CN107033735A - Surface of magnesium aluminium alloy coloured nano paint and preparation method thereof - Google Patents
Surface of magnesium aluminium alloy coloured nano paint and preparation method thereof Download PDFInfo
- Publication number
- CN107033735A CN107033735A CN201710285852.3A CN201710285852A CN107033735A CN 107033735 A CN107033735 A CN 107033735A CN 201710285852 A CN201710285852 A CN 201710285852A CN 107033735 A CN107033735 A CN 107033735A
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- Prior art keywords
- epoxy resin
- parts
- aluminium alloy
- magnesium aluminium
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to a kind of coloured nano paint of surface of magnesium aluminium alloy, it includes 1009 epoxy resin, 1009 epoxy resin black slurries, stock white, yellow pulp, 1175 enclosed shape curing agent, 6900 anti-settling agents, 3000 mesh talcum powder, nano silicone micro mist, 3001 levelling agents, phosphate ester, cyclohexanone, hexone, its preparation method includes plus 1009 epoxy resin, 1009 epoxy resin black slurries, stock white, yellow pulp, 1175 enclosed shape curing agent and 6900 anti-settling agents, dispersion machine is opened to disperse, when rotating speed reaches 400r/min, add 3000 mesh talcum powder and nano silicone micro mist, again during 400r/min that rotating speed is near, add 3001 levelling agents, phosphate ester, cyclohexanone and hexone.The present invention improves the curing rate of existing coating, improves to the adhesive force of surface of magnesium aluminium alloy, water boiling resistance and wearability.
Description
Technical field
The present invention relates to a kind of coloured nano paint and preparation method thereof, and in particular to a kind of metal alloy surface is with coloured
Nano paint and preparation method thereof.
Background technology
Existing coating has adhesive force on magnesium alloy, but the magnesium alloy product for being sprayed with paint is put into 100 DEG C of boiling water
In boil 1 hour, take out place 4 hours after survey adhesive force, be not attached to substantially.Because magnesium, two kinds of metals of aluminium are all very active,
Magnesium alloy can be dissolved in water in 100 DEG C, paint film is not had adhesive force.
The content of the invention
Goal of the invention:The invention aims to overcome deficiency of the prior art, there is provided the existing coating of one kind improvement
Curing rate, improve and the surface of magnesium aluminium alloy of the adhesive force of surface of magnesium aluminium alloy, water boiling resistance and wearability received with coloured
Rice coating and preparation method thereof.
Technical scheme:In order to solve the above-mentioned technical problem, the coloured nano paint of surface of magnesium aluminium alloy of the present invention,
Count by weight, it includes following components,
(1)1009 25-32 parts of epoxy resin;
(2)1009 2-3.5 parts of epoxy resin black slurries;
(3)1009 40-50 parts of epoxy resin stock whites;
(4)1009 1-1.5 parts of epoxy resin yellow pulps;
(5)1175 5-7.2 parts of enclosed shape curing agent;
(6)6900 0.5 part of anti-settling agents;
(7)3000 5-8.6 parts of mesh talcum powder;
(8)7-8.5 parts of nano silicone micro mist;
(9)3001 0.5 part of levelling agents;
(10)2-2.2 parts of phosphate ester;
(11)5-7.5 parts of cyclohexanone;
(12)7-9.2 parts of hexone.
3001 levelling agent is propylene acid esters levelling agent.
1009 epoxy resin uses 1009 epoxy resin of shell.
The 1009 epoxy resin black slurry is exactly the black slurry ground with 1009 epoxy resin.
The 1009 epoxy resin stock white is exactly the stock white ground with 1009 epoxy resin.
The 1009 epoxy resin yellow pulp is exactly the yellow pulp ground with 1009 epoxy resin.
The 1175 enclosed shape curing agent uses the enclosed shape curing agent of numbering 1175 of Japanese Asahi Kasei Corporation.
6900 anti-settling agent use day Ben Jinshi company's numbering for 6900 anti-settling agent.
3001 levelling agent uses Changzhou Bu Weilun trade Co., Ltds to number the propylene acid esters levelling agent for 3001.
A kind of preparation method of the coloured nano paint of surface of magnesium aluminium alloy, it comprises the following steps,
(1)Successively by 1009 epoxy resin, 1009 epoxy resin black slurries, 1009 epoxy resin stock whites, 1009 epoxy resin
Yellow pulp, 1175 enclosed shape curing agent and 6900 anti-settling agents add dispersion machine, open dispersion machine and disperse;
(2)When dispersing speed reaches 400r/min, add 3000 mesh talcum powder and nano silicone micro mist, rotating speed carry to
1000r/min, stirs 30min;
(3)During 400r/min that dispersing speed is near, 3001 levelling agents, phosphate ester, cyclohexanone and methyl-isobutyl first are added
Ketone, dope viscosity is transferred to 90-100 seconds, 200 mesh filter screens are filtered and packaged.
This coating is diluted to after 18-20 seconds with diluent and is sprayed on the magnesium alloy by pre-treatment, 150-160 DEG C
Baking 20-25 minutes.
Beneficial effect:Compared with prior art, its remarkable advantage is the present invention:Asphalt mixtures modified by epoxy resin of the present invention from water-tolerant
Fat does film forming matter with closure curing agent, adds nano silicone micro mist and does inserts, makes compact in paint film, and hardness is high, wear-resisting, no
It is easily permeable, phosphate is added, phosphate makes surface of magnesium aluminium alloy phosphatization, surface is had one layer of fine and close phosphating coat, phosphating coat
Do not dissolved by 100 DEG C of boiling water, the present invention effectively improves existing coating by accurate component proportion and rigorous procedure of processing
Curing rate, substantially increase the adhesive force to surface of magnesium aluminium alloy, water boiling resistance and wearability.
Embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1:
The coloured nano paint of surface of magnesium aluminium alloy of the present invention, is counted by weight, and it includes following components,
(1)1009 28 parts of epoxy resin;
(2)1009 2.5 parts of epoxy resin black slurries;
(3)1009 43 parts of epoxy resin stock whites;
(4)1009 1.2 parts of epoxy resin yellow pulps;
(5)1175 6 parts of enclosed shape curing agent;
(6)6900 0.5 part of anti-settling agents;
(7)3000 6.5 parts of mesh talcum powder;
(8)7.5 parts of nano silicone micro mist;
(9)3001 0.5 part of levelling agents;
(10)2.1 parts of phosphate ester;
(11)5.5 parts of cyclohexanone;
(12)8 parts of hexone.
3001 levelling agent is propylene acid esters levelling agent.
A kind of preparation method of the coloured nano paint of surface of magnesium aluminium alloy, it comprises the following steps,
(1)Successively by 1009 epoxy resin, 1009 epoxy resin black slurries, 1009 epoxy resin stock whites, 1009 epoxy resin
Yellow pulp, 1175 enclosed shape curing agent and 6900 anti-settling agents add dispersion machine, open dispersion machine and disperse;
(2)When dispersing speed reaches 400r/min, add 3000 mesh talcum powder and nano silicone micro mist, rotating speed carry to
1000r/min, stirs 30min;
(3)During 400r/min that dispersing speed is near, 3001 levelling agents, phosphate ester, cyclohexanone and methyl-isobutyl first are added
Ketone, dope viscosity is transferred to 90-100 seconds, 200 mesh filter screens are filtered and packaged.
Embodiment 2:
The coloured nano paint of surface of magnesium aluminium alloy of the present invention, is counted by weight, and it includes following components,
(1)1009 30 parts of epoxy resin;
(2)1009 3 parts of epoxy resin black slurries;
(3)1009 48 parts of epoxy resin stock whites;
(4)1009 1.3 parts of epoxy resin yellow pulps;
(5)1175 7 parts of enclosed shape curing agent;
(6)6900 0.5 part of anti-settling agents;
(7)3000 7.6 parts of mesh talcum powder;
(8)8 parts of nano silicone micro mist;
(9)3001 0.5 part of levelling agents;
(10)2 parts of phosphate ester;
(11)7.2 parts of cyclohexanone;
(12)9 parts of hexone.
3001 levelling agent is propylene acid esters levelling agent.
A kind of preparation method of the coloured nano paint of surface of magnesium aluminium alloy, it comprises the following steps,
(1)Successively by 1009 epoxy resin, 1009 epoxy resin black slurries, 1009 epoxy resin stock whites, 1009 epoxy resin
Yellow pulp, 1175 enclosed shape curing agent and 6900 anti-settling agents add dispersion machine, open dispersion machine and disperse;
(2)When dispersing speed reaches 400r/min, add 3000 mesh talcum powder and nano silicone micro mist, rotating speed carry to
1000r/min, stirs 30min;
(3)During 400r/min that dispersing speed is near, 3001 levelling agents, phosphate ester, cyclohexanone and methyl-isobutyl first are added
Ketone, dope viscosity is transferred to 90-100 seconds, 200 mesh filter screens are filtered and packaged.
The present invention does film forming matter from the epoxy resin and closure curing agent of water-tolerant, adds nano silicone micro mist
Inserts is done, makes compact in paint film, hardness is high, wear-resisting, is difficult permeable, phosphate is added, phosphate makes surface of magnesium aluminium alloy phosphorus
Change, surface is had one layer of fine and close phosphating coat, phosphating coat is not dissolved by 100 DEG C of boiling water, and the present invention passes through accurate component proportion
With rigorous procedure of processing, the curing rate of existing coating is effectively improved, the attachment to surface of magnesium aluminium alloy is substantially increased
Power, water boiling resistance and wearability.
The invention provides a kind of thinking and method, the method and approach for implementing the technical scheme are a lot, above institute
State only is the preferred embodiment of the present invention, it is noted that for those skilled in the art, is not being departed from
On the premise of the principle of the invention, some improvements and modifications can also be made, these improvements and modifications also should be regarded as the guarantor of the present invention
Protecting each part being not known in scope, the present embodiment can use prior art to be realized.
Claims (3)
1. the coloured nano paint of surface of magnesium aluminium alloy, it is characterised in that:Count by weight, it includes following components,
(1)1009 25-32 parts of epoxy resin;
(2)1009 2-3.5 parts of epoxy resin black slurries;
(3)1009 40-50 parts of epoxy resin stock whites;
(4)1009 1-1.5 parts of epoxy resin yellow pulps;
(5)1175 5-7.2 parts of enclosed shape curing agent;
(6)6900 0.5 part of anti-settling agents;`
(7)3000 5-8.6 parts of mesh talcum powder;
(8)7-8.5 parts of nano silicone micro mist;
(9)3001 0.5 part of levelling agents;
(10)2-2.2 parts of phosphate ester;
(11)5-7.5 parts of cyclohexanone;
(12)7-9.2 parts of hexone.
2. the coloured nano paint of surface of magnesium aluminium alloy according to claim 1, it is characterised in that:3001 levelling agent
For propylene acid esters levelling agent.
3. a kind of preparation method of the coloured nano paint of surface of magnesium aluminium alloy according to claim 1, it is characterised in that:
It comprises the following steps,
(1)Successively by 1009 epoxy resin, 1009 epoxy resin black slurries, 1009 epoxy resin stock whites, 1009 epoxy resin
Yellow pulp, 1175 enclosed shape curing agent and 6900 anti-settling agents add dispersion machine, open dispersion machine and disperse;
(2)When dispersing speed reaches 400r/min, add 3000 mesh talcum powder and nano silicone micro mist, rotating speed carry to
1000r/min, stirs 30min;
(3)During 400r/min that dispersing speed is near, 3001 levelling agents, phosphate ester, cyclohexanone and methyl-isobutyl first are added
Ketone, dope viscosity is transferred to 90-100 seconds, 200 mesh filter screens are filtered and packaged.
Priority Applications (1)
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CN201710285852.3A CN107033735A (en) | 2017-04-27 | 2017-04-27 | Surface of magnesium aluminium alloy coloured nano paint and preparation method thereof |
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CN201710285852.3A CN107033735A (en) | 2017-04-27 | 2017-04-27 | Surface of magnesium aluminium alloy coloured nano paint and preparation method thereof |
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CN107033735A true CN107033735A (en) | 2017-08-11 |
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CN201710285852.3A Pending CN107033735A (en) | 2017-04-27 | 2017-04-27 | Surface of magnesium aluminium alloy coloured nano paint and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115200420A (en) * | 2022-07-22 | 2022-10-18 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-repelling bomb and preparation method thereof |
CN116082916A (en) * | 2022-12-20 | 2023-05-09 | 广州三孚新材料科技股份有限公司 | Efficient anti-corrosion hole sealing liquid for magnesium alloy surface and application thereof |
Citations (4)
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CN102358797A (en) * | 2011-08-13 | 2012-02-22 | 江苏荣昌化工有限公司 | Water-proof and anti-corrosion resin compound |
CN102372992A (en) * | 2010-08-18 | 2012-03-14 | 马敏 | Anticorrosive coating and preparation method thereof |
CN105017819A (en) * | 2014-10-30 | 2015-11-04 | 合肥蓝天家具制造有限责任公司 | Rapid curing furniture fireproof paint |
CN106243929A (en) * | 2016-10-09 | 2016-12-21 | 广州福田新狮涂料有限公司 | One exempts from anti-corrosion primer and preparation method thereof of polishing |
-
2017
- 2017-04-27 CN CN201710285852.3A patent/CN107033735A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102372992A (en) * | 2010-08-18 | 2012-03-14 | 马敏 | Anticorrosive coating and preparation method thereof |
CN102358797A (en) * | 2011-08-13 | 2012-02-22 | 江苏荣昌化工有限公司 | Water-proof and anti-corrosion resin compound |
CN105017819A (en) * | 2014-10-30 | 2015-11-04 | 合肥蓝天家具制造有限责任公司 | Rapid curing furniture fireproof paint |
CN106243929A (en) * | 2016-10-09 | 2016-12-21 | 广州福田新狮涂料有限公司 | One exempts from anti-corrosion primer and preparation method thereof of polishing |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115200420A (en) * | 2022-07-22 | 2022-10-18 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-repelling bomb and preparation method thereof |
CN115200420B (en) * | 2022-07-22 | 2023-09-01 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-expelling bomb and preparation method thereof |
CN116082916A (en) * | 2022-12-20 | 2023-05-09 | 广州三孚新材料科技股份有限公司 | Efficient anti-corrosion hole sealing liquid for magnesium alloy surface and application thereof |
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Application publication date: 20170811 |