CN107057453A - A kind of light extinction composition of replacement flatting silica and its dumb light ink of preparation - Google Patents
A kind of light extinction composition of replacement flatting silica and its dumb light ink of preparation Download PDFInfo
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- CN107057453A CN107057453A CN201710073291.0A CN201710073291A CN107057453A CN 107057453 A CN107057453 A CN 107057453A CN 201710073291 A CN201710073291 A CN 201710073291A CN 107057453 A CN107057453 A CN 107057453A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
A kind of light extinction composition of replacement flatting silica, it is characterised in that the composition is made up of the raw material of following percentage:Barium sulfate 20~50wt% of powder, talcum powder 20~50wt% of powder, 20~50wt% of silicon powder powder.The method that the present invention has abandoned conventional traditional single use flatting silica to reduce gloss, the effect of reduction gloss is reached using addition talcum powder, silicon powder, barium sulfate;These three raw materials are the powder of common environment-friendly type, to human body and environment-friendly;The dumb light ink that the present invention is provided is that one kind brings convenience to enterprise, reduces entreprise cost, while but also with required matte effect, environment-friendly type ink, its mute degree can reach less than 5.
Description
Technical field
The present invention relates to ink preparing technical field, the light extinction composition of flatting silica can be replaced more particularly, to a kind of,
And the dumb light ink that the light extinction composition is prepared.
Background technology
Need to add flatting silica when preparing matt ink.The delustring principle of flatting silica is primarily due to flatting silica particle diameter itself
Small, without being ground, flatting silica reaches roughening in ink pellet surface after ink solidification, so as to reduce gloss, but bring
Many counter productives:1st, three-roller grinding can not being carried out using the ink of flatting silica, can not be carried out once gone wrong
Do over again, such as doing over again can cause that ink thixotropy is very big, and extinction effect drastically declines, serious causes ink directly to be scrapped, and gives
Enterprise brings very burden.2nd, due to that can not continue after grinding, ink solidification after addition flatting silica, ink pellet surface is very coarse, no
Scratch-resistant.3rd, after addition flatting silica, ink can not carry out for a long time, it is high-revolving scattered, so as to cause flatting silica to fill very much
Point be dispersed in ink, so as to cause the inconsistent of gloss between batch.4th, after addition flatting silica such as needs ground at the ink
Addition, adds production process, while extending the cycle of Printing ink producing.
The content of the invention
In view of the above-mentioned problems existing in the prior art, the applicant provide a kind of replacement flatting silica light extinction composition and
Its dumb light ink prepared.The method that the present invention has abandoned conventional traditional single use flatting silica to reduce gloss, using adding
Plus talcum powder, silicon powder, barium sulfate reduce the effect of gloss to reach;These three raw materials are the powder of common environment-friendly type,
To human body and environment-friendly;The dumb light ink that the present invention is provided is that one kind brings convenience to enterprise, reduces entreprise cost, while again
Possesses required matte effect, environment-friendly type ink, its mute degree can reach less than 5.
Technical scheme is as follows:
A kind of light extinction composition of replacement flatting silica, the composition is made up of the raw material of following percentage:
Barium sulfate 20~50wt% of powder, talcum powder 20~50wt% of powder, 20~50wt% of silicon powder powder;
Wherein, barium sulfate powder:Average grain diameter is 0.3~0.7 μm, and oil absorption is 19~25g/100g, and specific surface area is 6
~8m2/ g, proportion is 4.3~4.7g/m3;
Talcum powder:Average grain diameter is 3~8 μm, and oil absorption is 40~50g/100g, and proportion is 2.0~3.0g/m3;
Silicon powder powder:Average grain diameter is 2~6 μm, and oil absorption is 30~40g/100g, and proportion is 2.5~3.0g/m3。
The content of barium sulfate is 97~98.5wt% in the barium sulfate powder.
The raw material of the light extinction composition is surface-treated before ink is prepared, and is concretely comprised the following steps:
(1) three kinds of material powders are put into the container equipped with ethanol solution respectively and disperse 2~5 points with ultrasonic dispersing machine
Clock, is then filtered;
(2) powder after filtering is placed again into the container equipped with ethanol solution with ultrasonic dispersing machine scattered 2 respectively
~5 minutes, then filter;
(3) powder after filtering is respectively put into the ultrasonic dispersing machine scattered 5~10 in the container equipped with distilled water
Minute, then filter;
(4) surface modifier is added to and is placed with distilled water:Ethanol mass ratio is (6~10):Three appearances of 1 mixed solution
Scattered 6~10 minutes with ultrasonic dispersing machine in device, then the powder filtered is separately added into three mixed solutions by filtering
It is scattered 10~20 minutes with ultrasonic dispersing machine, filtering;
(5) powder after filtering is respectively put into the container of distilled water and disperseed 5~10 minutes with ultrasonic dispersing machine,
Then filter;
(6) powder after filtering is dispersed in clean container respectively again, used after then being dried at 50~80 DEG C
Sealing container is stored;
The surface modifier be KS-66, KSZ-66, BYK-110, BYK-354, hamming this SD-1, WELLMIX-1750,
One or more in WELLMIX-7900;Its consumption independently for three kinds of material powders each weight 0.1~1%.
A kind of dumb light ink without flatting silica, the dumb light ink is by component A and B component when in use with 2~5:1 matter
Amount ratio is mixed:
The Material Percentage of the component A is:
Resin carrier A:30~55wt%;Light trigger:1~10wt%;Pigment:1~5wt%;Solvent orange 2 A:4~
10wt%;Thixotropic agent:0.5~1wt%;Light extinction composition A:20~50wt%;
The Material Percentage of the B component is:
Resin carrier B:30~70wt%;Unsaturated monomer:1~12wt%;Solvent B:4~10wt%;Light extinction composition
B:15~50wt%.
The preparation method of the component A and B component is:By raw material on high speed dispersor with 2000~5000r/min
Rotating speed stir, then to being ground to below 8 μm of fineness on three-roll grinder.
The resin carrier A and resin carrier B are independently selected from Jiangsu Kuangshun Photosensitivity New-Material Stock Co., Ltd.
E170D, E170A, E170, NE170C, Q170, GQ170 in one or more.
The light trigger is benzoin, benzoin ethers, α, α '-dimethyl benzil ketals, α, α-diethoxybenzene
Ethyl ketone and its derivative species, 2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxy cyclohexyl phenylketones, 2- hydroxy-2-methyls -1-
To ethoxy ether phenylacetone, 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholine -1- acetone, 2- phenyl benzyl -2- dimethyl
Amine -1- (4- morpholine benzyls phenyl) butanone, 2,4,6- trimethylbenzoyl ethoxyl phenenyls phosphine oxide, 2,4,6- trimethylbenzene first
Acyl group diphenyl phosphine oxide, phenyl double (2,4,6- trimethylbenzoyls) phosphine oxide, 4- are to toluene sulfydryl benzophenone sulfur-bearing
Double (dimethylaminos) two of photoinitiator, benzophenone, 2,4,6- tri-methyl benzophenones, 4- methyl benzophenones, 4,4'-
Double (lignocaine) benzophenone of Benzophenone, 4,4'-, 4,4'- double (methyl, ethylamino) benzophenone, isopropyl thioxanthone anthracenes
The chloro- 4- propoxyl group thioxanthone of ketone, 2- chlorothiaxanthenones, 1-, 2,4- diethyl thioxanthones and its derivative, 2- EAQs
And its one or more in derivative.
The pigment is the one or more in red, yellow, blue, black, green flour.
Solvent orange 2 A and the solvent B is independently selected from ethylene glycol ether acetate, 2-Butoxyethyl acetate, diethyl
Glycol ether acetate, diethylene glycol dimethyl ether acetate, propylene glycol methyl ether acetate, dipropylene glycol methyl ether acetate, propane diols
One or more in monomethyl ether acetate, propandiol butyl ether acetate, dibasic acid ester mixture.
The thixotropic agent is the one or more in N-20, H-20, DM-20S, HB-615.
The unsaturated monomer is from styrene, vinylacetate, NVP, butyl acrylate, propylene
The different monooctyl ester of acid, isodecyl acrylate, lauryl acrylate, hydroxyethyl methacrylate, hydroxy propyl methacrylate, metering system
Acid glycidyl ester, isobornyl methacrylate, Tetrahydrofurfuryl Methacrylate, acrylate, diethyl
Glycols diacrylate, triethylene glycol class diacrylate, polyethyleneglycol diacrylate, DPG class diacrylate
Ester, tripropylene glycol class diacrylate, 1,4 butanediol diacrylate, the hexylene glycol class diacrylates of 1,6- bis-, new penta 2
Alcohol diacrylate, phthalic acid glycol diacrylate, trimethylolpropane trimethacrylate, the propylene of pentaerythrite three
Acid esters, tetramethylol methane tetraacrylate, two contracting trimethylolpropane tetra-acrylates, Dipentaerythritol Pentaacrylate, two seasons
One or more in the acrylate of penta tetrol six.
The barium sulfate powder of different proportion collocation, talcum powder powder may be selected in the light extinction composition A and light extinction composition B
With silicon powder powder.
The present invention is beneficial to be had technical effect that:
The present invention inherently improves the deficiency of use flatting silica without dumb light ink prepared by flatting silica completely
Place, the ink that this method makes:1st, finished product is made after can directly grinding, ink, which goes wrong, to be done over again, without report
It is useless, reduce entreprise cost.2nd, surface will not be coarse after the ink solidification, and scratch-resistant is very capable.3rd, the ink can carry out height
Speed is scattered, and stability is good between producing each batch.4th, process need not be increased by producing the ink, while the production cycle is reduced, so that
Reduce production cost.
A kind of photoextinction principle of method that dumb light ink is prepared without flatting silica described in this patent is to be used
Talcum powder be stratiform crystalline structure, itself possess certain photoextinction, after being surface-treated to it, its delustring effect
Fruit more protrudes, and is used in mixed way with silicon powder after treatment, barium sulfate, better.Slided by different proportion mixing addition
Stone flour, silicon powder, barium sulfate can improve hardness, insulating properties, heat resistance, resistance to acids and bases of ink etc., while can make ink
Thixotropy, levelability more preferably, the operation of convenient use side.
Embodiment
With reference to embodiment, the present invention is specifically described.
Embodiment 1:The preparation of light extinction composition 1
A kind of light extinction composition of replacement flatting silica, the composition is made up of the raw material of following percentage:
Barium sulfate powder 20wt%, talcum powder powder 50wt%, silicon powder powder 30wt%;
Wherein, barium sulfate powder:Average grain diameter is 0.7 μm, and oil absorption is 25g/100g, and specific surface area is 8m2/ g, proportion
For 4.7g/m3;The content of barium sulfate is 98.5wt% in barium sulfate powder;
Talcum powder:Average grain diameter is 3 μm, and oil absorption is 40g/100g, and proportion is 2.0g/m3;
Silicon powder powder:Average grain diameter is 4 μm, and oil absorption is 35g/100g, and proportion is 2.8g/m3。
The preparation method of the light extinction composition is:
(1) three kinds of material powders are put into the container equipped with ethanol solution respectively and disperseed 2 minutes with ultrasonic dispersing machine,
Then filter;
(2) powder after filtering is placed again into the container equipped with ethanol solution with ultrasonic dispersing machine scattered 5 respectively
Minute, then filter;
(3) ultrasonic dispersing machine being respectively put into the powder after filtering in the container equipped with distilled water is scattered 5 minutes,
Then filter;
(4) by surface modifier KS-66 (consumption be respectively three kinds of material powders each weight 0.5%), be added to and be placed with
Distilled water:Ethanol mass ratio is 10:It is scattered 10 minutes with ultrasonic dispersing machine in three containers of 1 mixed solution, filtering, so
The powder filtered is separately added into three mixed solutions to, filtering scattered 10 minutes with ultrasonic dispersing machine afterwards;
(5) powder after filtering is respectively put into the container of distilled water with ultrasonic dispersing machine scattered 10 minutes, so
After filter;
(6) powder after filtering is dispersed in clean container respectively again, with sealing after then being dried at 50 DEG C
Containers store;Three kinds of resulting powder are named barium sulfate powder F103, talcum powder F002, silicon powder powder respectively
S190。
Embodiment 2:The preparation of light extinction composition 2
A kind of light extinction composition of replacement flatting silica, the composition is made up of the raw material of following percentage:
Barium sulfate powder 50wt%, talcum powder powder 20wt%, silicon powder powder 30wt%;
Wherein, barium sulfate powder:Average grain diameter is 0.3 μm, and oil absorption is 19g/100g, and specific surface area is 6m2/ g, proportion
For 4.3g/m3;The content of barium sulfate is 97wt% in barium sulfate powder;
Talcum powder:Average grain diameter is 8 μm, and oil absorption is 50g/100g, and proportion is 3.0g/m3;
Silicon powder powder:Average grain diameter is 5 μm, and oil absorption is 36g/100g, and proportion is 3.0g/m3。
The preparation method of the light extinction composition is:
(1) three kinds of material powders are put into the container equipped with ethanol solution respectively and disperseed 5 minutes with ultrasonic dispersing machine,
Then filter;
(2) powder after filtering is placed again into the container equipped with ethanol solution with ultrasonic dispersing machine scattered 2 respectively
Minute, then filter;
(3) ultrasonic dispersing machine being respectively put into the powder after filtering in the container equipped with distilled water is scattered 10 points
Clock, is then filtered;
(4) by surface modifier BYK-110 (consumption be respectively three kinds of material powders each weight 1%) be added to and be placed with steaming
Distilled water:Ethanol mass ratio is 6:Scattered 6 minutes with ultrasonic dispersing machine in three containers of 1 mixed solution, then filtering will
The powder filtered is separately added into three mixed solutions, filtering scattered 20 minutes with ultrasonic dispersing machine;
(5) powder after filtering is respectively put into the container of distilled water with ultrasonic dispersing machine scattered 5 minutes, then
Filtering;
(6) powder after filtering is dispersed in clean container respectively again, with sealing after then being dried at 80 DEG C
Containers store;Three kinds of resulting powder are named barium sulfate powder F103, talcum powder F002, silicon powder powder respectively
S190。
Embodiment 3:The preparation of light extinction composition 3
A kind of light extinction composition of replacement flatting silica, the composition is made up of the raw material of following percentage:
Barium sulfate powder 20wt%, talcum powder powder 30wt%, silicon powder powder 50wt%;
Wherein, barium sulfate powder:Average grain diameter is 0.5 μm, and oil absorption is 22g/100g, and specific surface area is 7m2/ g, proportion
For 4.5g/m3;The content of barium sulfate is 98wt% in barium sulfate powder;
Talcum powder:Average grain diameter is 7 μm, and oil absorption is 45g/100g, and proportion is 2.5g/m3;
Silicon powder powder:Average grain diameter is 2 μm, and oil absorption is 30g/100g, and proportion is 2.5g/m3。
The preparation method of the light extinction composition is:
(1) three kinds of material powders are put into the container equipped with ethanol solution respectively and disperseed 3 minutes with ultrasonic dispersing machine,
Then filter;
(2) powder after filtering is placed again into the container equipped with ethanol solution with ultrasonic dispersing machine scattered 4 respectively
Minute, then filter;
(3) ultrasonic dispersing machine being respectively put into the powder after filtering in the container equipped with distilled water is scattered 8 minutes,
Then filter;
(4) by surface modifier WELLMIX-1750 (consumption be respectively three kinds of material powders each weight 0.1%) add
To being placed with distilled water:Ethanol mass ratio is 8:It is scattered 8 minutes with ultrasonic dispersing machine in three containers of 1 mixed solution, mistake
The powder filtered, is then separately added into three mixed solutions, filtering scattered 15 minutes with ultrasonic dispersing machine by filter;
(5) powder after filtering is respectively put into the container of distilled water with ultrasonic dispersing machine scattered 7 minutes, then
Filtering;
(6) powder after filtering is dispersed in clean container respectively again, with sealing after then being dried at 65 DEG C
Containers store;Three kinds of resulting powder are named barium sulfate powder F103, talcum powder F002, silicon powder powder respectively
S190。
Embodiment 4:The preparation of dumb light ink 1
Dumb light ink is mixed when in use by component A and B component, and each raw material selection of embodiment 4 is as shown in table 1.
The preparation method of component A is:Raw material is stirred on high speed dispersor with 2000r/min rotating speed,
Then to being ground to below 8 μm of fineness on three-roll grinder.
B component:Raw material is stirred on high speed dispersor with 5000r/min rotating speed, then ground to three rollers
It is ground on grinding machine below 8 μm of fineness.
(the unit of table 1:g)
Embodiment 5:The preparation of dumb light ink 2
Dumb light ink is mixed when in use by component A and B component, and each raw material selection of embodiment 5 is as shown in table 2.
The preparation method of component A is:Raw material is stirred on high speed dispersor with 5000r/min rotating speed,
Then to being ground to below 8 μm of fineness on three-roll grinder.
B component:Raw material is stirred on high speed dispersor with 5000r/min rotating speed, then ground to three rollers
It is ground on grinding machine below 8 μm of fineness.
(the unit of table 2:g)
Embodiment 6:The preparation of dumb light ink 3
Dumb light ink is mixed when in use by component A and B component, and each raw material selection of embodiment 6 is as shown in table 3.
The preparation method of component A is:Raw material is stirred on high speed dispersor with 3000r/min rotating speed,
Then to being ground to below 8 μm of fineness on three-roll grinder.
B component:Raw material is stirred on high speed dispersor with 2500r/min rotating speed, then ground to three rollers
It is ground on grinding machine below 8 μm of fineness.
(the unit of table 3:g)
Test case 1:
Selected according to the raw material of embodiment 6, prepare comparative example 1 and comparative example 2, the consumption of each raw material also with the phase of embodiment 6
Together, simply the preprocessing method of raw materials and consumption of light extinction composition are different, 1 and 2 raw material not to light extinction composition of comparative example
It is surface-treated.As shown in table 4.
(the unit of table 4:g)
The anti-solder ink that embodiment 6 and comparative example 1,2 are prepared, will be above-mentioned by 120mesh silk-screen printing techniques
Anti-solder ink is printed to the pre-processed printed wiring board with through hole, and the welding resistance for forming 25~30 μ m thicks is applied
Layer;It is placed in after 75 DEG C of oven dryings, (energy 1000mJ/cm is exposed using 8KW (will sage UVE-M720) ultraviolet exposure machine2), profit
With 0.8~1.2% sodium carbonate developing liquid developing (pressure 1.5kg/cm2, time 70sec), most bake 60min through 150 DEG C of high temperature afterwards.
Carry out gloss, adhesive force, resistance to tin-welding, acidproof/alkalescence test respectively to the solidify coating finally given, test result is shown in Table 5
It is shown.
Table 5
Project | Comparative example 1 | Comparative example 2 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Testing standard |
Gloss | 98 | 30 | 60 | 15 | 4 | —— |
Soldering resistance | OK | OK | OK | OK | OK | —— |
Hardness | 6H | 6H | 6H | 6H | 6H | GB6379-86 |
Adhesive force | Nothing comes off | Nothing comes off | Nothing comes off | Nothing comes off | Nothing comes off | GB/T9286-1998 |
Acid and alkali-resistance | OK | OK | OK | OK | OK | —— |
Method of testing:
Gloss:Pool degree instrument is closed using German BYK, model AG-4446 reads 60 ° of gloss datas.
Soldering resistance:By comparative example 1 and the gained solidification figure layer coating colophony type scaling powder of embodiment 4, it is set to be immersed into 288
DEG C slicker solder stove in 30s.Spent glycol butyl ether cleans surface, and 3M adhesive tapes (model 600) tearing three times represents resistance to if nothing falls oil
Hot OK, otherwise NG.
Acid and alkali-resistance:Comparative example 1 and the gained solidification of embodiment 4 figure layer are immersed into 10vol%H2SO4And in 10wt%NaOH
30min is soaked, clear water is cleaned up and dried.3M adhesive tapes (model 600) tearing three times, as without expression acid and alkali-resistance test if falling oil
OK, otherwise NG.
To sum up:It is a kind of environment-friendlyink ink that one kind described in this patent prepares dumb light ink without flatting silica, and it is every
Performance can meet the requirement of client, and its production process is simple, convenient, to Reducing Cost in Enterprises.
Described above is only the preferred embodiment of the present invention, and the invention is not restricted to above example.It is appreciated that ability
The oher improvements and changes that field technique personnel directly export or associated without departing from the spirit and concept in the present invention,
It is considered as being included within protection scope of the present invention.
Claims (13)
1. a kind of light extinction composition of replacement flatting silica, it is characterised in that the composition is made up of the raw material of following percentage:
Barium sulfate 20~50wt% of powder, talcum powder 20~50wt% of powder, 20~50wt% of silicon powder powder;
Wherein, barium sulfate powder:Average grain diameter be 0.3~0.7 μm, oil absorption be 19~25g/100g, specific surface area be 6~
8m2/ g, proportion is 4.3~4.7g/m3;
Talcum powder:Average grain diameter is 3~8 μm, and oil absorption is 40~50g/100g, and proportion is 2.0~3.0g/m3;
Silicon powder powder:Average grain diameter is 2~6 μm, and oil absorption is 30~40g/100g, and proportion is 2.5~3.0g/m3。
2. dumb light ink according to claim 1, it is characterised in that the content of barium sulfate is 97 in the barium sulfate powder
~98.5wt%.
3. dumb light ink according to claim 1, it is characterised in that the raw material of the light extinction composition is before ink is prepared
It is surface-treated, is concretely comprised the following steps:
(1) three kinds of material powders are put into the container equipped with ethanol solution respectively and disperseed 2~5 minutes with ultrasonic dispersing machine,
Then filter;
(2) powder after filtering is placed again into the container equipped with ethanol solution respectively scattered 2~5 points with ultrasonic dispersing machine
Clock, is then filtered;
(3) ultrasonic dispersing machine being respectively put into the powder after filtering in the container equipped with distilled water is scattered 5~10 minutes,
Then filter;
(4) surface modifier is added to and is placed with distilled water:Ethanol mass ratio is (6~10):In three containers of 1 mixed solution
Scattered 6~10 minutes with ultrasonic dispersing machine, then the powder filtered is separately added into three mixed solutions with super by filtering
Sound wave dispersion machine is scattered 10~20 minutes, filtering;
(5) powder after filtering is respectively put into the container of distilled water with ultrasonic dispersing machine scattered 5~10 minutes, then
Filtering;
(6) powder after filtering is dispersed in clean container respectively again, with sealing after then being dried at 50~80 DEG C
Containers store.
4. dumb light ink according to claim 3, it is characterised in that the surface modifier is KS-66, KSZ-66, BYK-
110th, the one or more in this SD-1, WELLMIX-1750, WELLMIX-7900 of BYK-354, hamming;Its consumption is independently
For three kinds of material powders each weight 0.1~1%.
5. the dumb light ink without flatting silica described in a kind of claim 1, it is characterised in that the dumb light ink is by component A and B
Component is when in use with 2~5:1 mass ratio is mixed:
The Material Percentage of the component A is:
Resin carrier A:30~55wt%;Light trigger:1~10wt%;Pigment:1~5wt%;Solvent orange 2 A:4~10wt%;Touch
Become agent:0.5~1wt%;Light extinction composition A:20~50wt%;
The Material Percentage of the B component is:
Resin carrier B:30~70wt%;Unsaturated monomer:1~12wt%;Solvent B:4~10wt%;Light extinction composition B:15
~50wt%.
6. dumb light ink according to claim 5, it is characterised in that the preparation method of the component A and B component is:Will
Raw material is stirred on high speed dispersor with 2000~5000r/min rotating speed, then to grinding on three-roll grinder
To 8 μm of fineness.
7. dumb light ink according to claim 5, it is characterised in that the resin carrier A and resin carrier B are independently
E170D, E170A, E170, NE170C, Q170, GQ170 selected from Jiangsu Kuangshun Photosensitivity New-Material Stock Co., Ltd. in
It is one or more.
8. dumb light ink according to claim 5, it is characterised in that the light trigger be benzoin, benzoin ethers,
α, α '-dimethyl benzil ketals, α, α-diethoxy acetophenone and its derivative species, 2- hydroxy-2-methyl -1- phenyl third
Ketone, 1- hydroxy cyclohexyl phenylketones, 2- hydroxy-2-methyl -1- are to ethoxy ether phenylacetone, 2- methyl isophthalic acids-(4- methyl mercaptos
Phenyl) -2- morpholine -1- acetone, 2- phenyl benzyl -2- dimethyl amines -1- (4- morpholine benzyls phenyl) butanone, 2,4,6- trimethylbenzene first
Double (the 2,4,6- trimethylbenzene first of acyl group ethoxyl phenenyl phosphine oxide, 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide, phenyl
Acyl group) phosphine oxide, 4- to toluene sulfydryl benzophenone sulfur-bearing photoinitiator, benzophenone, 2,4,6- tri-methyl benzophenones,
Double (dimethylamino) benzophenone of 4- methyl benzophenones, 4,4'-, double (lignocaine) benzophenone of 4,4'-, 4,4'- are double
(methyl, ethylamino) benzophenone, isopropyl thioxanthone, 2- chlorothiaxanthenones, the chloro- 4- propoxyl group thioxanthones of 1-, 2,
One or more in 4- diethyl thioxanthones and its derivative, 2- EAQs and its derivative.
9. dumb light ink according to claim 5, it is characterised in that the pigment is in red, yellow, blue, black, green flour
It is one or more.
10. dumb light ink according to claim 5, it is characterised in that solvent orange 2 A and the solvent B is independently selected from second
Glycol ether acetate, 2-Butoxyethyl acetate, diethylene glycol ether acetate, diethylene glycol dimethyl ether acetate, propane diols
Methyl ether acetate, dipropylene glycol methyl ether acetate, propylene glycol monomethyl ether acetate, propandiol butyl ether acetate, dibasic acid ester mixing
One or more in thing.
11. dumb light ink according to claim 5, it is characterised in that the thixotropic agent is N-20, H-20, DM-20S, HB-
One or more in 615.
12. dumb light ink according to claim 5, it is characterised in that the unsaturated monomer is from styrene, acetic acid second
Alkene ester, NVP, butyl acrylate, Isooctyl acrylate monomer, isodecyl acrylate, lauryl acrylate, methyl
Hydroxy-ethyl acrylate, hydroxy propyl methacrylate, GMA, isobornyl methacrylate, methyl-prop
Olefin(e) acid tetrahydrofuran methyl esters, acrylate, diethylene glycol class diacrylate, triethylene glycol class diacrylate,
Polyethyleneglycol diacrylate, DPG class diacrylate, tripropylene glycol class diacrylate, the propylene of BDO two
Acid esters, the hexylene glycol class diacrylates of 1,6- bis-, neopentylglycol diacrylate, phthalic acid glycol diacrylate,
Trimethylolpropane trimethacrylate, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, two contracting trimethylolpropanes
One or more in tetraacrylate, Dipentaerythritol Pentaacrylate, dipentaerythritol acrylate.
13. dumb light ink according to claim 5, it is characterised in that the light extinction composition A and light extinction composition B are optional
Select barium sulfate powder, talcum powder powder and the silicon powder powder of different proportion collocation.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107722726A (en) * | 2017-11-30 | 2018-02-23 | 佛山市华力达材料科技有限公司 | A kind of dumb light finishing impression ink and preparation method thereof |
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CN107722726A (en) * | 2017-11-30 | 2018-02-23 | 佛山市华力达材料科技有限公司 | A kind of dumb light finishing impression ink and preparation method thereof |
CN112812625A (en) * | 2021-01-26 | 2021-05-18 | 长兴科瑞照明电器有限公司 | Coating for enabling glass bulb to have frosted effect and preparation method and application thereof |
Also Published As
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