CN107056210A - A kind of enhanced Thistle board of energy storage, its preparation method and application - Google Patents
A kind of enhanced Thistle board of energy storage, its preparation method and application Download PDFInfo
- Publication number
- CN107056210A CN107056210A CN201710214702.3A CN201710214702A CN107056210A CN 107056210 A CN107056210 A CN 107056210A CN 201710214702 A CN201710214702 A CN 201710214702A CN 107056210 A CN107056210 A CN 107056210A
- Authority
- CN
- China
- Prior art keywords
- energy storage
- enhanced
- phase
- thistle board
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B13/08—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/02—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets
- E04F2290/023—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets for heating
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Ceramic Engineering (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Building Environments (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of enhanced Thistle board of energy storage, plaster matrix includes the following composition of percentage by weight：Building gypsum plaster 40 95%, porous sizing phase-change material 5 60%, water reducer 0.05 5%, modified starch 0.05 5%, fiber 0.5 10%, water 50 80%；Porous sizing phase-change material includes porous forming body and aliphatic acid phase variant.The preparation method of the plasterboard is also disclosed, including：Above-mentioned solid material is mixed according to weight than proportioning, stirred together；The water for adding 50 80% is quickly stirred, and gypsum slurry is made；Mask paper under being padded in grinding tool, pours into gypsum slurry, strikes off, mask paper on pad, flattens shaping.The enhanced Thistle board of energy storage of the present invention has the advantages that low thermal conductivity factor, suitable phase transition temperature, energy-saving.
Description
Technical field
The present invention relates to novel green building material technical field, particularly a kind of new stone acted on phase-change accumulation energy
Cream plate.
Background technology
Improved with China's economic development and living standards of the people, requirement of the people to Building Indoor Environment suitability degree is got over
Come higher, cause the pressure of air-conditioning and heating system constantly to increase.Meanwhile, China accelerate promote industrialization, urbanization and
New countryside construction, this causes one of the three big industries of building as energy resource consumption.Therefore, improving building efficiency has important society
Can meaning and economic benefit.
In addition, the supply and demand of the energy has very strong time dependence under many circumstances, supplied to solve heat energy
To the contradiction with demand mismatch, efficiency of energy utilization and environmental protection are improved, energy storage technology arises at the historic moment.Thermal energy storage can be divided into
The modes such as sensible heat energy storage, hidden heat energy storage and chemical energy storage.Relative to other energy storage modes, hidden heat energy storage density is big, temperature change
The advantage such as scope is small, performance is stable.Energy is realized using phase-changing energy storage material (phase change material, PCM)
Storage and utilization, help to develop the phase change composite material of environment-friendly and energy-efficient, PCM are combined with plaster of Paris, phase transformation storage is made
Energy construction material (phase change building materials, PCBM), can be entered energy in the form of latent heat of phase change
Row storage.
Plasterboard is one kind in construction material, and it is hollow to be divided into Thistle board, decorated gypsum board, plasterboard according to purposes
Bar, fibrous plaster etc..
Phase-changing energy-storing building materials are applied to building field, on the one hand can alleviate energy availability and demand both sides in time, strong
Conflict on degree and place, plays a part of the operation expense of peak load shifting, reduction air-conditioning or heating installation；On the other hand
The temperature fluctuation of architecture indoor can be reduced, hot comfort is improved, is a kind of effective way of reduction energy consumption.
The combination of phase-change material and building substrate mainly has following five kinds：(1) directly joining method is phase-change material
Powder or liquid are directly added into construction material matrix, and this is a kind of simplest mode.But, this mode phase-change material
Leakage situation incompatible with matrix material occurs in use, so as to limit the use of phase-change material.(2) infusion method
It is that construction material matrix is infiltrated into melt phase change material, allows phase-change material infiltration into construction material internal gutter.But,
Leak case also occurs in long-time use in this mode.(3) large capsule method is that phase-change material is packaged in pipeline, great circle
In ball or sheet material.Pass through the packaging of wall material, it is possible to resolve the leakage situation of phase-change material, and be also not in and construction material
Incompatible situation.But low thermal conductivity, with construction material combined process is complicated and limits the shortcomings of edge solidification trend
Its extensive use.(4) microcapsule method is that phase-change material is packaged in micron order or nanoscale ball-shaped or other shapes
In structure, it can effectively limit phase-change material and be revealed in solid-liquid transformation, and microcapsules are combined also ten with construction material matrix
Divide convenient.But this method preparation process is expensive, its industrialization is limited.(5) porous typing method is that phase-change material is inhaled
Formation form stable phase change composite material in another porous matrix material is invested, then by porous sizing phase-change material and building
Matrix material is compound to prepare phase-changing energy-storing building materials.This phase change composite material is due to suitable thermal conductivity factor, good
Thermal cycling stability and simple preparation technology the advantages of and receive significant attention.
The content of the invention
Therefore, the technical problem to be solved in the present invention is to provide a kind of simple production process, and heat insulation effect is significantly stored up
Can enhanced Thistle board.The invention solves the problems that another technical problem, be to provide the enhanced Thistle board of the energy storage
Preparation method, and provide the application of the Thistle board.
The technical scheme is that, a kind of enhanced Thistle board of energy storage, including plaster matrix and be covered in described
The mask paper of plaster matrix, the plaster matrix includes the following composition of percentage by weight：Building gypsum plaster 40-95%, it is porous
Sizing phase-change material 5-60%, water reducer 0.05-5%, modified starch 0.05-5%, fiber 0.5-10%, water 50-80%；Institute
Stating porous sizing phase-change material includes porous forming body and aliphatic acid phase variant.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that the fiber is selected from paper fiber, glass fibers
One or more in dimension, stalk fibre or wood-fibred.It is further preferred that fibre length is 10-60mm.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that the porous sizing phase-change material particle
Preparation is：By the way that porous forming body is stirred with aliphatic acid phase variant, in 50-60 DEG C of temperature, vacuum 0.3-0.9MPa conditions
Under, constant temperature 1-3 hours so that aliphatic acid phase variant is made well into the internal void of porous forming body or in layer structure
Obtain porous sizing phase-change material particle.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that porous forming body and aliphatic acid phase variant
Mass ratio is 1:1-1:4.
Preferably, the phase transition temperature of porous sizing phase-change material is 15-40 DEG C, and enthalpy of phase change is more than 60J/g.
When environment temperature is increased to phase transition temperature, phase-change material starts heat absorption storage heat, and the size of enthalpy of phase change is straight
Connect and determine how many heat can be absorbed, enthalpy of phase change is bigger, and the heat of absorption is more, phase-change material is got over to indoor adjustment effect
Greatly.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that the porous forming body is with porous knot
Expanded perlite, bentonite, montmorillonite, vermiculite or the one or more kinds of of silica flour of structure mix；The aliphatic acid phase variant
For one or more low melting point blends of aliphatic acid.
It is further preferred that above-mentioned aliphatic acid is one kind or many in capric acid, laurate, myristic acid, palmitic acid, stearic acid
Kind.
One or more eutectic blends refer to one kind of the above, and many of eutectic blends refer to above
Two kinds or three kinds of aliphatic acid phase-change materials, which compound, obtains only one of which fusing point and temperature is all lower than blending monomer is total to
Mixed thing.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that described building gypsum plaster is selected from natural stone
The one or more of cream powder or desulfurization gypsum powder.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that the water reducer is selected from polycarboxylic acid diminishing
Agent or naphthalene water reducer.
According to the enhanced Thistle board of energy storage of the present invention, it is preferred that the modified starch refers to that oxidation modification is formed sediment
Powder or acid treatment modified starch.
The present invention technical principle be：Porous sizing phase-change material plays phase-change accumulation energy effect, and water reducer primarily serves drop
The addition of low water, modified starch is the effect of cohesive mask paper and plate core, and fiber primarily serves the effect for improving mechanical property.
Phase-change material play a part of energy-saving and temperature-regulating principle be when environment temperature occur rise or reduce when, when up to
To phase-change material phase transition temperature when, phase-change material starts melting heat absorption or solidification heat release, at this moment when outdoor heat passes through wall
Absorbed during body, so as to delay outdoor heat to get in, reduce fluctuations in indoor temperature.
Present invention also offers a kind of preparation method of the enhanced Thistle board of energy storage, comprise the following steps：
(1) by building gypsum plaster 40-95%, porous sizing phase-change material 5-60%, water reducer 0.05-5%, modified starch
0.05-5%, fiber 0.5-10% are mixed according to weight than proportioning, are stirred together；
(2) water for adding 50-80% is quickly stirred, and gypsum slurry is made；
(3) mask paper under being padded in grinding tool, pours into gypsum slurry, strikes off, mask paper on pad, flattens shaping.
Present invention also offers application of the enhanced Thistle board of above-mentioned energy storage in terms of constructional ornamental material.It can be with
For ceiling, it can also be assembled on wall as ornament materials and use.
The enhanced Thistle board of energy storage of the present invention prepares the advantages of simple, cost is low, environmentally friendly, heat endurance is good, just
In in architectural application.
Embodiment
Embodiment 1
Step 1：The phase variant for the porous sizing phase-change material selected is capric acid-palmitic acid alloy, and mass ratio is 80:20,
Porous forming body is expanded perlite, and the phase transition temperature of porous sizing phase-change material is 28.2 DEG C, and enthalpy of phase change is 89J/g, porous
Sizing phase-change material preparation process is as follows：Porous forming body is stirred at 50 DEG C with aliphatic acid phase variant, vacuum 0.5MPa is permanent
Temperature 2 hours, is made porous sizing phase-change material particle.Using the natural gypsum as construction substrate, accounted for according to porous sizing phase-change material
The 5% of gross weight, polycarboxylate water-reducer (G-04, the auspicious high polymer material limited company in Shanghai three) accounts for 0.1%, and acid treatment changes
Property starch accounts for 0.1%, stalk fibre and accounts for 1.0%, and length is 25mm, water 60%, weighs each component.
By the way that porous forming body is stirred with aliphatic acid phase variant, in 50-60 DEG C of temperature, vacuum 0.3-0.9MPa conditions
Under, constant temperature 1-3 hours so that aliphatic acid phase variant is made well into the internal void of porous forming body or in layer structure
Obtain porous sizing phase-change material particle.
Step 2：By the building gypsum plaster accurately measured, porous sizing phase-change material powder, modified starch, stalk fibre and
Water reducer powder is sufficiently mixed stirring in advance, and the water accurately measured after stirring simultaneously continues stirring.
Step 3：According to the required shape that plasterboard is made, corresponding mould is prepared, lower mask paper is spread, fallen into mould
Enter gypsum slurry, slurry is uniformly deployed by concussion, spread mask paper.Extrusion forming.
Step 4：It is stripped, is dried by drying machine after coagulation forming, is eventually fabricated thickness enhanced for 12mm energy storage
Thistle board.
Anti- folding test experiments, obtained energy storage Thistle board rupture strength phase are carried out according to national standard GB/T 9775-2008
50% is improved for the energy storage Thistle board for being not added with stalk fibre.The enhanced Thistle board of energy storage prepared by embodiment 1
Sheet material under the simulated experiment room for preparing a height of 25cm × 25cm of length and width × 25cm with pure paper surface gypsum board is imposed a condition is protected
The heat-insulated contrast test of temperature, detection simulation room central temperature, impose a condition for：10 DEG C of simulated experiment room, external environment
50 DEG C, ambient temperature situation of change during testing 3 hours, experimental result is referred to shown in table 1.
Table 1
Embodiment 2
Step 1：The phase variant for the porous sizing phase-change material selected is capric acid-palmitic acid alloy, and mass ratio is 80:20,
Porous forming body is montmorillonite, and the phase transition temperature of porous sizing phase-change material is 28.6 DEG C, and enthalpy of phase change is 109J/g, porous sizing
Phase-change material preparation process is as follows：Porous forming body is stirred at 60 DEG C with aliphatic acid phase variant, vacuum 0.7MPa, constant temperature 3
Hour, porous sizing phase-change material particle is made.Using desulfurated plaster be the plaster of Paris that is made of raw material as base material, according to porous
Sizing phase-change material accounts for the 20% of gross weight, poly carboxylic acid series water reducer (G-04, the auspicious limited public affairs of high polymer material share in Shanghai three
Department) 0.2% is accounted for, oxidation modification starch accounts for 0.3%, wood-fibred and accounts for 1.2%, and length is 20mm, and water 60% weighs each component.
Step 2：By the building gypsum plaster accurately measured, porous sizing phase-change material powder, modified starch, wood-fibred and subtract
Aqua powder is sufficiently mixed stirring in advance, and the water accurately measured after stirring simultaneously continues stirring.
Step 3：According to the required shape that plasterboard is made, corresponding mould is prepared, lower mask paper is spread, fallen into mould
Enter gypsum slurry, slurry is uniformly deployed by concussion, spread mask paper.Extrusion forming.
Step 4：It is stripped, is dried by drying machine after coagulation forming, is eventually fabricated thickness enhanced for 15mm energy storage
Thistle board.
Anti- folding test experiments, obtained energy storage Thistle board rupture strength phase are carried out according to national standard GB/T 9775-2008
70% is improved for the energy storage Thistle board for being not added with stalk fibre.The enhanced Thistle board of energy storage prepared by embodiment 2
Sheet material under the simulated experiment room for preparing a height of 25cm × 25cm of length and width × 25cm with pure paper surface gypsum board is imposed a condition is protected
The heat-insulated contrast test of temperature, detection simulation room central temperature, impose a condition for：10 DEG C of simulated experiment room, external environment
50 DEG C, ambient temperature situation of change during testing 3 hours, experimental result is referred to shown in table 2.
Table 2
Embodiment 3
Step 1：Using desulfurated plaster be the plaster of Paris that is made of raw material as base material, the phase of the porous sizing phase-change material of selection
Variant is laurate and myristic acid alloy, mass ratio 83:17, porous forming body is expanded perlite, porous sizing phase transformation material
The phase transition temperature of material is 26.2 DEG C, and enthalpy of phase change is 101/g, and porous sizing phase-change material preparation process is as follows：By porous forming body
Stirred with aliphatic acid phase variant at 55 DEG C, vacuum 0.3MPa, constant temperature 2 hours, porous sizing phase-change material particle is made.With de-
Sulphur gypsum is that the plaster of Paris that raw material is made is base material, account for the 40% of gross weight, naphthalene system diminishing according to porous sizing phase-change material
Agent accounts for 0.2%, and oxidation modification starch accounts for 0.5%, glass fibre and accounts for 1.5%, and length is 15mm, and water 70% weighs each component.
Step 2：By the building gypsum plaster accurately measured, porous sizing phase-change material powder, modified starch, glass fibre and
Water reducer powder is sufficiently mixed stirring in advance, and the water accurately measured after stirring simultaneously continues stirring.
Step 3：According to the required shape that plasterboard is made, corresponding mould is prepared, lower mask paper is spread, fallen into mould
Enter gypsum slurry, slurry is uniformly deployed by concussion, spread mask paper.Extrusion forming.
Step 4：It is stripped, is dried by drying machine after coagulation forming, is eventually fabricated thickness for the enhanced paper of 9mm energy storage
Surface gypsum board.
Anti- folding test experiments, obtained energy storage Thistle board rupture strength phase are carried out according to national standard GB/T 9775-2008
85% is improved for the energy storage Thistle board for being not added with fiber.The enhanced Thistle board of energy storage prepared by embodiment 3 and pure
Thistle board prepare length and width a height of 25cm × 25cm × 25cm simulated experiment room imposed a condition under heat preservation of board every
Hot contrast test, detection simulation room central temperature, impose a condition for：10 DEG C of simulated experiment room, 50 DEG C of external environment,
Ambient temperature situation of change during testing 3 hours, experimental result is referred to shown in table 3.
Table 3
The energy storage that it can be seen from table 1 to table 3 prepared by the present invention strengthens Thistle board compared with ordinary gypsum board, by force
Degree is significantly increased, and has efficiently controlled fluctuations in indoor temperature, so as to play a part of reducing building energy consumption.
Claims (10)
1. a kind of enhanced Thistle board of energy storage, including plaster matrix and the mask paper for being covered in the plaster matrix, it is special
Levy and be：The plaster matrix includes the following composition of percentage by weight：Building gypsum plaster 40-95%, porous sizing phase transformation material
Expect 5-60%, water reducer 0.05-5%, modified starch 0.05-5%, fiber 0.5-10%, water 50-80%；The porous sizing
Phase-change material includes porous forming body and aliphatic acid phase variant.
2. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：The fiber be selected from paper fiber,
One or more in glass fibre, stalk fibre or wood-fibred.
3. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：The porous sizing phase-change material
The preparation of particle is：By the way that porous forming body is stirred with aliphatic acid phase variant, in 50-60 DEG C of temperature, vacuum 0.3-
Under the conditions of 0.9MPa, constant temperature 1-3 hours so that aliphatic acid phase variant is well into the internal void of porous forming body or stratiform
In structure, porous sizing phase-change material particle is made.
4. the enhanced Thistle board of energy storage according to claim 1 or 3, it is characterised in that：Porous forming body and fat
The mass ratio of sour phase variant is 1:1-1:4.
5. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：The porous forming body be with
Expanded perlite, bentonite, montmorillonite, vermiculite or the one or more kinds of of silica flour of loose structure mix；The aliphatic acid
Phase variant is one or more low melting point blends of aliphatic acid.
6. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：Described building gypsum plaster is selected from
The one or more of natural gesso or desulfurization gypsum powder.
7. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：The water reducer is selected from polycarboxylic acids
Class water reducer or naphthalene water reducer.
8. the enhanced Thistle board of energy storage according to claim 1, it is characterised in that：The modified starch refers to oxidation
Modified starch or acid treatment modified starch.
9. a kind of preparation method of the enhanced Thistle board of energy storage, it is characterised in that comprise the following steps：
(1) by building gypsum plaster 40-95%, porous sizing phase-change material 5-60%, water reducer 0.05-5%, modified starch
0.05-5%, fiber 0.5-10% are mixed according to weight than proportioning, are stirred together；
(2) water for adding 50-80% is quickly stirred, and gypsum slurry is made；
(3) mask paper under being padded in grinding tool, pours into gypsum slurry, strikes off, mask paper on pad, flattens shaping.
10. application of the enhanced Thistle board of energy storage described in claim 1 in terms of constructional ornamental material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214702.3A CN107056210A (en) | 2017-04-01 | 2017-04-01 | A kind of enhanced Thistle board of energy storage, its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214702.3A CN107056210A (en) | 2017-04-01 | 2017-04-01 | A kind of enhanced Thistle board of energy storage, its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107056210A true CN107056210A (en) | 2017-08-18 |
Family
ID=59602938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710214702.3A Pending CN107056210A (en) | 2017-04-01 | 2017-04-01 | A kind of enhanced Thistle board of energy storage, its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107056210A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108442606A (en) * | 2018-03-20 | 2018-08-24 | 泰山石膏有限公司 | Shock resistance Thistle board |
| CN108503320A (en) * | 2018-06-25 | 2018-09-07 | 合肥金同维低温科技有限公司 | A kind of building energy-saving heat-insulating material and its preparation process |
| CN108658564A (en) * | 2018-06-01 | 2018-10-16 | 合肥谦尧建筑装饰工程有限公司 | A kind of external wall compound insulating material and its preparation process |
| CN109678423A (en) * | 2019-01-11 | 2019-04-26 | 东南大学 | A kind of two temperature phase-changing and temperature-regulating expanded vermiculite plate and preparation method thereof |
| CN110698160A (en) * | 2019-11-14 | 2020-01-17 | 深圳市奇信集团股份有限公司 | Gypsum board slurry and preparation method thereof |
| CN111434746A (en) * | 2019-01-14 | 2020-07-21 | 中关村人居环境工程与材料研究院 | Phase-change energy storage material filled with phosphogypsum, phase-change energy storage plate and preparation method thereof |
| CN111499323A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board and preparation method thereof |
| CN111499321A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111499322A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111606653A (en) * | 2019-04-29 | 2020-09-01 | 中建材创新科技研究院有限公司 | Phase-change heat-storage gypsum plaster board and preparation method thereof |
| CN111691627A (en) * | 2020-05-20 | 2020-09-22 | 贵州开磷磷石膏综合利用有限公司 | Method for manufacturing metal facing composite gypsum board |
| CN113404175A (en) * | 2021-06-25 | 2021-09-17 | 中建材创新科技研究院有限公司 | Paper-surface gypsum board and preparation method thereof |
| CN113501701A (en) * | 2021-06-25 | 2021-10-15 | 中建材创新科技研究院有限公司 | Gypsum board and preparation method thereof |
| CN116855096A (en) * | 2023-06-26 | 2023-10-10 | 大连理工大学 | Eutectic phase-change composite insulation board and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1327024A (en) * | 2001-06-13 | 2001-12-19 | 华南理工大学 | Process for preparing organic phase change matter/bentonite nanometer composite phase change heat storage material |
| CN101549981A (en) * | 2008-04-01 | 2009-10-07 | 北新集团建材股份有限公司 | Phase-change energy-saving paper-surface plasterboard and preparation method |
| CN101565995A (en) * | 2009-06-06 | 2009-10-28 | 泰山石膏股份有限公司 | Process for producing thistle board by using desulphurization gypsum and natural gypsum |
| CN102417340A (en) * | 2011-08-31 | 2012-04-18 | 南京工业大学 | Gypsum-based phase change energy storage polymer thermal insulation mortar and preparation method thereof |
| CN102432258A (en) * | 2011-08-31 | 2012-05-02 | 南京工业大学 | Shaped phase change energy storage material for building and preparation method thereof |
-
2017
- 2017-04-01 CN CN201710214702.3A patent/CN107056210A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1327024A (en) * | 2001-06-13 | 2001-12-19 | 华南理工大学 | Process for preparing organic phase change matter/bentonite nanometer composite phase change heat storage material |
| CN101549981A (en) * | 2008-04-01 | 2009-10-07 | 北新集团建材股份有限公司 | Phase-change energy-saving paper-surface plasterboard and preparation method |
| CN101565995A (en) * | 2009-06-06 | 2009-10-28 | 泰山石膏股份有限公司 | Process for producing thistle board by using desulphurization gypsum and natural gypsum |
| CN102417340A (en) * | 2011-08-31 | 2012-04-18 | 南京工业大学 | Gypsum-based phase change energy storage polymer thermal insulation mortar and preparation method thereof |
| CN102432258A (en) * | 2011-08-31 | 2012-05-02 | 南京工业大学 | Shaped phase change energy storage material for building and preparation method thereof |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108442606B (en) * | 2018-03-20 | 2019-04-09 | 泰山石膏有限公司 | Shock resistance Thistle board |
| CN108442606A (en) * | 2018-03-20 | 2018-08-24 | 泰山石膏有限公司 | Shock resistance Thistle board |
| CN108658564A (en) * | 2018-06-01 | 2018-10-16 | 合肥谦尧建筑装饰工程有限公司 | A kind of external wall compound insulating material and its preparation process |
| CN108503320A (en) * | 2018-06-25 | 2018-09-07 | 合肥金同维低温科技有限公司 | A kind of building energy-saving heat-insulating material and its preparation process |
| CN109678423B (en) * | 2019-01-11 | 2021-11-12 | 东南大学 | Double-temperature phase-change temperature-regulating expanded vermiculite plate and preparation method thereof |
| CN109678423A (en) * | 2019-01-11 | 2019-04-26 | 东南大学 | A kind of two temperature phase-changing and temperature-regulating expanded vermiculite plate and preparation method thereof |
| CN111434746A (en) * | 2019-01-14 | 2020-07-21 | 中关村人居环境工程与材料研究院 | Phase-change energy storage material filled with phosphogypsum, phase-change energy storage plate and preparation method thereof |
| CN111499321B (en) * | 2019-01-30 | 2022-01-28 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111499322A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111499321A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111499323B (en) * | 2019-01-30 | 2022-04-29 | 中建材创新科技研究院有限公司 | Phase-change gypsum board and preparation method thereof |
| CN111499323A (en) * | 2019-01-30 | 2020-08-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board and preparation method thereof |
| CN111499322B (en) * | 2019-01-30 | 2022-01-07 | 中建材创新科技研究院有限公司 | Phase-change gypsum board with temperature control performance and preparation method thereof |
| CN111606653A (en) * | 2019-04-29 | 2020-09-01 | 中建材创新科技研究院有限公司 | Phase-change heat-storage gypsum plaster board and preparation method thereof |
| CN111606653B (en) * | 2019-04-29 | 2021-12-17 | 中建材创新科技研究院有限公司 | Phase-change heat-storage gypsum plaster board and preparation method thereof |
| CN110698160A (en) * | 2019-11-14 | 2020-01-17 | 深圳市奇信集团股份有限公司 | Gypsum board slurry and preparation method thereof |
| CN110698160B (en) * | 2019-11-14 | 2021-11-30 | 深圳市奇信集团股份有限公司 | Gypsum board slurry and preparation method thereof |
| CN111691627A (en) * | 2020-05-20 | 2020-09-22 | 贵州开磷磷石膏综合利用有限公司 | Method for manufacturing metal facing composite gypsum board |
| CN113404175A (en) * | 2021-06-25 | 2021-09-17 | 中建材创新科技研究院有限公司 | Paper-surface gypsum board and preparation method thereof |
| CN113501701A (en) * | 2021-06-25 | 2021-10-15 | 中建材创新科技研究院有限公司 | Gypsum board and preparation method thereof |
| WO2022267305A1 (en) * | 2021-06-25 | 2022-12-29 | 中建材创新科技研究院有限公司 | Gypsum board with good energy-saving, flame-retardant, waterproof, and sound insulation and noise reduction performances and preparation method therefor |
| WO2022267299A1 (en) * | 2021-06-25 | 2022-12-29 | 中建材创新科技研究院有限公司 | Gypsum plaster board having good energy-saving property and mechanical properties and preparation method therefor |
| CN116855096A (en) * | 2023-06-26 | 2023-10-10 | 大连理工大学 | Eutectic phase-change composite insulation board and preparation method and application thereof |
| CN116855096B (en) * | 2023-06-26 | 2024-09-13 | 大连理工大学 | Eutectic phase-change composite insulation board and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107056210A (en) | A kind of enhanced Thistle board of energy storage, its preparation method and application | |
| Mohseni et al. | Development of thermal energy storage lightweight structural cementitious composites by means of macro-encapsulated PCM | |
| CN100522867C (en) | Polystyrene foam particle heat-insulating mortar | |
| CN104609791B (en) | Phase-change accumulation energy double limit homoiothermic mortar and preparation method thereof | |
| CN102417340B (en) | Gypsum-based phase change energy storage polymer thermal insulation mortar and preparation method thereof | |
| CN101671149B (en) | Paraffin microencapsulated phase-change thermal-storage mortar and preparation method thereof | |
| Wang et al. | Influence of phase change material on mechanical and thermal properties of clay geopolymer mortar | |
| CN101575191B (en) | Expanded and vitrified microsphere insulating material for construction wall and production process | |
| CN102432258A (en) | Shaped phase change energy storage material for building and preparation method thereof | |
| CN104152114B (en) | The preparation method of gypsum clay composite phase-change energy-storing material | |
| CN106045428B (en) | A kind of phase-transition heat-preserving powder for building energy conservation temperature adjustment and preparation method thereof | |
| CN102127395A (en) | Paraffin wax phase change energy storage material and preparation method thereof | |
| CN103771808A (en) | Phase change thermal storage cement mortar containing rubber powder and preparation method thereof | |
| CN101880149A (en) | Phase-change and energy-storage desulfurized gypsum interior wall thermal-insulation mortar | |
| CN110759691B (en) | Environment-friendly phase-change gypsum board and preparation method thereof | |
| CN101693795A (en) | Pasty heat-insulating elastic putty | |
| CN105152598B (en) | A kind of rack type ceramsite foam concrete and preparation method thereof | |
| CN104529321B (en) | Layered composite phase change energy storage building material | |
| CN109942267A (en) | Gypsum-based composite light thermal insulation mortar and preparation method thereof | |
| CN101391872A (en) | Novel thermal insulation composite material composition and method of making the same | |
| CN110450259B (en) | Preparation method of straw phase-change plate | |
| CN106630901B (en) | Green high performance concrete | |
| CN109824323A (en) | A kind of steel bamboo composite fibre regeneration thermal insulation concrete and preparation method thereof | |
| CN101144006A (en) | Phase-change energy-storage mortar and preparation method thereof | |
| CN110204291A (en) | A kind of building exterior wall heat preserving plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170818 |
|
| WD01 | Invention patent application deemed withdrawn after publication |