CN107057097A - Active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof - Google Patents
Active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof Download PDFInfo
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- CN107057097A CN107057097A CN201710356400.XA CN201710356400A CN107057097A CN 107057097 A CN107057097 A CN 107057097A CN 201710356400 A CN201710356400 A CN 201710356400A CN 107057097 A CN107057097 A CN 107057097A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Abstract
The present invention relates to active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof, the raw material of the active transfer film of the artistic carrier green wood alcohols new type water coating and preparation method thereof includes polyvinyl alcohol, starch, plasticizer and surfactant, it is described that the figuratum specially treated film of print is placed on flattening activation in water, and the pattern on film is transferred in the presence of hydraulic pressure sprayed on priming paint or workpiece without primer spray, after film automatic dissolving, pattern will be printed on not advise in complicated stereo concave-convex face or circular arc shaped inside etc. in position, the techniques such as water coating transfer its preparation method processing cleaning, drying can all be used, then carrying out protection pattern and body surface in the even spray layer of transparent paint in its surface has good adhesive force, steady quality, good corrosion resistance, the clear effect of figure line is true to nature, the transfer film printing time is short, the degree of fixation of dyestuff is high, with the upgrading of technology new and innovative, available for multi-field industrialization production.
Description
Technical field
The invention belongs to Material Field of printing and dyeing, it is related to a kind of transfer film, more particularly to a kind of artistic carrier green wood alcohols is new
Type water coating activity transfer film and preparation method thereof.
Background technology
Water coating transfer printing process is will to print figuratum specially treated macromolecule membrane to be placed on flattening activation in water,
Pattern in the presence of hydraulic pressure on film, which is transferred in, have been sprayed on priming paint or workpiece without primer spray, will after film automatic dissolving
Figuratum workpiece cleaning, drying are printed, then a clear finish is sprayed again on its surface and is protected.The birth of the technique, is filled out
The blank of solid surface printed decoration in human history is mended.
Water coating transfer technique has lot of advantages, and such as multicolour pattern has good adhesive force with body surface, and film is equal
It is even, steady quality, good corrosion resistance；Figure line is clear with site, and stereovision is enriched, and aesthetic feeling is strong, and pattern effect is true to nature；Technique is simple
Fast, operability is good, and production efficiency is high, and cost is low.Either simple plane, or complicated stereo concave-convex face, circular arc
The irregular position such as shape inner side can all be handled with water coating transfer printing process.The pattern of water coating transfer film paper is wide in variety, commonly uses color
Sample just up to kind more than 1000, can according to the requirement of different clients make needed for pattern.The current technique plasthetics (ABS,
PP, PC, PU, PS, PVC, TPU, PE, TPR, EVA, nylon etc.), metal, glass, ceramics, carbon fibre, the material surface such as timber obtain
It is widely applied, and in automobile, motorcycle, electronics, LED, daily fine work, handicraft, room articles for use, hardware building materials, footwear material
It is promoted in terms of articles for use.
Reactive dye, also known as chemically-reactive dyes, are a class new dyes, are chemically reacted in dyeing with fiber.This
Containing the group that can be chemically reacted with fiber in class dye molecule, dyestuff and fiber-reactive, are formed therebetween during dyeing
Covalent bond, is integrally formed, and improves washable and fastness to rubbing.Reactive dye are complete with bright in colour, chromatogram simultaneously, using letter
Just, price is more honest and cleaner, strong adaptability, fastness are excellent and famous；In all kinds of dyestuffs that Cellulosic Fibres Worldwide is consumed, with tonnage
Meter, reactive dye account for 33%, in terms of the amount of money, and reactive dye account for 43%, no matter come from the tonnage number of consumption, or from consumption amount
See, reactive dye are occupied first of all kinds of cotton dyestuffs；Most important dye class in cotton dyestuff is developed into, as generation
The dye that boundary gives priority to and paid close attention to.
But group's color of water coating transfer technique is not general color properties high, and reactive dye can be very good to solve transfer
Color and luster problem, and water coating transfer be easily deformed, but the combination speed of reactive dye and printed thing soon, printing time
Shortening can reduce the expansion and contraction of transfer film, improve the quality of printing.But the active group on reactive dye, it is easy to water coating
Hydroxyl reaction on the primary raw material of transfer film, i.e. polyvinyl alcohol, and printing is substantially reduced, therefore solve to prepare one kind newly
Transfer film, the reaction that reactive dye and transfer film are greatly decreased is particularly significant.
The A of CN 105038054 disclose a kind of water transfer printing film, PVA resin of the water transfer printing film including 100 parts by weight,
The nonionic surfactant of the plasticizer of 20-40 parts by weight, the starch of 5-10 parts by weight and 5-15 parts by weight.Wherein described table
Face activating agent is a kind of polysubstituted tetrahydrofuran-compound.The morphotropism of this kind of water transfer printing film is low, is difficult excessively to stretch, still
Due to its raw material in addition to surfactant it is more conventional, active water coating transfer can not be used for.
The content of the invention
To solve technical problem present in prior art, the present invention provides a kind of artistic carrier green wood alcohols new type water and draped over one's shoulders
Active transfer film is covered, the transfer film printing time is short, the degree of fixation of dyestuff is high, efficiently solve reactive dye and transfer film
With reference to problem, and the raw material environmental protection of transfer film, preparation technology is simple, can be applied to multi-field industrialization production.
To reach above-mentioned technique effect, the present invention is using technical scheme once：
One of mesh of the present invention is to provide a kind of water coating active transfer film, and the raw material of the transfer film includes polyethylene
Alcohol, starch, plasticizer and surfactant, the surfactant are APG.
As currently preferred technical scheme, the APG includes APG081, APG1214, APG10 or APG06
In any one or at least two combination, combination typical case but non-limiting examples have：APG081 and APG1214 group
Close, APG1214 and APG10 combination, APG10 and APG06 combination, APG081 and APG06 combination or APG081,
APG1214 and APG10 combination etc., preferably APG1214.
Preferably, the mass parts of the surfactant be 5~20 parts, such as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11
Part, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts etc., it is not limited to cited numerical value,
Other unrequited numerical value are equally applicable in the number range, more preferably 10~15 parts, particularly preferably 12 parts.
Because the primary raw material of water coating transfer film is polyvinyl alcohol, and reactive dye contain active group, activity dye
Material is easily reacted when printing and dyeing onto transfer film with the hydroxyl on the polyvinyl alcohol of transfer film, and jail was combined with transfer film, is made
The decline of degree of fixation when will also result in active dye printing to substrate into the consumption of the extension of drying time, and active group.
Contain APG in the raw material for the water coating transfer film that the present invention is provided, one end of APG is glycosidic structure, containing many
Individual hydroxyl, can reduce its reactivity with the hydroxyl formation hydroxyl on polyvinyl alcohol, and the other end of APG is long alkane
Base, increases reaction steric hindrance, has further organized the reaction of reactive dye and polyvinyl alcohol, less coating transfer time, and
Add the degree of fixation after active dye printing.
The addition of APG is also critically important, when the addition of APG is less than 5 parts, because APG is uniform
After being distributed in transfer film, its intermolecular spacing is excessive, and steric hindrance reduces, when on active dye printing to transfer film, living
Property dyestuff due to fluid matasomatism, can be from being passed through between alkyl polyglycoside molecule, and contact and react with polyvinyl alcohol molecule.Work as alkane
When the addition of base glucosides is more than 20 parts, the hydrophobic effect on transfer film surface can be caused excessive, and make processed heavy transfer film
The time of dissolving increases, and extends drying time, and is unfavorable for holding of the reactive dye on transfer film, causes the change of pattern
Shape.
Preferably, the degree of polymerization of the polyvinyl alcohol be 2000~4000, such as 2000,2200,2500,2800,3000,
3200th, 3500,3800 or 4000 etc., it is not limited to other unrequited numerical value in cited numerical value, the number range
It is equally applicable.
As currently preferred technical scheme, the plasticizer includes diisooctyl phthalate, phthalic acid
Any one in di-n-octyl, dinonyl phthalate or didecyl phthalate or at least two combination, described group
Close typical case but non-limiting examples have：The combination of diisooctyl phthalate and di-n-octyl phthalate, O-phthalic
The combination of sour di-n-octyl and dinonyl phthalate, the combination of dinonyl phthalate and didecyl phthalate,
The combination of didecyl phthalate and diisooctyl phthalate or diisooctyl phthalate, phthalic acid two are just
Combination of monooctyl ester and dinonyl phthalate etc..
Preferably, the mass parts of the plasticizer be 10~20 parts, such as 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts,
16 parts, 17 parts, 18 parts, 19 parts or 20 parts etc., it is not limited to other are unrequited in cited numerical value, the number range
Numerical value is equally applicable.
As currently preferred technical scheme, the starch includes cornstarch, starch from sweet potato, wheaten starch or Ma Ling
In sweet potato starch any one or at least two combination, combination typical case but non-limiting examples have：Cornstarch and red
The combination of sweet potato starch, the combination of starch from sweet potato and wheaten starch, combination, cornstarch and the horse of wheaten starch and farina
The combination or cornstarch of bell sweet potato starch, the combination of starch from sweet potato and wheaten starch etc..
Preferably, the mass parts of the starch be 1~5 part, such as 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts or 5 parts etc., it is not limited to other unrequited numerical value are equally applicable in cited numerical value, the number range.
As currently preferred technical scheme, include according to the raw material of transfer film described in mass parts meter：
As currently preferred technical scheme, the raw material of the transfer film includes glycine betaine.
Preferably, the glycine betaine include dodecyldimethylammonium hydroxide inner salt, dodecyldimethylamine base glycine betaine or
Any one during any one in octodecyl betaine or at least two combination are described or at least two combination,
The combination is typical but non-limiting examples have：The group of dodecyldimethylammonium hydroxide inner salt and dodecyldimethylamine base glycine betaine
Combination, the octodecyl betaine and ten of conjunction, dodecyldimethylamine base glycine betaine and octodecyl betaine
The combination of dialkyl dimethyl glycine betaine or dodecyldimethylammonium hydroxide inner salt, dodecyldimethylamine base glycine betaine and octadecyl
Combination of dimethyl betaine etc., preferably dodecyldimethylamine base glycine betaine.
Preferably, the mass parts of the glycine betaine be 1~10 part, such as 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts,
9 parts or 10 parts etc., it is not limited to other unrequited numerical value are equally applicable in cited numerical value, the number range, enter
One step is preferably 3~8 parts, particularly preferably 5 parts.
Preferably, the mass ratio of the APG and the glycine betaine is (2~5):1, such as 2:1、2.5:1、3:1、
3.5:1、4:1、4.5:1 or 5:1 etc., it is not limited to other unrequited numerical value in cited numerical value, the number range
It is equally applicable, more preferably (2~4):1, particularly preferably 3:1.
Because the APG other end is long alkyl chain structure, while increase reaction steric hindrance, due to its polarity and work
Property dyestuff gap it is larger, conservation degree of the reactive dye on transfer film can be caused to decline, reactive dye bad student easily on transfer film
Capillary flow and the deformation for causing pattern, and the solid rate of dyestuff color decline.Therefore the present invention can also add sweet tea in transfer film
Dish alkali, because glycine betaine can include long alkyl chain, carboxyl and ammonium salt structure, alkyl sugar can be effectively improved by being doped in transfer film
The hydrophobicity on the transfer film surface that glycosides is brought, adds stability of the reactive dye on transfer film surface, adds reactive dye
The solid rate of color, while accelerating dissolving of the transfer film in water, reduce drying time, APG cooperates with work with glycine betaine
With serving reduction drying time, the purpose of the solid rate of increase color.
Ratio for APG and glycine betaine should be controlled, when the mass ratio of APG and glycine betaine is less than 2:
When 1, the hydrophily on transfer film surface can be made too strong, transfer film rapid can dissolve in water, make transfer process uncontrollable.And work as alkane
The mass ratio of base glucosides and glycine betaine is more than 5:When 1, glycine betaine can be coated in APG, substantially played and alkyl sugar
Acted on as glycoside, and the hydrophobicity on transfer film surface can not be reduced.
As currently preferred technical scheme, the raw material of the transfer film includes water.
Preferably, the parts by weight of the water be 5~15 parts, such as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts,
13 parts, 14 parts or 15 parts etc., it is not limited to other unrequited numerical value are equally fitted in cited numerical value, the number range
With.
The two of the object of the invention are to provide a kind of preparation method of above-mentioned transfer film, and the preparation method includes following step
Suddenly：
(1) polyvinyl alcohol is preheated, and mixed according to addition with starch, surfactant and plasticizer, starched
Material；
(2) slurry for obtaining step (1) casting film-forming in a heated condition, obtains transfer film.
As currently preferred technical scheme, the temperature of the polyvinyl alcohol preheating is 70~90 DEG C, such as 70 DEG C, 72
DEG C, 75 DEG C, 78 DEG C, 80 DEG C, 82 DEG C, 85 DEG C or 90 DEG C etc., it is not limited in cited numerical value, the number range other
Unrequited numerical value is equally applicable.
Preferably, step (1) mixing is carried out under agitation.
Preferably, the rotating speed of the stirring be 2000~12000rpm, such as 2000rpm, 3000rpm, 4000rpm,
5000rpm, 6000rpm, 7000rpm, 8000rpm, 9000rpm, 10000rpm, 11000rpm or 12000rpm etc., but not
It is only limitted to other unrequited numerical value in cited numerical value, the number range equally applicable.
Preferably, the time of the stirring is 2~8h, such as 2h, 3h, 4h, 5h, 6h, 7h or 8h, it is not limited to institute
Other unrequited numerical value are equally applicable in the numerical value enumerated, the number range.
As currently preferred technical scheme, the temperature of step (2) described heating is 60~80 DEG C, such as 60 DEG C, 62
DEG C, 65 DEG C, 68 DEG C, 70 DEG C, 72 DEG C, 75 DEG C, 78 DEG C or 80 DEG C etc., it is not limited to cited numerical value, the number range
Other interior unrequited numerical value are equally applicable.
Compared with prior art, the present invention at least has the advantages that：
(1) the active transfer film of a kind of artistic carrier green wood alcohols new type water coating that the present invention is provided, the transfer film print
The brush time is short, and printing time is no more than 60s, and the degree of fixation of dyestuff is high, and degree of fixation is up to 93.5%；
(2) a kind of active transfer film of artistic carrier green wood alcohols new type water coating that the present invention is provided, the transfer film has
Effect solves the problems, such as the combination of reactive dye and transfer film, and the raw material environmental protection of transfer film；
(3) a kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating that the present invention is provided, institute
Preparation method technique is stated simple, available for industrialized production.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in understanding the present invention, is not construed as the concrete restriction to the present invention.
Embodiment 1
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, methods described includes following step
Suddenly：
(1) the 100g degree of polymerization is preheated for 2000 polyvinyl alcohol at 70 DEG C, and with 1g cornstarch, 5g APG081
And 10g diisooctyl phthalates stir mixing 8h under 2000rpm rotating speeds, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming under the conditions of 60 DEG C, obtains transfer film.
Embodiment 2
A kind of preparation method methods described of the active transfer film of artistic carrier green wood alcohols new type water coating includes following step
Suddenly：
(1) the 100g degree of polymerization is preheated for 4000 polyvinyl alcohol at 90 DEG C, and with 5g starch from sweet potato, 20g
APG1214 and 20g di-n-octyl phthalates stir mixing 2h under 12000rpm rotating speeds, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming under the conditions of 80 DEG C, obtains transfer film.
Embodiment 3
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, methods described includes following step
Suddenly：
(1) the 100g degree of polymerization is preheated for 3000 polyvinyl alcohol at 80 DEG C, and with 3g farinas, 10g
APG10 and 12g dinonyl phthalates stir mixing 4h under 8000rpm rotating speeds, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming under the conditions of 70 DEG C, obtains transfer film.
Embodiment 4
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, methods described includes following step
Suddenly：
(1) the 100g degree of polymerization is preheated for 2500 polyvinyl alcohol at 65 DEG C, and with 2g wheaten starches, 18g APG06
And 18g didecyl phthalates stir mixing 5h under 6000rpm rotating speeds, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming under the conditions of 70 DEG C, obtains transfer film.
Embodiment 5
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, methods described includes following step
Suddenly：
(1) the 100g degree of polymerization is preheated for 3000 polyvinyl alcohol at 70 DEG C, and with 3g cornstarch, 12g
APG1214 and 15g diisooctyl phthalates stir mixing 3h under 10000rpm rotating speeds, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming under the conditions of 70 DEG C, obtains transfer film.
Embodiment 6
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is additionally added outside 1g dodecyldimethylammonium hydroxide inner salts and 5g water, and other conditions are same as Example 1.
Embodiment 7
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is additionally added outside 6g octodecyl betaines and 15g water, and other conditions are same as Example 5.
Embodiment 8
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is additionally added outside 5g dodecyldimethylamine base glycine betaines and 10g water, and other conditions are same as Example 5.
Embodiment 9
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is additionally added outside 1g dodecyldimethylamine base glycine betaines and 10g water, and other conditions are same as Example 5.
Embodiment 10
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is additionally added outside 10g dodecyldimethylamine base glycine betaines and 10g water, and other conditions are same as Example 5.
Embodiment 11
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) APG1214 addition is that other conditions are same as Example 5 outside 2g.
Embodiment 12
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) APG1214 addition is that other conditions are same as Example 5 outside 30g.
Comparative example 1
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is substituted outside APG1214 using dodecyl sodium sulfate, and other conditions are same as Example 5.
Comparative example 2
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is substituted outside APG1214 using neopelex, and other conditions are same as Example 5.
Embodiment 3
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is substituted outside APG1214 using cetyl trimethylammonium bromide, and other conditions are same as Example 5.
Embodiment 4
A kind of preparation method of the active transfer film of artistic carrier green wood alcohols new type water coating, the preparation method is except step
Suddenly (1) is added without outside APG1214, and other conditions are same as Example 5.
With the transfer film prepared by embodiment 1-12 and comparative example 1-4, Cibacron Huangs FN-2R is reactive dye, right
Wool fabric enters water-filling coating transfer, under drying time point is than being 30s, 60s, 120s, 180s and 300s, the fixation after printing and dyeing
Rate is tested, and test result difference is as shown in table 1.
Table 1
It can see according to table 1, color solid rates of the embodiment 1-5 when printing and dyeing 120s with 180s is identical, therefore embodiment 1-5
The drying time of the transfer film prepared is less than or equal to 120s, and the solid rate of color reaches 92%,.And turn prepared by embodiment 6-8
Die also added glycine betaine, and the solid rate of color is identical with 120s size in 60s, therefore embodiment 6-8 can complete print in 60s
Dye, and the solid rate of color reaches 93%.And the glycine betaine of embodiment 9 and the ratio of APG are too low, the glycine betaine of embodiment 10 with
The ratio of APG is too high, so the solid rate of the color of embodiment 9 and 10 will be less than embodiment 5, it is 92.2% and 91.5%.Implement
The addition of the APG of example 11 is very few and the APG addition of embodiment 12 is excessive, so the color of embodiment 9 and 10 is consolidated
Rate will be less than embodiment 5, be 90.1% and 91.2%.Comparative example 1-3 does not add APG, and is changed to dodecyl sulphur respectively
Sour sodium, neopelex and cetyl trimethylammonium bromide, the solid rate of color for the transfer film that comparative example 1-3 is prepared
Only 83.2%, 85.3% and 52.1%, and drying time is in 3-5min.Comparative example 4 does not add APG, and the solid rate of color is only
For 60.3%.
Applicant states that the present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (10)
1. a kind of active transfer film of artistic carrier green wood alcohols new type water coating, it is characterised in that the raw material bag of the transfer film
Polyvinyl alcohol, starch, plasticizer and surfactant are included, the surfactant is APG.
2. transfer film according to claim 1, it is characterised in that the APG include APG081, APG1214,
Any one in APG10 or APG06 or at least two combination, preferably APG1214；
Preferably, the mass parts of the surfactant are 5~20 parts, more preferably 10~15 parts, particularly preferably 12
Part；
Preferably, the degree of polymerization of the polyvinyl alcohol is 2000~4000.
3. transfer film according to claim 1 or 2, it is characterised in that it is different pungent that the plasticizer includes phthalic acid two
Any one in ester, di-n-octyl phthalate, dinonyl phthalate or didecyl phthalate or at least two
Combination；
Preferably, the mass parts of the plasticizer are 10~20 parts.
4. the transfer film according to claim any one of 1-3, it is characterised in that the starch includes cornstarch, sweet potato
In starch, wheaten starch or farina any one or at least two combination；
Preferably, the mass parts of the starch are 1~5 part.
5. the transfer film according to claim any one of 1-4, it is characterised in that according to the original of transfer film described in mass parts meter
Material includes：
6. the transfer film according to any one of Claims 1 to 5, it is characterised in that the raw material of the transfer film includes beet
Alkali；
Preferably, the glycine betaine includes dodecyldimethylammonium hydroxide inner salt, dodecyldimethylamine base glycine betaine or 18
Any one during any one in alkyl dimethyl betaine or at least two combination are described or at least two combination, preferably
For dodecyldimethylamine base glycine betaine；
Preferably, the mass parts of the glycine betaine are 1~10 part, particularly preferably more preferably 3~8 parts, 5 parts；
Preferably, the mass ratio of the APG and the glycine betaine is (2~5):1, more preferably (2~4):1, it is special
You Xuanwei 3:1.
7. the transfer film according to claim any one of 1-6, it is characterised in that the raw material of the transfer film includes water；
Preferably, the parts by weight of the water are 5~15 parts.
8. the preparation method of the transfer film described in a kind of any one of claim 1-7, it is characterised in that the preparation method includes
Following steps：
(1) polyvinyl alcohol is preheated, and mixed according to addition with starch, surfactant and plasticizer, obtain slurry；
(2) slurry for obtaining step (1) casting film-forming in a heated condition, obtains transfer film.
9. preparation method according to claim 8, it is characterised in that the temperature of the polyvinyl alcohol preheating is 70~90
℃；
Preferably, step (1) mixing is carried out under agitation；
Preferably, the rotating speed of the stirring is 200~1200rpm；
Preferably, the time of the stirring is 2~8h.
10. preparation method according to claim 8 or claim 9, it is characterised in that the temperature of step (2) described heating is 60~
80℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710356400.XA CN107057097A (en) | 2017-05-19 | 2017-05-19 | Active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710356400.XA CN107057097A (en) | 2017-05-19 | 2017-05-19 | Active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof |
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| CN107057097A true CN107057097A (en) | 2017-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710356400.XA Pending CN107057097A (en) | 2017-05-19 | 2017-05-19 | Active transfer film of a kind of artistic carrier green wood alcohols new type water coating and preparation method thereof |
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| CN (1) | CN107057097A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4231829A (en) * | 1978-05-16 | 1980-11-04 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Process of transfer printing |
| CN1871138A (en) * | 2003-10-22 | 2006-11-29 | 可乐丽股份有限公司 | Method of hydraulic transfer and hydraulic transfer base film |
-
2017
- 2017-05-19 CN CN201710356400.XA patent/CN107057097A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4231829A (en) * | 1978-05-16 | 1980-11-04 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Process of transfer printing |
| CN1871138A (en) * | 2003-10-22 | 2006-11-29 | 可乐丽股份有限公司 | Method of hydraulic transfer and hydraulic transfer base film |
Non-Patent Citations (1)
| Title |
|---|
| 董彦博 等: "淀粉对水转印用PVA膜的改性研究", 《应用化工》 * |
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Application publication date: 20170818 |