed oil, ethylenediamine, three oxidations
The mass ratio of aluminium is 100:1.5~3:1~1.5 ratio, rapeseed oil, ethylenediamine, alchlor are mixed, it is warming up to 100~
120 DEG C, 3~4h of insulation reaction, the mass ratio according still further to acrylic acid and rapeseed oil is 5~10:100 ratio, adds acrylic acid,
It is warming up to after 125~135 DEG C, 3~4h of insulation reaction, modified colza is made.
Preferably, the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, comprises the following steps：
Take the raw material of the epoxidized soybean oil modified polyurethane resin of following portions by weight：It is 15~20 parts of polyisocyanates, many
First 20~35 parts of alcohol, 10~20 parts of epoxidized soybean oil, 10~15 parts of diethanol amine, 10~15 parts of the first chain extender, the second chain extension
5~7 parts of agent, 0.1~0.5 part of organic bismuth catalyst, 2~4 parts of organic solvent；After epoxidized soybean oil and diethanol amine are mixed,
50~60 DEG C are warming up under the protection of inert gas, 2~3h of insulation reaction obtains the epoxidized soybean oil of open loop；Again by high-carbon
After alcohol sulfosuccinate, PPG and the mixing of the epoxidized soybean oil of open loop, 75~85 DEG C are warming up to, insulation reaction 2~
3h, is cooled to not higher than 60 DEG C, adds the first chain extender, the second chain extender and organic bismuth catalyst and organic solvent,
65~85 DEG C of 3~4h of reaction, are emulsified after cooling, neutralization, are added ethylenediamine dilution and are reacted 10~15min, epoxy is made
Soybean oil modified polyurethane resin.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyalcohol bag
Include but be not limited to polytetramethylene ether diol, polycaprolactone polyol, polycarbonate polyol, PolyTHF ethoxylated polyhydric alcohol,
One or more in polyethylene oxide polyol, polyoxypropylene polyol and end hydroxy butadiene.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyalcohol
For polytetramethylene ether diol.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the polyisocyanic acid
Ester includes but is not limited to higher alcohols sulfosuccinate, toluene di-isocyanate(TDI), IPDI, diphenyl methane
Diisocyanate, hexamethylene diisocyanate, XDI, naphthalene -1,5- diisocyanate, polymethylene are more
Phenyl isocyanate, tetramethylxylylene diisocyanate, Methylcyclohexyl diisocyanate and dicyclohexyl methyl hydride two
One or more in isocyanates.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, many isocyanides
Acid esters is higher alcohols sulfosuccinate.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, first chain extension
Agent include but is not limited to dihydromethyl propionic acid, dimethylolpropionic acid, dihydroxymethyl valeric acid and dihydroxymethyl octanoic acid in one kind or
It is several.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, described first expands
Chain agent is dihydromethyl propionic acid.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, second chain extension
Agent include but is not limited to ethylene glycol, diglycol, 1,4- butanediols, 2,3- butanediols, 1,6-HD, neopentyl glycol,
One or more in diethylene glycol (DEG), glycerine, sorbierite, trimethylolpropane and hydroxymethyl-cyclohexane.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, described second expands
Chain agent is 1,4- butanediols.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organo-bismuth is urged
One kind that agent includes but is not limited in Coscat83, organo-bismuth 1610, organo-bismuth 2010, organo-bismuth 2810, organo-bismuth 2808
Or it is several.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organo-bismuth
Catalyst is organo-bismuth 1610.
It is further preferred that in the preparation method for the polyurethane resin that the epoxidized soybean oil is modified, the organic solvent
Including but not limited to acetone.
Preferably, the Al2O3The preparation method of sol-gel modified Leather Waste micro mist, comprises the following steps：By Leather Waste
After micro mist is mixed with water, Alumina gel is instilled with 10~15d/min speed, is warming up to and is not less than 60 DEG C, insulated and stirred reaction 1~
2h, is dried with spray dryer and Al is made2O3Sol-gel modified Leather Waste micro mist, it is standby, wherein, the Leather Waste micro mist, go
Ionized water, the mass ratio of Alumina gel are 1:2~4:0.05~0.5.
It is 0.05~2nm of average length, straight it is further preferred that the mass fraction of solid is 7~15% in the Alumina gel
0.005~2nm of footpath, in threadiness.
Preferably, the condition of the first time ultrasonication is:Frequency is that 10~60kHz, power are 100~500W.
Preferably, the condition of second of ultrasonication is:Frequency is that 10~60kHz, power are 100~500W.
Preferably, present invention also offers a kind of leather surface treatment agent, the leather surface treatment agent is using this hair
The preparation method of leather surface treatment agent described in bright second aspect is made.
Beneficial effect of the present invention relative to prior art：
(1) modified colza and epoxidized soybean oil modified polyurethane resin effectively can be permeated in leather, absorb leather
A certain amount of grease, strong to UV absorbing properties, resultant Leather is glossy after stuffing feels, effectively prevent leather it is hardened, folding
Split, be worthy to be popularized and use；
(2)Al2O3Sol-gel modified Leather Waste micro mist forms a kind of polymer with nanometer layer so that pass through the surface
The coating that the leather surface of inorganic agent processing has, with more stable lasting superpower water repellent, refuses oil, antifouling properties；Contact
To leather original surface nano-particle can and the bumps of original surface carry out deep combination, further increase coating and leather
Connection, makes greasy dirt or moisture not to penetrate into inside leather directly, substantially increases water repellent, refuses oil and antifouling property.
Embodiment
Below by embodiment, the present invention is described in detail.
Embodiment 1
The embodiments of the invention provide a kind of preparation method of leather surface treatment agent, comprise the following steps：
(1) preparation of modified colza：Mass ratio according to rapeseed oil, ethylenediamine, alchlor is 100:2:1 ratio
Example, rapeseed oil, ethylenediamine, alchlor are mixed, 100 DEG C are warming up to, insulation reaction 3h, according still further to acrylic acid and rapeseed oil
Mass ratio is 8:100 ratio, adds acrylic acid, is warming up to after 125 DEG C, insulation reaction 4h, and modified colza is made, standby；
(2) preparation for the polyurethane resin that epoxidized soybean oil is modified：Take the epoxidized soybean oil of following portions by weight to be modified to gather
The raw material of urethane resin：15 parts of higher alcohols sulfosuccinate, 20 parts of PPG (Mn=1000, N-210), epoxy soybean
10 parts of oil, 10 parts of diethanol amine, 10 parts of dihydromethyl propionic acid, 5 parts of diethylene glycol (DEG), 1,610 0.2 parts of organo-bismuth, 2 parts of acetone；By ring
Oxygen soybean oil and diethanol amine are added in four-hole bottle, 50 DEG C are warming up under the protection of nitrogen, insulation reaction 2h obtains open loop
Epoxidized soybean oil, then by after the mixing of higher alcohols sulfosuccinate, PPG and the epoxidized soybean oil of open loop, it is warming up to 85
DEG C, insulation reaction 2h is cooled to not higher than 60 DEG C, adds dihydromethyl propionic acid, diethylene glycol (DEG) and organo-bismuth 1610 and acetone,
4h is reacted at 65 DEG C, after cooling, neutralizing, frozen water is added and emulsifies at a high speed, ethylenediamine dilution reaction 10min is added, is made
The polyurethane resin that epoxidized soybean oil is modified, it is standby；
(3)Al2O3The preparation of sol-gel modified Leather Waste micro mist：Leather Waste micro mist is mixed with deionized water stirring, with
10d/min speed instills Alumina gel, and (in Alumina gel, the mass fraction of solid is 7%, and average length 1nm, diameter 0.5nm are in
Threadiness) 60 DEG C are warming up to, insulated and stirred reaction 1h is dried with spray dryer and Al is made2O3Sol-gel modified Leather Waste is micro-
Powder, it is standby, wherein, the Leather Waste micro mist, deionized water, the mass ratio of Alumina gel are 1:3:0.25；
(4) preparation of leather surface treatment agent：Modified colza obtained by step (1), the epoxy obtained by step (2) is big
Soya-bean oil modified polyurethane resin, deionized water, silicone emulsion, organic silicon defoamer mix 2h, are warming up to 35 DEG C, add bright
Glue, then in frequency be that 50kHz, power are that ground, filtering obtains emulsion under conditions of 500W after ultrasonication 10min；Again
Polyurethane associative thickener is added, is stirred, the Al obtained by step (3) is added2O3Sol-gel modified Leather Waste micro mist, then
It is that 50kHz, power are ultrasonication 20min under conditions of 500W in frequency, leather surface treatment agent one is made；
Wherein, in step (4), the parts by weight of each raw material are as follows：
| Sequence number | Material name | Parts by weight/part |
| 1 | Modified colza obtained by step (1) | 30 |
| 2 | Epoxidized soybean oil modified polyurethane resin obtained by step (2) | 30 |
| 3 | Deionized water | 40 |
| 4 | Silicone emulsion | 2 |
| 5 | Organic silicon defoamer | 1 |
| 6 | Gelatin | 0.2 |
| 7 | Polyurethane associative thickener | 2 |
| 8 | Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist | 4 |
Embodiment 2
In order to further illustrate beneficial effects of the present invention, the step of repeating the embodiment of the present invention 1 (1), step (2) and
Step (3), then by the modified colza obtained by step (1), the epoxidized soybean oil modified polyurethane resin obtained by step (2), go
Ionized water, silicone emulsion, organic silicon defoamer mix 2h, are warming up to 35 DEG C, add gelatin, then in frequency are 50kHz, work(
After rate is ultrasonication 10min under conditions of 500W, ground, filtering obtains emulsion；Add the thickening of polyurethane association type
Agent, stirs, and adds the Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist, then in frequency be that 50kHz, power are
Ultrasonication 20min under conditions of 500W, is made leather surface treatment agent two；
Wherein, in step (4), the parts by weight of each raw material are as follows：
| Sequence number | Material name | Parts by weight/part |
| 1 | Modified colza obtained by step (1) | 20 |
| 2 | Epoxidized soybean oil modified polyurethane resin obtained by step (2) | 30 |
| 3 | Deionized water | 40 |
| 4 | Silicone emulsion | 2 |
| 5 | Organic silicon defoamer | 1 |
| 6 | Gelatin | 0.2 |
| 7 | Polyurethane associative thickener | 2 |
| 8 | Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist | 4 |
Embodiment 3
In order to further illustrate beneficial effects of the present invention, the step of repeating the embodiment of the present invention 1 (1), step (2) and
Step (3), then by the modified colza obtained by step (1), the epoxidized soybean oil modified polyurethane resin obtained by step (2), go
Ionized water, silicone emulsion, organic silicon defoamer mix 2h, are warming up to 35 DEG C, add gelatin, then in frequency are 50kHz, work(
After rate is ultrasonication 10min under conditions of 500W, ground, filtering obtains emulsion；Add the thickening of polyurethane association type
Agent, stirs, and adds the Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist, then in frequency be that 50kHz, power are
Ultrasonication 20min under conditions of 500W, is made leather surface treatment agent three；
Wherein, in step (4), the parts by weight of each raw material are as follows：
Embodiment 4
In order to further illustrate beneficial effects of the present invention, the step of repeating the embodiment of the present invention 1 (1), step (2) and
Step (3), then by the modified colza obtained by step (1), the epoxidized soybean oil modified polyurethane resin obtained by step (2), go
Ionized water, silicone emulsion, organic silicon defoamer mix 2h, are warming up to 35 DEG C, add gelatin, then in frequency are 50kHz work(
After rate is ultrasonication 10min under conditions of 500W, ground, filtering obtains emulsion；Add the thickening of polyurethane association type
Agent, stirs, and adds the Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist, then in frequency be that 50kHz power is
Ultrasonication 20min under conditions of 500W, is made leather surface treatment agent four；
Wherein, in step (4), the parts by weight of each raw material are as follows：
| Sequence number | Material name | Parts by weight/part |
| 1 | Modified colza obtained by step (1) | 18 |
| 2 | Epoxidized soybean oil modified polyurethane resin obtained by step (2) | 45 |
| 3 | Deionized water | 40 |
| 4 | Silicone emulsion | 2 |
| 5 | Organic silicon defoamer | 1 |
| 6 | Gelatin | 0.2 |
| 7 | Polyurethane associative thickener | 2 |
| 8 | Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist | 4 |
Embodiment 5
In order to further illustrate beneficial effects of the present invention, the step of repeating the embodiment of the present invention 1 (1), step (2) and
Step (3), then by the modified colza obtained by step (1), the epoxidized soybean oil modified polyurethane resin obtained by step (2), go
Ionized water, silicone emulsion, organic silicon defoamer mix 2h, are warming up to 35 DEG C, add gelatin, then in frequency are 50kHz work(
After rate is ultrasonication 10min under conditions of 500W, ground, filtering obtains emulsion；Add the thickening of polyurethane association type
Agent, stirs, and adds the Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist, then in frequency be that 50kHz power is
Ultrasonication 20min under conditions of 500W, is made leather surface treatment agent five；
Wherein, in step (4), the parts by weight of each raw material are as follows：
Effect example 1
Inorganic agent obtained by embodiment 1~5 is used to handle with batch leather, and performance survey is carried out to the leather after processing
It is fixed, as a result as shown in table 1.
Influence of the different disposal agent of table 1 to leather texture
As shown in Table 1, with modified colza and epoxidized soybean oil modified polyurethane resin weight than increase, leather table
The pliability of face inorganic agent is significantly increased, when the weight ratio is 1:During 1~3 interval, the pliability change of leather surface treatment agent
It is unobvious；And when modified colza and epoxidized soybean oil modified polyurethane resin weight ratio are 1:When 2, leather surface treatment agent pair
Mould inhibiting rate is best.
Embodiment 6
The embodiments of the invention provide a kind of preparation method of leather surface treatment agent, comprise the following steps：
(1) preparation of modified colza：Mass ratio according to rapeseed oil, ethylenediamine, alchlor is 100:3:1.5 ratio
Example, rapeseed oil, ethylenediamine, alchlor are mixed, 120 DEG C are warming up to, insulation reaction 4h, according still further to acrylic acid and rapeseed oil
Mass ratio is 5:100 ratio, adds acrylic acid, is warming up to after 135 DEG C, insulation reaction 3h and modified colza is made, standby；
(2) preparation for the polyurethane resin that epoxidized soybean oil is modified：Take the epoxidized soybean oil of following portions by weight to be modified to gather
The raw material of urethane resin：20 parts of higher alcohols sulfosuccinate, 35 parts of PPG (Mn=1000, N-210), epoxy soybean
17 parts of oil, 15 parts of diethanol amine, 15 parts of dihydromethyl propionic acid, 7 parts of diethylene glycol (DEG), 1,610 0.2 parts of organo-bismuth, 4 parts of acetone；By ring
Oxygen soybean oil and diethanol amine are added in four-hole bottle, 60 DEG C are warming up under the protection of nitrogen, insulation reaction 3h obtains open loop
Epoxidized soybean oil, then by after the mixing of higher alcohols sulfosuccinate, PPG and the epoxidized soybean oil of open loop, it is warming up to 75
DEG C, insulation reaction 3h is cooled to not higher than 60 DEG C, sequentially adds dihydromethyl propionic acid, diethylene glycol (DEG) and the and of organo-bismuth 1610
Acetone, 3h is reacted at 75 DEG C, after cooling, neutralizing, and is added frozen water and is emulsified at a high speed, adds ethylenediamine dilution reaction 15min,
The polyurethane resin that epoxidized soybean oil is modified is made, it is standby；
(3)Al2O3The preparation of sol-gel modified Leather Waste micro mist：Leather Waste micro mist is mixed with deionized water stirring, with
15d/min speed instill Alumina gel (in Alumina gel, the mass fraction of solid is 15%, average length 1nm, diameter 0.1nm,
In threadiness) 60 DEG C are warming up to, insulated and stirred reaction 1h is dried with spray dryer and Al is made2O3Sol-gel modified Leather Waste is micro-
Powder, it is standby, wherein, the Leather Waste micro mist, deionized water, the mass ratio of Alumina gel are 1:4:0.5；
(4) preparation of leather surface treatment agent：Modified colza obtained by step (1), the epoxy obtained by step (2) is big
Soya-bean oil modified polyurethane resin, deionized water, silicone emulsion, organic silicon defoamer mix 0.5h, are warming up to 35 DEG C, addition
Gelatin, then in frequency be that 50kHz, power are that ground, filtering obtains emulsion under conditions of 500W after ultrasonication 10min；
Polyurethane associative thickener is added, is stirred, the Al obtained by step (3) is added2O3Sol-gel modified Leather Waste micro mist,
It is again that 50kHz, power are ultrasonication 20min under conditions of 500W in frequency, leather surface treatment agent six is made；
Wherein, in step (4), the parts by weight of each raw material are as follows：
| Sequence number | Material name | Parts by weight/part |
| 1 | Modified colza obtained by step (1) | 20 |
| 2 | Epoxidized soybean oil modified polyurethane resin obtained by step (2) | 40 |
| 3 | Deionized water | 40 |
| 4 | Silicone emulsion | 2 |
| 5 | Organic silicon defoamer | 1 |
| 6 | Gelatin | 0.2 |
| 7 | Polyurethane associative thickener | 2 |
| 8 | Al obtained by step (3)2O3Sol-gel modified Leather Waste micro mist | 4 |
Embodiment 7
In order to further illustrate beneficial effects of the present invention, step (1) in the embodiment of the present invention 6, step (2), step are repeated
Suddenly (3), step (4), by the step of the embodiment of the present invention 6 (4) " mix 0.5h " be substituted for " mix 1h ", it is " mixed
Stirring 2h " is closed, " 3h " is mixed, " mixes 4h ", leather surface treatment agent seven, leather surface treatment agent is respectively prepared
8th, leather surface treatment agent nine, leather surface treatment agent ten.
Effect example 2
Inorganic agent obtained by embodiment 6~7 is used to handle with batch leather, and performance survey is carried out to the leather after processing
It is fixed, as a result as shown in table 2.
Influence of the different disposal agent of table 2 to leather texture and fungistatic effect
As shown in Table 2, with the increase of the time of mixing, Al is conducive to2O3Sol-gel modified Leather Waste micro mist formation one
The polymer with nanometer layer is planted so that the coating that the leather surface handled by the surface conditioning agent has, with more steady
Determine lasting superpower water repellent, refuse oil, antifouling properties；Touching the nano-particle of leather original surface can enter with the bumps of original surface
The deep combination of row, further the connection of increase coating and leather, makes greasy dirt or moisture not to penetrate into inside leather directly, significantly
Improve water repellent, refuse oil and antifouling property.
Embodiment 7
In order to further illustrate beneficial effects of the present invention, the step of repeating the embodiment of the present invention 3 (1), step (2), step
Suddenly (3) and step (4), then by " rapeseed oil " in step (1) replace respectively into " tung oil ", " soybean oil ", " sunflower oil ",
" peanut oil ", is made leather surface treatment agent 11, leather surface treatment agent 12, leather surface treatment agent 13, skin respectively
Remove from office surface conditioning agent 14.
Effect example 3
Inorganic agent obtained by embodiment 6 is used to handle with batch leather, and performance measurement is carried out to the leather after processing,
As a result it is as shown in table 3.
Influence of the different disposal agent of table 3 to leather texture and fungistatic effect
As shown in Table 3, it is best using the fungistatic effect of rapeseed oil leather surface treatment agent three made from raw material, and pliability
Most preferably.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert
The specific implementation of the present invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the present invention's
Protection domain.
Claims (10)
1. a kind of leather surface treatment agent, it is characterised in that the raw material of the leather surface treatment agent, is counted by weight, bag
Include：15~25 parts of modified colza, 30~45 parts of epoxidized soybean oil modified polyurethane resin, 30~45 parts of deionized water, emulsification
1~4 part of silicone oil, 0.5~2 part of organic silicon defoamer, 1~5 part of polyurethane associative thickener, 0.1~0.5 part of gelatin, Al2O3
Sol-gel modified 1~5 part of Leather Waste micro mist.
2. leather surface treatment agent as claimed in claim 1, it is characterised in that in the raw material of the leather surface treatment agent,
The mass ratio of the modified colza and the epoxidized soybean oil modified polyurethane resin is 1:1~3.
3. leather surface treatment agent as claimed in claim 1, it is characterised in that in the raw material of the leather surface treatment agent,
The mass ratio of the modified colza and the epoxidized soybean oil modified polyurethane resin is 1:1、1:1.5、1:2、1:2.5 or 1:
3。
4. a kind of preparation method of leather surface treatment agent, it is characterised in that comprise the following steps：
Take the raw material of the leather surface treatment agent of following portions by weight：15~25 parts of modified colza, epoxidized soybean oil are modified poly-
30~45 parts of urethane resin, 30~45 parts of deionized water, 1~4 part of silicone emulsion, 0.5~2 part of organic silicon defoamer, polyurethane
1~5 part of association thickener, 0.1~0.5 part of gelatin, Al2O3Sol-gel modified 1~5 part of Leather Waste micro mist；
Modified colza, epoxidized soybean oil modified polyurethane resin, deionized water, silicone emulsion, organic silicon defoamer are mixed
0.5~2h is stirred, 30~40 DEG C are warming up to, added after gelatin, then first time 5~30min of ultrasonication, ground, filtering,
Obtain emulsion；Polyurethane associative thickener is added, is stirred, Al is added2O3Sol-gel modified Leather Waste micro mist, then second
Secondary 10~60min of ultrasonication, is made leather surface treatment agent.
5. the preparation method of leather surface treatment agent as claimed in claim 4, it is characterised in that the system of the modified colza
Preparation Method, comprises the following steps：Mass ratio according to rapeseed oil, ethylenediamine, alundum (Al2O3) is 100:1.5~3:1~1.5
Ratio, by the mixture of rapeseed oil, ethylenediamine and alchlor, is warming up to 100~120 DEG C, 3~4h of insulation reaction, according still further to
The mass ratio of acrylic acid and rapeseed oil is 5~10:100 ratio, adds acrylic acid, is warming up to 125~135 DEG C, insulation reaction 3
Modified colza is made after~4h.
6. the preparation method of leather surface treatment agent as claimed in claim 4, it is characterised in that the epoxidized soybean oil is modified
Polyurethane resin preparation method, comprise the following steps：
Take the raw material of the epoxidized soybean oil modified polyurethane resin of following portions by weight：15~20 parts of polyisocyanates, polyalcohol
20~35 parts, 10~20 parts of epoxidized soybean oil, 10~15 parts of diethanol amine, 10~15 parts of the first chain extender, the second chain extender 5~
7 parts, 0.1~0.5 part of organic bismuth catalyst, 2~4 parts of organic solvent；After epoxidized soybean oil and diethanol amine are mixed, in inertia
50~60 DEG C are warming up under gas shield, 2~3h of insulation reaction obtains the epoxidized soybean oil of open loop；Again by higher alcohols sulfo group amber
After amber acid esters, PPG and the mixing of the epoxidized soybean oil of open loop, 75~85 DEG C are warming up to, 2~3h of insulation reaction is cooled to
Not higher than 60 DEG C, the first chain extender, the second chain extender and organic bismuth catalyst and organic solvent are added, it is anti-at 75~85 DEG C
3~4h is answered, is emulsified after cooling, neutralization, ethylenediamine dilution is added and reacts 10~15min, epoxidized soybean oil is made and is modified
Polyurethane resin.
7. the preparation method of leather surface treatment agent as claimed in claim 4, it is characterised in that the Al2O3It is sol-gel modified useless
The preparation method of old leather micro mist, comprises the following steps：Leather Waste micro mist is mixed with deionized water stirring, with 10~15d/
Min speed instills Alumina gel, is warming up to and is not less than 60 DEG C, insulated and stirred reacts 1~2h, is dried and be made with spray dryer
Al2O3Sol-gel modified Leather Waste micro mist, it is standby, wherein, the Leather Waste micro mist, deionized water, the mass ratio of Alumina gel are
1:3:0.25。
8. the preparation method of leather surface treatment agent as claimed in claim 7, it is characterised in that solid in the Alumina gel
Mass fraction is 7~15%, 0.05~2nm of average length, 0.005~2nm of diameter, in threadiness.
9. the preparation method of leather surface treatment agent as claimed in claim 4, it is characterised in that at the first time ultrasonic wave
The condition of reason is：Frequency is that 10~60kHz, power are 100~500W；The condition of second of ultrasonication is：Frequency
It is 100~500W for 10~60kHz, power.
10. a kind of leather surface treatment agent, it is characterised in that be using at the leather surface as described in claim 3~9 is any
The preparation method for managing agent is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710346840.7A CN107057552A (en) | 2017-05-16 | 2017-05-16 | A kind of leather surface treatment agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710346840.7A CN107057552A (en) | 2017-05-16 | 2017-05-16 | A kind of leather surface treatment agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057552A true CN107057552A (en) | 2017-08-18 |
Family
ID=59609575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710346840.7A Pending CN107057552A (en) | 2017-05-16 | 2017-05-16 | A kind of leather surface treatment agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057552A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666122A (en) * | 2018-11-28 | 2019-04-23 | 耿佃勇 | Epoxy soybean oil modified urethanes leather finishing agent and preparation method thereof |
| CN111842082A (en) * | 2020-07-28 | 2020-10-30 | 漳浦致远皮革有限公司 | Production method of antifouling folding-resistant leather |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746236A (en) * | 2005-08-25 | 2006-03-15 | 复旦大学 | High-performance organic-inorganic resin coating material with hybrid acrylic ester and production thereof |
| CN101532067A (en) * | 2009-04-03 | 2009-09-16 | 陕西科技大学 | Preparation method for polyether type organic silicone-modified fat-liquoring agent for leather |
| CN102633975A (en) * | 2012-04-10 | 2012-08-15 | 嘉兴市罗星化工有限公司 | Epoxidized soybean oil based modified waterborne polyurethane gloss oil and preparation method thereof |
| CN104479532A (en) * | 2014-12-17 | 2015-04-01 | 广东菲安妮皮具股份有限公司 | Leather surface treating agent |
| CN105713175A (en) * | 2016-04-12 | 2016-06-29 | 昆山市张浦彩印厂 | Preparation method of ring-opening epoxidized soybean oil modified sulfonated waterborne polyurethane |
| CN106280960A (en) * | 2016-09-14 | 2017-01-04 | 嘉兴禾大科技化学有限公司 | The resistance to colour migration of aqueous moves black wax and throws leather surface treatment agent and preparation method thereof |
| CN106566353A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Aluminum sol modified antibacterial leather coating and preparation method thereof |
| CN106634504A (en) * | 2016-10-14 | 2017-05-10 | 四川达威科技股份有限公司 | Patching agent for corrected grain leather and preparation method of patching agent |
-
2017
- 2017-05-16 CN CN201710346840.7A patent/CN107057552A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746236A (en) * | 2005-08-25 | 2006-03-15 | 复旦大学 | High-performance organic-inorganic resin coating material with hybrid acrylic ester and production thereof |
| CN101532067A (en) * | 2009-04-03 | 2009-09-16 | 陕西科技大学 | Preparation method for polyether type organic silicone-modified fat-liquoring agent for leather |
| CN102633975A (en) * | 2012-04-10 | 2012-08-15 | 嘉兴市罗星化工有限公司 | Epoxidized soybean oil based modified waterborne polyurethane gloss oil and preparation method thereof |
| CN104479532A (en) * | 2014-12-17 | 2015-04-01 | 广东菲安妮皮具股份有限公司 | Leather surface treating agent |
| CN105713175A (en) * | 2016-04-12 | 2016-06-29 | 昆山市张浦彩印厂 | Preparation method of ring-opening epoxidized soybean oil modified sulfonated waterborne polyurethane |
| CN106280960A (en) * | 2016-09-14 | 2017-01-04 | 嘉兴禾大科技化学有限公司 | The resistance to colour migration of aqueous moves black wax and throws leather surface treatment agent and preparation method thereof |
| CN106634504A (en) * | 2016-10-14 | 2017-05-10 | 四川达威科技股份有限公司 | Patching agent for corrected grain leather and preparation method of patching agent |
| CN106566353A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Aluminum sol modified antibacterial leather coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 饶舟等: "环氧大豆油改性水性聚氨酯的制备及性能表征", 《化工新型材料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666122A (en) * | 2018-11-28 | 2019-04-23 | 耿佃勇 | Epoxy soybean oil modified urethanes leather finishing agent and preparation method thereof |
| CN111842082A (en) * | 2020-07-28 | 2020-10-30 | 漳浦致远皮革有限公司 | Production method of antifouling folding-resistant leather |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108912654B (en) | A kind of PPU glue and the production technology that dipped gloves are prepared using the PPU glue | |
| CN106220817B (en) | A kind of no-solvent type interior leather for automobiles middle layer polyurethane resin and preparation method thereof | |
| CN106543406B (en) | Aqueous polyurethane dispersion slurry and method for preparing wet-process bass by using same | |
| CN106046287B (en) | A kind of preparation method of graphene modified aqueous polyurethane | |
| CN102127200B (en) | Preparation method of high-hardness organic silicon hybridization water-soluble polyurethane dispersoid | |
| CN101435159B (en) | Cation type aqueous full fluorine polyurethane textile finishing agent and preparing method thereof | |
| CN107057552A (en) | A kind of leather surface treatment agent and preparation method thereof | |
| CN101613451B (en) | High-content aqueous polyurethane latex and preparation method thereof | |
| CN101284937B (en) | Processing agent for wet-method chemical leather | |
| CN101445697B (en) | Hyper branched polyurethane leather coating agent and preparation method thereof | |
| CN104448206B (en) | A kind of environment-friendly type strippable water-soluble polyurethane resin and its preparation method and application | |
| CN109232851A (en) | Water-based aliphaic polyurethane dispersion and the aqueous dry-pasting glue of use for synthetic leather including it | |
| CN103146181B (en) | Preparation method of high-solid content wide-temperature range damping polyurethane aqueous dispersion containing nanofiller | |
| CN101985541A (en) | Polyurethane coating and preparation method thereof | |
| CN108715629A (en) | The special urethane raw of makeup sponge for liquid foundation | |
| CN103468124A (en) | Waterproof and root-resistant polyurethane coating for planting roof | |
| CN107419542A (en) | A kind of production method of non-solvent foamed type polyurethane synthetic leather | |
| CN102942673A (en) | Composition for preparing sponge powder puff and preparation method of composition | |
| CN109096466A (en) | A kind of preparation method of biology base water polyurethane bass | |
| CN109957089A (en) | A kind of high attachment aqueous polyurethane mirror surface resin and its preparation method and application | |
| CN107794777A (en) | A kind of preparation method of ventilative moisture absorption PU leather | |
| CN110157322A (en) | High durable UV water paint and preparation method thereof | |
| CN111892693A (en) | Antibacterial and antiviral cationic waterborne polyurethane resin and preparation method thereof | |
| CN109627409A (en) | A kind of aqueous polyurethane, dumb light aqueous polyurethane and preparation method | |
| CN108727965A (en) | A kind of preparation method of electromagnetic masking aqueous polyurethane leather |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xiong Shaowen Inventor after: He Ruifang Inventor after: Deng Xiaolu Inventor after: Chen Shiheng Inventor after: Zheng Jianming Inventor after: Liu Hongan Inventor before: Liu Hongan Inventor before: He Ruifang Inventor before: Chen Shiheng Inventor before: Deng Xiaolu Inventor before: Zheng Jianming |
|
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 510000 Building A, No. 19 Guannan Yong Industrial Road, Shiji Town, Panyu District, Guangzhou City, Guangdong Province Applicant after: Guangdong Meiji Fashion Leather Co., Ltd. Address before: 510000 Building A, No. 19 Guannan Yong Industrial Road, Shiji Town, Panyu District, Guangzhou City, Guangdong Province Applicant before: GUANGZHOU MINGZHI LEATHER PRODUCTS CO., LTD. |
|
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170818 |