CN107033659A - A kind of preparation method of floatation waste paper composite deinking agent - Google Patents
A kind of preparation method of floatation waste paper composite deinking agent Download PDFInfo
- Publication number
- CN107033659A CN107033659A CN201710202781.6A CN201710202781A CN107033659A CN 107033659 A CN107033659 A CN 107033659A CN 201710202781 A CN201710202781 A CN 201710202781A CN 107033659 A CN107033659 A CN 107033659A
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- CN
- China
- Prior art keywords
- weight
- deinking agent
- parts
- waste paper
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
- C08F251/02—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
- D21C5/027—Chemicals therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Toxicology (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of preparation method of floatation waste paper composite deinking agent, kaolin and nano micro crystal cellulose are first subjected to solution blending, then by monomer of butyl methacrylate, benzoyl peroxide be initiator, N, N methylene-bisacrylamides are that crosslinking agent carries out graft crosslinking kaolin/microcrystalline cellulose/polybutyl methacrylate organic-inorganic hybrid material is made, with composite deinking agent is made after the composition such as surfactant compounding.The waste paper composite deinking agent that preparation method of the present invention is obtained has excellent absorptive collection ability to granule foreigns such as ink, improves the flotation collecting effect of deinking agent, is adapted to floatation deinking technique.
Description
Technical field
The present invention relates to deinking technical field, more particularly to a kind of preparation side of floatation waste paper composite deinking agent
Method.
Background technology
Deinking is exactly by printing-ink and fiber separation, so as to return by comprehensive functions such as chemicals, mechanical forces
The technique of collection slurry.Floatation is the main method of current deinking slurrying, and its principle is the different surfaces by variable grain
The purpose of separation can be reached.Wherein, the selection of deinking agent is to influence an important step of floatation and ink removing effect.Deinking agent
Effect is by ink emulsification, departs from fiber, and prevents it to be attached to again on fiber, conventional deinking agent be surfactant and
The compound of inorganic medicine.But the powder collection ability of surfactant is generally poor, accordingly, it would be desirable to explore significantly more efficient
Deinking agent.
Document《Improvement of the kaolinite soil matrix chemicals to deinking》Utilize modified kaolin and surfactant composition one
New deinking agent is planted, the flotation collecting effect of deinking agent is improved, is more efficiently separated and removes ink, dust in waste paper
With gluing composition granule.However, single kaolin is limited in one's ability to the absorptive collection of the granule foreigns such as ink as adsorbent, need
Further exploitation.
The content of the invention
The object of the invention be exactly in order to make up the defect of prior art there is provided it is a kind of it is high to ink adsorptivity, while flotation
The preparation method of the excellent floatation waste paper composite deinking agent of collecting effect.
The present invention is achieved by the following technical solutions:
A kind of preparation method of floatation waste paper composite deinking agent, comprises the following steps:
(1)10-15 parts by weight kaolin clay and 0.5-1 weight account polyethylenes alcohol are first added into 40-60 parts by weight nano microcrystalline fibers
1-2h is stirred in 85-95 DEG C in the plain aqueous solution, 3-5 weight parts of methacrylic acid butyl ester, 0.03- are then added under nitrogen protection
0.05 parts by weight benzoyl peroxide and 0.03-0.05 parts by weight N,N methylene bis acrylamide are in 70-80 DEG C of stirring reaction
2-4h, with being dried after absolute ethyl alcohol and distillation water washing, grinding uniform, obtains composite granule;
(2)By 10-15 parts by weight steps(1)Obtained composite granule and 10-20 parts by weight sodium sulfate of polyethenoxy ether of fatty alcohol,
5-10 parts by weight sodium lignin sulfonate, 1-2 parts by weight Tween-80s are added in blender stir in order, obtain
Floatation waste paper composite deinking agent.
The solid content of the nano micro crystal cellulose aqueous solution is 10-20%.
The molecular weight of the polyvinyl alcohol is 800-10000.
The kaolin is 300-400 mesh.
The step(2)Stirring condition be:30-35 DEG C of whipping temp, speed of agitator 400-600r/min.
It is an advantage of the invention that:
Kaolin and nano micro crystal cellulose are first carried out solution blending by the present invention, then by monomer of butyl methacrylate,
Benzoyl peroxide is that initiator, N,N methylene bis acrylamide are that crosslinking agent carries out graft crosslinking kaolin/crystallite is made
Compound deinking is made after cellulose/polybutyl methacrylate hybrid inorganic-organic materials, with the composition such as surfactant compounding
Agent.The present invention first compounds kaolin and microcrystalline cellulose as adsorbing base, is then grafted with butyl methacrylate
It is cross-linking modified to assign high absorption property of the material to low pole organic matter, so as to improve the adsorption capacity to ink;And formed
Composite there is porous network structure, be conducive to the collection of the granule foreigns such as ink, what preparation method of the present invention was obtained answers
Closing ink absorbent has excellent absorptive collection ability to granule foreigns such as ink, improves the flotation collecting effect of deinking agent, fits
Close floatation deinking technique.
Embodiment
A kind of preparation method of floatation waste paper composite deinking agent, comprises the following steps:
(1)First 10kg kaolin and 0.5kg polyvinyl alcohol are added in the 40kg nano micro crystal cellulose aqueous solution in 85 DEG C of stirrings
1h, then adds 3kg butyl methacrylates, 0.03kg benzoyl peroxides and 0.03kgN, N- methylene under nitrogen protection
Bisacrylamide, with being dried after absolute ethyl alcohol and distillation water washing, grinding uniform, obtains composite powder in 70 DEG C of stirring reaction 2h
Body;
(2)By 10kg steps(1)Obtained composite granule and 10kg sodium sulfate of polyethenoxy ether of fatty alcohol, 5kg lignin sulfonic acids
Sodium, 1kg Tween-80s are added in blender stir in order, obtain floatation waste paper composite deinking agent.
The solid content of the nano micro crystal cellulose aqueous solution is 10%.
The molecular weight of the polyvinyl alcohol is 800.
The kaolin is 300 mesh.
The step(2)Stirring condition be:30 DEG C of whipping temp, speed of agitator 400r/min.
Claims (5)
1. a kind of preparation method of floatation waste paper composite deinking agent, it is characterised in that comprise the following steps:
(1)10-15 parts by weight kaolin clay and 0.5-1 weight account polyethylenes alcohol are first added into 40-60 parts by weight nano microcrystalline fibers
1-2h is stirred in 85-95 DEG C in the plain aqueous solution, 3-5 weight parts of methacrylic acid butyl ester, 0.03- are then added under nitrogen protection
0.05 parts by weight benzoyl peroxide and 0.03-0.05 parts by weight N,N methylene bis acrylamide are in 70-80 DEG C of stirring reaction
2-4h, with being dried after absolute ethyl alcohol and distillation water washing, grinding uniform, obtains composite granule;
(2)By 10-15 parts by weight steps(1)Obtained composite granule and 10-20 parts by weight sodium sulfate of polyethenoxy ether of fatty alcohol,
5-10 parts by weight sodium lignin sulfonate, 1-2 parts by weight Tween-80s are added in blender stir in order, obtain
Floatation waste paper composite deinking agent.
2. the preparation method of a kind of floatation waste paper composite deinking agent according to claim 1, it is characterised in that described to receive
The solid content of the rice microcrystalline cellulose aqueous solution is 10-20%.
3. the preparation method of a kind of floatation waste paper composite deinking agent according to claim 1, it is characterised in that described poly-
The molecular weight of vinyl alcohol is 800-10000.
4. a kind of preparation method of floatation waste paper composite deinking agent according to claim 1, it is characterised in that the height
Ridge soil is 300-400 mesh.
5. a kind of preparation method of floatation waste paper composite deinking agent according to claim 1, it is characterised in that the step
Suddenly(2)Stirring condition be:30-35 DEG C of whipping temp, speed of agitator 400-600r/min.
Priority Applications (1)
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CN201710202781.6A CN107033659A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of floatation waste paper composite deinking agent |
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CN201710202781.6A CN107033659A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of floatation waste paper composite deinking agent |
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CN201710202781.6A Pending CN107033659A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of floatation waste paper composite deinking agent |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108774425A (en) * | 2018-05-15 | 2018-11-09 | 潘荣强 | A kind of preparation method of detergent for ink |
CN115197372A (en) * | 2022-08-10 | 2022-10-18 | 威海银河生物技术有限公司 | Preparation method and application of cellulose-based material for absorbing oily wastewater |
-
2017
- 2017-03-30 CN CN201710202781.6A patent/CN107033659A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108774425A (en) * | 2018-05-15 | 2018-11-09 | 潘荣强 | A kind of preparation method of detergent for ink |
CN115197372A (en) * | 2022-08-10 | 2022-10-18 | 威海银河生物技术有限公司 | Preparation method and application of cellulose-based material for absorbing oily wastewater |
CN115197372B (en) * | 2022-08-10 | 2023-09-22 | 威海银河生物技术有限公司 | Preparation method and application of cellulose-based material for absorbing oily wastewater |
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Application publication date: 20170811 |
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