CN107055608A - A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application - Google Patents
A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application Download PDFInfo
- Publication number
- CN107055608A CN107055608A CN201610920051.5A CN201610920051A CN107055608A CN 107055608 A CN107055608 A CN 107055608A CN 201610920051 A CN201610920051 A CN 201610920051A CN 107055608 A CN107055608 A CN 107055608A
- Authority
- CN
- China
- Prior art keywords
- zirconium dioxide
- dispersion liquid
- nano zirconium
- preparation
- transparent dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Abstract
The present invention discloses transparent dispersion liquid of a kind of nano zirconium dioxide and preparation method and application, belongs to field of nanometer material technology.This method step is as follows：Zirconium oxychloride solution is added in ammonia spirit during stirring, solution suction filtration is then obtained into zirconium hydroxide gel, stirring in absolute ethyl alcohol is finally added to and obtains ethanol zirconium gel；Above-mentioned ethanol zirconium gel is added, oleic acid, oleyl amine and ethanol are mixed, is then transferred into autoclave, solvent thermal reaction obtains nano zirconium dioxide；Then nano zirconium dioxide is added in solvent and obtains the transparent dispersion liquid of nano zirconium dioxide.The cost of material such as basic zirconium chloride, ammoniacal liquor, ethanol, oleic acid that the present invention is used are cheap, and technique is simple, reproducible, and yield is high, easy expanding production.Nanometer ZrO prepared by the present invention2Do not reunite in homogeneously dispersed state, particle size is homogeneous；Available for refractory material, ceramic toughening, solid-state fuel cell materials, the field such as sensor and ornament materials.
Description
Technical field
The invention belongs to field of nanometer material technology, and in particular to a kind of transparent dispersion liquid of nano zirconium dioxide and preparation method thereof
With application.
Background technology
Nano zirconium dioxide has the ability of resist chemical and microbial attack, its good dispersion, with relatively good
Thermo-chemical stability, electric conductivity and higher intensity and toughness, machinery, calorifics, electricity, optical property are good, catalytic performance
Very well.Nano zircite particle diameter is small, stability strong, with acidproof, alkaline-resisting, corrosion-resistant, resistant to elevated temperatures premium properties.Chemical property
It is stable, and with the property of high-melting-point, high resistivity, high index of refraction and low thermal coefficient of expansion.Make it in refractory material, ceramics increase
It is tough, solid-state fuel cell materials, extensive application on sensor and ornament materials.
The A of Chinese patent CN 103523830 provide a kind of preparation side of the pure monoclinic phase zirconium dioxide of high-specific surface area
Method, but particle size is uneven.The A of Chinese patent CN 103708548 provide one kind and monocline are synthesized between profit using crystal seed method
The method of crystal formation zirconium dioxide nanoparticles, its zirconium dioxide nanoparticles dispersiveness is preferable, but with organic solvent compatibilities not
It is good.The A of Chinese patent CN 103739014 provide a kind of preparation method of biocompatibility nanometer titanium dioxide zirconium powder, but real
Test process more.
The content of the invention
In order to overcome the shortcoming and deficiency that zirconium dioxide nanoparticles particle size differs and easily reunited in the prior art, this
The primary and foremost purpose of invention is to provide a kind of preparation method of single dispersing zirconium dioxide nanoparticles.The present invention is by titanium dioxide
Zirconium nano grain surface is modified, and develops a kind of preparation method of the transparent dispersion liquid of nano zirconium dioxide.
Another object of the present invention is that the nano zirconium dioxide that offer is prepared by above-mentioned preparation method is transparent scattered
Liquid.
The final purpose of the present invention is the application for providing the transparent dispersion liquid of above-mentioned nano zirconium dioxide.
The purpose of the present invention is achieved through the following technical solutions：
A kind of preparation method of the transparent dispersion liquid of nano zirconium dioxide, comprises the following steps：
(1) preparation of ethanol zirconium gel：ZrOCl is prepared first2The aqueous solution and ammonia spirit；Then during stirring
By ZrOCl2Solution is added in ammonia spirit, and solution suction filtration then is obtained into zirconium hydroxide gel, is finally added to anhydrous second
Stirring obtains ethanol zirconium gel in alcohol；
(2) preparation of nano zirconium dioxide：Add the ethanol zirconium gel that step (1) is obtained, oleic acid, oleyl amine and ethanol mixing
Stirring, is then transferred into autoclave, solvent thermal reaction obtains nano zirconium dioxide；
(3) preparation of the transparent dispersion liquid of nano zirconium dioxide：Solvent is added to by nano zirconium dioxide is obtained in step (2)
In obtain the transparent dispersion liquid of nano zirconium dioxide.
ZrOCl described in step (1)2Concentration range be 0.01~3g/mL；Preferably 0.1~3g/mL.
The volume fraction range of ammoniacal liquor described in step (1) is 1%~25%；Preferably 2.5%.
Ethanol zirconium gel described in step (2)：Oleic acid：Oleyl amine：Ethanol=(0.1~10) g：(1~50) mL：(0.1~
10)mL：(0.1~10) mL.
The temperature of solvent heat described in step (2) is 150 DEG C~250 DEG C；Preferably 210 DEG C.
The reaction time of solvent heat described in step (2) is 10~48 hours；Preferably 24 hours.
Solvent described in step (3) is non-polar solven or polar solvent；
Described non-polar solven is at least one of benzene, carbon tetrachloride, chloroform, dichloroethanes and hexamethylene etc.；
Described polar solvent is at least one of formic acid, acetic acid, acrylic acid and oleic acid etc..
A kind of transparent dispersion liquid of nano zirconium dioxide, is prepared by above-mentioned preparation method.
The transparent dispersion liquid of described nano zirconium dioxide is in refractory material, ceramic toughening, solid-state fuel cell materials, sensing
Application in device, the field such as optical coating and rub resistance photocurable resin material.
The present invention has the following advantages and effect relative to prior art：
(1) cost of material such as basic zirconium chloride, ammoniacal liquor, ethanol, oleic acid that the present invention is used is cheap, and technique is simple, repeatability
Good, yield is high, easy expanding production.
(2) compared to some weak points of existing technology, such as ZrO2Particle size differs, and easily reunites, in a solvent easily
Sedimentation etc., it is homogeneous for 10nm or so, the dispersed nanometer ZrO without reunion the invention provides a kind of particle size2It is transparent
Dispersion liquid.
(3) the nanometer ZrO prepared by the present invention2Available for refractory material, ceramic toughening, solid-state fuel cell materials are passed
Sensor, the field such as optical coating and rub resistance photocurable resin material.
Brief description of the drawings
Fig. 1 be embodiment 1 the transparent dispersion liquid of nano zirconium dioxide in ZrO2XRD.
Fig. 2 be embodiment 1 the transparent dispersion liquid of nano zirconium dioxide in ZrO2TEM figure.
Fig. 3 be embodiment 2 the transparent dispersion liquid of nano zirconium dioxide in ZrO2XRD.
Fig. 4 be embodiment 2 the transparent dispersion liquid of nano zirconium dioxide in ZrO2TEM figure.
Fig. 5 be embodiment 3 the transparent dispersion liquid of nano zirconium dioxide in ZrO2XRD.
Fig. 6 be embodiment 3 the transparent dispersion liquid of nano zirconium dioxide in ZrO2TEM figure.
Fig. 7 is the transparent dispersion liquid instance graph of nano zirconium dioxide of the present invention.
Embodiment
With reference to embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention are not limited
In this.
Reagent is all conventional reagent purchased in market or raw material unless stated otherwise used in embodiment.
The instance graph of the transparent dispersion liquid of nano zirconium dioxide prepared by the present invention is as shown in Figure 7.
Case study on implementation 1
(1) preparation of ethanol zirconium gel：The ZrOCl that concentration is 3g/mL is prepared first2The aqueous solution and 1% ammonia spirit, so
Afterwards by ZrOCl during stirring2Solution, which is added in ammonia spirit, obtains zirconium hydroxide gel, is finally added to anhydrous second
Stirring obtains ethanol zirconium gel in alcohol.
(2) preparation of the transparent dispersion liquid of nano zirconium dioxide：0.1g ethanol zirconium gel is added to oleic acid：Oleyl amine：Second
Alcohol is 50mL：0.1mL：0.1mL mixed solution is neutralized and stirred, and is then transferred into autoclave, 150 DEG C of solvent heats
Reaction 10 hours, obtains nano zirconium dioxide, is then dissolved in obtaining the transparent dispersion liquid of nano zirconium dioxide in solvent.
XRD, the TEM figures for the transparent dispersion liquid of nano zirconium dioxide that the implementation case is obtained, as shown in Figure 1 and Figure 2.Knot
ZrO in the transparent dispersion liquid of nano zirconium dioxide in fruit display, Fig. 12, with ZrO2Main peak in standard card PDF#49-1642
30.1 °, 34.9 °, 50.2 °, 59.7 ° it is corresponding with 73.9 ° on.From TEM figures as can be seen that in the transparent dispersion liquid of nano zirconium dioxide
ZrO2Nano-particle is not reunited in homogeneously dispersed state, and particle size is homogeneous, 10nm or so.
Case study on implementation 2
(1) preparation of ethanol zirconium gel：The ZrOCl that concentration is 0.1g/mL is prepared first2The aqueous solution and 2.5% ammoniacal liquor are molten
Liquid, then by ZrOCl during stirring2Solution, which is added in ammonia spirit, obtains zirconium hydroxide gel, is finally added to
Ethanol zirconium gel is obtained in absolute ethyl alcohol.
(2) preparation of the transparent dispersion liquid of nano zirconium dioxide：5g ethanol zirconium gel is added to oleic acid：Oleyl amine：Ethanol
For 40mL：5mL：5mL mixed solution is neutralized and stirred, and is then transferred into autoclave, 210 DEG C of solvent thermal reactions 24
Hour, nano zirconium dioxide is obtained, is then dissolved in obtaining the transparent dispersion liquid of nano zirconium dioxide in solvent.
XRD, the TEM figures for the transparent dispersion liquid of nano zirconium dioxide that the implementation case is obtained, as shown in Figure 3, Figure 4.Knot
ZrO in the transparent dispersion liquid of nano zirconium dioxide in fruit display, Fig. 32, with ZrO2Main peak in standard card PDF#49-1642
30.1 °, 34.9 °, 50.2 °, 59.7 ° it is corresponding with 73.9 ° on.From TEM figures as can be seen that in the transparent dispersion liquid of nano zirconium dioxide
ZrO2Nano-particle is not reunited in homogeneously dispersed state, and particle size is homogeneous, 10nm or so.
Case study on implementation 3
(1) preparation of ethanol zirconium gel：The ZrOCl that concentration is 0.1g/mL is prepared first2The aqueous solution and 25% ammoniacal liquor are molten
Liquid, then by ZrOCl during stirring2Solution, which is added in ammonia spirit, obtains zirconium hydroxide gel, is finally added to
Ethanol zirconium gel is obtained in absolute ethyl alcohol.
(2) preparation of the transparent dispersion liquid of nano zirconium dioxide：10g ethanol zirconium gel is added to oleic acid：Oleyl amine：Ethanol
For 1mL：10mL：10mL mixed solution is neutralized and stirred, and is then transferred into autoclave, 250 DEG C of solvent thermal reactions
48 hours, nano zirconium dioxide is obtained, is then dissolved in obtaining the transparent dispersion liquid of nano zirconium dioxide in solvent.
XRD, the TEM figures for the transparent dispersion liquid of nano zirconium dioxide that the implementation case is obtained, as shown in Figure 5, Figure 6.Knot
ZrO in the transparent dispersion liquid of nano zirconium dioxide in fruit display, Fig. 52, with ZrO2Main peak in standard card PDF#49-1642
30.1 °, 34.9 °, 50.2 °, 59.7 ° it is corresponding with 73.9 ° on.From TEM figures as can be seen that in the transparent dispersion liquid of nano zirconium dioxide
ZrO2Nano-particle is not reunited in homogeneously dispersed state, and particle size is homogeneous, 10nm or so.
Above-described embodiment is preferably embodiment, but embodiments of the present invention are not by above-described embodiment of the invention
Limitation, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of preparation method of the transparent dispersion liquid of nano zirconium dioxide, it is characterised in that comprise the following steps：
(1) preparation of ethanol zirconium gel：ZrOCl is prepared first2The aqueous solution and ammonia spirit；Then will during stirring
ZrOCl2Solution is added in ammonia spirit, and solution suction filtration then is obtained into zirconium hydroxide gel, absolute ethyl alcohol is finally added to
Middle stirring obtains ethanol zirconium gel；
(2) preparation of nano zirconium dioxide：The ethanol zirconium gel that step (1) is obtained is added, oleic acid, oleyl amine and ethanol mixing are stirred
Mix, be then transferred into autoclave, solvent thermal reaction obtains nano zirconium dioxide；
(3) preparation of the transparent dispersion liquid of nano zirconium dioxide：Nano zirconium dioxide will be obtained in step (2) to be added in solvent
To the transparent dispersion liquid of nano zirconium dioxide.
2. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (1)
Described in ZrOCl2Concentration range be 0.01~3g/mL.
3. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (1)
Described in ammoniacal liquor volume fraction range be 1%~25%.
4. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (2)
Described in ethanol zirconium gel：Oleic acid：Oleyl amine：Ethanol=(0.1~10) g：(1~50) mL：(0.1~10) mL：(0.1~10)
mL。
5. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (2)
Described in solvent heat temperature be 150 DEG C~250 DEG C.
6. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (2)
Described in solvent heat reaction time be 10~48 hours.
7. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 1, it is characterised in that：Step (3)
Described in solvent be non-polar solven or polar solvent.
8. the preparation method of the transparent dispersion liquid of nano zirconium dioxide according to claim 7, it is characterised in that：Described is non-
Polar solvent is at least one of benzene, carbon tetrachloride, chloroform, dichloroethanes and hexamethylene；
Described polar solvent is at least one of formic acid, acetic acid, acrylic acid and oleic acid.
9. a kind of transparent dispersion liquid of nano zirconium dioxide, it is characterised in that pass through the preparation side described in any one of claim 1~8
Method is prepared.
10. the transparent dispersion liquid of nano zirconium dioxide described in claim 9 is in refractory material, ceramic toughening, Solid-state fuel cell
Application in material, sensor, optical coating and rub resistance photocurable resin material field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610920051.5A CN107055608A (en) | 2016-10-21 | 2016-10-21 | A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610920051.5A CN107055608A (en) | 2016-10-21 | 2016-10-21 | A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107055608A true CN107055608A (en) | 2017-08-18 |
Family
ID=59617053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610920051.5A Pending CN107055608A (en) | 2016-10-21 | 2016-10-21 | A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107055608A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109718738A (en) * | 2017-10-27 | 2019-05-07 | 中国石油化工股份有限公司 | A kind of zirconium oxide spherical adsorbent and its preparation method and application |
| CN109850943A (en) * | 2019-02-22 | 2019-06-07 | 肇庆市辰业电子有限公司 | A kind of preparation method of nano zircite suspension |
| CN111205709A (en) * | 2020-01-17 | 2020-05-29 | 宁波新安涂料有限公司 | Water-based heat-insulating anticorrosive paint and preparation method thereof |
| JPWO2020196400A1 (en) * | 2019-03-27 | 2020-10-01 | ||
| CN115044250A (en) * | 2022-06-15 | 2022-09-13 | 深圳市华星光电半导体显示技术有限公司 | Zirconium dioxide monomer dispersion liquid, preparation method thereof and high-refraction ink |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101547866A (en) * | 2006-12-01 | 2009-09-30 | 大日本涂料株式会社 | Zirconium oxide particle dispersion liquid, zirconium oxide particle-containing photohardening composition, and hardened film |
| CN102031026A (en) * | 2009-09-28 | 2011-04-27 | 复旦大学 | Aqueous nano zirconia particle paint and method for preparing paint film thereof |
| CN102180516A (en) * | 2011-03-15 | 2011-09-14 | 宣城晶瑞新材料有限公司 | Preparation method of non-hydrosol gel of high-dispersibility nano zirconia |
| CN102264645A (en) * | 2008-12-24 | 2011-11-30 | 堺化学工业株式会社 | Zirconium oxide dispersion liquid and manufacturing method therefor |
| CN103043718A (en) * | 2013-01-07 | 2013-04-17 | 北京理工大学 | Preparation method of zirconia quantum dots |
| CN103588247A (en) * | 2013-11-05 | 2014-02-19 | 北京理工大学 | Novel method for carrying out solvothermal synthesis to obtain monodisperse high-crystallinity zirconia quantum dots |
-
2016
- 2016-10-21 CN CN201610920051.5A patent/CN107055608A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101547866A (en) * | 2006-12-01 | 2009-09-30 | 大日本涂料株式会社 | Zirconium oxide particle dispersion liquid, zirconium oxide particle-containing photohardening composition, and hardened film |
| CN102264645A (en) * | 2008-12-24 | 2011-11-30 | 堺化学工业株式会社 | Zirconium oxide dispersion liquid and manufacturing method therefor |
| CN102031026A (en) * | 2009-09-28 | 2011-04-27 | 复旦大学 | Aqueous nano zirconia particle paint and method for preparing paint film thereof |
| CN102180516A (en) * | 2011-03-15 | 2011-09-14 | 宣城晶瑞新材料有限公司 | Preparation method of non-hydrosol gel of high-dispersibility nano zirconia |
| CN103043718A (en) * | 2013-01-07 | 2013-04-17 | 北京理工大学 | Preparation method of zirconia quantum dots |
| CN103588247A (en) * | 2013-11-05 | 2014-02-19 | 北京理工大学 | Novel method for carrying out solvothermal synthesis to obtain monodisperse high-crystallinity zirconia quantum dots |
Non-Patent Citations (1)
| Title |
|---|
| 郑平等: "乙醇锆的合成及其在氧化锆、锆钛酸铅微粉溶胶-凝胶法制备中的应用", 《湖北教育学院学报》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109718738A (en) * | 2017-10-27 | 2019-05-07 | 中国石油化工股份有限公司 | A kind of zirconium oxide spherical adsorbent and its preparation method and application |
| CN109718738B (en) * | 2017-10-27 | 2022-08-12 | 中国石油化工股份有限公司 | Zirconia spherical adsorbent and preparation method and application thereof |
| CN109850943A (en) * | 2019-02-22 | 2019-06-07 | 肇庆市辰业电子有限公司 | A kind of preparation method of nano zircite suspension |
| CN109850943B (en) * | 2019-02-22 | 2021-11-05 | 肇庆市辰业电子有限公司 | Preparation method of nano zirconia suspension |
| JPWO2020196400A1 (en) * | 2019-03-27 | 2020-10-01 | ||
| WO2020196400A1 (en) * | 2019-03-27 | 2020-10-01 | 国立大学法人東海国立大学機構 | Zirconia microparticulate material, catalyst for gas treatment use, and method for producing same |
| JP7188822B2 (en) | 2019-03-27 | 2022-12-13 | 国立大学法人東海国立大学機構 | Zirconia fine particle material, gas processing catalyst and method for producing the same |
| CN111205709A (en) * | 2020-01-17 | 2020-05-29 | 宁波新安涂料有限公司 | Water-based heat-insulating anticorrosive paint and preparation method thereof |
| CN115044250A (en) * | 2022-06-15 | 2022-09-13 | 深圳市华星光电半导体显示技术有限公司 | Zirconium dioxide monomer dispersion liquid, preparation method thereof and high-refraction ink |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107055608A (en) | A kind of transparent dispersion liquid of nano zirconium dioxide and preparation method and application | |
| Kulkarni et al. | Microfluidic devices for synthesizing nanomaterials—a review | |
| Bressi et al. | Graphene quantum dots by eco-friendly green synthesis for electrochemical sensing: Recent advances and future perspectives | |
| Darroudi et al. | Green synthesis and characterization of gelatin-based and sugar-reduced silver nanoparticles | |
| Li et al. | Ionic liquid-functionalized fluorescent carbon nanodots and their applications in electrocatalysis, biosensing, and cell imaging | |
| Tseng et al. | Three-dimensional self-assembled hierarchical architectures of gamma-phase flowerlike bismuth oxide | |
| Janus et al. | Facile synthesis of surface-modified carbon quantum dots (CQDs) for biosensing and bioimaging | |
| Iijima et al. | Surface modification of silicon carbide nanoparticles by azo radical initiators | |
| CN103832993A (en) | Method for preparing luminescent carbon dots from carbohydrate | |
| CN105038810B (en) | A kind of preparation method of physics of liquid crystals gel complex material and products thereof | |
| Fang et al. | High-throughput preparation of silk fibroin nanofibers by modified bubble-electrospinning | |
| Długosz | Natural deep eutectic solvents in the synthesis of inorganic nanoparticles | |
| Morselli et al. | Poly (methyl methacrylate)-TiO2 nanocomposite obtained by non-hydrolytic sol–gel synthesis | |
| Shamsuri et al. | Utilization of an ionic liquid/urea mixture as a physical coupling agent for agarose/talc composite films | |
| CN103466600A (en) | Preparation method of environment-friendly low-toxic fluorescent carbon nano particle liquor | |
| Chen et al. | Effect of redox reaction products on the luminescence switching behavior in CePO4: Tb nanorods | |
| Ádám et al. | Ultrasound-assisted hydrazine reduction method for the preparation of nickel nanoparticles, physicochemical characterization and catalytic application in Suzuki-Miyaura cross-coupling reaction | |
| Varshney et al. | An overview on biomedical applications of versatile silica nanoparticles, synthesized via several chemical and biological routes: A review | |
| Iglesias | Gold nanoparticles as colorimetric sensors for the detection of DNA bases and related compounds | |
| Li et al. | Folic acid-modified cerium-doped carbon dots as photoluminescence sensors for cancer cells identification and Fe (III) detection | |
| CN102180516B (en) | Preparation method of non-hydrosol gel of high-dispersibility nano zirconia | |
| CN105079806A (en) | Carbon nanomaterial directly modified by polypeptide as well as preparation method and application thereof | |
| Sun et al. | Preparation of SiS and SiO2 nanospheres | |
| Sriram et al. | The fabrication of a La2Sn2O7/f-HNT composite for non-enzymatic electrochemical detection of 3-nitro-l-tyrosine in biological samples | |
| Sun et al. | Surface organic modification of CaCO3-TiO2 composite pigment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |
|
| RJ01 | Rejection of invention patent application after publication |