CN107034728A - A kind of paper water resistant anti-blushing agent - Google Patents
A kind of paper water resistant anti-blushing agent Download PDFInfo
- Publication number
- CN107034728A CN107034728A CN201710300412.0A CN201710300412A CN107034728A CN 107034728 A CN107034728 A CN 107034728A CN 201710300412 A CN201710300412 A CN 201710300412A CN 107034728 A CN107034728 A CN 107034728A
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- China
- Prior art keywords
- quality
- monomer
- reaction type
- water resistant
- resistant anti
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/04—Hydrocarbons
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of paper water resistant anti-blushing agent, including monomer, cationoid reaction type monomer, non-ionic reaction type monomer, cationic emulsifier, nonionic emulsifier, hydrophobicity auxiliary agent；Wherein the quality of cationoid reaction type monomer is 5% the 20% of monomer mass；Wherein the quality of non-ionic reaction type monomer is 2% the 4% of monomer mass；Wherein the quality of cationic emulsifier is 1% the 3% of monomer mass；Wherein the quality of nonionic emulsifier is 1% the 3% of monomer mass；Wherein the quality of hydrophobicity auxiliary agent is 3% the 10% of monomer mass.The performance of water resistant anti-blushing agent that is prepared from by present invention proportioning is good, while inking is ensured, ensure paper product water proofing property, more suitable for modern paper technique.
Description
Technical field
The present invention relates to a kind of anti-blushing agent, the paper anti-blushing agent of specifically a kind of cationic structural.
Background technology
Allow in finished product cardboard or paper manufacturing process, inside paper containing a certain amount of natural moisture, so paper pulp
Mass dryness fraction must reach 90% -94% after head box, wet end, press section, front and rear drying portion, but be due to Paper or cardboard
Steam is full of in the environment stored or used, it is relatively moister, so in the case where not doing any protective separation measure, mass dryness fraction
The moisture of suitable paper meeting absorption air.
After steam of the Paper or cardboard in absorption air, moisture can have a strong impact on product quality more than 10%, enter
And the physical index of finished paper can be influenceed, eventually influence the sale of finished paper.So, existing paper product is in the fabrication process
Water resistant anti-blushing agent can be added, it is ensured that the suitable water content of its finished product, but composition due to existing water resistant anti-blushing agent and
Chemical characteristic, existing anti-blushing agent is the reason for composition and structure, it is impossible to which isolation water vapour is to Paper or cardboard fiber well
Between adhesion destruction, and the laminating processing and inking of paper can be influenceed while protection against the tide, does not adapt to as commodity and
Requirement of the important packaging material of commodity to Paper or cardboard.
The content of the invention
It is moistureproof there is provided a kind of paper of cationic structural present in prior art it is an object of the invention to overcome the shortcomings of
Agent.
To achieve the above object, the technical solution adopted in the present invention is：
A kind of paper water resistant anti-blushing agent, including it is monomer, cationoid reaction type monomer, non-ionic reaction type monomer, cation emulsified
Agent, nonionic emulsifier, hydrophobicity auxiliary agent；
Wherein the quality of cationoid reaction type monomer is the 5%-20% of monomer mass；
Wherein the quality of non-ionic reaction type monomer is the 2%-4% of monomer mass；
Wherein the quality of cationic emulsifier is the 1%-3% of monomer mass；
Wherein the quality of nonionic emulsifier is the 1%-3% of monomer mass；
Wherein the quality of hydrophobicity auxiliary agent is the 3%-10% of monomer mass.
Further, butadiene of the monomer including quality accounting 10-30%, quality account for 10-40% styrene, quality accounting
1%-3% itaconic acid, quality accounting 10%-40% butyl acrylate, quality accounting 10%-40% cycloaliphatic acrylates, matter
Measure accounting 30%-55% vinylidene chloride.
Further, cationoid reaction type monomer includes dimethyl diallyl ammonium chloride, acrylate
One or more in ethyl ester, dimethylamino-propyl Methacrylamide, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride.
Further, polyethers EO=10 of non-ionic reaction type monomer including the base containing double bond, the base containing double bond polyethers EO=
One or more in polyethers EO=30 of 20/ base containing double bond.
Further, cationic emulsifier include hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide,
OTAC, Cetyltrimethylammonium bromide, Gemini（GEMINI）Quaternary ammonium salt cationic surface-active
One or more in agent.
Further, nonionic emulsifier includes the one or more in alkyl alcohol block polyether, side chain C13 alcohol ethers.
Further, hydrophobicity auxiliary agent includes one kind in rosin and its modifier, C9 Petropols and its modifier
Or it is a variety of.
The performance of water resistant anti-blushing agent that is prepared from by present invention proportioning is good, while inking is ensured, ensure paper product
Water proofing property, more suitable for modern paper technique.
Embodiment
For convenience of to the present invention make under understanding, now enumerate embodiment, the present invention is further illustrated.
Embodiment 1：
The present invention includes monomer, cationoid reaction type monomer, non-ionic reaction type monomer, cationic emulsifier, non-ionic emulsifier
Agent, hydrophobicity auxiliary agent, the wherein quality of cationoid reaction type monomer are the 6% of monomer mass；Wherein non-ionic reaction type monomer
Quality is the 2% of monomer mass；Wherein the quality of cationic emulsifier is the 2.5% of monomer mass；Wherein nonionic emulsifier
Quality is the 1% of monomer mass；Wherein the quality of hydrophobicity auxiliary agent is the 3% of monomer mass.Monomer includes the fourth of quality accounting 20%
Diene, quality account for 10% styrene, the itaconic acid of quality accounting 1%, the butyl acrylate of quality accounting 20%, quality accounting 20%
The vinylidene chloride of cycloaliphatic acrylates, quality accounting 32%.Cationoid reaction type monomer includes dimethyl diallyl chlorination
Ammonium, acrylate.Polyethers EO=10 of non-ionic reaction type monomer including the base containing double bond, the base containing double bond it is poly-
Polyethers EO=30 of ether EO=20/ base containing double bond.Cationic emulsifier includes hexadecyltrimethylammonium chloride, cetyl front three
Base ammonium bromide, OTAC, Cetyltrimethylammonium bromide, Gemini（GEMINI）Quaternary ammonium salt cationic
Surfactant.Nonionic emulsifier includes alkyl alcohol block polyether, side chain C13 alcohol ethers.Hydrophobicity auxiliary agent include rosin and its
Modifier, C9 Petropols and its modifier.
Embodiment 2：
The present invention includes monomer, cationoid reaction type monomer, non-ionic reaction type monomer, cationic emulsifier, non-ionic emulsifier
Agent, hydrophobicity auxiliary agent, the wherein quality of cationoid reaction type monomer are the 12% of monomer mass；Wherein non-ionic reaction type monomer
Quality be monomer mass 3%；Wherein the quality of cationic emulsifier is the 3% of monomer mass；Wherein nonionic emulsifier
Quality is the 2% of monomer mass；Wherein the quality of hydrophobicity auxiliary agent is the 5% of monomer mass.Monomer includes the fourth of quality accounting 10%
Diene, quality account for 15% styrene, the itaconic acid of quality accounting 2%, the butyl acrylate of quality accounting 22%, quality accounting 25%
The vinylidene chloride of cycloaliphatic acrylates, quality accounting 33%.Cationoid reaction type monomer includes dimethyl diallyl chlorination
Ammonium, acrylate.Non-ionic reaction type monomer is polyethers EO=10 of the base containing double bond.Cationic emulsifier bag
Include hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide, Gemini（GEMINI）Live on quaternary ammonium salt cationic surface
Property agent.Nonionic emulsifier include alkyl alcohol block polyether,.Hydrophobicity auxiliary agent is rosin and its modifier.
Embodiment 3：
The present invention includes monomer, cationoid reaction type monomer, non-ionic reaction type monomer, cationic emulsifier, non-ionic emulsifier
Agent, hydrophobicity auxiliary agent, the wherein quality of cationoid reaction type monomer are the 10% of monomer mass；Wherein non-ionic reaction type monomer
Quality be monomer mass 3%；Wherein the quality of cationic emulsifier is the 5% of monomer mass；Wherein nonionic emulsifier
Quality is the 1% of monomer mass；Wherein the quality of hydrophobicity auxiliary agent is the 3% of monomer mass.Monomer includes the fourth of quality accounting 17%
Diene, quality account for 15% styrene, the itaconic acid of quality accounting 1%, the butyl acrylate of quality accounting 20%, quality accounting 35%
The vinylidene chloride of cycloaliphatic acrylates, quality accounting 55%.Cationoid reaction type monomer includes dimethyl diallyl chlorination
Ammonium.Non-ionic reaction type monomer is polyethers EO=10 of the base containing double bond.Cationic emulsifier includes cetyl trimethyl chlorination
Ammonium, Gemini（GEMINI）Quaternary cationics.Nonionic emulsifier is alkyl alcohol block polyether.Hydrophobicity is helped
Agent is rosin.
The above described is only a preferred embodiment of the present invention, not making any formal limitation to the present invention, appoint
What those skilled in the art changed or be modified to possibly also with the technology contents of the disclosure above equivalent variations etc.
Embodiment is imitated, but it is all without departing from technical solution of the present invention content, and the technical spirit according to the present invention is made to above example
Any simple modification, equivalent variations and modification, in the range of still falling within technical solution of the present invention.
Claims (7)
1. a kind of paper water resistant anti-blushing agent, it is characterised in that：Including monomer, cationoid reaction type monomer, non-ionic reaction type list
Body, cationic emulsifier, nonionic emulsifier, hydrophobicity auxiliary agent；Wherein the quality of cationoid reaction type monomer is monomer mass
5%-20%；Wherein the quality of non-ionic reaction type monomer is the 2%-4% of monomer mass；The quality of wherein cationic emulsifier is
The 1%-3% of monomer mass；Wherein the quality of nonionic emulsifier is the 1%-3% of monomer mass；The wherein quality of hydrophobicity auxiliary agent
For the 3%-10% of monomer mass.
2. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Monomer includes quality accounting 10-30%
Butadiene, quality account for 10-40% styrene, quality accounting 1%-3% itaconic acid, quality accounting 10%-40% acrylic acid fourth
Ester, quality accounting 10%-40% cycloaliphatic acrylates, quality accounting 30%-55% vinylidene chloride.
3. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Further, cationoid reaction
Type monomer include dimethyl diallyl ammonium chloride, acrylate, dimethylamino-propyl Methacrylamide,
One or more in MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride.
4. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Non-ionic reaction type monomer includes containing
One or more in polyethers EO=10 of double bond base, polyethers EO=30 of the base containing double bond of the polyethers EO of the base containing double bond=20/.
5. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Cationic emulsifier includes hexadecane
Base trimethyl ammonium chloride, cetyl trimethylammonium bromide, OTAC, octadecyl trimethyl bromination
Ammonium, Gemini（GEMINI）One or more in quaternary cationics.
6. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Nonionic emulsifier includes alkylol
One or more in block polyether, side chain C13 alcohol ethers.
7. a kind of paper water resistant anti-blushing agent as described in claim 1, it is characterised in that：Hydrophobicity auxiliary agent include rosin and its
One or more in modifier, C9 Petropols and its modifier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710300412.0A CN107034728A (en) | 2017-05-02 | 2017-05-02 | A kind of paper water resistant anti-blushing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710300412.0A CN107034728A (en) | 2017-05-02 | 2017-05-02 | A kind of paper water resistant anti-blushing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107034728A true CN107034728A (en) | 2017-08-11 |
Family
ID=59538165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710300412.0A Pending CN107034728A (en) | 2017-05-02 | 2017-05-02 | A kind of paper water resistant anti-blushing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107034728A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111424462A (en) * | 2020-04-01 | 2020-07-17 | 广东麦可瑞化工科技有限公司 | Water-resistant moisture-proof agent for paper and preparation method thereof |
| CN114395066A (en) * | 2022-01-20 | 2022-04-26 | 九洲生物技术（苏州）有限公司 | Paper moisture-proof agent and preparation method thereof |
| CN115287937A (en) * | 2022-08-04 | 2022-11-04 | 杭州君明化工有限公司 | Preparation method of chloride-free waterproof agent for cationic paper pulp |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1208737A (en) * | 1997-08-14 | 1999-02-24 | 中国石油化工总公司 | High stability carboxy styrene butadiene rubber latex |
| CN1504611A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Sizing agent and recording sheet having the same |
| CN101139413A (en) * | 2006-09-05 | 2008-03-12 | 中国石油天然气集团公司 | Method for synthesizing carboxyl butadiene-styrene latex used for cement group water-proofing material |
| CN101649580A (en) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | Method for preparing cation colophony/AKD neutral sizing agent |
| CN102395644A (en) * | 2009-04-23 | 2012-03-28 | 旭硝子株式会社 | Water and oil repellent composition, method for producing same, and method for treating article |
| US20140316043A1 (en) * | 2011-11-11 | 2014-10-23 | Franco Federici | Aqueous polymer composition for paper coating |
-
2017
- 2017-05-02 CN CN201710300412.0A patent/CN107034728A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1208737A (en) * | 1997-08-14 | 1999-02-24 | 中国石油化工总公司 | High stability carboxy styrene butadiene rubber latex |
| CN1504611A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Sizing agent and recording sheet having the same |
| CN101139413A (en) * | 2006-09-05 | 2008-03-12 | 中国石油天然气集团公司 | Method for synthesizing carboxyl butadiene-styrene latex used for cement group water-proofing material |
| CN102395644A (en) * | 2009-04-23 | 2012-03-28 | 旭硝子株式会社 | Water and oil repellent composition, method for producing same, and method for treating article |
| CN101649580A (en) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | Method for preparing cation colophony/AKD neutral sizing agent |
| US20140316043A1 (en) * | 2011-11-11 | 2014-10-23 | Franco Federici | Aqueous polymer composition for paper coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111424462A (en) * | 2020-04-01 | 2020-07-17 | 广东麦可瑞化工科技有限公司 | Water-resistant moisture-proof agent for paper and preparation method thereof |
| CN114395066A (en) * | 2022-01-20 | 2022-04-26 | 九洲生物技术（苏州）有限公司 | Paper moisture-proof agent and preparation method thereof |
| CN114395066B (en) * | 2022-01-20 | 2023-08-18 | 九洲生物技术（苏州）有限公司 | Paper moisture-proof agent and preparation method thereof |
| CN115287937A (en) * | 2022-08-04 | 2022-11-04 | 杭州君明化工有限公司 | Preparation method of chloride-free waterproof agent for cationic paper pulp |
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| PB01 | Publication | ||
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Application publication date: 20170811 |