CN107042100A - A kind of regenerating active carbon system of combination microwave radiation and ozone activation - Google Patents
A kind of regenerating active carbon system of combination microwave radiation and ozone activation Download PDFInfo
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- CN107042100A CN107042100A CN201710066511.7A CN201710066511A CN107042100A CN 107042100 A CN107042100 A CN 107042100A CN 201710066511 A CN201710066511 A CN 201710066511A CN 107042100 A CN107042100 A CN 107042100A
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- activated carbon
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 149
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 230000004913 activation Effects 0.000 title claims abstract description 27
- 230000005855 radiation Effects 0.000 title claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 19
- 230000001172 regenerating effect Effects 0.000 title claims abstract description 13
- 238000001994 activation Methods 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000005406 washing Methods 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011358 absorbing material Substances 0.000 claims abstract description 6
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 4
- 239000000919 ceramic Substances 0.000 claims abstract description 3
- 239000006096 absorbing agent Substances 0.000 claims description 17
- 238000001816 cooling Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000002826 coolant Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 239000001301 oxygen Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 3
- 125000000524 functional group Chemical group 0.000 abstract description 2
- 230000000274 adsorptive effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- WURFKUQACINBSI-UHFFFAOYSA-M ozonide Chemical compound [O]O[O-] WURFKUQACINBSI-UHFFFAOYSA-M 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 102000011931 Nucleoproteins Human genes 0.000 description 1
- 108010061100 Nucleoproteins Proteins 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- -1 alkenes compounds Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002510 pyrogen Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3441—Regeneration or reactivation by electric current, ultrasound or irradiation, e.g. electromagnetic radiation such as X-rays, UV, light, microwaves
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
The present invention relates to the regenerating active carbon system of a kind of combination microwave radiation and ozone activation, the present invention makes full use of microwave method quick, efficient advantage and ozone increase oxygen-containing functional group to improve the advantage of activated carbon adsorptive capacity in activated carbon, by the two innovative combination, system point three-stage, one section of microwave-heating reaction unit, two sections of heat-exchange devices, three sections of ozone activations and water washing device, wherein activated carbon storage warehouse is prepared with ferrite wave-absorbing material, charging aperture and discharge outlet are provided with end socket cover and the anti-Vent of microwave leaks total member, conveying pipeline is aluminium oxide ceramics material, heat exchanger is used in energy exchange, condenser, carry out heat exchange；Activated carbon reservoir entry is connected with ozone generator outlet, and activated carbon is not less than 2 hours with ozone contact, and washing time is not less than 10h.
Description
Technical field
Microwave radiation and ozone activation are combined the present invention relates to Regenevating Waste Activated Carbon processing technology field, more particularly to one kind
Regenerating active carbon system.
Background technology
Activated carbon has highly developed gap structure and objective specific surface area, and has extremely strong suction to different kinds of molecules
Attached ability, is a kind of excellent adsorbent.With the increase of activated carbon dosage, the process problem of waste active carbon is also protruded all the more,
For the secondary pollution for avoiding it from bringing, the regeneration treatment technology for waste active carbon also attracts attention all the more.
Microwave radiation regenerated carbon refers to make desorption, charing, activation by high temperature, so as to recover its adsorption capacity
A kind of method.Microwave is the electromagnetic radiation being located in electromagnetic spectrum between far infrared and radio wave.During microwave radiation, have
The absorption microwave energy that organic pollutants can not continue is to reach the temperature needed for degraded, and activated carbon can effectively absorb microwave energy
Temperature is set to reach more than 1000 DEG C.Organic pollution overcomes Van der Waals force to attract to start desorption under microwave action, with micro-
The aggregation of wave energy, is carbonized under pyrogenicity and nonthermal effect collective effect.Microwave irradiation has a good application prospect.
Ozone is a kind of extremely strong unstable gas of oxidisability, and ozone output concentration is influenceed by many factors, its lumen
Temperature is one of epochmaking factor；Ozone is decayed in 1 minute half in 30 degree or so Shi Hui.Declined at 40 ~ 50 DEG C
Subtract and reach 80%.More than 60 DEG C ozone can be decomposed at once.The chemical property of ozone is extremely unstable, all can be slowly in air and water
Resolve into oxygen.Temperature is raised, and ozone decomposed speed is accelerated, when temperature is more than 100 DEG C, is decomposed very violent, is reached 270
During DEG C high temperature, oxygen can be immediately converts into.Decomposition rate of the ozone in water is accelerated with the raising of water temperature and pH values.
After ozone is by the rapid decomposable organic or inorganic material for producing stink and its other smells of its strong oxidation performance
Deodorising effect is reached, stink original material is resolved into innocuous substance.
Ozone can react with organic matter：(1) the reaction of ozone and alkenes compounds：Ozone easily with double-strand
Olefin(e) compound reacts, and the final product of reaction is probably the mixing of monomer, polymerization or ozonide staggeredly
Body.Ozonide resolves into aldehyde and acid.(2) the reaction of ozone and aromatic compound：The reaction of ozone and aromatic compound
It is relatively slow, in serial benzene<Naphthalene<It is luxuriant and rich with fragrance<Pyrene<In anthracene, its rate constant gradually increases.(3) to nucleoprotein（Amino acid）System,
Organic amino also all reacts.In theory, ozone can effectively remove the organic substance adsorbed in waste active carbon, play activation again
Raw purpose.
Activated and modified in activated carbon, increase the oxygen-containing functional group of carbon surface, research shows, using ozone, lives
Change and modification, the oxy radical effect to increase activated carbon surface is notable.
Activated carbon usage amount increases increasingly, and the activated carbon of saturation needs regeneration treatment.Existing equipment to activated carbon again
Raw processing also has energy dissipation, fails effectively utilization, and regeneration rate is low, high energy consumption.Activated carbon to being adsorbed with organic matter, it is living
Change the waste gas of processing generation there is also the hidden danger of pollution environment, while activation effect is less desirable.
The content of the invention
The present invention is not enough for more than, and novelty utilizes microwave radiation and ozone, and one is provided in terms of regenerating active carbon
Cover the good regeneration treatment system of regeneration rate height, small energy consumption, safety, activation effect.Especially the waste active carbon for adsorbing organic matter is imitated
Fruit is more preferably.
The present invention is realized by the following means：With reference to three sections of the regenerating active carbon system point of microwave radiation and ozone activation
Formula：
（1）One section of microwave-heating reaction unit, including wave-absorber, magnetron, temperature detector, fan, controller, magnetron is
Microwave generating source, wave-absorber is the activated carbon storage warehouse prepared with ferrite wave-absorbing material, in microwave-heating reaction unit
Centre, the activated carbon storage warehouse charging aperture and discharge outlet are provided with end socket cover and the anti-Vent of microwave leaks total member, and conveying pipeline is oxygen
Change aluminium ceramic material, end socket cover is sealed by end socket sealing ring；Temperature detector detects wave-absorber temperature, and connects with controller
Connect, controller is connected with temperature detector；Fan is located above wave-absorber, the heat on microwave magnetron source can be directed into suction
Ripple body.
Ferrite wave-absorbing material in the case where being not added with outer Constant charge soil, from the magnetic of incident alternating magnetic field and crystal it is each to
The precessional resonance that different in nature equivalent field collective effect is produced, when the angular frequency and the magnetic anisotropy equivalent field of crystal of alternating magnetic field
When the intrinsic angular frequency determined is equal, ferrite wave-absorbing material is by a large amount of electromagnetic wave absorption energy.
（2）Activated carbon in two sections of heat-exchange devices, including heat exchanger, condenser, activated carbon storage warehouse is successively through changing
Hot device, condenser carry out heat exchange.Activated carbon in wave-absorber specially after microwave radiation, activated carbon storage warehouse is micro-
High temperature is gradually under wave radiation, the activated carbon in storage warehouse is subjected to heat exchange through heat exchanger, condenser successively.
（3）Three sections of ozone activations and water washing device, including ozone generator, activated carbon storage facility, water pump, activated carbon warp
After two sections of heat-exchange devices, it is fitted into activated carbon storage facility, activated carbon reservoir entry connects with ozone generator outlet
Connect；When ozone generator is opened, the other outlets of activated carbon storage facility are in sealing state, and activated carbon is not less than with ozone contact
2 hours；Water is squeezed into by activated carbon storage facility by water pump, stirring is opened, washing, washing time is not less than 10h.It is smelly in this section
Oxygen is fully contacted with activated carbon, after activated carbon and ozone contact are not less than 2 hours, is washed or pickling.Addition acid is adjusted
Section pH purpose is to promote ozone decomposed complete, it is to avoid cause environment hidden danger.
Microwave source in one section of microwave-heating reaction unit is closing microwave source, and its irradiation unit is arranged on closed cavity
It is interior, it is resonator multi-mode electrically magnetic radiation, frequency band is 915MHz ~ 2450MHz.
Two sections of heat-exchange devices, using multi-stage condensing, respectively air cooling, water cooling, coolant is cold.Three sections of ozone activations and
Water washing device, air-tight state is in when ozone is not drained all the time, while acid is added dropwise to promote ozone decomposed in washing.
In the present invention, microwave activation temperature is 400 ~ 1000 DEG C, and the volatile combustible gases that activation process is produced are not together with
The activation gas of reaction is recycled by pipeline together, is reached environmental protection standard discharge or is burnt.Add because microwave is unique
Hot mode, the reaming soak time of activated carbon is significantly reduced.In the present invention, the activated carbon temperature after activation is higher, using multistage
Condensation and the mode of heat exchange, iterative cycles cooling make activated carbon be cooled to room temperature.Activated carbon enters three sections, contacts ozone, depth
Activation, reaches the purpose of regenerating active carbon.
Brief description of the drawings
Fig. 1 is the regenerating active carbon system schematic with reference to microwave radiation and ozone activation；Label meaning is respectively in figure：
1：One section of microwave-heating reaction unit；2：Two sections of heat-exchange devices；3：Three sections of ozone activations and water washing device；4：Temperature detection
Device；5：Magnetron；6：Fan；7：Wave-absorber；8：End socket cover；9：Sealing ring；10：Activated carbon storage warehouse charging aperture；11：Control
Device；12：The anti-Vent of microwave leaks total member；13：Activated carbon stores bin discharge port external；14：Heat exchanger；15：Condenser；16：Water pump；17：
Water pipe；18：Ozone generator；19：Activated carbon storage facility；20：Agitator.
Embodiment
As shown in drawings, it is divided into three sections with reference to the regenerating active carbon system of microwave radiation and ozone activation, by set about
Duan Shixian.
（1）One section of microwave-heating reaction unit, including wave-absorber, magnetron, temperature detector, fan, controller, magnetic control
Manage as microwave generating source, wave-absorber is the activated carbon storage warehouse prepared with ferrite wave-absorbing material, react and fill positioned at microwave-heating
Center is put, the activated carbon storage warehouse charging aperture and discharge outlet are provided with end socket cover and the anti-Vent of microwave leaks total member, conveying pipeline
For aluminium oxide ceramics material, end socket cover is sealed by end socket sealing ring；Temperature detector detects wave-absorber temperature, and and controller
Connection, controller is connected with temperature detector；Fan is located above wave-absorber, can be directed to the heat on microwave magnetron source
Wave-absorber.
（2）Activated carbon in two sections of heat-exchange devices, including heat exchanger, condenser, activated carbon storage warehouse is successively through changing
Hot device, condenser carry out heat exchange.Activated carbon in wave-absorber specially after microwave radiation, activated carbon storage warehouse is micro-
High temperature is gradually under wave radiation, the activated carbon in storage warehouse is subjected to heat exchange through heat exchanger, condenser successively.
（3）Three sections of ozone activations and water washing device, including ozone generator, activated carbon storage facility, water pump, activated carbon warp
After two sections of heat-exchange devices, it is fitted into activated carbon storage facility, activated carbon reservoir entry connects with ozone generator outlet
Connect；When ozone generator is opened, the other outlets of activated carbon storage facility are in sealing state, and activated carbon is not less than with ozone contact
2 hours；Water is squeezed into by activated carbon storage facility by water pump, stirring is opened, washing, washing time is not less than 10h.It is smelly in this section
Oxygen is fully contacted with activated carbon, after activated carbon and ozone contact are not less than 2 hours, is washed or pickling.Addition acid is adjusted
Section pH purpose is to promote ozone decomposed complete, it is to avoid cause environment hidden danger.
Microwave source in one section of microwave-heating reaction unit is closing microwave source, and its irradiation unit is arranged on closed cavity
It is interior, it is resonator multi-mode electrically magnetic radiation, frequency band is 915MHz, two sections of heat-exchange devices, using multi-stage condensing, difference
It is cold for air cooling, water cooling, coolant.Three sections of ozone activations and water washing device, air-tight state are in when ozone is not drained, together all the time
When washing when be added dropwise acid for adjusting pH to 4, to promote ozone decomposed.
Claims (4)
1. a kind of regenerating active carbon system of combination microwave radiation and ozone activation, it is characterised in that the system point three-stage,
One section of microwave-heating reaction unit, including wave-absorber, magnetron, temperature detector, fan, controller, magnetron produce for microwave
Source of students, wave-absorber is the activated carbon storage warehouse prepared with ferrite wave-absorbing material, described positioned at microwave-heating reaction unit center
Activated carbon storage warehouse charging aperture and discharge outlet are provided with end socket cover and the anti-Vent of microwave leaks total member, and conveying pipeline is aluminium oxide ceramics
Material, end socket cover is sealed by end socket sealing ring；Temperature detector detects wave-absorber temperature, and is connected with controller, controller
It is connected with temperature detector；Fan is located above wave-absorber, the heat on microwave magnetron source can be directed into wave-absorber；Two sections
Activated carbon in heat-exchange device, including heat exchanger, condenser, activated carbon storage warehouse is carried out through heat exchanger, condenser successively
Heat exchange；Three sections of ozone activations and water washing device, including ozone generator, activated carbon storage facility, water pump, activated carbon is through two
After section heat-exchange device, it is fitted into activated carbon storage facility, activated carbon reservoir entry is connected with ozone generator outlet；
When ozone generator is opened, the other outlets of activated carbon storage facility are in sealing state, and it is small that activated carbon is not less than 2 with ozone contact
When；Water is squeezed into by activated carbon storage facility by water pump, stirring is opened, washing, washing time is not less than 10h.
2. the regenerating active carbon system of a kind of combination microwave radiation according to claim 1 and ozone activation, its feature exists
Microwave source in one section of microwave-heating reaction unit is closing microwave source, and its irradiation unit is arranged in closed cavity,
For resonator multi-mode electrically magnetic radiation, frequency band is 915MHz ~ 2450MHz.
3. the regenerating active carbon system of a kind of combination microwave radiation according to claim 1 and ozone activation, its feature exists
In two sections of heat-exchange devices, using multi-stage condensing, respectively air cooling, water cooling, coolant is cold.
4. the regenerating active carbon system of a kind of combination microwave radiation according to claim 1 and ozone activation, its feature exists
In three sections of ozone activations and water washing device, air-tight state is in all the time when ozone is not drained, while being added dropwise in washing
Acid is to promote ozone decomposed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710066511.7A CN107042100A (en) | 2017-02-07 | 2017-02-07 | A kind of regenerating active carbon system of combination microwave radiation and ozone activation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710066511.7A CN107042100A (en) | 2017-02-07 | 2017-02-07 | A kind of regenerating active carbon system of combination microwave radiation and ozone activation |
Publications (1)
| Publication Number | Publication Date |
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| CN107042100A true CN107042100A (en) | 2017-08-15 |
Family
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| CN201710066511.7A Pending CN107042100A (en) | 2017-02-07 | 2017-02-07 | A kind of regenerating active carbon system of combination microwave radiation and ozone activation |
Country Status (1)
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| CN (1) | CN107042100A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110420628A (en) * | 2019-07-17 | 2019-11-08 | 河北科技大学 | Zeolite molecular sieve regenerating unit and regeneration method |
| CN115382523A (en) * | 2022-08-31 | 2022-11-25 | 聊城鲁西双氧水新材料科技有限公司 | Treatment process for recycling alumina balls and hydrogen peroxide working solution by using microwave technology |
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|---|---|---|---|---|
| CN110420628A (en) * | 2019-07-17 | 2019-11-08 | 河北科技大学 | Zeolite molecular sieve regenerating unit and regeneration method |
| CN115382523A (en) * | 2022-08-31 | 2022-11-25 | 聊城鲁西双氧水新材料科技有限公司 | Treatment process for recycling alumina balls and hydrogen peroxide working solution by using microwave technology |
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