CN107034721B - It is a kind of with pueraria lobata fiber manufacture cigarette paper additive method and its additive obtained with application - Google Patents

It is a kind of with pueraria lobata fiber manufacture cigarette paper additive method and its additive obtained with application Download PDF

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Publication number
CN107034721B
CN107034721B CN201710458797.3A CN201710458797A CN107034721B CN 107034721 B CN107034721 B CN 107034721B CN 201710458797 A CN201710458797 A CN 201710458797A CN 107034721 B CN107034721 B CN 107034721B
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China
Prior art keywords
cigarette
paper
pueraria lobata
cigarette paper
additive
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CN107034721A (en
Inventor
何沛
凌军
向能军
刘志华
杨光宇
王晋
韦克毅
申钦鹏
刘春波
朱瑞芝
司晓喜
张凤梅
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China Tobacco Yunnan Industrial Co Ltd
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China Tobacco Yunnan Industrial Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/02Pretreatment of the raw materials by chemical or physical means
    • D21B1/021Pretreatment of the raw materials by chemical or physical means by chemical means
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02Material of vegetable origin

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)

Abstract

The method of cigarette paper additive and its additive application obtained being manufactured with pueraria lobata fiber the present invention relates to a kind of, belongs to technical field of cigarettes.Obtained crude pueraria lobata fiber is recycled during this method crushes pueraria lobata particle, and through being overpressurized sour processing, it is added in the paper pulp of cigarette paper after mashing, carries out the cigarette papers such as the manufacture of cigarette paper, including manufacture cigarette paper, forming paper and tipping paper.Due to have passed through crushing and pressurization acid processing, fibre structure and ingredient all have changed a lot this kind of pueraria lobata fiber, and while cost-effective, new approach is also provided for the functionalization of cigarette paper.This method processing is simple, easy, and involved equipment is market existing device, and cheap.Obtained additive can effectively promote the organoleptic quality of cigarette after cigarette is added, and can effectively reduce the CO contents in flue gas under the premise of not influencing paper quality parameter.

Description

It is a kind of to manufacture the method for cigarette paper additive and its addition obtained with pueraria lobata fiber Agent and application
Technical field
The invention belongs to technical field of cigarettes, and in particular to a method of manufacturing cigarette paper additive with pueraria lobata fiber And its additive application obtained.
Background technology
With the fast development of Chinese tobacco industry, the formation of famous brand, the requirement of cigarettes reduce coke damage and tobacco product Class it is further perfect, the demand to high-quality essence spice for cigarette is also growing day by day.Generally according to the source of fragrance, can incite somebody to action It is divided into natural perfume material and synthetic perfume two major classes, and being currently known natural perfume material has more than 3000 kinds, and synthetic perfume is more up to 7000 Remaining kind, and new kind is also continuing to bring out.
Pueraria lobata system pulse family Pueraria lobota category perennial plant, is the often feeding vegetables of some provinces and regions of southern china, taste is sweet, cool and tasty, often It is used as Baoshang, also can be used as medicinal application.The flavones proposed in pueraria lobata can increase brain and coronal vascular flow amount, reduce blood Pipe resistance.Contained daizeol has spasmolysis, reduces the multiple functions such as blood glucose.Pueraria lobata itself also has promote the production of body fluid to quench thirst equal work( Effect.China possesses 14 Pueraria kinds, and germ plasm resource is most abundant, occupies first place in the world.
Requirement with consumer to cigarette quality is higher and higher, how to enhance flue gas comfort, improve cigarette quality at For the hot spot of each tobacco productive corporation research and development.Pueraria lobata granular materials addition cigarette filter is also just had been carried out before very early Commercial application, has also obtained extensive favorable comment.But what is applied in the past is the property using pueraria starch mostly, but for Pueraria lobata fiber is in cigarette field there is not yet related application.
Invention content
It manufacturing cigarette paper It is an object of the present invention to solve the deficiency of the existing technology and provide a kind of with pueraria lobata fiber and adds Add the method for agent and its additive application obtained.Since pueraria lobata fiber has very long applicating history in field of food, and obtain Extensive approval and favorable comment are arrived, therefore by pueraria lobata fiber applications in cigarette paper field, with reliable safety and extensively Acceptance.The present invention be by during manufacturing pueraria lobata particle and crushing obtained crude pueraria lobata fiber be recycled, And through being overpressurized sour processing, it is added in the paper pulp of cigarette paper after mashing, carries out the manufacture of cigarette paper, including manufacture cigarette The cigarette papers such as paper, forming paper and tipping paper can substitute a part of paper pulp, reduce the dosage of paper pulp, reduce papermaking cost.By Pressurization acid processing is have passed through in this fiber, fibre structure and ingredient all have changed a lot, most significantly staple fiber Content increases, and fibre structure becomes loose, be conducive to breathe freely, and the sense organ efficacy characteristics with original pueraria lobata, save at This while, also provides new approach for the functionalization of cigarette paper.
To achieve the above object, the technical solution adopted by the present invention is as follows:
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is pueraria lobata fiber volume 1- that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle 1.5 times of mass concentration is the aqueous acetic acid of 3-5%, and is boiled in the case where pressure is 1-2atm, and keeps boiling 1-5h, is obtained Mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 2- 3 times, the volume of addition water is be evaporated object product 1-1.5 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 73-75%, mashing Degree is 59-61 ° of SR to get to cigarette paper additive.
It is further preferred that in step(3)Fragrance is added in pulping process.
It is further preferred that the addition of fragrance is the 0.1%-0.5% of stock quality, but not limited to this, fragrance adds Entering amount can specifically be adjusted according to actual needs.
It is further preferred that the fragrance is menthol, agalloch eaglewood extract or Rosa Damascana, but not limited to this.
Present invention simultaneously provides it is a kind of it is above-mentioned with pueraria lobata fiber manufacture the method for cigarette paper additive made from cigarette use Paper additive.
The present invention also provides application of the above-mentioned cigarette paper additive in preparing cigarette paper.
Specifically application process is:Cigarette paper additive is added in cigarette paper paper pulp, after mixing, carries out conventional make Paper program, the quality of addition are the 5%-20% of cigarette paper pulp quality.
Product of the present invention optionally flavoring during preparation.In general, in manufacture cigarette paper and forming paper When, a certain amount of fragrance can be added as needed as flue gas flavoring;And it is typically chosen when manufacturing tipping paper Not flavoring.
The present invention can make coarse-fibred fibre bundle generate the effect of internal expansion in this way by the way of evaporated in vacuo, The fillibility for increasing fiber in follow-up paper-making process, is conducive to the cigarette paper for producing high-air-permeability.Although being added with microwave Heat can also achieve the effect that it is similar, but microwave heating be difficult to control, be easy to cause overheat, damaged fiber structure.
The process for the pueraria lobata fiber that pueraria lobata particle sieves after crushing is similar with the extracting method of common plant fiber, and one As be to be sieved under the sieve of 40-60 mesh after crushing pueraria lobata, it is after powder is detached with fibrous raw material, gained fiber is former Material is put into a concentration of 2% NaOH solution, and boils 100min under the conditions of 100 DEG C, waits for that solution temperature is down to 70~80 DEG C Later, a concentration of 5% H is added2O2Aqueous solution continues to heat 0.5h, and it is 70~80 DEG C to keep temperature, is filtered later, with distillation Water fully washs filter residue to neutrality, and fiber sample is obtained after dry.This method is the method for traditional extraction fiber.
Compared with prior art, the present invention advantage is:
The present invention using pueraria lobata fiber pressurize after acid processing, then is beaten, and is added in the paper pulp of cigarette paper, Carry out the cigarette papers such as the manufacture of cigarette paper, including manufacture cigarette paper, forming paper and tipping paper.This fiber is due to experienced Pressurization acid processing, fibre structure and ingredient all have changed a lot, and are reducing paper pulp dosage, while cost-effective, New approach is also provided for the functionalization of cigarette paper.
The method of the present invention processing is simple, easy, and involved equipment is market existing device, and cheap.Gained Paper pulp is added in the additive arrived, and cigarette paper, and the organoleptic quality for can effectively promote cigarette after cigarette manufacture is made, Sensory evaluation score can promote 1-1.5 points.
Product of the present invention can save the paper pulp usage amount of cigarette paper, and the production cost of cigarette paper can reduce about 10%. Under the premise of not influencing paper quality parameter, the burst size about 20% of CO in flue gas can be effectively reduced.
When pueraria starch is applied in cigarette filter, the effect for increasing flue gas moisture feeling is primarily served, to the retention shadow of flue gas It rings little.Pueraria lobata fiber is added in cigarette filter in the present invention, can not only play the role of centainly increasing flue gas moisture feeling(Although Effect is weaker than pueraria starch), but after the present invention is handled, which can preferably play the retention to harmful ingredients in flue gas Effect, while reducing tow dosage.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, but is not limited to lifted material and condition.This Field technology personnel will be understood that the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is real It applies and particular technique or condition person is not specified in example, according to technology or condition described in document in the art or according to product Specification carries out.Reagents or instruments used without specified manufacturer, being can be by buying the conventional products obtained.
Embodiment 1
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is 1 times of pueraria lobata fiber volume that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle Mass concentration be 3% aqueous acetic acid, and pressure be 1atm under boil, and keep boiling 1h, obtain mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 2 Secondary, the volume of addition water is be evaporated object product 1 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 74%, beating degree For 60 ° of SR, it is added menthol simultaneously in pulping process, the addition of menthol is the 0.5% of stock quality to get to cigarette Use Paper additive.
The cigarette paper additive of gained is added in cigarette paper paper pulp, and conventional Paper making procedure, cigarette are entered after mixing The quality being added with Paper additive is the 5% of paper pulp total amount.
Conventional specification is made in the cigarette paper roll that above-mentioned additive is added(24mm circumference, releasing content of coke tar 10mg)Cigarette. Under the premise of ensureing identical paper quality parameter, for the cigarette product relative to the cigarette that the additive is not added, flue gas is soft It is protruded with peppermint refrigerant sense, moisture feeling is reinforced, and sensory evaluation score increases by 1 point, and can effectively reduce CO burst sizes in flue gas 15%。
Embodiment 2
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is pueraria lobata fiber volume 1.5 that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle The aqueous acetic acid that mass concentration again is 5%, and boiled in the case where pressure is 2atm, and boiling 5h is kept, obtain mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 3 Secondary, the volume of addition water is be evaporated object product 1.5 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 73%, beating degree For 59 ° of SR, agalloch eaglewood extract is added simultaneously in pulping process, the addition of agalloch eaglewood extract is stock quality 0.1% to get to cigarette paper additive.
The present embodiment is not specifically limited the preparation method of agalloch eaglewood extract, is such as made using common extraction.
The cigarette paper additive of gained is added in cigarette paper paper pulp, and conventional Paper making procedure, cigarette are entered after mixing The quality being added with Paper additive is the 20% of paper pulp total amount.
Conventional specification is made in the cigarette paper roll that above-mentioned additive is added(24mm circumference, releasing content of coke tar 10mg)Cigarette. Under the premise of ensureing identical paper quality parameter, for the cigarette product relative to the cigarette that the additive is not added, flue gas is soft It is protruded with agalloch eaglewood fragrance, sweet tea sense and moisture feeling have reinforcement, and sensory evaluation score increases by 1.5 points, and can effectively reduce flue gas Middle CO burst sizes 20%.
Embodiment 3
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is pueraria lobata fiber volume 1.3 that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle The aqueous acetic acid that mass concentration again is 4%, and boiled in the case where pressure is 1.5atm, and boiling 3h is kept, obtain mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 3 Secondary, the volume of addition water is be evaporated object product 1.2 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 775%, beating degree It is 61 ° of SR to get to cigarette paper additive.
The cigarette paper additive of gained is added in cigarette paper paper pulp, and conventional Paper making procedure, cigarette are entered after mixing The quality being added with Paper additive is the 10% of paper pulp total amount.
Conventional specification is made in the cigarette paper roll that above-mentioned additive is added(24mm circumference, releasing content of coke tar 10mg)Cigarette. Under the premise of ensureing identical paper quality parameter, the cigarette product is relative to the cigarette that the additive is not added, flue gas profit Sense increased, and sensory evaluation score increases by 1 point, and can effectively reduce CO burst sizes 25% in flue gas.
Embodiment 4
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is pueraria lobata fiber volume 1.2 that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle The aqueous acetic acid that mass concentration again is 5%, and boiled in the case where pressure is 2atm, and boiling 5h is kept, obtain mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 3 Secondary, the volume of addition water is be evaporated object product 1.4 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 74%, beating degree It is 60 ° of SR to get to cigarette paper additive.
The cigarette paper additive of gained is added in cigarette paper paper pulp, and conventional Paper making procedure, cigarette are entered after mixing The quality being added with Paper additive is the 15% of paper pulp total amount.
Conventional specification is made in the cigarette paper roll that above-mentioned additive is added(24mm circumference, releasing content of coke tar 10mg)Cigarette. Under the premise of ensureing identical paper quality parameter, the cigarette product is relative to the cigarette in embodiment 3, flue gas mildness and association Tonality is declined slightly, but sweet tea sense and moisture feeling significantly increase.This illustrates that addition difference has an impact final flue gas organoleptic quality.
Embodiment 5
A method of cigarette paper additive being manufactured with pueraria lobata fiber, is included the following steps:
Step(1), it is pueraria lobata fiber volume 1.1 that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle The aqueous acetic acid that mass concentration again is 4%, and boiled in the case where pressure is 1.3atm, and boiling 2h is kept, obtain mixture;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 3 Secondary, the volume of addition water is be evaporated object product 1.2 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 74%, beating degree For 60 ° of SR, be added Rosa Damascana simultaneously in pulping process, the addition of Rosa Damascana be the 0.1% of stock quality to get to Cigarette paper additive.
The cigarette paper additive of gained is added in cigarette paper paper pulp, and conventional Paper making procedure, cigarette are entered after mixing The quality being added with Paper additive is the 12% of paper pulp total amount.
Conventional specification is made in the cigarette paper roll that above-mentioned additive is added(24mm circumference, releasing content of coke tar 10mg)Cigarette. Under the premise of ensureing identical paper quality parameter, for the cigarette product relative to the cigarette that the additive is not added, flue gas is soft With coordination, moisture feeling increased, and with the presence of apparent rose fragrance, sensory evaluation score increases by 1.5 points, and can be effective Reduce CO burst sizes 20% in flue gas.
Contrast test
Comparative example 1
Comparative example 1 and the method for the present invention difference lies in:The concentration of aqueous acetic acid not within the protection scope of the present invention, Remaining is all identical.
As a result it shows:
If aqueous acetic acid excessive concentration(More than 5%), fiber is more serious by acetic acid erosion, is easily broken off, staple fiber contains Measure it is excessive, be step(3)In blended increase difficulty;Furthermore, it is also possible to can lead to have part acetic acid molecule residual in the fibre, To after cigarette filter is made, influence the organoleptic quality of cigarette.If aqueous acetic acid concentration is too low(Less than 3%), fiber by Acetic acid corrosion function is too small, can not cause loose structure feature, short fibre content that can also become smaller therewith, cause it that filter tip is made Practical retention efficiency afterwards reduces.
Comparative example 2
Comparative example 2 and the method for the present invention difference lies in:The model that volume used in aqueous acetic acid is not protected in the present invention In enclosing, remaining is all identical.
As a result it shows:
The volume that the present invention limits aqueous acetic acid is to ensure that aqueous acetic acid can not have pending pueraria lobata fine Dimension, if very few can cause the fiber treatment effect for not submerging solution undesirable, crossing can at most cause to waste.
Comparative example 3
Comparative example 3 and the method for the present invention difference lies in:It is evaporated without multiple washing, remaining is all identical.
As a result it shows:
Evaporated in vacuo can make coarse-fibred fibre bundle generate the effect of internal expansion, increase in follow-up paper-making process fine The fillibility of dimension is conducive to the cigarette paper for producing high-air-permeability.If without this process, the porousness of fiber It is not high, can have an impact to the air permeability of paper after papermaking, and then influence the reducing effect of the burst size of CO in cigarette smoke.
Comparative example 4
Comparative example 4 and the method for the present invention difference lies in:Beating degree not within the protection scope of the present invention, remaining all phase Together.
As a result it shows:
Beating degree is small, and the paper medium-length fibre content of manufacture is more, and the mechanical strength enhancing of paper, uniformity is bad, breathes freely Spend it is relatively low, to the CO reducing effect unobvious in flue gas;Beating degree is excessive, and paper middle short fiber is excessive, and it is high thoroughly to be conducive to manufacture The paper of manner, but mechanical strength is weaker, is easy during following process by tearing.
Comparative example 5
Comparative example 5 and the method for the present invention difference lies in:When mashing, water content not within the protection scope of the present invention, It is remaining all identical.
As a result it shows:
Water content when mashing is primarily used to be conducive to mashing operation after making fibrous absorbent be swollen, and water content is too low, Fiber swelling effect can be made bad, to the serious wear of beater blade;Water content is excessively high, and can largely waste water, and increases Subsequent cost for wastewater treatment.
Comparative example 6
Comparative example 6 and the method for the present invention difference lies in:Pressure and boiling time not within the protection scope of the present invention, It is remaining all identical.
As a result it shows:
When pressure is too small or boiling time is too short, acid processing is not enough, and is caused in step(2)In expansion effect not It is good, the filling line of fiber is influenced, and finally influence the air permeability of cigarette paper.Pressure is excessive or boiling time is long, acid processing Intensity is excessive, and fiber can be caused excessively to be corroded, and mechanical strength weakens, and is easy during following process by tearing.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (7)

1. a kind of method manufacturing cigarette paper additive with pueraria lobata fiber, which is characterized in that include the following steps:
Step(1), it is 1-1.5 times of pueraria lobata fiber volume that volume, which is added, in the pueraria lobata fiber that sieves after being crushed to pueraria lobata particle Mass concentration be 3-5% aqueous acetic acid, and pressure be 1-2atm under boil, and keep boiling 1-5h, mixed Object;
Step(2), by step(1)Obtained mixture evaporated in vacuo, evaporated in vacuo again after washing with water later repeat 2-3 times, The volume of addition water is be evaporated object product 1-1.5 times cleaned every time, obtains solid content;
Step(3), to step(2)Water is added in obtained solid content to be beaten, control water content is 73-75%, and beating degree is 59-61 ° of SR is to get to cigarette paper additive.
2. the method according to claim 1 for manufacturing cigarette paper additive with pueraria lobata fiber, it is characterised in that:In step (3)Fragrance is added in pulping process.
3. the method according to claim 1 for manufacturing cigarette paper additive with pueraria lobata fiber, it is characterised in that:Fragrance Addition is the 0.1%-0.5% of stock quality.
4. the method according to claim 3 for manufacturing cigarette paper additive with pueraria lobata fiber, it is characterised in that:Described Fragrance is menthol, agalloch eaglewood extract or Rosa Damascana.
5. described in claim 1-4 any one with pueraria lobata fiber manufacture the method for cigarette paper additive made from cigarette use Paper additive.
6. application of the cigarette paper additive in preparing cigarette paper described in claim 5.
7. application of the cigarette paper additive according to claim 6 in preparing cigarette paper, which is characterized in that will roll up Cigarette is added to Paper additive in cigarette paper paper pulp, after mixing, carries out conventional Paper making procedure, the quality of addition is cigarette paper paper pulp The 5%-20% of quality.
CN201710458797.3A 2017-06-16 2017-06-16 It is a kind of with pueraria lobata fiber manufacture cigarette paper additive method and its additive obtained with application Active CN107034721B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4109663A (en) * 1974-10-17 1978-08-29 Takeda Chemical Industries, Ltd. Tobacco product containing a thermo-gelable β-1,3-glucan-type polysaccharide
CN101781801A (en) * 2010-01-29 2010-07-21 武汉科技学院 Method for preparing pueraria fibre from pueraria waste residue
CN103689801A (en) * 2013-12-03 2014-04-02 红云红河烟草(集团)有限责任公司 Kudzuvine root porous particles and application thereof to cigarettes
CN105559140A (en) * 2016-02-25 2016-05-11 云南中烟工业有限责任公司 Porous material made of Chinese herbal medicine extracted residues and application of porous material
CN106723284A (en) * 2017-01-04 2017-05-31 云南中烟工业有限责任公司 A kind of method and its application that cigarette paper additive is manufactured with fermenting tobacco leaf residue

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4109663A (en) * 1974-10-17 1978-08-29 Takeda Chemical Industries, Ltd. Tobacco product containing a thermo-gelable β-1,3-glucan-type polysaccharide
CN101781801A (en) * 2010-01-29 2010-07-21 武汉科技学院 Method for preparing pueraria fibre from pueraria waste residue
CN103689801A (en) * 2013-12-03 2014-04-02 红云红河烟草(集团)有限责任公司 Kudzuvine root porous particles and application thereof to cigarettes
CN105559140A (en) * 2016-02-25 2016-05-11 云南中烟工业有限责任公司 Porous material made of Chinese herbal medicine extracted residues and application of porous material
CN106723284A (en) * 2017-01-04 2017-05-31 云南中烟工业有限责任公司 A kind of method and its application that cigarette paper additive is manufactured with fermenting tobacco leaf residue

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